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By O. F. Brown

The use of quality materials (aggregates and asphalt binder) in optimal proportions is the key to producing optimally performing hot mix asphalt (HMA). The Superpave mix design standard in the US introduced specific volumetric and binder property requirements in HMA design. Different methods for HMA constituent proportioning have been proposed in various guidelines. The design process to determine the HMA blend is currently iterative and engineers rely almost exclusively on experience. This approach is time consuming and often does not result in cost-optimal HMA mixtures. This paper introduces a mixed integer linear programming (MILP) optimization model for hot-mix asphalt constituent proportioning. The MILP model minimizes the total mix cost while satisfying all the volumetric, binder and mix property specification requirements. The model has been successfully validated with real-life example. The aggregates and binder ratios from the model were in close agreement with those from the contractor. The Bailey ratios and the gradation constraints were also satisfied. The cost of the optimal mix was $0.804/Mg less than that of the contractors?. This marginal reduction might make all the difference in an industry that is highly competitive. The MILP model also demonstrated that adding RAP to the contractor?s design would reduce the cost of the blend by $5.74/Mg. The virgin binder content was reduced by 1% because of the recycled asphalt contained in the RAP. This work represents the first successful attempt in incorporating both aggregate and asphalt performance requirements into the optimization formulation. Applying these models will ensure the minimum cost mix that meets all constraints and will increase profit margins for plant operators.

Jan 1, 2012

By Alexander Garcia

Roof and rib falls are the basic ground control hazards associated with underground roadways during development, stand up and, if applicable, retreat. Falls of ground can happen following the deterioration of supports or rock conditions over time, and particularly as a consequence of continuing rock deformation and/ or failure to install adequate support. Once developed, the risk of a failure is increased due to the effects of time as well as to front abutment stresses through retreat mining. The measurement of strata displacement using monitoring equipment is a form of ground control risk assessment. These monitoring systems are active, or ?live?, in a sense that risk is assessed real-time. However, there are circumstances in which falls of ground can occur without the prior recording of excessive movement. In addition, monitoring equipment is typically placed at set intervals, and strata conditions could vary between these points. Consequently, a visual assessment of other factors contributing to the risk of a fall should be made in order to complete a ground control risk assessment. Such surveys are usually one-off, thus capturing roadway conditions at one particular point in time. Ongoing deterioration is not documented through such one-time surveys, and there is a requirement for real-time or live assessment where a system is in place so that observation data can be updated on an ongoing basis, and a useful summary of prevailing roadway states produced on demand. To address the shortfalls of one-time assessments, a ?live? computerbased quantitative ground control risk assessment process has been developed. It combines visual observations processed in a quantitative manner with existing monitoring data into an interpretable output which indicates zones of roadway where there is an increased risk of a fall of ground from the roof or sides, so that remedial action can be carried out to mitigate that risk. Through improved procedures, it is now possible to generate a ground control risk assessment for each roadway, and one which can be updated frequently. This paper aims to outline and describe the assessment process.

Jan 1, 2012

Abrasivity and wear resistance are not intrinsic properties of materials, but rather parameters describing the interaction between the wear part and the material exerting the wearing action. Moreover, wear or, at least, that part of the wear which is due to the cumulative effect of minute scratches, is linked to the hardness disparity concept. Abrasivity, in this context, is a relative concept, pertaining to a metal-rock pair, rather than to a rock. Based on this assumption, a methodology has been developed and checked against actual cases, enabling description of the abrasiveness of a rock or the abrasion resistance of a metal through the ratio of comparable quantitative indicators. The paper describes the methods and provides examples of applications to practical cases (namely: rock cutting, excavation by means of tunnel boring machines (TBMs), rock crushing, and hydro-mill cutting).

Jan 1, 2012

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluorides1,2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02.SiO2) with the ammonium acid fluoride (NH4F.XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo¬dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By C. I. Walker

Field tests at a number of large mineral processing operations have been undertaken to better understand the wear life impact of different aspects of pump design, materials of construction and maintenance procedures. Data are presented for wear rates, and typical result variability is explored. To improve the availability of pumping equipment in a milling circuit it is not only important to improve the wear life, but also reduce the variability in the wear life of components so that the incidence of premature failure is lessened. Localised gouging wear due to flow separation and turbulent eddy formation is often the point at which part-holing occurs. A number of improvements to the design of pump impeller and throatbush (suction side liners) to reduce the localised gouging wear are outlined. Also, results are presented on the use of composite materials (mix of metal, rubber and ceramic) for throatbush materials to protect specific areas against wear.

Jan 1, 2012

By S. C. Tadolini

Roof support systems have evolved from standing posts and timbers to a generation termed ?big nails? where steel bars are inserted into boreholes and anchored with expansion shells and/or resin cartridges. These systems have been effective but are limited to mining height. Additionally, the properties of steel do not resists shear forces or have the flexibility being required in difficult ground conditions. The next generation of roof support systems is coupling the best parts of the ?big nail? and resin grouted cable bolt systems. This paper will present the advanced technical solutions of the next generation of cable systems that includes an indented high-capacity PC-strand used with a variety of fixtures. Case histories of support applications will be presented.

Jan 1, 2012

By G. van Aswegen

The geometry and morphology of a set of low-angle fractures around a stope in a deep Witwatersrand gold mine are explained in terms of extension fractures forming under variable conditions of stress. Primary extension fractures (E1) form some distance ahead of an advancing stope along the s1, s2 plane. With stope advance, a couple of these fractures end up in a stress regime conducive to transpressional shear and a secondary set of extension fractures(E2) is formed at a high angle to the primary fractures. i.e. at a low angle to the stope. As the E2 fractures are undermined, they migrate into a stress regime of transtensional shear and a third set of extension fractures (E3) may develop between E2 fractures. These have sigmoidal shapes, being parallel to the E2 fractures at the E2 discontinuity where s3 is negative, and curved through the unfractured rock between E2 fractures where s3 is positive at the instant of fracturing. The fractures all display fractographic features characteristic of dynamic extension failure with striae indicative of the direction of rupture propagation and the local, instantaneous orientation of s1.

Jan 1, 2012

By K. Koruyan

Although remote sensing technology has been available for many years, it has rarely been used for monitoring mining activity. Recent studies indicate that remote sensing is also a valuable tool for managing and planning certain aspects of the mining operation. In this paper, we examine areal expansion of marble quarries and the affected vegetation over a period of 10 years in the Mugla region in Turkey, using geographic information system (GIS) and remote sensing (RS) techniques. Images captured by ASTER Level 3A01 (3D Ortho Data Set), Landsat 5, and Landsat 7 satellites between 2001 and 2009 were used for the analysis. Changes in the natural vegetation as a function of the production level in the marble quarry were calculated using the normalized difference vegetation index. According to the study results, land cover and natural vegetation decreased by less than 3 per cent and 1 per cent respectively between 2001 and 2009, following an upsurge in mining activity in the region.

Jan 1, 2012

By P. P. Rosario

A research project was conducted at the University of British Columbia (UBC) resulting in the development and evaluation of a novel comminution circuit incorporating autogenous grinding and parallel trains of cone crushers and high-pressure grinding rolls (HPGR). A primary driver for the circuit was to treat ore from deposits with clay and variable hardness. This paper summarizes the unique pilot-plant test program that was developed as a basis for experimental simulation and lists the main findings of the research, including the circuit?s potential operational cost savings compared to a conventional SAG circuit.

Jan 1, 2012

By Jorge Alberto Soares Tenório, Flávia Paulucci Cianga Silvas, Bianca Medeiros, Denise Crocce Romano Espinosa, Ivo André Homrich Schneider, Daniella Cardoso Buzzi, José Roberto de Oliveira

"AMD is one of the main problems associated with mining activities and the techniques used in their treatment may be the biosorption. The aim of this work was to study the rice husk as a biosorbent for the AMD treatment keeping constant: pH (2.6), biomass concentration (1g.L-1), temperature (25°C) and agitation (175rpm). And varying the contact time of 5, 20, 60 and 240 minutes. Rice husk samples will be characterized before and after the biosorptives tests through analysis of SEM and IR. The micrographs indicate the occurrence of micro-precipitation and changes in biomass physical structure. Since the infrared spectra indicate changes in functional groups present in the biomass before and after the biosorptives tests. AMD synthetic solutions will be analyzed by ICP in order to quantify the metals concentration captured by biomassIntroductionThe preoccupation for the environment has led the industry in general, to treat their waste. As the only industrial activity is increasing, the pollutants generated must undergo treatment processes aimed at reducing pollution, and therefore, less aggression ecosystems.In mining there is waste water with accumulation of heavy metals, and these are harmful to health of living beings, thus being one of those industries responsible for some pollution of the environment. These wastewater in contact with oxygen to generate an acidic water is called acid mine drainage (AMD). This aqueous solution has a pH below 3 and varieties of dissolved metals. When this solution comes in contact with water, generates a series of environmental problems, so there is a need to recover the metals present in the DAM."

Jan 1, 2012

By W. G. Huang

To recover the coal resources of high-sulphur anthracite in Jincheng Mining Area, underground coal gasification (UCG) of No. 15 seam in Fenghuangshan Coal Mine was proposed. The feasibility of the project was confirmed by investigations of occurrence conditions, coal properties, and roof conditions, as well as experimental studies and theoretical analysis. It was found that UCG technology is appropriate to be adopted in the mining of the No. 15 seam, due to the stable rock conditions, simple geological structure and hydrogeology, the high carbon content of the coal, non-cohesiveness, medium-thermal stability, high ash fusion temperature, and weak reactivity with CO2. Further factors are the characteristics of the immediate roof, which consists of 9.11 m of limestone and mudstone with a compact structure and low permeability, and 4.27 m of dominantly mudstone with low permeability.

Jan 1, 2012

By A. Bascetin

Waste materials caused by mining activities are an important environmental problem. Paste technology is a good alternative for waste management because it has many benefits in the aspects of environment, cost and safety. Disposal of process wastes in paste form is an attractive option for waste management, as it eliminates or reduces the risks associated with conventional methods. Due to the geotechnical characteristics of the paste, it is very similar to soil materials. So determining the geotechnical properties of the paste material is essential to durability of the paste. The some important geotechnical properties are compressive strength, porosity, shear strength, hydraulic conductivity, water content, consolidation, etc. In this study, the important parameters and the relation between them were investigated and obtained some results which will affect for optimum design of waste management.

Jan 1, 2012

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

By Greg Beckstrom

On Oct. 1-3, SME?s Twin Cities chapter (SME TC), in cooperation with the University of Minnesota ? Duluth?s Precambrian Research Center (UMD-PRC), cohosted a symposium on silica sand mining and processing. The conference was held at the Earle Brown Heritage Center near Minneapolis. The symposium was followed by a day-long field trip to operating mines, processing plants and loading facilities located in southwestern Wisconsin. Speakers and attendees at the symposium included university professors, industry experts, regulators, mining company representatives, equipment suppliers, consulting engineers and service companies. Approximately 320 people attended the conference. In addition, about 50 people who oppose mine development and the oil and gas industry showed up to voice their displeasure with the event and those companies that operate in this space.

Jan 1, 2012

By Xie Zhang, Jiang Diao, Xiaojun Li, Bing Xie

"Vanadium is widely utilized as an important element to improve the quality of alloyed steels in iron and steel industry. Moreover, the crystallization process of V-containing spinels plays a significant role due to the aim of achieving a fairly larger size of spinel crystals in vanadium extraction. Thus, a comprehensive exploration and discussion on the competitive precipitation and growth of vanadium, chromium and titanium spinel crystals in vanadium slag during a cooling process were carried out in the present study on the basis of a crystallization kinetic model. To be more specific, the abilities of forming crystal, precipitation order and suitable temperature range for crystallization of the three kinds of spinels were discussed with both theoretical and experimental methods.IntroductionVanadium is an important element which is used almost exclusively in ferrous and non-ferrous alloys due to its excellent physical properties such as high tensile strength, hardness, and fatigue resistance [1]. Various kinds of processes of vanadium extraction from V-containing hot metal are available at present. However, only four processes which are the Highveld process (South Africa), the Pan-steel process (China), the NTMK duplex process (Russia) and the New Zealand steel process (New Zealand) take the dominant positions [2, 3]. Although the type of reactor and the initial vanadium content in hot metal are different in these techniques, they share the same principle that vanadium is oxidized by oxygen into vanadium slag."

Jan 1, 2012

By G. Barr

"The Polymetallic Twin Metals Project deposits in Northern Minnesota are being developed by Twin Metals Minnesota. Amongst the flowsheet alternatives being examined at a prefeasibility study level is one involving flotation of a bulk concentrate followed by high temperature autoclaving of the concentrate using the PlatsolTM Process to solubilize all the valuable metals in the concentrate (Cu, Ni, Pt, Pd and Au). Autoclave operating conditions have been established in which recoveries of all the pay metals are in the 92 to 99% range, and the autoclave residence time has been reduced to an hour. The stability of the precious metals in solution after autoclaving has been assessed, as well as the impact of internally recycling process liquors to the feed to the autoclave.INTRODUCTIONPlatinum group metals (PGMs; platinum, palladium, rhodium, ruthenium, iridium and osmium) are traditionally recovered from their ores by production of a high-grade concentrate by flotation and/or gravity concentration followed by smelting of the concentrate. Concentrates are smelted to remove nonsulphide minerals and converted to remove iron and sulphur. The resulting high PGM grade matte is processed hydrometallurgically to leach the base metals, leaving a residue with a very high grade (20-40%) PGM concentrate for final refining to individual PGMs. Due to the complexity of this process and its high capital cost, this process can only be applied economically to high grade PGM ores. Lower grade PGM concentrates might be accepted as copper and nickel concentrates but may not yield attractive payment terms for the PGMs. The mineralized Duluth Gabbro region of Minnesota hosts several low grade base and PGM deposits and Twin Metals Minnesota is working to develop the Twin Metals Project deposits. Earlier studies at both pre-feasibility and feasibility level, by other mining companies, have failed to yield an economically viable project based on the traditional process. It is possible to produce a saleable copper concentrate from these ores, but economic recovery of nickel and PGMs into saleable concentrates proved elusive.In the late 1990’s and early 2000’s the Platsol™ process was developed at SGS in Lakefield, Ontario (at the time Lakefield Research Limited) for the NorthMet deposit (also within the Duluth Gabbro) owned by PolyMet Mining. The process developed was a high temperature chloride-assisted pressure oxidation process capable of dissolving simultaneously the base metals (Cu, Ni, Co, Zn), gold and the PGMs."

Jan 1, 2012

By Jilai Xue, Jun Zhu, Yongqiang Liu

"Up-grading silicon feedstock by removing B and metal impurities can improve process efficiency and lower production cost in metallurgical processing for solar cells production. Hydrometallurgical study has been carried out in laboratory through alternative treatments of the metallurgical grade (MG) silicon (-200 mesh) by using hydrogen peroxide, hydrofluoric acid (4 mol/L) and NH4Cl-NH4 F (30:5) solution. The experiments were usually performed under mechanical agitation at 70 ? for 5 h. ICP-AES analysis showed that B content in MG silicon after the hydrometallurgical treatment has reduced by 92.4 %, and Fe, Al, and Ca contents by 98.8 %, 98.0 % and 81 %, respectively. Kinetics of these processes was also studied for better understanding of the effects of silicon powder size, acid concentration, leaching and oxidizing time on the processing chemistry.IntroductionAs one of the most clean and promising new energy, solar energy is used more and more in many countries all over the world, especially in United States, Japan and European Union. Most of industrialized states have made their national photovoltaic plans, which have stimulated further increase in use of solar energy. Photovoltaic Industry is at a high growth rate about 30 % [1-2]. For silicon solar cells to remain the mainstay for the photovoltaic industry it is necessary to develop a low-cost solar grade silicon feedstock [3]. At the same time, the availability of the currently M-G silicon from the semiconductor industries becomes limited [4]. With the advantages of low cost and low energy consumption, metallurgical routes to product solar–grade silicon get more attention [5]. These routes mainly include pickling, slagging, vacuum processing and directional solidification, etc [6]. Among them the most important processing step is the directional solidification, but it still can not satisfy the industrial demand for removing B. Removing B from Si remains as one of the most difficult and important processes in making M-G silicon [7]."

Jan 1, 2012

By Liyuan Chai, Bing Peng, Ji Peng, Di Yu

"Electric arc furnace (EAF) stainless steel dust has been classified as a hazardous waste by various government regulatory agencies as it releases heavy metals to environment. The solidification of EAF dust is to stabilize the hazardous components to the amorphous silica-alumina-based clays. The process of solidification is investigated and the softening temperatures of dust and additive clay mixtures are measured for economical thermal treatment. The results indicate that the mixture of dust and local clay with the ratio of 1:1 has the lowest softening temperature 1100 °C and it could pass the toxicity characteristics leaching procedure (TCLP) test for the environmental regulatory limits after thermally treated at softening temperature for 15 min. Major phases of thermal solidification product clinker are CaAl2Si2O8, (Fe, Cr)2O3, (Fe, Mg)(Cr, Al)2O4 and Al6Si2O13.IntroductionThe yield of stainless steels in China arrived to 10 million tons in 2006 and more than 0.2 million tons of stainless steel dust are produced annually. Approximately 1-2 wt.% of scrap charged to an electric arc furnace (EAF) enters the off-gases and then is converted into the dust and reported to the bag-house. The disposal or landfill of the dust becomes a serious environmental problem in China due to the increased production of stainless steels in recent years. The dust contains elements such as chromium (Cr), nickel (Ni), lead (Pb), zinc (Zn), cadmium (Cd) and their solubility in leaching media exceeds the environmental regulatory limits [1]. Even though easily feasible for low-grade MgO, it is not appropriate to stabilize the heavy metals from the heavily contaminated soils after the dust landfill [2]. Several dust treatment technologies have been developed and they can be divided into two types. One is to recover the metals from the dust [3, 4] and another is to stabilize hazardous components present in the dust [5, 6]. Recycling of the dust generated in EAF is a remediation option for cleaner production. Direct recycling of EAF stainless steel dust was developed to recover the metal value from the dust and protect the environment [7], but it was only suitable for the dust with high contents of Ni, Cr and Fe. As for the dust with low valuable metal content, thermal solidification is an appropriate choice for the dust treatment."

Jan 1, 2012

By E. Krystad, G. Tranell

"The kinetics of boron removal from liquid silicon during slag refining, as a process step in the production of solar grade silicon, has been investigated by means of small scale mass transfer experimental series at 1600°C, using a graphite crucible. The slags were SiO2-CaO based, with or without addition of approx. 19 wt% MgO. Experiments were carried out at slag-metal ratios of 1 or 2, where the silicon initially contained approx. 250 ppm boron. The metal-slag mass transfer coefficients for boron were found to be in the order of 1-3 · 10-6 m/s and were largely influenced by slag composition. The mass transfer rate was higher for the MgO-containing slag than the slags without MgO. The final equilibrium distribution of boron between metal and slag, LB, was determined to be in the order of 2.3-3.3.I. INTRODUCTIONRecent years have seen a race in industry and research aimed at obtaining a reliable metallurgical route for production of silicon for solar cells (SoG-Si) from metallurgical grade (MG) silicon. Metallurgical routes can successfully challenge the traditional chemical routes for production of SoG-Si if they generate metal of sufficient purity while being less expensive in terms of production cost and energy consumption. Efficient removal of boron is one of the greatest obstacles in the refining of silicon by a metallurgical route, because the segregation coefficient of boron in silicon makes directional solidification unfeasible; in addition, the vapour pressure of boron is not high enough for removal by vacuum refining. However, the thermodynamic properties of boron makes removal from silicon by oxidation possible, and thus the process of slag refining of silicon has been receiving increasing attention as a method for boron removal."

Jan 1, 2012

By M. B. Shongwe

Pt-based alloys are being developed for high-temperature applications with the aim of replacing some of the currently used Ni-based superalloys (NBSAs) in the highest temperature applications. The Pt-based alloys have a similar structure to the NBSAs, and since Pt is more chemically inert than nickel and has a higher melting point, they can potentially be used at higher temperatures, up to 1300°C, and in more aggressive environments. Several experimental Pt-based alloys were studied at Mintek, and an optimum composition was found to be Pt84:Ahi:Ru2:Cr3 (at.%). On the basis of hardness and microstructure, a later study identified a new optimum: Ptr8:A111:Ru5:Cr6 (at.%). There are at least two Pt3A1 allotropes, and the high-temperature cubic structure has better properties than the lower temperature tetragonal form, and so needs to be stabilized. This work describes the latest results obtained in transmission electron microscopy (TEM) studies of the quaternary Pt-based superalloys. These results are both interesting and important, because the samples have a higher precipitate density compared to those from earlier work. The precipitate morphology is mainly cubic, with minor areas having irregular-shaped precipitates. The high volume fraction of the precipitates is a major breakthrough, since the objective of this work is to improve the alloys. A prior disadvantage was that the proportion of the precipitates was too low in samples before this work, especially compared with the work from Germany on Pt-Al-Cr-Ni¬-based alloys as well as the NBSAs. TEM -Pt3A1 diffraction patterns were studied, and for each diffraction pattern, many possible lattice point combinations were tried, with the angle between the lattice spots as well as interplanar spacings being calculated for each phase (cubic or tetragonal) to match the measured results. An overall analysis of the diffraction results indicates that the cubic phase fitted the experimental lattice points with much lower errors compared to the tetragonal phase. Thus, with the close match achieved with the cubic structure, the structure of -Pt3A1 precipitates is likely to be cubic. X-ray diffraction has been carried out on selected samples, and the results confirmed the presence of cubic -Pt3A1 and (Pt). Different X¬ray diffractometers were used to further verify the results, and the results were also compared with those from TEM.

Jan 1, 2012