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By Mike Dry, Mani Manimaran, Mykolas Gladkovas, Mariam Melashvili, Chris Fleming

Development of a new hydrometallurgical flowsheet requires quantitative description and optimisation of all chemical processes in each step in the process, as well as mass and energy balances across a fully integrated circuit incorporating all the unit operations. This paper covers steps leading to early modelling of a gold processing plant based on a bromine/bromide lixiviant. Research conducted at SGS Lakefield in collaboration with Albemarle provided the data that were used in the development of this model. A previous investigation in this series described the leaching behaviour of various mineral types in Stabilized Bromine reagent. This paper is concerned with the gold recovery operations associated with a conceptual bromine leaching process. The recovery of gold by different types of resin and activated carbon was studied, along with various methods of stripping the gold from the extractant. The circuit is closed by electrolysing the spent leach liquor to oxidize some of the contained bromide back to bromine that would allow recycling the regenerated leach solution back to the leach step in the process.

Jan 1, 2015

By Xingkai Wang, Wenbing Xie

"To control the large deformation of soft rock around the roadway subjected to high stress, it is important to improve the stability of support structure, in addition to increasing support strength. In this study, the causes for the destabilization of U-steel frame and its loading characteristics were analyzed by theoretical analysis, laboratory experiments and field tests. The technology of constant support resistance, the principle of support structure compensation and the compensation technique are proposed. The results indicated that the main reasons for frame structure destabilization are caused by low strength of connector, irrational structure of connector, poor interaction between the surrounding rocks and support frame and structure, and unstable support structure. Thus, the corresponding technological measures, such as connector with high strength and rational structure are adopted. The bearing capacity of frame is unstable after slipping. In order to maintain the high support resistance when the frame is performing the support function, the frame connector should be retightened after slipping. Though the working resistance may be improved greatly by using the backfilling or back grouting of U-steel, the frame remains unstable because of the unstable frame structure. Therefore, according to the deformation characteristics of rocks surrounding the roadway and the structure instability of U- steel frame, the stable structure device is used to carry out the structural compensation of U-steel frame, and the whole bearing capacity of the frame and its structural stability are improved greatly.INTRODUCTIONThroughout the development of the roadway supports for coal mines in China, it can be seen that the supporting strength and supporting resistance increase continuously with increase in mining depth and supporting difficulties [1]. With respect to the ground control mechanism and supporting technology of rocks surrounding the soft rock roadways subjected to high stress, considerable research has been done both at home and abroad. The backfilling technology behind the high-resistance and yieldable U-steel wall, the new type of grout/bolt support technology and the bolting with high-strength mesh support technology were developed, and have been used widely in coal mines with notable economic benefits [2-7]. However, a large number of engineering practices show that in many cases the existing rock control technology of roadway may not control the large deformation of the soft rock roadways subjected to high stress. The reason that the large deformation of soft rock roadway occurs is mainly due to poor structure stability of existing frame bearing structure, not insufficient support strength."

Jan 1, 2015

By N. J. Castilla, R. Giglio

"Circulating fluidized-bed (CFB) combustion technology has been around for over 40 years, but over the last 6 years it has been commercially demonstrated at the 500 MWe scale at the Lagisza plant located in Bedzin, Poland. The CFB at the Lagisza plant has unique first-of-a-kind design features, such as vertical-tube supercritical steam technology and a lowtemperature flue-gas heat extraction that allows the plant to achieve high plant efficiencies of over 43% (net lower heating value). Another unusual feature for a coal power plant is that this plant meets all its atmospheric emission permit levels without any post-combustion de-NOx or de-SOx equipment such as selective catalytic reduction (SCR) or flue-gas desulphurization (FGD).CFB clean coal power technology is entering the utility power sector just in time to help deal with declining quality in internationally traded coals and to promote the large-scale use of economic, low-quality domestic fuels. Owing to the very attractive price discounts, growing supplies of low-quality Indonesian coals are outpacing the supply of high-quality Australian, Russian, and US coals. In Germany and Turkey, the use of domestic lignites for power production provides a secure and economic energy solution while creating domestic jobs.Conventional pulverized coal (PC) boilers will have trouble accepting these off-specification coals because of their narrow fuel specifications; they typically call for heating values above 5500 kcal/kg. This limitation is not an issue for CFB technology because of its ability to burn the worst and best of coals with heating values ranging from 3900 to 8000 kcal/kg.This paper provides an outlook for future coal supply, quality, and price, as well as a review of the technical and economic benefits of CFB technology firing low-quality fuels for utility power generation."

Jan 1, 2015

By Dongsheng Zhang, Xufeng Wang, Wei Zhang, Gangwei Fan

"Large-scale longwall mining of shallow coal seams could cause mining-induced fractures to communicate with the surface immediately in Northwest China, leading to a series of mine safety and environmental issues, including crack formation, water loss, vegetation deterioration, land desertification, and spontaneous coal combustion. Therefore, an accurate and effective understanding of the spatiotemporal evolution law of mining-induced fractures in overlying strata and its relationship to upper aquifers is critical. In this paper, the application of the geophysical-chemical properties of radon in mining engineering is explored as a potential solution to the shortcomings of existing surveying methods. A radioactive measurement method is proposed for the detection of the development of mining-induced fractures in overlying strata in the Baoshan Coal Mine (BCM). The on-site trial indicated that the first weighting step is approximately 60 m, the average periodic weighting step is approximately 20 m, and the influence coverage of the advanced abutment pressure is approximately 30 m. The presented method could be used as an indirect technical support to increase the safety of coal mining by acting as a simple, fast, and reliable method of detecting mining-induced fractures in overlying strata.INTRODUCTIONAccording to the latest coalfield prediction results provided by China’s National Administration of Coal Geology (CNACG) (Zhou et al., 2013), China’s coal resources are mainly distributed throughout the West, e.g., Inner Mongolia, Xinjiang, Shaanxi, Shanxi, Ningxia, and Guizhou. Two major coal mining areas have been established in the Northwest and the Southwest, and are typically represented by Inner Mongolia and Guizhou (Zhang et al., 2010). Northwest China is an arid to semi-arid area, where the coal seams are typically shallow and covered by a thin layer of bedrock. In its natural state, the surface’s ecological environment is fragile. Large-scale longwall mining of shallow coal seams could cause mining-induced fractures to communicate with the surface immediately, leading to a series of mine safety and environmental issues, including crack formation, water loss, vegetation deterioration, land desertification, and spontaneous coal combustion. This can propel any potential ecological fragility into a state of actual destruction (Zhang et al., 2011). Therefore, an accurate and effective understanding of the spatiotemporal evolution law of mininginduced fractures in overlying strata has become the theoretical basis of solving the above issues."

Jan 1, 2015

By B. Genc

"The risk of spontaneous combustion is well known in the South African coal mining industry. In the coming years it is very possible that the incidence of spontaneous combustion will increase from current levels, due to factors such as an increased rate of mining, re-working of previously mined seams, more stooping and total extraction for underground mines, and higher stripping ratios for surface mines, leading to more spoils. It is also fairly certain that coal mining will face tougher environmental emissions legislation in the near future. To determine the areas where the risks of spontaneous combustion are high, it is necessary to improve on our current laboratory procedures for testing and evaluating coal samples, combining the results with site and field data, and if necessary revising the laboratory rating system to refine our understanding of South African conditions.Currently, laboratory tests are conducted in order to determine both the Wits-EHAC index and the crossing-point temperature which, when combined, give an indication of the spontaneous combustion propensities of the coal samples. This procedure has enabled the establishment of a database of results to review and evaluate South African coal seams. Using this database, the high-risk areas in terms of spontaneous combustion are identified. Tests have been undertaken for five consecutive years, between 2008 and 2012. In total, 119 coal samples from different coal seams and production coalfields have been analysed and classified through a series of laboratory tests. A comprehensive database of these results is available, and is continually being updated as new test results are added. This database will continue to expand, and to provide the basis for an improved risk evaluation methodology for spontaneous combustion"

Jan 1, 2015

By W. Hermülheim, J. Brune

"This paper analyzes mine emergency management and rescue practices in German underground coal mines and compares them to those used in the United States. The German mining industry has developed these practices over more than 100 years, and they have successfully managed numerous fire, water inundation and ground control emergencies using these techniques. The authors interviewed German mine emergency professionals about rescue team and emergency operations. These operations were then analyzed to determine which of these German principles would be of interest to United States mine rescue teams. Implementing these programs into United States mine rescue and emergency operations was analyzed. INTRODUCTION Coal mining has become much safer industry than it has been in the past. Advances in safety and health regulations and company polices have improved working conditions for miners all over the world. Even with these advances there is still a need for continued attention to safety and health. It is also important for mine safety professionals to observe practices and procedures in other countries and cultures and learn what and how to apply this knowledge in their own systems. Coal mine rescue has been an integral part in improving coal mine safety. Mine rescue procedures have evolved with time, experience and technology development. Today, coal mine rescue teams are still needed and must be continually trained and prepared for any mine emergency. Although it is hoped that improved mine safety policies and practices will eliminate coal mine disasters in the future, accidents remind us that disasters can still happen today. In May 2014, Turkey experienced a severe coal mine disaster where 301 people were killed [G.Tuysuz, 2014]. Our industry must learn from these incidents, focusing on disaster prevention and making improvements in mine rescue operations. Mine rescue procedures differ from country to country due different regulatory environments and different historical evolution of emergency response. Sharing practices and procedures from one country to another enables learning from different experiences and cultural backgrounds. Sharing is also a way of preserving information, identifying and learning best practices."

Jan 1, 2015

By S. K. Kawatra, J. A. Halt

"Low-grade iron ores are finely ground and processed to recover iron-bearing minerals. However, the iron-rich powder is too fine to be used directly in blast furnaces and most direct reduction furnaces, and must be agglomerated or pelletized into a usable product called “pellets.” Bentonite clay has traditionally been used as a binder to make iron ore concentrate pellets, but it is expensive and contaminates the pellets. Organic binders may be a viable alternative to bentonite clay. This manuscript reviews organic materials that have been used to make iron ore concentrate pellets. Included are discussions on the development of organic binders, common pros and cons to organic binder use, organic binder structure and its effects on agglomeration, and additives to organic binders.IntroductionIron ore agglomeration turns finely disseminated, low-grade iron ores into a usable product, called pellets. During pellet production, fine-grained, iron-rich minerals are liberated from low-grade ores, concentrated, and agglomerated into round balls that are thermally hardened or cold-bonded to form pellets. Pellets are then transported to blast furnaces or direct reduction operations where they are used to produce iron; iron is further refined and shaped into the wide variety of steel-based industrial and consumer products in use today.Over the years, pellet production has become increasingly more prevalent with the increased exploitation of low-grade iron ores and increased iron and steel consumption around the world. In 2010, world iron ore pellet production was 388 Mt. It could be argued that the current pellet production process has been enabled by the use of binders – practical experience has shown that it would be nearly impossible to agglomerate iron ore concentrates using rotary drums and discs without using a binder."

Jan 1, 2015

By N. Erarslan, M. Ghamgosar

The size of rock fragments depends on the nature of the loading applied the strength of the minerals and the texture of the rock. Research in the literature demonstrates that there is a distinct difference in the rock fracturing process for static and cyclic loading. The tensile strength of brittle rocks is also one of the most significant parameters influencing the rock fracturing process and the propagation of micro-fractures on the crushing, blasting and cutting of rock. The Brazilian indirect tensile test, one of the methods approved by the International Society for Rock Mechanics (ISRM), has been used to determine rock fracture behaviour under different cyclic loading modes. In this study, the dimensions of Brisbane Tuff specimens have been selected according to the method outlined by the ISRM. The main aim of this study is to evaluate the effect of cyclic loading amplitude and frequency on the Fracture Process Zone (FPZ) at the micro-, meso- and macro-scales. The post-failure behaviour of the Brisbane Tuff specimens was obtained under cyclic loading with frequencies varied from 1 to 10 Hz. The amplitude was varied from 10% of Ultimate Tensile Strength (UTS) up to 80% UTS. Laboratory investigations of rock fragment size revealed that different loading frequencies and amplitudes produce different FPZ dimensions. Multivariate Analysis of Variance (MANOVA) results demonstrated that the FPZ dimension is relatively sensitive to the frequency change. Fragment size analysis showed that the FPZ is a consequence of the initiation, propagation and coalescence of micro-fractures and depends on the nature of the loading. Laboratory evidence showed that the FPZ dimension, for the cyclic tests performed on Brisbane tuff, is ranged from 0.07 to 20 mm. The achievement of this study highlights a key finding in the understanding of fracture patterns and propagation models in the FPZ under cyclic loading, which is the dominate mechanical action in the oscillator disc cutter (ODC).

Jan 1, 2015

By Dinesh Hinduja, Pérez: Miguel

"Large structures are generally exposed to dynamic and structural loading. They require usually either foundation connected to hard rock through sockets or driven foundations, which encounter boulders as well.In this regards drilling hard-rock sockets or boulder offshore or onshore can be a challenging job especially when deep foundations are mandatory. To overcome the challenge, specialized equipment like a Pile Top Drilling rig (PBAs) can be used, which have to be correctly set-up and operated in order to get its maximum drilling performance. High performance drilling with PBAs requires maximizing key elements of its operation. The configuration and management of the drill string components are important. The key elements are constant weight on bit which is done by adjusting ballast and managing thrust force; and selection of cutters and proper flowing discharge.The methodology is based on the experience from over 40 years of building and operating PBAs for different project applications. These applications include drilling offshore and onshore for:?Superstructures and buildings?Drilling platforms, barges and jack-ups?Harbours, jetties, dry docks and dolphins?Bridges, piers and causeways?Marine sewerage diffusers?Offshore wind farms?Dam rehabilitationMHWirth documented methodologies demonstrate that by using PBAs properly it is possible to improves performance of underwater drilling for hard-rock sockets and boulders which ultimately reduces project-cost.Background. There is a significant percentage of total project cost in structural foundations. Equipment capabilities and technics to drill shaft with rock-sockets and embedded boulders onshore and offshore are highly developed due to the dramatic equipment advancement and experience in the last 40 years. Formerly, driven piles accounted for the majority of foundations either onshore or offshore, following the experience of previous practice in the market. Nowadays, deep drilled foundations can be constructed to carry the load through the overburden down to the sound load carrying rock or soil.Scope and objectives. The overall objectives of this study are:?Synthesis information on current practices to drill shaft with rock-socket and/or embedded boulders onshore and offshore with Pile Top Drill Rigs?Identify the principal challenges evolving with practice?Provide suggestions for improvements in the construction of drilled shafts through proper operation of Pile Top Drill Rigs?Convey information through case studies and experiences"

Jan 1, 2015

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

By F. Baczek, S. S. Rocks, D. Chaiko, T. Walters

The atmospheric leaching of chalcopyrite concentrates using acidic ferric sulfate lixiviants is well known to suffer from slow leach kinetics and poor copper recoveries. A number of approaches have been proposed for improving both leach kinetics and recoveries in this system. Many of these, while effective, suffer from high CAPEX and/or OPEX. As many mine sites begin transitioning from heap leaching of copper oxides to processing of primary copper sulfides, cost-efficient leach processes that are compatible with existing SX/EW processes will be needed to maintain existing cathode production. To this end, FLSmidth is exploring process options and reactor technology for the hydrometallurgical processing of primary sulfides. One approach that appears to be highly effective at increasing copper recoveries takes advantage of the enhanced reactivity of transitory, surface-defect structures generated during particle fracture. Significant process efficiencies are gained by matching the rate of grinding to the rate of electrochemical leaching in Mechano-Chemical leach processes. The patent-pending FLSmidth® ROL process uses a Stirred Media Reactor (SMRt reactor) to achieve copper recoveries of 97+% in 6 hours or less. This approach overcomes many of the surface passivation problems that have hindered other atmospheric leach processes. New insights to leach mechanisms are presented.

Jan 1, 2015

By X. S. Fan, T. R. Feng, D. Chen

To meet the flotation process requirements, the large-scale flotation cell must be designed for sufficient pulp mixing, reasonable air dispersion and solid suspension, which is very difficult to design for super large-scale flotation cell. Hence, the flotation cell scale-up and optimization for a short period is a challenge for super large-scale flotation cell design. Computational fluid dynamics simulation has been applied in flotation cell study, which is effective, timesaving and low cost in the study of the flow field distribution for super large-scale flotation cell. This paper demonstrates the flow field characteristics in the 600m3 flotation cell by CFD. The flotation cell model is meshed with hexahedral grid and the high mesh quality assures the computational precision. MRF model, namely a steady-state approximation, ensures that individual cell zones can be assigned different rotational speed. Euler-Euler approach is chosen for multiphase flow simulation to treat different phases as interpenetrating continua. Numerical simulation of single phase, two-phase and three-phase are investigated respectively. Results suggested that the flotation cell has the apparent upper and lower flow circulation. In condition of the impeller rotation, the air is dispersed reasonably. In addition, the solid phase volume concentration distribution in the cell has a little difference.

Jan 1, 2015

By J. L. Feng, F. Zhang, S. K. Hu

"Cracking is one of the most serious damages in tunnel linings, which is often observed by in-situ inspection to tunnel engineering. It is difficult to better characterise for the deformations from continua to discontinua by the traditional continuum mechanics due to emerging of crack initiation, crack propagation, and coalescence, at several scales. In this paper, the process of failure that was from micro damage to macro crack in concrete tunnel linings under experimental load conditions, was quantitatively simulated by the combined finite-discrete element method (FDEM). Comparison of the simulating results with that obtained by the full-scale test of concrete lining under different loading conditions in the literature was respectively good agreed and shows that such FDEM technique is appropriate to model the continuousdiscontinuous problems. The present study indicates that the FDEM technique could be benefit to quantitatively evaluate the stability and damage level of tunnel lining system. INTRODUCTIONMost damage to tunnel linings is caused during the construction phase, which can emerge in a form of single macro cracks or even large-scale spalling. The cause of such damage is mostly the occurrence of, either impermissibly large contact stresses resulting from high thrust loads combined with production and installation tolerances in the segments resulting in a geometrical lack of fit (Maidl et al., 2012; Transportation Research Board, Basic Research and Emerging Technologies Related to Concrete Committee, 2006), or unallowable tensile/shear stresses appearing in the tunnel linings under complicated loading conditions (Ansell, 2010). Such a macro failure phenomenon may also be regarded to as a result of growth, coalescence, initiation of microcracks in tunnel linings due to the complicated loading action, and even potentially lead to an instability or collapse of the local or entire tunnel system. Much work has been devoted to investigate for the characters of micro and macro cracks, the influence factors of damage patterns, the settlement of a tunnel, the width, length and density of lining cracks, especially from classifiedly and qualitatively (Wang, 2010; Huang et al., 2013). However, the safety evaluation of tunnel is definitely required to not only inspect in situ, but further also quantify computing and analyzing for tunnel lining systems, so as to provide a global viewpoint of process of the tunnel deformation, which aims to help for subsequent decisions, e.g. controlling traffic flow or immediately repairing task. Additionally, the design of lining thickness and its structural analysis that is mostly determined by previous experience and similar construction examples is also needed to be improved."

Jan 1, 2015

By G. L. Zhu, Y. F. Wu, H. Nagaumi

A novel eutectic-type alloy Al12Si-HTC with high thermal conductivity has been developed by strict chemical composition control and heat treatment. The thermal conductivity of the alloy is about 30 % higher than that of current commercial Al12Si alloy. The Al12Si-HTC alloy has a silicon content of 10~12 wt.%, which provides excellent castability. Trace element strontium or calcium is added to modify eutectic silicon, and contents of transition elements such as copper, manganese are controlled in a low level. By appropriate heat treatment, thermal conductivity of the castings increases by 7.5 % and finally reaches 172 W/(m·K). It is found that eutectic silicon modification which makes average particle size finer than 2µm plays a dominant role in improving thermal conductivity, as well as further spheroidization of eutectic silicon and reduction of lattice defects in a-Al microstructure in subsequent heat treatment process. The alloy is successfully applied to produce a certain communication enclosure with complex finned structure by die casting process in industrial scale. The results of numerical simulation and thermal analysis experiments show that when manufactured by Al12Si-HTC alloy, the surface temperature of chips in the enclosure is reduced by 2.0~4.5 ? and the temperature distribution is more homogeneous compared with traditional Al12Si alloy.

Jan 1, 2015

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By H. Tsuruta, A. Fujibayashi, I. Sumi, A. Murao, R. Murai

Injection of biomass into blast furnace as alternative reducing agent is so effective for the purpose of mitigation of carbon dioxide emissions from steel industries, because biomass is considered to be carbon neutral raw materials. Certain amount of Palm Kernel Shell (PKS) is abandoned after Palm oil extraction process. To use as a reducing agent of blast furnace, PKS was carbonized and classified by 100 mesh sieve. To examine the gasification behavior of PKS carbide under the blast furnace conditions, several combustion experiments were conducted using hot model experimental furnace. The experimental results showed that the gasification efficiency of PKS carbide increased as the quantity of volatile matter increased. This tendency is the almost the same for the pulverized coal, so carbide of PKS can be used at blast furnace at appropriate amount of volatile matter that can be controlled by carbonization condition. In addition, the pressure drop of the furnace tends to decrease because the amount of ash in PKS carbide may be smaller than that of pulverized coal. PKS carbide is a suitable reducing agent in that respect.

Jan 1, 2015

By T. Shumka, M. J. Druckenmiller

"INTRODUCTION As we push further into the 21st century and closer to a more efficient mine, safety and operational enhancements are the two major keys towards attaining success. The Crusher Vision Automation System (CVAS) is a technological advance that will allow an operator to achieve higher safety and higher operational goals in the same piece of equipment. The CVAS is a patent pending system and method for measuring and maintaining the closed side setting (CSS) on gyratory crushers. In the same equipment and technology package, the CVAS will also allow safer placement of main shaft pieces for maintenance and replacement. This technology yields multiple uses and allows a site to significantly enhance safety and operational efficiencies. This measurement technique is used to provide more accurate data and faster data collection times than current techniques used today. It will give crusher operators accurate and reliable measurement for the CSS in a live, operating environment. Measurement data can be collected in five minutes allowing for fast adjustment of the mantle position and subsequent enhancement and streamlining of a crusher and downstream flowsheet. The advantage of this system is that it is permanently mounted at the crusher location, where the operator can turn the system on and off as many times as they like throughout the day with a goal of maintaining a constant CSS gap based on production and maintenance criteria to help streamline operations and enhance safety efficiencies.Regarding its other main functional area, mainshaft maintenance, it allows this work to be performed remotely while keeping personnel safer and out of harm’s way. SAFETY ENHANCEMENT The safety factor enhancement with this system is extreme. It does not require the use of overhead cranes, cleaning out the crusher, lowering people into the crusher or having the operator lower paint cans or lead balls into the crusher pocket while the crusher is in operation for measuring the setting. In order to perform the CSS measurements, the operator only needs to operate the laser through manipulation of a joystick while watching the video feed. Danger of a person falling into the crusher while trying to take measures is eliminated, as are the effects of handling lead balls and tracer dyes."

Jan 1, 2015

By B. Yu, S. Kelebek, C. Gibson, M. Aghamirian

There are a number of high grade niobium deposits worldwide which have been deemed untreatable by flotation due to the very fine grained nature of the in situ pyrochlore, the primary niobium bearing mineral. A known method of recovering extremely fine particles is through the use of chelating reagents such as hydroxamic acids which have a strong affinity for transition metals. However, one of the major issues in the flotation of niobium bearing minerals using hydroxamic acids is the corresponding recovery of other transition metal gangue minerals including magnetite, hematite, and pyrite. In order to better understand the differences in behavior of niobium and iron bearing minerals in flotation with benzohydroxamic acid (BHA) and sodium hexametaphosphate (SHMP) at a range of pulp temperatures, a Box-Behnken experimental design was employed. Regression models for the global recovery of iron indicated that iron mineral recovery was significantly influenced by both BHA and SHMP dosage. Upon examinination of flotation products by semi-quantitative XRD, it was observed that recovery of iron oxide and sulphide minerals (hematite, magnetite, goethite, and pyrite) was problematic at high benzohydroxamic acid dosage, while sodium hexametaphosphate was mainly helpful for carbonate mineral depression. Iron rich carbonates (likely an iron rich dolomite) largely reported to the tails with increased SHMP dosage.

Jan 1, 2015

By M. Abdellatif

"SynopsisCalcined basic nickel carbonate (BNC) concentrate was smelted in a pilotscale DC arc furnace to produce a nickel metal. The furnace was continuously operated for 12 days (24 hour/day), during which twelve different smelting conditions were investigated, with the major variables being reductant type and feed rate, flux composition and addition, and BNC feed rate.The 200 kW DC arc furnace was operated at power levels between 110 and 165 kW and at a total feed rate of 78 to 96 kg/h, resulting in an average slag and metal tapping temperature of about 1650°C. A total of 7.2 t of BNC were smelted, producing about 5.44 t of nickel metal and 2.94 t of slag. Nickel recoveries of 96.4% and higher were achieved, and the slag nickel content was as low as 0.1%. The major impurities in the metal were iron (mostly from oxygen lancing) and carbon. The calculated feed carry-over was less than 0.85% and the graphite electrode consumption was between 2.8–3.3 kg/MWh.IntroductionOne of the most distinctive advantages of DC open-arc smelting is the ability to process fine raw materials without any major issues with regard to the operability of the furnace, metal recovery, and metal quality. This has been demonstrated in Mintek’s DC arc pilot plant facilities over a period of about three decades (Curr et al., 1983). The materials that have been processed include laterite (Kotze, 2002), chromite fines (Curr et al., 1983), manganese fines (Lagendijk et al., 2010), PGM concentrates (Shaw et al., 2013), electric arc furnace (EAF) dust (Denton et al., 2005; Abdellatif, 2002a) and stainless steel (SS) dust (Denton et al., 2005; Abdellatif, 2002a; Goff and Denton, 2004), and petroleum fly ash (Abdellatif, 2002b). The top particle size of such materials can vary from a few millimetres (e.g. laterite) to micrometres (EAF and SS dust). Dusting, whether due to physical carryover of feed or to the arc side reactions, has been proven to be a non-issue. As such, the applications of DC open-arc furnaces have the potential to be extended to other raw materials such as particulate nickel oxide, which has a particle size much less than 100 µm.Nickel oxide is typically produced from laterite ore by sulphuric acid leaching, purification, and precipitation as basic nickel carbonate (BNC) (Rhamdhani, Jak, and Hayes, 2008) or as mixed hydroxide precipitate (MHP) (Mackenzie, Virnig, and Feather, 2006), and finally calcining at moderate temperatures (800–1200°C). The NiO product is very fine, with an average particle size in the range of 10–20 µm and a NiO content of more than 99%."

Jan 1, 2015

By B. H. Sadagah

"Construction of mountain roads at north westerly Saudi Arabia is a difficult task in rugged terrains, where the rock masses are steep slopes, and full of geomorphological constraints.Werka descent lies at the north west region of Saudi Arabia. The Werka descent, constructed four years ago harmed due to rainstorm. The rock masses are metabasalt and metaryolite tuff rocks. The road is eight m-wide, surround by unsupported sharp manmade slope cuts, reaches up to 15 to 40 m height on both sides. Failures took place at both sides of the road, and blocked it. The road of almost 2 km long subjected to all modes of slope instability such as rockfalls, manmade slope failures and debris flows in the absence of the remedial measures. The very precipitous 40 m-high rock slope-cut along the road has no benches, backed by a natural slope of almost 80 m height. Both types of slopes suffer from rockfalls and slope failure’s incidents, frequently took place mainly in rainy seasons. The steep manmade rock slope cut is less than 1 m close to the road, with no ditches, form a potentially source area for rockfall’s hazards.Intensive geotechnical study includes utilization of the RMR and GSI rock masses classifications indicates that the rocks are fair to poor quality. The DIPS, RocFall, Swedge, RocTopple, RocPlane computer program, in addition to GIS and DEM image utilized to perform modeling and deterministic analysis, in order to suggest the mitigation measures for the natural and manmade slope cuts and rockfalls. The seismic coefficients of 0.1 to 0.4 taken into consideration in modeling processes. Input parameters to model the rockfalls and slope failure’s characteristics were studied such as GSI, block size; seeder points, locations of fallen blocks; slope angle, restitution coefficients, and slope roughness. The programs modeled the proposed location, height and energy of the rockfall barriers, collectors, and rock bolts. Two manmade slope cuts studied and modeled utilizing the integrated techniques were to eliminate the risk of slope failures and rockfalls through the construction of remedial measures, this is the study objectives."

Jan 1, 2015