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By Monte R. Hieb

Study of moisture-induced swelling strain in Pennsylvanian Period rocks of the Appalachian Plateau in West Virginia shows a 2:1 biaxial horizontal anisotropy which trends NW-SE. Oriented in-situ slabs of coal mine roof rock were collected across West Virginia, dry-sawed to size, air-dried to stability, and then monitored for moisture changes and deformations in the horizontal plane through one wetting cycle and drying cycle. Biaxial swelling strains were exhibited in nearly all rocks tested, with maximum horizontal deformations occurring normally-incident to the strike of regional geologic fold structures. This relationship persists as fold strike varies across the study area. A connection with Alleghanian fold development and/or post-Alleghanian fold relaxation is suggested. Deformations were largest in shales, but occurred in sandstones and siltstones as well. During testing, moisture-induced fractures (MIF) developed parallel to the regional fold structure and ranged in size from hairline cracks to sample-destroying cracks that were orthogonal to the observed biaxial swelling strain direction. Preferential wetting and swelling of clay minerals along NE-trending fractures, related to a fold-parallel fracture fabric of regional extent across West Virginia, is the most likely reason for the observed systematic NW-oriented biaxial swelling strains. The testing methods used in this study are simple and inexpensive and produce robust results that offer insight into a regional, anisotropic mechanical weakness that imparts a dynamic, asymmetrical horizontal stress to moisture-sensitive coal mine roof rocks over time. Because a similar mechanical fabric has been reported in Devonian-age shales, these findings may have implications for shale gas developers in the Appalachian Basin challenged by rapid aperture closure rates along horizontallydrilled induced fracture networks in Devonian rocks like the Marcellus Shale. The paper concludes with an example of how the concept of a preferred swelling strain direction might be applied to improve the effectiveness of roof trusses.

Jan 1, 2013

By Guo Chen, Jin Chen, Jinhui Peng

"In this paper, the methods of life cycle assessment for microwave hot air systems, and the concept of green degree were proposed. Greenness evaluation index, evaluation system and evaluation model of microwave hot air systems were established. Also, life cycle assessment processing based on these ideas was introduced. Analytic hierarchy process and fuzzy decision- making method were utilized to establish and solve the greenness evaluation of assessment model, while the scores of green degree in microwave hot air systems were obtained. The results show that Life cycle assessment can be applied effectively and efficiently to the microwave hot air systems.IntroductionHot air systems are an important industrial operation condition, which is used to provide high temperature air for materials processing. Nowadays, high temperature airs are manufactured by the conventional heating processes, in which some ceramic materials are used as heating materials. However, these processes pollute the environment. Therefore, to explore new method to produce high temperature air with low energy consumption and less environment pollution are necessary.Microwaves are now being used in various technological and scientific fields in order to heat dielectric materials [1]. Microwaves irradiation has been explored in materials processing in recent years [2-3]. The main advantage of using microwave heating is that the treatment time can be considerably reduced, which in many cases represents a reduction in the energy consumption as well. Since there is energy absorption but no heat conduction, the heating is very rapid and highly efficient, resulting in energy savings and the shortened processing time [2, 4]. Compared with conventional heating techniques, the additional advantage of using microwave irradiation is that microwave irradiation achieves both internal and uniform heating [5-7]. In addition, it is more convenient to control the microwave irradiation processing, because of no direct contact between the heating source and heated materials with less equipment size and waste [2, 8-9]. Life cycle assessment is used and accepted methods for the evaluation of the environmental impacts of products or systems [10]. Recently, many appropriate evaluation methods have been developed for life cycle assessment [11-12]. These proposed methods usually are employed for the evaluating product and analyzing results [13]. Among them, the analytic hierarchy process and the fuzzy comprehensive evaluation stand out as a popular method utilized in many fields [14-16]. Analytic hierarchy process and fuzzy comprehensive evaluation are a combination of mathematical and statistical technique that is useful for analyzing the effects of several independent assessment aspects on the system goal without the need of the predetermined relationship between the objective function and the assessment aspects [17-19]."

Jan 1, 2013

By G. A. Slabbert

The paper describes work undertaken to identify the influence of the matrix structure on the metal dusting rate of stainless steel alloys. Specifically, the difference in metal dusting rate between austenitic and ferritic stainless steels of similar chromium contents was investigated. The alloys were exposed to metal dusting conditions and their performance compared by weight loss, optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Raman spectroscopy. The specific gas mixture used for all the tests were 18.9% CO-79.1% H2-2% H2O at 650°C. For austenitic stainless steels, Types 304, 321, 316, and 316Ti were compared to two ferritic grades, namely Types 430 and 441. The resistance of the ferritic grades was found to be significantly better than that of the austenitic grades. This was attributed to greater permeability of chromium through the matrix structure to maintain the protective oxide scale. The results will be used in the development of novel alloys to combat metal dusting.

Jan 1, 2013

By Truan-Sheng Lui, Li-Hui Chen, Fei-Yi Hung, Cheng-Yi Chen

"This research used the austempering heat treatment on the SCM435 thin specimen with a type of double loop and obtained the Cr-Mo bainite structure, and then we could further investigate the mechanical properties of SCM435 bainite structure. Experimental data showed the stability of the mechanical properties of specimen with austempering temperature 830°C for 25 minutes was better than that of 15 minutes. The size of austenite grain affected the strength of thin specimen. After austempering at 830°C-25minutes and salt bath at 290°C, the stability of UTS was better than that of salt bath at 310°C and 330°C. The average hardness of all specimens was about more than HRA70. The specimen with austempering at 830°C-25minutes and salt bath at 290°C-30minutes had bigger grain size of austenite and retained y, it also had higher hardness and strength toughness. So, its stability was improved for tensile strength comparing with traditional tempered martensite process.IntroductionSCM435 is a Cr-Mo steel with high strength and high hardness properties, and it has been widely used in machine parts, shafts, gears and strength screw products [1-3]. However, this system often has lower reliability due to the brittleness of high-temperature tempering and quenching inequality. Considering the austempering heat treatment can obtain the uniform bainite structure to improve the temper brittleness, and the austempering heat treatment is a continuous process that it also has efficiency and uniformity. For the thin plate specimens, the mechanical properties of the bainite structure are better than traditional martempering structures."

Jan 1, 2013

By Enrique Munaretti, Cathy Aimone-Martin, Vitor Rosenhaim, Jair Koppe

Production blasts at one of Copelmi’s coal mine operations will be carried out 100 m (330 ft) from a neighborhood located in the town of Butiá, southern Brazil. Mine management is concerned about the possibility of damages and complaints due to blasting operations at close distances to structures of substandard construction. Blasting in the area is characterized by the use of very low powder factor resulting in confined shots in which movement is restricted to a point of almost undershooting the rock. Over the past year, tests were conducted mainly in the overburden area to determine the best approach to be implemented when blasts move closer to the town. Mine management wants vibration levels to be reduced lower than the damage limits proposed by Brazilian regulations to ensure a safety margin and mitigate perception by the community hoping to reduce the number of complaints.

Jan 1, 2013

By T. Johnson

Hydrometallurgical processes can be exceptionally corrosive. This is particularly true in acid leaching processes for copper, cobalt, nickel and rare earth elements. In the last five years, several large hydromet plants have been built in North America (Vale - Long Harbour, Baja Mining ? El Boleo and MolyCorp - Mountain Pass). Hundreds of storage tanks, extraction vessels and electrowinning cells along with miles of piping were designed and fabricated to withstand the aggressive environments inherent in these processes. One key element all three projects had in common was the extensive use of FRP in equipment design. As a material of construction, FRP provided equal if not improved durability relative to alternative corrosion resistant alloys at a considerably lower cost. This paper will highlight the extensive use of FRP in these three world scale projects and why it was chosen for each process.

Jan 1, 2013

By Hongli Wen, Guangkun Shen, Qiong Deng, Xuling Chen, Min Gan, Xiaohui Fan

"In this research, pyrite cinder which contains 53.51% Fe and 0.54% Pb was processed by magnetic roasting separation to obtain a concentrate with 64.62% Fe and 0.56% Pb. The concentrate was then leached with hydrochloric acid to remove lead. Several technological parameters which may influence the removal efficiency were investigated: the mass fraction of hydrochloric acid, pulp density, the leaching time and temperature. On the conditions that the mass fraction of hydrochloric acid of 5%, pulp density of 30%, the leaching time of 30 minutes and leaching temperature of20°C, the lead content in the concentrate was reduced to 0.19%. The product was suitable for agglomeration and pelletization. Through the analysis of the lead distribution and phase change during the whole process, the mechanism of lead separation from pyrite cinder was analyzed.IntroductionPyrite cinder is rich in iron, which defines its most extensive and effective use as raw materials for iron making. However, some pyrite cinders contain much non-ferrous metals, which is detrimental for the iron making process. Lead, one of the harmful elements, will destroy the blast furnace lining. Besides, it causes pollution of the environment[1]. Therefore it is necessary to remove excessive lead before entering the blast furnace. To separate the lead from pyrite cinder, much research was done, including flotation, high temperature evaporation and leaching. High temperature evaporation consumed too much energy. The flotation was difficult to obtain high- grade iron ore concentrate[2]. Majority of the leaching was direct leaching of pyrite cinder, which was also difficult to get high-grade iron ore concentrate[3]. This article explored the magnetic roasting method to get high-grade iron ore concentrate, acid leaching method of the concentrate to remove excessive lead, providing guidance for the efficient utilization of pyrite cinder."

Jan 1, 2013

By Roberto Folchi, Hans Wallin, Mara Battocchio

An understanding of explosives science and technology, and the competence to harness it is central to maintaining Explosives capability, national security, and in sustaining a competitive industry. A consequence of eroding this competence is the increased likelihood of explosives accidents. These are often catastrophic as demonstrated by accidents in Nigeria, Russia, Toulouse and Enschede. In addition to the serious loss of life there was the very significant damage to houses, domestic and industrial infrastructure and to the environment at a cost of many millions of Euros.

Jan 1, 2013

By Jilai Xue, Jun Zhu, Baisong Li

"TiB2-C/C Function Gradient Materials (FGM) is used in cathode materials to improve aluminum wettability and melt penetration in aluminum electrolysis. In this investigation, FGM was tested for use as part of the cathode materials, where a 10 mm thick TiB2-rich layer was on the top as an Al-wettable surface, the TiB2-C layers in the middle as a gradient layer and the carbon on the bottom as a base. Electrical resistances ofFGM were determined in the temperature range of25- 9600C in argon atmosphere. The results show that the present of TiB2-C gradient layer can reduce the open porosity and the electrical resistance of the cathodes materials at elevated temperatures. The cathode samples after aluminum electrolysis usually demonstrates an increase in electrical resistance, but the application of FGM layer can compensate such an increase for certain extend due to less variation in porosity and lower the level of melts penetration.IntroductionCarbon is still used for aluminum reduction cathodes dominantly, but it has a poor wetting properties by liquid aluminum and the anode-cathode distance has to be kept about 4-5cm with an additional 1.3-2.0 V voltage drop [l]. TiB2 has better wettability by liquid aluminum with higher electrical conductivity and stronger chemical resistance to the electrolyte attack. And the wettability ofTiB2-C composites cathode on liquid aluminum can be also improved, while liquid aluminum can completely wet the cathode surface ifTiB2 content exceeds 27% [2-4]. However, during the process of TiB2-C composites cathodes preparation and aluminum electrolysis, the deformation by temperature variation or sodium penetration are great disparity between TiB2 and carbon due to their physical properties difference. This will accelerate the cathodes cracking and deterioration."

Jan 1, 2013

By Charles S. Spirakis

The consistent occurrence of organic carbon early in the paragenesis of Mississippi Valley-type sulfide deposits suggests a genetic link between organic carbon and the sulfide ores. Reduction of sulfate in the mineralizing solution by organic carbon at the sites of mineralization is commonly proposed as the precipitation mechanism for these deposits, but inorganic sulfate reduction is too slow to be important to the chemistry of the ore zone, and bacteria, which catalyze sulfate reduction at low temperatures, are not known to survive at the temperatures of mineralization. Sulfate reduction with or without bacteria is not consistent with the sulfur Isotope evidence. Sulfur isotope studies also indicate that the derivation of sulfur from hydrocarbon at the sites of mineralization is unlikely. Organometallic complexing may be involved in the transport of metals, but no plausible mechanism for breaking these complexes at the sites of mineralization has been proposed. Reduction of partly oxidized sulfur species in the mineralizing solution by organic carbon at the sites of mineralization is a possibility which deserves further scrutiny.

Jan 1, 2013

By Thomas A. Printz

The wide use of carbon steel in construction and engineering projects makes this engineering material accountable for approximately 85% of the total annual steel production worldwide. Despite the lack of corrosion resistance of carbon steel, it is incorporated into the permanent work for marine applications, power plants, transportation projects, chemical processing, mining, petroleum production and refining, pipelines, mining and construction equipment. Corrosion is an electro-chemical process that occurs in the presence of water and air. When an electric current is introduced to water or soil, the rate of carbon steel corrosion increases rapidly. Gaseous atmospheric constituents that are capable of electrolytic activity can also increase the rate of corrosion. Corrosion tends to be more rapid in environments in which the steel is exposed to water, and then air, rather than being constantly submerged. The exposure to seawater increases steel pitting because the electrical conductivity is improved in salt water.

Jan 1, 2013

By A. Butler

This paper explains the politics of mine nationalization in contemporary South Africa. Nationalization and privatization typically occur in the oil, mineral resources, and state utilities sectors, and they tend to follow one another in a long-term cyclical pattern. The paper explains why the current international environment has encouraged demands for nationalization and other forms of ?resource nationalism? in the South African minerals sector. It goes on to describe how the resurgence of resource nationalism has been influenced by internal factional politics in the African National Congress. It concludes that nationalization is unlikely to be the outcome of current policy deliberations within the ANC.

Jan 1, 2013

Decision-making regarding plant-scale reagent dosage regimes and air rates is a topic of ongoing investigation and high importance. The current work explains some techniques that have proven useful in deciding on plant-scale flotation operating regimes. Specific focus has been placed on the reagents: frother and depressant, as well as some discussion around the control of air rate and froth depth. Air rate has been selected based on its effects on the froth phase. Froth velocity and froth height above the cell lip are the two variables measured and used to select the operating air rate. Pulp level is then adjusted to increase or decrease mass pull. A technique has been developed using the Anglo Platinum Bubble Sizer on an industrial flotation cell to determine the relationship between bubble size and frother concentration. This technique has been extended to measure the equivalent frother concentration or frothabilities of various streams on a rougher bank. A mass balance for frother was performed successfully, and this provided a better understanding of the way frother moved in the rougher bank. With this knowledge, more informed decisions can be made about frother addition required in subsequent flotation stages. For depressant, a new protocol for deciding on dosage rate has been developed. The depressant dosage should be based on the amount of fresh feed material reporting to a bank. Currently 400 g per ton of fresh feed has been assumed a reasonable starting point, with promising results. Improved froth stability and grades were observed. There is scope for more accurately defining the optimal dosage rate. Importantly, the combined effect of changing the chemistry and the hydrodynamics together has been demonstrated. A significant upward shift in the grade-recovery relationship for a cleaner bank was observed.

Jan 1, 2013

By Sen-xiang Yang, Xin-teng Liang, Gui-jun Li, Jian-hua Zeng, Yong Chen

"This research is based on PANSTEEL 120t steelmaking converter technology to have the quantitative description of the time needed in uniform mixing of molten steel in the converter with the computer. In present work, the numerical simulation approach is used to analyze oxygen lance nozzle, the flow condition of oxygen and flow status of molten steel in the converter. The various oxygen jet flows that come out from different angles and the flow status of all kinds of jet flows in the converter have also been simulated. All of the simulation parameters are based on the specifically practical conditions according to the physical conditions of PANSTEEL 120 t steelmaking converter. Through numerical simulation, the angle parameter of the oxygen lance nozzle is 16 °. The optimized oxygen lance 536-16 has a good performance in industrial application. This kind of phenomenon shows that the ways and processes of numerical simulation in this research are right.IntroductionThe oxygen lance system is the significant process in semi-steel making converter. It's related to whether the converter or even the whole system can function well. While in actual production, many problems emerge in the process of using the former oxygen lance, such as re-drying, slopping, high lance position, dead burning and even blowing out. In continuous fast-paced process, the unstableness of oxygen lance will lead to speed droop or even stop pouring. Analysis shows that all these problems are not only related to the raw materials but also the design of oxygen lance. Bad oxygen lance's scorification kinetics condition and low content of FeOn in early slag are the direct factors that we cannot easily control in steelmaking at present [l]. Therefore, the good scorification kinetics condition which is related to nozzle has good influence on BOF steel making."

Jan 1, 2013

By Patrick G. Hatcher

Studies of sedimentary humic acids by nuclear magnetic resonance (NMR), stable isotopes, and elemental analysis show they are derived by oxidative degradation of complex plant macromolecules that are insoluble in aqueous or organic solvents. The mechanism by which humic acids originate is fundamental to our understanding of the role of organic matter in ore deposition, because these substances can complex and mobilize a number of metal ions. The organic matter associated with uranium ores of the San Juan Basin, New Mexico and Carlin-type disseminated gold deposits of Nevada has certain organic geochemical characteristics that suggest an origin from humic acids.

Jan 1, 2013

By Mark Alan Marlkos

Blebs of solid bitumen from the Magmont West orebody of the Viburnum Trend were examined and analyzed in an attempt to relate hydrocarbon distribution and origin to ore genesis. The bitumen was calculated to be approximately 48 to 63 percent aliphatic and is considered to be a polymerized normal crude oil. Polymerization, which was probably caused by water-washing, hardened the bleb surfaces and appears to have "frozen" the blebs during primary migration from local source beds. Comparison of the bitumen to kerogen in local shaly partings strongly Indicates that the oil was derived locally. The polymerized oil blebs are considered to have been derived from a type II (marine) kerogen. Textural analyses indicate that oil migration occurred after lead-zinc mineralization and at temperatures that exceed normal ancient or present geothermal gradients. The following sequence of events is postulated for the Magmont West orebody: 1 Generation of hydrogen sulfide during diagenesis of a normal organic-rich carbonate sequence. 2 Introduction of pulses of hot, metal-rich fluids that resulted in: a Lead-zinc mineralization by the following reaction: Me++ + H2S ? MeS + 2H+ b Solution of carbonates by excess acid produced during the above reaction. c Brecciation of host rock in some cases. 3 Passages of the pulse resulted in: a Carbonate buffering of fluid system to more alkaline conditions. b Precipitation of dolomite c Slight temperature drop. 4 Eventually the high temperatures Introduced by heated brine caused oil generation and initiated primary migration. 5 Water-washing and mild biodegradation altered the hydrocarbon blebs to their present composition.

Jan 1, 2013

By Andrzej Walentek

In polish coal mining due to specificity of seams lying the multiple extraction is used. In this kind of mining, it is essential to take into account all geological and mining conditions which have an influence on stability and functionality of workings during their using. In view of above, for one of polish coalmines, by mean of Phase2 program, the numerical calculation were made for assessment of the influence of advancing excavation front on convergence of roadway located 30 meters above longwall was analysed. In order to verify developed prognosis, in analyzed roadway the underground investigations in scope of convergence measurement and changes of load exerted on working support were carried. As a result of these investigations it was found that real convergence on certain part of roadway was significantly larger then determined in prognosis. Additional calculations and analysis showed that the main cause of differences was underestimation of influence of dynamic load, which was an effect of numerous low energetic rockmass tremors. These tremors, related to excavated longwall, were located in close proximity of roadway in its part where the biggest convergence occurred. In current practice, in this type of convergence prognosis, the maximal value of dynamic load exerted on roadway resulted from single rockmass tremor is taken into consideration. Quantitative consideration of all tremors including their location is impossible at the stage of convergence prognosis because of lack of this type of data. This paper presents results of roadway convergence prognosis compared to results of underground investigation. Conclusions formulated on that base allow in future similar designing works for obtaining more accurate results.

Jan 1, 2013

By Onuralp Yiicel, Ozlem Okur, Murat Alkan

"In this study, Co-Cr-Mo alloys were produced using a mixture of Co304, Cr203 and Mo03 powders with Al powders by a Self-propagating high temperature synthesis process. SHS is a process of material synthesis that has revealed a number of reactants combinations capable of much higher energy release than conventional explosives. Al203 is added to the mixture to decrease the adiabatic temperature of the system. The thermodynamic simulations and the calculations of adiabatic temperature were examined with FactSage 6.2. In the SHS experiments, different Co304/ Cr203/Mo03 ratios were examined, and their effects on the metal recovery and alloy compositions were carried out. The samples were characterized by using chemical analysis, XRD, XRF and SEM/EDS techniques.IntroductionSelf Propagating High Temperature Synthesis (SHS) has significant advantages compared to the high technology furnace applications, such as very short processing time, simple operation, low energy requirement and low cost [l, 2]. In a SHS process, the ignition starts the combustion and propagates throughout the reactant mixture yielding the desired product. However, the disadvantages of the process such as inhomogeneous or unreacted products due to undesirable reaction rates needs to be overcome by changing some parameters such as ignition temperature, particle size, additive, atmosphere etc. [3, 4]. This work aims to establish a scientific and engineering background in the production of some cast Co-Cr-Mo master alloys via SHS (Self Propagating High Temperature Synthesis) metallurgy which is attractive process technique regarding fast and low-cost production ability of cast alloys."

Jan 1, 2013

By Kimberlee Falkenstein, Volha Kibitkina, Jessica Steeves

A series of experiments were conducted to obtain site specific constants for the vibration produced by a single charge and by more charges detonating in sequence, using short delay intervals. All charges were placed in relatively long boreholes in granite without a free face other than the ground surface. The boreholes were filled with water to provide good coupling with the rock and to provide identical confinement for all the blasts. Vibrations were recorded close to each blast in the vertical direction by uniaxial high frequency geophones and far field using a triaxial geophone.

Jan 1, 2013

By R. Venugopal, Saxena. V. K., U. Sankrityayan

"There is a dire need of a technology which can break the mineral interfaces to enhance liberation with minimum energy consumption in mineral beneficiation processes. Understanding of mineral crystal system and interfaces is essential to develop such methodology. So, this study is carried out to find out the role of mineral crystallography in milling and liberation. Data related of mineral crystallography, Vickers Hardness Number, Bond Work Index and beneficiation processes were collected from literature and detailed statistical analysis has been carried out to establish a correlation among these parameters. It was found that atomic weight and cell parameters shown statistically significant relationship with Vickers Hardness Number of minerals, which controls the milling characteristics of ores. Liberation characteristics of five different kinds of ores were analyzed considering the types of interfaces between valuable and gangue minerals. It was found that phase interfaces play vita role in liberation and coarser liberation can be achieved in the minerals of incoherent crystal systems like manganese and zinc ores. Study of this subject can help us to understand the effect of stress wave propagation in solids and its effect on crystal interfaces. It can also help us to design a technology of future to break the mineral interfaces.INTRODUCTIONCommunition is energy intensive mineral processing operation and consumes up to 2% of the total electric power generated in the world. Energy consumption due to comminution is increasing every year as there is growing needs to exploit lower grade ore bodies and process rejects (Blazy et al., 1994; DOE, 2005). Low grade ores require crushing and grinding to liberate the valuable minerals which are further separated from gangues by various beneficiation methods like gravity separation, floatation, leaching etc. Currently, comminution methods are selected based on the reduction ratio and energy consumption but effect of grinding methods on subsequent processing methods specially on liberation also need to be studied to optimize the entire beneficiation process. Most of the attempts made in past to minimize the energy consumption in milling to enhance the mineral liberation were focused on compression mechanism, chemical additives, thermal treatment, microwave treatment and electric disintegration (Kilpelm and Austin, 1982; Norgate and Weller et al, 1994; Bearman et al., 1997; Kumar et al., 2010; Wang el al., 2011; Singh et al., 2012). But the role of mineral crystallography on milling and liberation behavior of minerals not fully explored yet."

Jan 1, 2013