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By Elizabeth A. Johnson

The vaporization thermodynamics of the aluminum-silicon carbides Al4SiC4 and Al8SiC7 were studied by the Bureau of Mines over the temperature range of approximately 1,500 to 1,700 K. Vapor pressures were measured by a Knudsen effusion-mass spectrometry technique in which powdered samples were effused from graphite crucibles through small orifices. For each compound, a total of six orifice diameters was tested to verify equilibrium within the cell. Aluminum, mass number 27, was the only vapor species detected over the range 4 to 200 amu. Experimental results are based on the following equations for incongruent decomposition: A14SiC4(cr) - 4A1(g) + SiC(a,hex) + 3C(gr); Al8SiC7(cr) - 8A1(g) + SiC(a,hex) + 6C(gr). The observed vapor pressure-temperature relationships determined with a cell orifice area of 2.0 x 10-3 cm2 for Al4SiC4 and 1.81 x 10-3 cm2 for A18SiC7 are the following: Log P - (-18,682/T) + 12.476, for Al4SiC4 (1,550 to 1,643 K) and Log P = (-19,308/T) + 12.421, for Al8SiC7 (1,526 to 1,784 K), with P in pascals and T in kelvins. Third-law analysis of the data provided the following heats of formation: A14SiC4 ?H at 298.15 K - -50.0 kcal/mol and A18SiC7 ?H at 298.15 K - -92.1 kcal/mol.

Jan 1, 2011

By Lichao Ding, Jingbiao Fan, Yunnen Chen

"With the development of industrial production, more and more wastewater containing high concentration ammonia nitrogen was discharge into the environmemt, which caused serious harm to the environmemt. Treating the wastewater has great significance to protect water resources. Using air-stripping combined with oxidation to uptake high concentration of ammonia nitrogen wastewater. The influence of operating parameters was investigated. Experimental results revealed that pH of solution, aeration time and aeration strength showed heavy influence on ammonia nitrogen removal. Air-stripping combined with oxidation can be considered as an alternative approach for the removal of high concentration of ammonia nitrogen from practical metallurgical wastewater. When pH was 11, aeration time 20 min, aeration strength 1040 Lh-1, and oxidation with 10 % NaClO solution 10 min, the initial ammonia nitrogen 2130 mgr1 could reduce to 12 mgr1. Other items could also be removed to meet the ""Integrated wastewater discharge standard (GB8978-88)"".1. IntroductionThe rapid development of human activities has caused a worldwide increase of nitrogen in rivers, lakes and coastal waters. It leads to considerable eutrophication and an increase in the frequency of toxic algae blooms [1,2]. The concentrations of nitrogen in the water of China are pervading high [3]. The discharge of wastewater containing high concentration of ammonia nitrogen is one of the most important factors. Great efforts have been devoted to the removal of ammonia nitrogen from wastewater. Traditional methods include biological denitrication [ 4 ], chemical precipitation with magnesium ammonium phosphate [5], electrochemical conversion [6], air-stripping [7] and so on. Biological denitrication is the most common process in the treatment of ammonia nitrogen wastewater. But the process is only suitable for the removal of relatively low ammonia concentration due to the requirement of appropriate C/N ratio [8]. Chemical precipitation needs additional reagents, which may introduce new pollutants to water body. Electrochemical method often uses expensive metal or metal oxide as electrodes, and also consumes large quantity of energy [6].Although air-stripping makes use of stripping tower and consumes energy, it is very suitable for the removal of relatively high ammonia concentration. Different air-stripping conditions would appear different removal efficiency. And only air-stripping the effluent can not be attained the ""Integrated wastewater discharge standard (GB8978-88)"". In this study, we use air-stripping and oxidation to removal high concentration of ammonia nitrogen from simulated and real ammonia nitrogen wastewater."

Jan 1, 2011

By Catalin Florin Petre, Elahe Ghasemian Langeroudi, Abdelaaziz Azizi, Éric Proulx, Caroline Olsen, Paul Blatter, Faïçal Larachi, Claude Gagnon

"The recovery of gold from ores is often accompanied by the release of other species in the leach solution. This state of affairs leads to depleted free cyanide levels in the slurry. Therefore, separation and quantification of these cyanicides and free cyanide at different stages of the cyanidation process as well as in waste solutions is crucial to provide mitigation tools by preventing leaching of deleterious metals for environmental considerations.COREM and the research group of Prof. Larachi have been working together on the control of gold passivation and cyanicides during cyanidation for several years. Previously, a first capillary electrophoresis (CE) protocol for the speciation of sulfur and cyanicides (SCN-, Cu, Fe) during cyanidation of gold complex sulfide ores was developed and validated for assessing industrial process water.The separation of zinc cyanide complexes used to be confronted with a number of difficulties due to the weak and/or undetectable cyanocomplexes in formally available CE protocols. Moreover, according to our knowledge, no direct CE protocol exists to separate free cyanide. Therefore, a new study aimed at developing a second CE protocol for the detection and quantification of cyanide complexes of zinc and nickel as well as of free cyanide in the cyanidation process water.To achieve this goal, six common carrier electrolytes such as pyridine, trimellitic acid, 4-methylbenzylamine, sodium chromate, phthalic acid and tris base were studied, using an indirect UV detection method. The best results were obtained using sodium chromate for which all ions were successfully separated and quantified. In addition, the effect of electric field strength, injection volume, electro-osmotic flow (EOF) modifier and background electrolyte (BGE) concentration were examined, while peak height, peak area and noise were considered for optimization.As a result, the new protocol is expected to complete the initial CE protocol by detecting cyanide complexes of zinc and nickel as well as free cyanide. Moreover, analytical determination of free cyanide in the presence of weak cyanide complexes achieved by the new protocol was also compared to conventional titration using silver nitrate solution. This new CE protocol will contribute to applied research and help plants to better understand and eventually control the behaviour of cyanidation circuits."

Jan 1, 2011

By G. Van Weert

In the spring of 2010 double refractory ores from historical stockpiles were processed through Barrick's Goldstrike pressure oxidation facility, thereby providing preg robbing feeds for a variety of metallurgical testwork. This paper describes the effects of amount, type, place and time of addition of activated carbons on CIL gold recovery and shows that native carbon in plant PDX'ed discharge solids can still preg rob gold loaded activated carbon.

Jan 1, 2011

By P. S. G. Leon

One of the most difficult areas in concession contracts in resource-rich developing countries is achieving an equitable balance between the interests of investors, host states and, increasingly, mine and near mine communities. While some countries in the Andean region have resorted to outright or creeping expropriation of natural resource contracts under the guise of resource nationalism, others such as the Democratic Republic of the Congo (DRC), have claimed international best practice in the review (and setting aside) of important concession contracts.

Jan 1, 2011

By Willem Le Roux

1.1 Section 47(1) of the Mine Health and Safety Act, 29 of 1996 (?the MHSA?) establishes a Mine Health and Safety Inspectorate which is administered by the Chief Inspector of Mines. The Mine Health and Safety Inspectorate is part of the Department of Mineral Resources. The Chief Inspector is appointed by the Minister of Mineral Resources (see section 48(1) of the MHSA). 1.2 The Chief Inspector must, amongst other things, ensure that the provisions of the MHSA are complied with and enforced, and that all the duties imposed upon the Chief Inspector and the other Inspectors of Mines in terms of the MHSA and any other law are performed. The Chief Inspector of Mines must appoint Principal Inspectors of Mines and Inspectors of Mines to assist him/her to discharge his/her duties (see section 49(1)(a) and (c) of the MHSA).

Jan 1, 2011

By K. R. Long

Until it was defunded in 1995, the U.S. Bureau of Mines maintained a Cost Estimating System (CES) for prefeasibility-type economic evaluations of mineral deposits and estimating costs at producing and non-producing mines. This system had a significant role in mineral resource assessments to estimate costs of developing and operating known mineral deposits and predicted undiscovered deposits. For legal reasons, the U.S. Geological Survey cannot update and maintain CES. Instead, statistical tools are under development to estimate mining costs from basic properties of mineral deposits such as tonnage, grade, mineralogy, depth, strip ratio, distance from infrastructure, rock strength, and work index. The first step was to re-estimate ?Taylor?s Rule? which relates operating rate to available ore tonnage. The second step was to estimate statistical models of capital and operating costs for open pit porphyry copper mines with flotation concentrators. For a sample of 27 proposed porphyry copper projects, capital costs can be estimated from three variables: mineral processing rate, strip ratio, and distance from nearest railroad before mine construction began. Of all the variables tested, operating costs were found to be significantly correlated only with strip ratio.

Jan 1, 2011

By C. Pattenden

The viability, self-reliance and resilience of small communities are perennial challenges in regional Australia. Recent developments in Australian mining regions seek to govern the minerals industry in a more holistic way that contributes to sustainable futures for affected communities in different contexts. In some areas of the State of Queensland land use conflicts and the cumulative impacts of multiple projects and activities across time and space have come to the fore. In more isolated regions of Western Australia the dominant issues relate to overstretching people, infrastructure and services in predominantly mining towns. In both cases, there is an ambition for regional towns with a strong extractive industry presence to transition into desirable, liveable and affordable cities with a diversified economy. The paper analyses two strategies - the Pilbara Plan in Western Australia, and the Sustainable Resource Communities Policy in Queensland - to identify how these governance instruments are contributing to sustainable development.

Jan 1, 2011

By A. L. Coello Velázquez

The subject of this paper is particle population balance models (PBM) that describe mineral impact crushing behavior; it is mainly concerned with the selection and fragmentation distribution function due to their importance in this context. The data obtained by Datta (1999) by applying impact pendulum testing to single limestone particles, used by Austin (2002, 2004a and 2004b) to obtain the principal parity of fragmentation functions, were processed in order to compare them with the results of other authors, such as Nikolov (2002 and 2004) and Vogel and Peukert (2003 and 2005) so as to increase knowledge of impact crushing. From this data it has been possible to obtain the performance models of the principal parameters of fragmentation function, thereby reducing the number of experiments necessary to model the impact crushing process. The authors also propose a simplification of the selection function model posited by Austin (2002).

Jan 1, 2011

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By Yuanyuan Zhang, Patrick J. Masset

"The reduction of FexO in slag is one of the fundamental reactions in iron and steelmaking technology, including the blast furnace process (BF). Experiments on the reduction reaction of iron oxide using CaO-SiO2-Al2O3-FexO-C mixtures were carried out using thermogravimetric analysis (TGA) under reducing conditions at temperatures up to 1100°C. The composition of the primary slag was chosen so that the FexO concentration varied between 0 and 75 wt % and the CaO/SiO2 ratio being kept constant to 0.90. From the TGA curves recorded isothermally at different temperatures the kinetic parameters of the iron oxide reduction were determined.IntroductionIn blast furnace the iron ores and coke are charged in layers from the top. The reduction of iron oxide by coke is one of the fundamental reactions in the blast furnace process. Although a great amount of work has been done on the topic of reduction of composites [1, 2, 3], gasification of carbon [4, 5] and reduction of iron oxides by CO [4, 5, 6], the mechanism of reduction in iron oxide - carbon powder mixtures is not fully understood. Fruehan [1] and Rao [2] studied the reaction rate of the reduction of iron oxide by different types of carbon and concluded that the reaction mechanism is controlled by the oxidation of carbon at temperatures up to 1200°C. Rao [2] studied the reaction of hematite with graphite as carbon source up to 1080°C. An activation energy close to 300 kJ/mol was calculated within the temperature range of 950°C to 1087°C. In his study, Fruehan [1] determined the rate of reduction of Fe2O3 and FeO by coal, coke and coconut charcoal as carbon sources within the 900°C to 1200°C temperature range. He found that the reduction of Fe2O3 by carbon occurs in two stages and that the reduction of Fe2O3 to FeO is faster than that of FeO to Fe. This is due to the fact that the CO2/CO equilibrium ratio is higher, and hence, the rate of oxidation of carbon is faster. Fortini and Fruehan [3] have studied the reduction reaction of wustite by graphite and wood charcoal. They found that the wustite reduction can have a significant effect on the overall rate of reduction in composites at high temperatures or in the presence of a large excess of carbon. The calculated activation energy of the reduction reaction by wood charcoal was close to 368 kJ/mol, while the activation energy of the reduction reaction by graphite was 444 kJ/mol."

Jan 1, 2011

By P. J. Sylvester, S. J. Piercey, S. Maloney, S. M. Brueckner, L. Pilgrim, D. Hyde, G. Ogilvie

The 1806 zone is part of a Au-rich volcanogenic massive sulfide deposit at the Rambler Camp on the Baie \/erte Peninsula, northwestern Newfoundland, and is characterized by high Au grades (3.97 g/t), relatively low Cu and Zn grades (0.60 wt% Cu, 1.17 wt% Zn), and moderate Ag grades (27.83 g/t) at ca. 0.37 Mt ore. Gold and Ag occur as electrum and different Ag varieties including Ag-Hg ± Au alloys, miargyrite, and pyrargyrite that occur often in close proximity to electrum. Additionally, Ag-, As-, Sb-, and Sn-bearing sulfosalts are frequently observed and usually close to electrum. These textural relations strongly favor a syngenetic/magmatic origin for the 1806 zone, despite having a metamorphic overprint.

Jan 1, 2011

By Mark H. Balfe

Over the last decade, Fenway Park has undergone annual improvements to modernize the facility for players and fans. These renovations include the Monster Seats, the Right Field Roof expansion, a new pavilion behind home plate, expansion of the Red Sox clubhouse, additional roof seating, and concourse improvements. Retrofitting the historic ballpark to bring it up to current standards required installation of foundations to support the new structural loads for each of the alteration projects. This required evaluation of existing conditions, and in many cases augmentation of the foundations at existing columns to accommodate the structural changes to the park. New foundations, generally consisting of drilled-in micropiles, were installed in numerous configurations and conditions. Since 2003, a total of 215 drilled-in micropiles have been installed to augment various columns around the park. The micropiles range in capacity between 40 and 70 tons and are installed through Fill and Organic Soils and embedded into the dense Glaciofluvial Sand and Gravel layer. Issues and learning related to the foundation augmentation include schedule constraints (work is typically conducted during the off-season and schedule is very aggressive), encountering old/abandoned utilities or foundations, ventilation of equipment, and management of spoils during micropile installation.

Jan 1, 2011

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

By A. Mboma

Keywords: Furnace, decommissioning, care and maintenance, re-start, funding, nickel Bindura Nickel Corporation (BNC) operates two nickel mines, and treats concentrates from these mines as well as toll concentrates from the region around its Bindura Smelter and Refinery (BSR) complex. At the smelter, concentrates of at least 5% nickel content are blended and dried to 4% moisture in a coal-fired rotary kiln. Matte smelting of concentrate is carried out in a six-in-line electric arc furnace, where the furnace slag is granulated and discarded. Furnace matte is transferred via ladles into Peirce-Smith converters, where, after granulation, a leach alloy containing 68%Ni, 20%Cu, and 6%S is produced. Converter slag is recycled via the matte-smelting furnace. The onset of the global economic recession towards the end of 2008 resulted in a collapse of metal prices, worsening the local situation that was already marred by unfavourable macro-economic conditions in Zimbabwe. As a result, BNC mines were put on care and maintenance in November 2008, followed by Bindura Smelter and Refinery in February and March 2009 respectively. The business environment has since changed, and BNC is getting ready to re-start the plant. This paper describes the decommissioning of the Bindura furnace, asset preservation during the care and maintenance programme in the past two years, and preparation for starting up of the Bindura smelter in the near future.

Jan 1, 2011

By D. R. Wilburn

This summary of international mineral exploration activities for the year 2010 draws upon available information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry and presents analyses of exploration activities performed by the mineral industry. Three sources of information are reported and analyzed in this annual review of international exploration for the year 2010: 1) budgetary statistics expressed in U.S. nominal dollars provided by Metals Economics Group (MEG) of Halifax, Nova Scotia; 2) regional and site-specific exploration activities that took place in 2010, as compiled by the USGS, and 3) regional events including economic, social and political conditions that affected exploration activities. These were derived from published sources and unpublished discussions with USGS and industry specialists.

Jan 1, 2011

By R. J. Hundermark

Keywords: Anglo American, Anglo Platinum Ltd, Waterval, Mortimer, Polokwane, ACP, pyrometallurgy, platinum, PGMs Anglo Platinum Ltd is the largest primary platinum producer in the world and operates three smelters in South Africa: Waterval, Mortimer and Polokwane. The operational details of the smelters are covered in previous reviews, thus only unit operations that have been upgraded are discussed. The most significant of the upgrades include the installation of a second ACP converter at Waterval Smelter in 2006 and the anticipated upgrade of Mortimer Smelter to 38MW in 2011. Several advances have been made in the smelting operations to improve the furnace stability and longevity. Control of the chromium input to each of the smelters has substantially allowed continued operations at levels below the spinel saturation point in slag, which results in lowered matte and slag temperatures. Mogalakwena concentrate, arising from the Platreef ore, is used to dilute high chromium-containing concentrates. In addition, furnace controls have improved in terms of crucible temperature and condition monitoring, improved feeding control, management of alarms and trips and having the quality of instrumentation and operational rigour required to support this. Advances have been made on the ACP converter in terms of good converter matte quality, and increased intensity and efficiency of operation. Combined with improvements to both the conventional and tower sulfuric acid plants, the emissions from Waterval Smelter have been reduced substantially since the introduction of the ACP. This is in spite of increasing metal throughput. The Anglo Platinum Ltd smelting operations have made significant progress since 2006 and further advances are envisaged to further improve on safety, reduce costs, increase efficiencies and throughput, while reducing emissions.

Jan 1, 2011

By E. P. Wiechrnann, C. M. Castro, G. A. Vidal, F. A. Muñoz

Different authors and publications indicate that Optibar Segmented Intercell Bars cause a remarkable distortion in the distribution of the current in a cell group. However, these results were based in inaccurate computer based models and do not represent the technology. During the last trimester of 2010, a 92 cells circuit from Barrick Zaldívar EW plant was implemented with Optibar Segmented Intercell Bars. The technology was incorporated progressively without disrupting the plant production. Depending on operational conditions, this led to a 2 to 4% current efficiency increase and 3 to 5% specific energy consumption reduction. By October 2011, 40,000 tons of copper will be produced with the technology.

Jan 1, 2011

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Jan 1, 2011

By K. J. R. Ford, Botz. M. M.

Porphyry copper ores are frequently a source of low-grade gold ore, but gold in these ores is often associated with significant levels of cyanide-soluble copper. Cyanide leaching of such ores increases flowsheet complexity and operating costs, and requires thorough planning to satisfy environmental requirements for tailings disposal and mine closure. This paper presents a review of the chemistry of cyanide leaching of gold-copper porphyry ores, carbon adsorption phenomena and means of removing base metals from leach solution. The primary economic drivers behind the processing of such complex ores are also analyzed.

Jan 1, 2011