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By C. Gosselin, G. M. Payenzo, C. Bazin, M. Desnoyers, G. Chevalier

"ArcelorMittal Mines Canada operates hydraulic classifiers to reduce the silica content of an iron oxide concentrate from 4.5% to less than 1.2% SiO2. Sampling campaigns were conducted to develop a preliminary model for the hydraulic classifier. Results show that iron oxide and quartz are respectively concentrated in the coarse and fine size fractions of the classifier feed. The mineral partition curves in the classifier and the size distribution of the minerals in the feed are used to simulate the classifier operation in order to identify the source of variability observed in the daily plant production data. Results indicate that most of the variation is probably caused by unsteady operating conditions of the classifiers.INTRODUCTION Hydraulic classifiers are a class of gravity separation devices (Wills, 1992) used to classify particles according to their size and specific gravity. Hydraulic classifiers also known as density separators (Hearn, 2002) combine hindered settling and upward flow of water to selectively entrain light particles to an overflow stream. Denser particles settle to an underflow stream. Hydraulic classifiers are used for various purposes ranging from cleaning of coal (Das, Sarkar, & Mehrotra, 2009), recovery of chromite from plant tailings (Kumar, Tripathy, & Rao, 2009) to upgrading iron oxide concentrate (Hearn, 2002). ArcelorMittal Mines Canada operates several hydraulic classifiers to upgrade an iron oxide concentrate by removing fine quartz and other light minerals from hematite that is the main iron oxide mineral. A project was initiated to analyze the operation of the classifier in an attempt to identify the source of the variability in the production results and to assess the potential of increasing iron recovery in the classifier. One possible disturbance for the classifier operation is the change in the classifier feed composition and size distribution, while the other considered disturbance is the operation of the classifier. The paper is divided into five sections. The first section summarizes the ore processing sequence for the production of iron oxide pellets to identify the position of the hydraulic classifier in the process. The second section describes the hydraulic classifier. The third section discusses the sampling campaigns conducted on the hydraulic classifier. The method used to process the data from sampling, the results of the data processing and simulation of the classifier are discussed in the remaining sections."

Jan 1, 2012

By S. Makni, A. Faucher, F. Robichaud, A. Bouajila

"Optimizing the ball charge in a grinding mill may be needed to maximise throughput or alternatively, to achieve proper product size in more challenging situations. Efforts to optimise the ball charge however are essentially empirical and suffer from the lack of appropriate, accessible and reliable tools. To address these limitations, a new model-based technology was developed that relies on 3D Discrete Element Method and population balance techniques: it takes on the form of a simulator that aims to significantly decrease the time required to optimise the size distribution and the grinding media load within a ball mill. This paper summarizes the research work related to the development of this simulator. The calibration of the different constituting sub-models will be highlighted. The successful use of the simulator to predict the effect of ball make-up on the grinding product size distribution in one plant is also reported.INTRODUCTION Adjusting the characteristics of the grinding media charge in grinding mills holds significant potential for optimisation of mill performance. For example, properly adjusting the ball size distribution in a ball mill can help achieving specified targets for final product size distribution and/or throughput capacity. However, several problems appear when reviewing the process and the available tools to optimise ball mill load: • The current empirical simulation tools are lacking with regard to the ability to predict the performance of grinding when changes to mill ball make-up are made; • Generally, these tools estimate the top size of the charge so it is difficult to predict the effect of mixed ball make-up; • As the quality of prediction of these tools is low, the operators try to optimise the ball charge by a ""trial and error"" method and proceeding with conservative changes. The influence of these changes on grinding performance is often less than the measurement precision and the improvements then remain imperceptible; • A change in ball make-up may require an average of about 6 months waiting period before reaching the stationary state of mill ball load. This exercise is due to be costly if applied change decreases the mill performance. In its effort towards the comminution process optimisation, COREM R&D portfolio had addressed the herein described opportunity during the last five years This paper describes the technology already developed for the optimisation of ball charge. It takes on the form of a simulator that aims to predict the evolution of the grinding media load, the grinding energy available in the ball mill and the final product size distribution. The simulator was first validated in a pilot scale ball mill and then applied in an industrial case."

Jan 1, 2012

By G. van Aswegen

The geometry and morphology of a set of low-angle fractures around a stope in a deep Witwatersrand gold mine are explained in terms of extension fractures forming under variable conditions of stress. Primary extension fractures (E1) form some distance ahead of an advancing stope along the s1, s2 plane. With stope advance, a couple of these fractures end up in a stress regime conducive to transpressional shear and a secondary set of extension fractures(E2) is formed at a high angle to the primary fractures. i.e. at a low angle to the stope. As the E2 fractures are undermined, they migrate into a stress regime of transtensional shear and a third set of extension fractures (E3) may develop between E2 fractures. These have sigmoidal shapes, being parallel to the E2 fractures at the E2 discontinuity where s3 is negative, and curved through the un-fractured rock between E2 fractures where s3 is positive at the instant of fracturing. The fractures all display fractographic features characteristic of dynamic extension failure with striae indicative of the direction of rupture propagation and the local, instantaneous orientation of s1.

Jan 1, 2012

By Ben Burger

This paper describes the design, the first three years of operation and optimization of a large, single stage SAG mill at Minera Yanacocha?s Gold Mill facility located in northern Peru. The Gold Mill was commissioned in March 2008 with a 32? x 32? EGL, 16.5MW single stage SAG mill, to process 5 million tonnes per annum high grade oxide Au/Ag ore. Operational control, feed size distribution, grinding media, mill liner, grate and pulp lifter optimisation have allowed the mill to operate 15-30% above design throughput rates, but with a product P80 coarser than design. As part of the optimization, full grinding circuit surveys were conducted. Historical operating data and survey data were analyzed and used to evaluate possible circuit changes and determine alternative operating strategies. A number of changes were implemented which allowed the SAG mill to operate similarly to a large ball mill and achieve finer mill product that was closer to design. This paper summarizes life to date data analysis and improvements made by Minera Yanacocha as well as the grinding circuit optimisation study conducted by Metso Process Technology and Innovation.

Jan 1, 2012

By S. Kelebek, B. Nanthakumar

ABSTRACT The sensitivity of sulphide minerals towards oxidation depends on the mineralogical makeup and nature of sulphide ores. This paper focuses on chalcopyrite behaviour in a nickel-copper sulphide- ore matrix that was aged in the mine-site stockpiles. Results of collectorless, collector-induced flotation and recovery by size are presented following a discussion of XPS analysis that was used to gain insight into oxidative alteration of chalcopyrite’s surface chemistry. Chalcopyrite maintains its high flotation activity despite exposure to weeks of oxidative conditions. It is concluded that chalcopyrite is quite tolerant to stockpile oxidation due to various factors related to alteration of its surface chemistry.

Jan 1, 2012

By Ruilin Yang

The following simple equations are frequently used within the blast vibration community;PPA f PPV v = 2p · , PPV f PPD d = 2p · ,a f PPV PPA 2p = , and v f PPD PPV 2p = where, PPA is the peak particle acceleration, PPV is the peak particle velocity, PPD is the peak particle displacement, and fa , fv , and fd are the frequency of the particle acceleration, particle velocity, and particle displacement vibration waveforms, respectively. Conceptually, the frequency should be selected to be the frequency of a simple sinusoidal wave that is used to approximate the blast vibration. In the literature, f is sometimes chosen as the dominant frequency (fdm) estimated from the Fast Fourier Transform (FFT) of the blast vibration wave, on other occasions, f is chosen to be the principal frequency (fpr) from the vibration cycle with the peak vibration amplitude.

Jan 1, 2012

By Gaifeng Xue, Lijun Lu, Honghui Fang, Jiannyang Hwang

"Steel slag has been stockpiled in many steel mills due to its poor performance in various construction related applications. Free lime in steel slag has been considered as a major barrier for its utilizations. Composite of steel slag and powders of granulated blast furnace slag have been found an excellent cementitious material for concrete. Portland cement is not required in this kind of concrete. Concretes with various amounts of steel slag and powders of granulated blast furnace slag additions have been investigated. Physical and chemical properties of the products were examined. High performance concrete can be obtained. Field testing of the concrete products was conducted for various applications, including buildings and pavements, and the results demonstrated the soundness of the concrete. Drill cores of field tested concrete, with ages up to 26 years, were examined for the microstructures under SEM.IntroductionIn the steel industry, a major source of the solid waste is steel slag. Steel slag has poor stability in construction applications. This is a major reason that only a small amount of steel slag has been utilized. Some of the reported applications include the land filling/creation in the sea, road base materials, soil treatment for acid neutralization and micronutrients supply, and sintering aid in the sintering plant of the steel industry [1].To solve the stability problem for using steel slag as construction materials, the common approach is to find a method capable of depressing or eliminating the expansion of steel slag. Free lime in steel slag is the major component that causes the expansion. Aging and hydration pretreatment of free lime in steel slag are the well known methods for increasing the steel slag stability. However, there has been limited success on these approaches due to that a large portion of free lime is locked in the grains during the pretreatment process."

Jan 1, 2012

By R. K. Rajamani

Discrete Element Method simulation of charge motion in ball, SAG and autogenous mills has become a standard for design of mill internals, power draft evaluation, etc. Both two-dimensional and three-dimensional codes are being used. The two-dimensional code dominates the user market since the code completes a simulation in one or two hours. On the other hand, three-dimensional codes have been in the domain of specialists who can handle the complexity of the code and have access to parallel computing hardware. For the first time, this barrier is overcome via computing with graphic processing units (GPU). Commodity graphics cards now allow parallel computation with hundreds of processors. It is shown that the computational time has been reduced by a factor of fifty using GPU computing. Hence, SAG charge simulation results in three dimensions are achievable in a few hours using affordable desktop machines. The GPU computing shown here enables the three dimensional simulation into a manageable daily task for mill designers and researchers. On the technical side, the simulations can be elevated to a higher level of complexity to simulate breakage and transport. First, the speedup factor of fifty is established for the Nvidia GeForce GTX 580 graphics card. Next, four simulation tasks, consisting of AG, SAG and ball mills are reported. The simulation of AG and SAG mills are completed in less than 8 hours. The ball mill simulation with 1.25 million spheres is completed in 27 hours. In the near future, as the graphic card hardware advances the compute time can be halved.

Jan 1, 2012

By Alberto Oalvez, Lucya Yunus, Pengfii Tan

"Laboratory flotation tests of slow cooled converter slag have showed that 92.5% copper recovery at the copper cut-off grade of 24 - 25 % can be achieved by using a 50:50 ratio of DSP330 and SIBX (sodium isobutyl xanthate) at the natural pH of 7 and with a grinding time of 18.5 minutes. 70ìéç is the P80 achieved at this grinding time. MIBC is the frother and the solid content of the flotation feed was 46%. In the plant trials, two types of collectors at two different feed particle sizes for both the normal and slow cooled slag were operated. The particle size was controlled by the feed rate. The P80 of 75 ìçé at a feed rate between 32 - 36 t/h were tested. The plant trials have demonstrated that the copper recovery in the milling and flotation process of the slow cooled slags was improved by 3%. IntroductionIt is proposed to float the slow cooled converter slag, in the auxiliary circuit of the copper concentrator at Mount Isa, by using the processing conditions identified from several laboratory flotation tests. Among these laboratory tests, one produced a copper recovery of 4 % higher than those achieved from a normal cooled slag with the same slag feed grade and the same copper content (24 - 26 %) in the concentrate. These test conditions were selected for further studies.Laboratory Test Work and Plant TrialsThere has been a lot of work conducted under laboratory and plant conditions [1]. However, the achieved results did not justify their total implementation in the Mount Isa Copper Concentrator. Initially, the lab trials were carried out with slag cooled 100% in air; then it was changed to combined cooling for 12 h with air and 2.5 days with water sprays. The reason for this change was the shortage of space when the slag was cooled 100% in air, as it takes several days to achieve safe temperatures for its removal. The San Manuel Copper Smelter has reported that their slag was left for air cooling in pits for 8 h and then was followed by water cooling for 2-3 days [2]"

Jan 1, 2012

By R. Khanna, I. Mansuri, S. Devasahayam

"Recycling polymer based end-of-life materials as carbon resources for a partial replacement of coke/coal can make important contributions towards enhancing the environmental sustainability of steelmaking processes. An in-depth high temperature (1550°C) investigation has been carried on waste CDs/DVDs focussed specifically on char generation, characterization and dissolution into molten iron. The simultaneous presence of carbon and oxygen in polymeric chains on polycarbonate substrates resulted in the generation of a significant pore structure and exposed surfaces. Carbon dissolution studies into molten iron were carried out on the raw polymer as well on chars; high levels of carbon pick-up were observed in both cases after 15 minutes of contact at high temperatures. INTRODUCTIONOver the past sixty years, plastics have played an important part of our daily lives and are being increasingly used in all aspects of the global economy. More than 260 million tons of plastics are produced annually worldwide. Their rapid growth and extensive utilization with a short life span (such as packaging) has created a massive waste problem. Although the waste plastic component in municipal solid waste (MSW) amounts to only about 10 %, plastics have a high volume-to-weight ratio and these are generally not biodegradable. In Australia, ~19.20 % of plastics were recycled in 2009-2010 (PACIA, 2010); with the total consumption being estimated at 1,501,258 tonnes, 288,194 tonnes of plastics were recycled. There are serious environmental concerns with the two key waste management options, i.e. land filling and incineration, and there exists an urgent need for developing alternative recycling approaches. In this paper, we focus our attention on recycling waste CDs/DVDs polycarbonate substrates as a carbon resource in steelmaking.CDs/DVDs used for music/data/image are made from aromatic polycarbonate resin (hereafter abbreviated PC). This resin is also widely used as an engineering plastic in applications such as automobiles, mobile phones, notebook type personal computers, cameras & video cameras, electric & electronic appliances, fire equipment, life & living goods, roofing sheets, etc. High consumption and growth (~10% annually) of PC utilization is attributed to its excellent properties such as outstanding impact resistance, transparency, heat resistance, and dimensional stability. The molecular formula and composition of PC resin is given below:"

Jan 1, 2012

By Lawrence Nordell

A Conjugate Anvil-Hammer Mill (CAHM) has the potential to replace conventional crushers and SAG mills, with their respective conveyors and stockpiles, in a SABC circuit. It may improve comminution circuit efficiency by 100%. CAHM compresses rock in a more efficient way, similar to 19th century stamp mills, which follows the fundamental research of Schönert (1990 & 1996). CAHM efficiency is being proven through the use of ROCKY (2011) Discrete Element Method (DEM). ROCKY features allow it to simulate realistic comminution. CAHM is customizable with many geometries that are rock-property specific. ROCKY?s wear modeling compliments the structural integrity of the design.

Jan 1, 2012

By P. Rambalee

A multiple coal fired boiler house provides steam for utility usage in various production plants. Maintaining stable header pressure and boiler availability is of critical importance for downstream consumers. Advanced Process Control comprising of a G2 based expert system and Model Predictive Control was implemented to improve the boiler house performance. The results yielded improvements in the main header pressure stability, reduction in boiler saturation and significant saving in coal consumption. All information used for this document is from a published whitepaper written and led by Prevlen Rambalee (Anglo Platinum) and Gustaf Gous (BluESP) titled, ?Control and Stabilization of a Multiple Boiler Plant: An APC Approach?.

Jan 1, 2012

In 2009 Newmont Mining Corporation?s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Jan 1, 2012

Experimental determination of the response of an AG/SAG mill treating two components of significantly different impact resistance is challenging for two main reasons: firstly, small scale laboratory tests have yet to be confirmed as valid representations of the full scale milling environment, and secondly pilot plant testing requires 10-20 tonnes of ore per scenario which precludes the use of drill core, rendering the process very expensive. In order to mitigate these difficulties, modelling was considered as a potential way forward. However, as the JKSimMet AG/SAG model currently has no capacity to simulate the interaction of two ore types with differing impact resistance, density and/or feed size distributions, an alternative modelling approach was developed. This approach aims to essentially calibrate the AG/SAG process under a set of given conditions, for which survey data and the ore properties of the main components in the feed blend already exist. This paper describes a new conceptual model, which provides a simplified approach for investigating the multi-component behaviour of two ores of differing hardness/SG in a given AG/SAG milling environment, and which can potentially be used for scale-up from laboratory/pilot testwork and geometallurgical estimation of throughput.

Jan 1, 2012

By K. Becerra, D. G. Almond, T. D. Maru

"Nkomati Nickel Mine in South Africa processes one of the world’s hardest ores in a 375k TPM autogenous grinding circuit. The plant employs an unconventional processing circuit, comprising a primary autogenous mill (AG or FAG) and pebble crushing circuit followed by a secondary hybrid pebble/ball mill and classification cyclone cluster.Advanced Process Control (APC) or Expert Control is now generally accepted as an advantage in most modern high capacity concentrator grinding circuits. This paper reviews the installation of model predictive control at Nkomati and examines the results and benefits of installation in an autogenous mill during plant ramp-up. The paper also demonstrates how predefining process control objectives together with good plant and supplier cooperation can achieve a robust and reliable APC implementation on a very short site program.The results conclusively demonstrate operational and economic benefits during circuit operation with the advanced process control system ON. Production performance and circuit stability were significantly better than during manual control."

Jan 1, 2012

By V. “Ram” Ramachandran

"In view of the increasing number of environmental regulations that have been promulgated all over the world in the last thirty years, non-ferrous smelters and refineries have had to learn and adapt to treating process bleed waste streams containing heavy metals. The result of such treatment invariably yields a gypsum-saturated solution containing salts such as alkali metal sulfates, chlorides and fluorides. Presence of anions such as sulfates, chlorides and fluorides in the discharge streams – presently not a major problem- are coming under increasing scrutiny and will have to be addressed in the near future. It is envisaged that discharge limits for sulfate ions will be in place in the near future. Treatment of brackish water to produce drinking water also results in brine streams containing alkali salts that have to be addressed for proper disposal. This paper reviews treatment options for such streams containing high levels of total dissolved solids with emphasis on sulfate removal. Areas covered would be: a) chemical treatment for removal of various constituents that make up the total dissolved solids b) processes for sulfate removal processes –thermal and non-thermal-to recover and reuse of treated water and c) brine use and treatment options.INTRODUCTIONThe rising cost of water and meeting the ever-changing stringent environmental discharge regulations make water recycling and reuse essential. The metallurgical industry has used water as a medium for dissolving and/or rejecting metals and chemicals in addition to removing thermal energy. Any excess process effluent is collected and sent to end-of-pipeline treatment and ultimately discharged to surface water for disposal under a permit. The conventional- and probably the cheapest way -of treating metal-bearing process effluent streams is lime neutralization followed by sulfide polishing for elimination of heavy metals to produce a stream that meets NPDES discharge limits. This results in a stream containing dissolved solids.These dissolved solids normally comprises of inorganic salts. The possible constituents are cations calcium, magnesium, sodium and potassium. The anions are sulfate, chloride, fluoride, nitrate, carbonate and bicarbonate. In addition to these constituents, the treated effluent streams contain very small amounts of heavy metals, oxyanions such as arsenites, arsenates, selenites and selenates. Process streams from gold operations contain residual cyanide. Small amounts of ammonium ions are also present in these streams based on the pH of the solution."

Jan 1, 2012

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By Jyri Talja, Shaolong Chen, Hannu Mansikkaviita

"Drying (water removal) prior to smelting is always economically feasible. Unnecessary heating of vapour can thus be eliminated resulting in savings of5-15 MUSD every year.Thermodynamically removal of one ton of water out of copper concentrate at 100 °C (with 10 % moisture) requires approximately 3150 MJ/tH2o, consisting of heating of the water (377 MJ), heating of the concentrate (509 MJ) and water evaporation (2260 MJ). This is quite independent of the selected drying technology. In reality some more heat is needed as higher temperature is practiced to enhance the drying performance and to reduce the equipment size.Major nominator in drying energy efficiency is amount of gases, which depends greatly on the drying technology. Dryers based on direct heating with fossil fuels have high gas flow rates, and thus they require additional energy of about 1400-1600 MJ/tH2o, compared to indirect modemsteam drying at 250-400 MJ/tH2o.Significant benefits in energy consumption (900-1300 MJ/tH2o) with additional potential for a bonus profit of 2-4 MUSD/y year, together with full elimination of some 40 000 tpy CO2 per mid-size dryer is available by selecting sustainable, energy efficient steam drying.IntroductionRemoval of water from the concentrate is very energy intensive thus having a significant environmental impact. However, drying prior to smelting is always economically feasible and very often viable also from the perspective of process operations. This environmental impact of drying can, however, be decreased or even fully eliminated with proper selection of the drying technology.Energy incorporated in drying consists always of a number of phases like liquid (water), solids (concentrate) and gases (water vapour, purging I dilution air, combustion gases). Each phase is heated to a specific temperature during the drying process.Heating of water, heating of the concentrate and water evaporation consumes more or less the same amount of energy despite of the drying technology (3150 MJ per ton of water). In conventional drying this amount of energy is achieved by combustion of fossil fuels wirg subsequent CO2 emission. Alternatively, chemical energy derived from sulphide smelting can be utilized in a form of steam thus generating zero emission ofCO2, in modem steam drying."

Jan 1, 2012

By Tom Gabardi, Peter Clarke

"MillMapperTM is a new 3D laser scanning technology that has only recently been introduced into the North American mining industry. It enables mill operators to gain a much more complete understanding of the condition of their mill internals and to more accurately predict how liners will perform in the future. This paper describes the technology and techniques used to obtain data on internal mill conditions, how this data is processed into meaningful information which enables better prediction of liner life and gives examples of the reports provided by the software. Examples are given, using client sites data, on how this information is being used to reduce the costs and improve the revenue from SAG and ball mills.INTRODUCTION Scanalyse Pty Ltd developed the MillMapperTM technology in Australia over a number of years and has recently introduced it into North America with a significant take-up in Canada. The technology was commercially released in Australia in late 2006 and there has been significant technical development in the features provided since that time. MillMapperTM has been accepted as a useful technology in the Australasian region and more recently has been introduced to sites in Chile, Peru, Brazil, USA, Canada, Laos and South Africa. Over 100 different mills have been scanned and the technology has been thoroughly tested and validated. It has become an integral tool in condition monitoring and improvement programs for SAG and Ball mills across many sites and is now providing significant and measurable benefits to the mining industry. Some of these benefits will be described in this paper using actual examples."

Jan 1, 2012

By Fernando Aracati Botelho, Jose Antonio Silva Souza, Luis Alves Venancio, Emanuel Negrão Macedo

"1 AbstractThe production of alumina from bauxite using the Bayer process generates 0.7 to 2.0 ton of the residue known as red mud and about 800 kg of CO2 per ton of alumina. The direct use of exhaust gases to react and neutralize the bauxite residue may allow a double gain: open a wide range of new applications for bauxite residue reducing its reactivity and sequester from 3 8 to 107 kg of CO2 per ton of alumina. This paper shows a pilot scale reaction of a suspension of bauxite residue-water with flue gas produced from direct burning oil, similar to the exhaust gases of a refinery. Two different types of reactors are used, a spray tower and a packed column. The inlet and exhaust gases are analyzed using electrochemical cells and non-dispersive infrared sensors. The pH of the suspension is monitored during the reaction and after to evaluate the buffer effect. 2 IntroductionThe production of millions of tons per year of alumina around the world generates from 0. 7 to 2.0 ton of the residue known as red mud (RM) per ton of alumina. The vast majority of the red mud is stored in large sealed lakes. Due to the high reactivity this material is considered dangerous and currently there is no operating process capable of reusing all the material produced at any refinery. These lakes after filled of solid material eventually have the surface revegetated [4]. In any case they will remain as an environmental passive and needs monitoring for decades. The search of a industrial process that combines the reduction of the CO2 emission and the reduction the pH of the red mud opening the possibility of large scale and economically viable ways is the main objective of this work.The use of the exhaust gases of the refmeries to neutralize the bauxite residue may allow a double gain: Open a large array of new applications for the residue with the reduction of its reactivity and sequester millions of tones ofCO2 plus other gases like SO2 [7] and NOx. This project studies the reaction of the exhaust gases from a boiler burning diesel with RM in different reactor types and conditions in order to obtain parameters to design equipment capable of process this reaction on a larger scale. With these objective compositions of red mud were processed with flue gas at concentration similar to the exhaust gases of the calcination process and boilers of the refmeries."

Jan 1, 2012