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By Omer F. Usluogullari, C. Vipulanandan

"It is critical to monitor the ground conditions during excavation and drilling of boreholes during construction to identify possible changes in the soil and rock formations. Drilled shafts are increasingly used as foundations to support structures, bridges and other facilities in geomaterials such as soft-rocks and hard clays. Locating the bottom of the borehole during construction with the required design strength is critical. Hence developing a simple device that could be easily adapted/used with the drilling tool was of interest in this study. Determining the shear strength of the geomaterial in the borehole and at various elevations including the bottom of the borehole can lead to better quality control of construction by identifying the various layers based on strength.In this study, a down-hole penetrometer (DHP-CIGMAT) was designed, built, calibrated and tested in the field to determine its effectiveness in measuring the strength of soil/soft rock in the boreholes. Based on limited field tests, linear correlations between geomaterial strengths and DHP-CIGMAT deflection have been developed. The DHP-CIGMAT can be used to identify soils and soft rocks.IntroductionIn-situ tests are increasingly used to determine the soil properties for geotechnical analysis and design of deep foundations (Ampadu and Arthur 2006; Hsu and Huang 1999). Static and dynamic penetration resistances have been used to classify and characterize subsoil (Ahmadi et al. 2005). The penetrometers evolved from the need of acquiring data on subsurface soils that could not be easily sampled by any other method. Laboratory testing undisturbed samples requires great care to avoid disturbance during handling, or systematical disturbance during testing, and it may be difficult to relate the laboratory test results to the in-situ properties of the soil (Sanglerat 1972). There is always a certain degree of disturbance to the samples because the confining pressures, which exist in the ground, are forcibly changed when the sample is collected."

Jan 1, 2017

By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017

By Masahiro Eguchi, Giuseppe Granata, Chiharu Tokoro, Hiroki Fukuda, Yuichiro Toba, Shungo Hobo

"Currently, large amounts of wastewater containing boron are discharged from industries like coal-fired power plants. Although coagulation-sedimentation is widely employed for their treatment, only a little consideration has been given to its mechanism. An additional problem is that the produced sludge has poor solid-liquid separation. This study is focusing on coagulation-sedimentation using magnesium, examining the mechanism and improving the solid-liquid separation. First, the co-precipitation with magnesium hydroxide was conducted against high-concentration boron wastewater with 500 mg/dm3as B. Second, in order to improve the solid-liquid separation by maintaining high reactivity, low-crystalline magnesium oxide was synthesized from magnesium carbonate by calcination at 400–700°C. It was tested as an adsorbent of boron and compared to co-precipitation with magnesium hydroxide. Co-precipitation showed high removal capacity. X-ray diffraction (XRD) of the sludge revealed the presence of other compounds besides magnesium hydroxide. This result suggests that other processes play a role other than simple adsorption on to magnesium hydroxide, and provides a plausible explanation for the observed high separability. As for the adsorption, the synthesized magnesium oxide immobilized as much or more amount of boron than co-precipitation. Furthermore, the results of fourier transform infrared spectroscopy (FT-IR) suggested the residual magnesium carbonate improved solid-liquid separability due to its poor solubility.INTRODUCTIONBoron is used in various industrial applications. In glass industry, the addition of a little amount of boron into glass products can enhance heat-resistance and chemical-resistance. Semi-conductor industry also employs boron as dopant for silicon. From these industries, large amounts of wastewater containing boron have been discharged. Additionally, coal-fired power plants have been recently discharging highly concentrated boron wastewater because the amount of boron contained in coal has been increasing due to a gradual decrease of the quality of coal. Since boron is partially proved to be toxic for animals, plants, and human beings (WHO, 1998),the guideline of the World Health Organization limit the boron concentration in drinking water to 2.4 mg/dm3(WHO, 2009).Because boron does not precipitate from solutions by simply changing the pH, the removal could be carried by operations such as adsorption or ion exchange. However, since ion exchange is an expensive operation with relatively low capacity, it is not suitable to treat the large amounts of wastewater produced by heavy industries like the coal-fired power plants. Therefore, coagulation-sedimentation method is still widely used as a suitable alternative way."

Jan 1, 2017

By Brian Wilson, Megan Atkinson, Richard Diggle, Nathan Sweeney

"Ruskin Dam, located near Mission, British Columbia, was constructed in 1929 and 1930 and comprises of a concrete gravity dam structure founded on bedrock. At the right abutment, which consists mostly of dense to very dense sands and silt, the dam abuts against overburden soils, and connects to a cutoff wall system consisting of sloping concrete slabs. Significant seepage and piping issues were encountered during first filling of the reservoir in 1930. In 2012, BC Hydro, the owner of the dam, awarded a contract for the construction of seepage control measures at the right abutment, including construction of a plastic concrete cut-off wall extending upstream of the dam, a plastic concrete seepage training wall extending downstream of the dam, tie-in of the new cutoff wall to the dam, consisting of jet grouting of the soils adjacent to the dam to allow for the construction of the special cutoff connecting the cutoff wall to the dam, and construction of additional jet-grouting ground improvement downstream of the dam.Integral to the upgrade was the requirement for the special tie-in cutoff wall, consisting of a highly flexible, impermeable membrane to connect the concrete dam to the new, 1 m thick plastic concrete cutoff wall. The tie-in extends vertically into bedrock through the dam and jet grout columns constructed adjacent and beneath the overhanging portion of the dam at the right abutment. The membrane is required to survive the anticipated earthquake induced deformation between the dam and the abutment soils.This paper describes the processes used to develop a material suitable to meet the specified flexibility and permeability criteria, as well as the innovative construction techniques utilized to construct the slot and place the bituminous material within it. The final dimensions of the slot were in the order of 7 m long by 25 m deep by 0.17 m wide. The bituminous material was placed under a head of water which was required to maintain stability of the slot, and was placed at temperatures in excess of 120 degrees Celsius."

Jan 1, 2017

"In response to mine head grades declining and orebodies becoming more complex, Glencore Technology has developed an alternative method for recovering economic minerals once leached into solution, rather than relying on conventional flowsheet options. The method involves the precipitation and separation of base metals from solution with limestone or lime. The final grade of these precipitate is not usually high enough to attract favourable terms of sale due to dilution from gypsum and sulphate salts. A set of operating conditions have been developed to allow the separation of the base metal precipitate from gypsum by exploiting the difference in particle size. A high-grade oxide product can be easily separated from the gypsum stream at very low cost. This process was originally developed by Glencore for zinc and copper systems. This paper reports on the successful application to nickel and cobalt, and this process has significant advantages over the incumbent precipitation process utilising magnesia.INTRODUCTION During evaluation of transitional and oxide zinc ore deposits during the 1990’s, Noranda Inc. (now Glencore) developed a sulphate based ore leach process to extract zinc into solution. For flowsheet development, conventional schemes dictated that once the zinc was dissolved in an acidified solution it was recovered by means of purification or solvent extraction followed by electrowinning and casting to produce zinc ingots. The deposits Noranda evaluated were high grade but had a relatively short mine life (10 years) and economic analysis showed that the projects couldn’t sustain the investment of a full zinc refinery. Compounding this problem was the lack of power supply infrastructure and the high power cost in the region. Noranda then evaluated alternative means of recovering zinc from solution. Laboratory testwork showed that a high-grade zinc precipitate (+50 wt% Zn) could be produced as an oxide, carbonate or sulphide by contacting acidified zinc sulphate solution with a number of reagents including soda ash, sodium hydroxide, and sodium hydrogen sulphide. Economic evaluation showed that the cost of the reagents are prohibitive, especially when the final product is still a metal intermediate (ZnO, ZnCO3 or ZnS). Noranda then continued to focus on fine zinc oxide precipitation for supply into the automotive tyre industry as this product would attract favourable terms of sale as a premium on Special High Grade (SHG) zinc."

Jan 1, 2017

By O. M. Arafat, J. A. Finch

"The Functional Performance Equation calculated from a plant grinding survey defines two distinct ball mill circuit efficiencies and how they relate to total production rate through the target grind size. The survey data are also used to calculate a complete ball mill size distribution model, represented by the energy specific grinding rates, not just through the target grind size, but through all the size classes. Cyclone separation performance is represented by individual size recoveries to underflow. When these two unit operation performances are entered into the circuit modelling program (Streamline™), along with the circuit feed rate and size distribution, all the circuit survey size distributions and mass flows are perfectly regenerated by the program. The many issues associated with the historical Epstein (breakage-selection) models are eliminated. Once the circuit program is populated, pump and cyclone performance changes can be evaluated using a step-by-step procedure in order to maximize Classification System Efficiency. Mill water use and media sizing opportunities are also diagnosed in order to maximize Mill Grinding Efficiency at the size of interest. An example is provided. This circuit analysis and modelling system, and related training, is provided through a web-based application. INTRODUCTION Since its development (McIvor, 1988), the Functional Performance Equation for ball milling has facilitated new understanding of industrial circuit cause and effect relationships, leading to significant strides in operational performance. Success stories of this refreshing approach to plant circuit performance improvement are now too numerous to list. Finch and McIvor (circa 1986) also discovered that the Functional Performance “Mill Grinding Rate” at the size of interest was the same cumulative grinding rate that is calculated from mill feed and discharge size distributions using a first-order rate equation. By calculating these cumulative grinding rates for all screen sizes, a complete ball mill model is generated (as used by Finch and Ramirez, 1981). Others in industry, Hinde and Kalala (2009), for example, have noted the same. Lacking the complexity needed to maintain their interest, most researchers have ignored this model, broadly opting instead for Epstein’s (1948) characterization of grinding as a chemical reaction, combining “selection rate” and “breakage size distribution” functions. The much simpler ball mill model presented here has previously been incorporated into a proprietary circuit modeling program (McIvor, 2005) and used for plant improvement work (for example, see McIvor and Finch, 2007, and McIvor, 2014). Now, by combining this extremely business-friendly ball mill model with optimization criteria from Functional Performance Analysis, a circuit modeling system (including the needed supplementary steps to assure successful plant implementation of circuit design changes) is at the disposal of every plant metallurgist, grinding equipment/material provider, and circuit designer."

Jan 1, 2017

"Real time analysis of conveyed bulk materials can be used to improve process performance by reducing variability and upgrading ore quality through selective removal of increments of flow that do not meet appropriate selection criteria. This paper focusses on proven Prompt Gamma Neutron Activation Analysis (PGNAA) and microwave transmission technologies used to representatively measure conveyed ore quality in real time so that meaningful decisions can be made between the mine and mill. This enables the effective removal by bulk diversion of small increments of conveyed flow such as waste, highly deleterious material or sub-economic material from the mill feed. Improved ore quality in plant feed optimises process performance, reduces processing costs and minimises tailings generation. Analysis is unaffected by particle size, dust, layering or segregation, mineralogy and belt speed. Technologies are explained and performance examples given from installations in copper and iron ore. The technology has been used successfully in bulk sorting for over twenty years typically using measured increments of a few minutes. Improvements in technology and calibration performance have resulted in accurate measurements over increments of thirty seconds and below.INTRODUCTION Ore quality variability exists on a number of scales. Block model grades represent a few hundred to many thousands of tonnes. Grade control at the mine occurs on a scale typically down to the size of a haul truck, which may be a few hundred tonnes. Highly variable ore quality is detrimental to process efficiency and effectiveness. Processing waste or low grade ore when higher quality feed is available represents a lost opportunity to generate higher revenues earlier in the operational life. Measuring ore quality accurately over short time increments during conveying enables small increments to be measured and diverted according to their quality. The paper explains the technology and benefits. Neutron irradiation techniques were considered potentially suitable for conveyed bauxite measurement by Beurton et al, 1995. Tran & Evans (2001) concluded there was no equivalent technology to Prompt Gamma Neutron Activation Analysis (PGNAA) in terms of material penetration power. PGNAA was evaluated by Nelson & Riddle (2003) for possible use in the phosphate industry and recommended its use for further characterisation of the mine’s various ore types to improve stockpile allocation and grade control. Cottle (2007) discussed test work for an iron sinter application and Delwig et al (2011) described the successful installation in 2009 and performance of PGNAA for base-to-acid ratio control in sinter feed with the analyser output used to control lime addition. Geoscan (PGNAA) works very well on iron ore and can “improve control over what is happening in the plant” and that comfort can be provided in knowing that the product is on-spec according to Minnett (2010). PGNAA is not yet used in the minerals sector for tariff purposes as has occurred since 2000 with Coalscan (PGNAA) in coal (Minnett, 2010)."

Jan 1, 2017

By Chaz Weaver, James Sheahan, Michael Mo

"The Virginia Department of Transportation (VDOT) undertook a program to replace four bridges along approximately 4 mi (6.4 km) of US 340 in Northwest Virginia. Two of these bridges, which span Compton Creek and the Norfolk Southern Railroad respectively, are the subject of this article. HDR provided roadway and structural design as well as geotechnical engineering services for the Norfolk Southern Railroad Bridge while their subconsultant, Saeed Associates, provided structural engineering services in support of the HDR roadway and geotechnical team for the Compton Creek Bridge.The project is located in the Valley and Ridge Geologic Province of Virginia, on an alignment that is adjacent to the Shenandoah River. The project lies within the Beekmantown Group consisting of limestone and dolostone that are prevalent and prone to karstic activity in a band that passes through the project area and north into Central and Eastern Pennsylvania. This area has been impacted by karst limestone conditions where caves and sinkhole activity is common. Caves at Luray and Front Royal, located to the south and north of the project, respectively, are popular public attractions.Since the potential for variability of subsurface conditions can be, and often is, greater in karst terrain, the need to develop a design that provides as much flexibility as possible during construction, and then to be prepared to efficiently review and respond to construction questions is heightened. Coordination and communication among the design staff, VDOT’s design and construction staff, and the contractor was a key factor in completion of this project.Compton Creek BridgeThe alignment for the new Compton Creek Bridge is located about 125 ft (38 m) west of the existing bridge, placing it between that bridge and the existing Norfolk Southern Railroad Bridge. No information about the foundations was available for the existing bridges. Borings in the Compton Creek valley encountered extensive voids (some clay filled and some open) with numerous boulders, rock ledges and pinnacles, particularly on the north side of the creek. Geophysical and geotechnical investigations indicated that below a poor and variable upper zone of rock was a layer of more competent and consistent limestone, which appeared to contain little or no voids."

Jan 1, 2017

By M. Buxton

"Advanced data acquisition and process modelling technology provides online data and decision support about different aspects of the resource extraction process. Real-time approaches have recently been applied to utilize the value of this information for improved production control in mineral resource extraction in different operational set ups including coal, polymetallic ore and gold deposits. The key concept of these approaches promotes the change in paradigm from discontinuous intermittent process monitoring to a continuous process and quality management system in the resource extraction process. The framework includes a real-time feedback control loop that rapidly links online material characteristics data acquired during extraction at the mining face, during material handling and processing with a sequentially up-datable resource model. This will allow near real-time optimization of decisions related to long-term planning, short-term sequencing and production control. The contribution reviews recent developments in the three main constituents sensor based material characterisation, rapid updating of grade control models and simulation based optimization for improved production control. Technological readiness is assessed and critical gaps for further technology development are identified. The value added is illustrated by means of selected case studies. INTRODUCTION With the depletion of known and established mineral reserves, the decrease in head grades and the continuing demand of mineral raw materials by the modern society, future exploitation will move towards extraction of deposits under geologically more complex conditions. Complex deposits are characterized by a low continuity in grade, presence of deleterious elements such as arsenic and high irregularity in the geometry of the ore boundaries. The profitable exploitation of such deposits becomes significantly more challenging. To be able to better utilize such unconventional mineral resources of the future, smart autonomous mining systems are needed, which integrate local exploration of spatially varying material characteristics in–situ and have the ability to follow and extract the pay zones in the ore body while minimizing dilution (Buxton and Benndorf, 2013). The main barriers to overcome for the successful economic exploitation are: • effective grade control which will maximize resource potential along the whole value chain, • minimization of handling zero-value material introduced by dilution, thus • reducing unnecessary expenditure of energy and financial resources and • management and control of the geological uncertainty due to limited information available,"

Jan 1, 2017

By Pierre-Yves Declercq, Andre Vervoort

"After the mass closures of entire coal mine districts in Europe at the end of the last century, a new phenomenon of surface movement was observed—an upward movement. Although most surface movement (i.e., subsidence) occurs in the months and years after mining by the longwall method, surface movement still occurs many decades after mining is terminated. After the closure and flooding of underground excavations and surrounding rock, this movement is reversed. This paper focuses on quantifying the upward movement in two neighboring coal mines (Winterslag and Zwartberg, Belgium). The study is based on data from a remote sensing technique: interferometry with synthetic aperture radar (INSAR). The results of the study show that the rate of upward movement in the decade after closure is about 10 mm/year on average. The upward movements are not linked directly to the past exploitation directly underneath a location. The amounts of subsidence at specific locations are linked mainly to their positions relative to an inverse trough shape situated over the entire mined-out areas and their immediate surroundings. Local features, such as geological faults, can have a secondary effect on the local variation of the uplift. The processes of subsidence and uplift are based on completely different mechanisms. Subsidence is initiated by a caving process, while the process of uplift is clearly linked to flooding. INTRODUCTION After the mass closures of entire coal mine districts in Europe at the end of the last century, a new phenomenon of surface movement was observed—upward movement in the area above the past exploitation and in the immediate surroundings. Of course, most surface movement (i.e., subsidence) occurs in the months and years after mining by the longwall method (Peng, 1986). This downward movement continues to occur at a smaller rate many decades after mining has been terminated when the water in the underground excavations is pumped to the surface. This is the case as long as a mine is in operation. However, after the closure and flooding of the underground excavations and the surrounding rock, this movement is reversed, and the surface is uplifted. A total uplift of about half a meter has been recorded to date. This phenomenon has been described in several different coal basins in Europe, for example, in Belgium (Devleeschouwer et al., 2008), France (Samsonov, d’Oreye, and Smets, 2013), Germany (Baglikow, 2011), the Netherlands (Caro Cuenca, Hooper, and Hanssen, 2013), and Poland (Preusse, Kateloe, and Sroka, 2013). To date, research has focused mainly on understanding the phenomenon (e.g., Herrero et al., 2012) and identifying general trends, whereby the link with the rise in water levels is an important issue (Caro Cuenca, Hooper, and Hanssen, 2013). The most accepted explanation is linked to the swelling of clay minerals in the argillaceous rocks in the coal strata (Herrero et al., 2012). Without doubt, the full explanation is complex, and swelling is probably not the only cause of the residual movement. Most coal strata rock is weakened upon contact with water. The increase in water pressure also results in a decrease in the effective stress. Both aspects facilitate the fracturing of rock, which normally would result in further subsidence. However, decreases in the effective stresses also result in the relaxation or expansion of the rock, which induces an upward movement (Fjar et al., 2008). All of these aspects, including the long-term residual subsidence due to compaction under dry conditions, result in a net upward movement. The phenomenon discussed here is clearly different from the upsidence, sometimes observed on other continents (e.g., in Australia, Galvin, 2016). When upsidence occurs, the rock near the surface bends and buckles upwards due to the overstressing of the floors of the valleys."

Jan 1, 2017

By Sedat Esen

"This paper presents a critical review of the fragmentation data obtained from some large open pit copper and gold mines. Database ncludes 35 mines with Uniaxial Compressive Strength values ranging from 19 MPa to 227 MPa (2756 psi to 32923 psi). Variation in the fragmentation data and the causes are discussed in detail. Quality assurance/quality control (QA/QC) in drilling and blasting was shown to have significant impact on fragmentation. In addition, controllable blast design parameters including drill pattern, powder factor, blast timing, stemming length, etc as well as the large blast sizes havesignificant potential to improve fragmentation. Feed size requirements of crushing and grinding circuits were discussed in detail. The paper discusses the effects of different size fractions (top size, 80 %passing size and % passing 10 mm (0.5 in)) on the downstream processes and the role of the fragmentation model in the mine to mill process. Blast domains based on rock strength and structure canbe established by using a fragmentation model which is calibrated using measured fragmentation data. This allows the blast engineer to compensate for changing rock characteristics and stabilize the ROMfragmentation size and result in increased crusher and mill throughput. Two case studies were presented to demonstrate the benefits achieved in downstream processes. Main benefits were reduced downtime at crusher circuits, improved mill throughput as well as reduced total operating cost. A simple relationbetween uniaxial compressive strength and powder factor was proposed using the database for the optimized mines as a guideline to allow site engineers to compare their sites against the other sites."

Jan 1, 2017

By J. Sjöberg, T. Savilahti, S. B. Umar

"Sublevel caving in Malmberget mine results in mining-induced surface deformation. One of the currently mined orebodies is the Printzsköld orebody. As mining deepens there is need to assess the behaviour of the cave formed in the subsurface above this orebody. Numerical analysis was used to assess the effects of extraction to deeper levels and perform strength parametric studies. Stress redistribution was studied, and the results showed high stress buildups in the hangingwall and the crown pillar. Two failure mechanisms have been identified – shear and tensile. Reducing cohesion by 50% increased the area of the yielded zone by more than 100% in the hangingwall.IntroductionThe Malmberget mine is owned and operated by the Luossavaara-Kiirunavaara AB (LKAB) mining company. Iron ore is extracted by large-scale sublevel caving. The mine comprises a total of 20 orebodies, about 10 of which are in production today (Figure 1). The mine is located in the municipality of Gallivare, about 100 km north of the Arctic Circle (Figure 2).Successful sublevel caving requires progressive caving of the orebody after initial blasting. This results in caving of the hangingwall, sometimes all the way to surface, resulting in surface deformation. As mining progresses to deeper levels a larger area is affected by deformation. Over the years, extraction from the Malmberget orebodies has led to deformation of the ground surface, affecting residential areas and existing infrastructure.Forecasting the caving process is not straightforward as it can be rapid or slow, depending on the rock mass conditions, stress conditions, the failure mechanisms at work, etc. Moreover, several of the orebodies in Malmberget are non-daylighting, which makes reliable caving analysis even more difficult, primarily since there is less available experience from such cases. The present study was designed to improve the understanding of the caving and deformation mechanisms at Malmberget, and in particularly for the Printzskold orebody"

Jan 1, 2017

By S. Bhattacharaya, S. Aich, B. K. Nandi

"At present scenario, there has been an increasing demand in the usage of blend coal in power sector; regardless of how, specific knowledge on burning and ignition characteristics and their interactive effects is stingy. In this work a detailed investigation was therefore taken up to study in detail the combustion characteristics of selected coal samples and their blends. Certain parameters were believed to have significant effects on combustion characteristics of individual coal and their blend. Major parameters identified for this purpose included proximate analysis, combustion conditions, heating rate, reaction regions, blending ratios, ignition condition, reactivity (or reaction rate) and burnout temperatures. With the help of these parameters, thermal features and reaction kinetics of the individual and blended samples were investigated through a qualitative and quantitative thermo-gravimetric analysis of two different individual coals and their blend carried out in an oxygen atmosphere from ambient to 800 0C at a constant heating rate of 10 K/min. A significant difference in terms of rate of mass loss with temperature correlated from Arrhenius expression along with coal-coal blend interactions and deviation from their expected behaviour, have been observed between the kinetics of individual and blend samples, the latter showing better ignition performance and comprehensive combustion phase. It was also found that particles having the lowest percentages of volatile matter and ash could possibly be blended with particles having high ash and volatile matter to meet the required burning condition which can be effective in terms of cost savings, improved fuel economy, reduced undesirable exhaust emissions and improved safety of coal burning equipment. Experimental results further indicated that individual samples and coal blend samples have different combustion features in terms of residue left, peak temperatures and activation energies. Thermodynamic activation parameters such as activation energy, pre-exponential factor and order of reaction were computed from the thermal data using the modified form of non-isothermal methods. INTRODUCTION Coal has been the most significant source of energy for India and would remain so at least for the next few decades. About 60-65% of the electricity produced in India is from coal fired power plants. Indian coal is of drift origin and of high ash content. Ash content of the coal burnt in power plants in India is in the range of 30-45%, most of it being Run-of-Mine coal. Most of the power plants in India source their coal from number of mines, most common being multiple sourcing. Usually coal from each source [1] is burnt separately. For various reasons mostly associated with logistics, burning of blended coal is rarely practiced. Blending of coal is practised mainly for improving the quality of available coal and meets the shortage of coal supply. Blending technique is generally practised in power industries to reduce the cost of power generation along with mitigating combustion performance or slagging problem ensuring consistency in as fired coal quality and also for environmental compliance. Blending good quality imported coal can improve coal quality and helps in preserving indigenous coal resources for longer period [2]. Use of blended coal shall reduce load on all boiler components (Mill, CHP, Boiler, AHP) & reduce O&M cost and increase the availability. The main purpose of blending is to get a blended as fired coal having ash, volatile matter and gross calorific value close to design coal and the two coals are to be blended in such ratio proportions that resultant coal blend have desired ash, volatile matter and gross calorific value [3]. For a coal to be blended certain parameters have to be considered to get compatibility with respect to combustibility ( Burn ability) of coal, grindability ( HGI), ash fusion behavior, swelling characteristics of coal, need to be checked"

Jan 1, 2017

By J. Y. Lee, J. Kang

"A selective chlorination process using cuprous chloride (CuCl) was investigated for producing high-grade chalcocite (Cu2S) from chalcopyrite (CuFeS2) feed. The chalcopyrite feed was reacted with CuCl in the presence or absence of sulfur (S) at temperatures between 900 and 1,100 K for five hours under an argon gas atmosphere. The experimental results indicate that iron (Fe) was selectively removed from the chalcopyrite feed as ferrous chloride (FeCl2) at 1,100K and the mass percentage of Fe thus decreased from 31.5 percent in the feed to less than 0.05 percent in the residue, under certain conditions. As a result, high-grade Cu2S was obtained from chalcopyrite in a single step. This new selective chlorination of chalcopyrite using CuCl as a chlorinating agent is therefore feasible for producing high-grade Cu2S.IntroductionCurrently, blister copper (Cu) is commercially produced from sulfide ores by pyrometallurgical methods. These methods entail matte smelting and converting, with the removal of iron (Fe) and sulfur (S) as slag — mainly Fe2SiO4 — and sulfur dioxide (SO2) gas, respectively.In the pyrometallurgical method, as shown in Fig. 1 (Schlesinger et al., 2011), Fe is removed through two steps at high temperatures of around 1,500 K to reduce the loss of Cu during slag formation. However, the slag still contains 1 to 8 percent Cu. Therefore, Cu in the slag is recovered by slag treatment processes, after which the concentration of Cu in the slag decreases to around 0.4 to 1.3 percent. Although Cu is recovered, the slag that had undergone the treatment processes is difficult to use as a feedstock for ironmaking owing to the small amount of Cu remaining in the slag (Schlesinger et al., 2011).In addition, large amounts of SO2 gas are generated by the oxidation of S in the current Cu production process. The SO2 gas generated is captured and used to produce sulfuric acid (H2SO4). However, despite the development of SO2 gas-capture technologies, the emission of SO2 gas is still a problem in terms of environmental considerations.Several studies had been carried out in the past to overcome the drawbacks of the current process. The extraction of Cu from sulfide ores using a chlorination process is one alternative that had been investigated by several researchers. Most chlorination processes used chlorine gas (Cl2) as a chlorinating agent at temperatures between 573 and 1,023 K under an inert atmosphere (Donaldson and Kershner, 1962; Olsen et al., 1973; Kumar, Li and Warren, 1985, 1987; Kanari et al., 1999; Kanari, Gaballah and Allain, 2001)."

Jan 1, 2017

By Lars Richter, Franz-Werner Gerressen

"The Eglinton Crosstown Line was conceived as the Eglinton Crosstown LRT, a partially underground light rail line, announced in 2007 as part of the Transit City plan, which included the implementation of six other light rail lines across Toronto.There were 43 stops planned for the Eglinton Crosstown LRT, 13 of which would be underground . For those underground stations a lot of specialty foundation works needed to be carried out. King piles, soldier piles with lagging and secant piles were mainly required fulfilling the tasks of installing the retaining wall system.The paper will focus on the original design and alternative solutions, discussing the benefits and limits of these. It will also explain the installation process in general as well as some specific features related to specific site conditions, e.g. limits in installation depth, soil characteristics etc. The required equipment will be explained showing the benefits and limits.INTRODUCTIONThe Eglinton Crosstown project is a 19-kilometre LRT line that will bring much needed relief to the transit woes of Torontonians. Traversing the city in an east-west slice across the midtown artery of Eglinton Avenue, the Crosstown rail line involves a combination of 15 underground stations and 10 atgrade surface stops. It is one of the largest transit infrastructure projects under way in North America today. Aecon has joined partners ACS Infrastructure Canada, Ellis Don, and SNC-Lavalin to form Crosslinx Transit Solutions (Crosslinx).As with many of today’s mega public transportation projects, the Crosstown LRT follows the Public- Private Partnership (P3) model. Aecon is an equal partner in the $5.3-billion Crosslinx consortium to develop the Eglinton Crosstown LRT project in Toronto. Upon the LRT's completion in 2021, Metrolinx, the region’s transit authority and also the project client/owner, will turn to the Toronto Transit Commission (TTC) to operate it. The impact of this highly anticipated LRT line on commuters in the Greater Toronto Area (GTA) is expected to be dramatic and immediate once the first train leaves the station five years from now. In fact, Metrolinx is estimating that within its first 10 years of service, the Crosstown line will be carrying 5,500 passengers per hour (in peak direction) and making 100 million passenger trips annually."

Jan 1, 2017

By Anuj K. Singh, Shuvranshu Rout, Manos De

"Foundation for tracks of coke transfer car and dust extraction pipe was designed as series of isolated foundations spaced at 11.0m along length of coke oven battery resting on soil at depth of 2.5m. In one region the foundations are close to adjacent 12m deep underground junction house. Five foundations in this zone were constructed on backfilled soil without proper compaction instead of engineering soil fill or concrete fill. The foundations settled under loads and the supported frame structure tilted after equipment erection and during trials endangering the safety of the structure and equipment operation. The distorted structure had to be rectified in-situ by arresting settlement. In order to stabilize the foundation and supported structure the supporting soil had to be strengthened in situ without any dismantling, reconstruction and adverse effect to equipment operation. This paper presents the case study on the evaluation of defects for the foundation failure and analysis of the problem, proposed rectification of the situation by appropriate soil stabilization scheme, monitoring of the stabilization operations and verification of effectiveness of the rectification work by measurement of settlements. The implemented solution has ensured safety of the structure and equipment without any adverse impact on normal operation.INTRODUCTION AND BACKGROUNDNew Coke Oven Battery was being installed for an integrated Steel Plant. The hot coke from oven is pushed out after completion of coking process through a coke transfer car onto a hot coke receiving car. The coke transfer car runs on rail track parallel to the line of ovens forming the coke oven battery. One rail is supported on the structure of the operating platform of the battery and the second rail rests on independent structure of track beams. A large diameter pipe for extraction of the dust emitted during coke pushing operation is also supported on the same structure that supports the track beams. The entire structure rests on columns spaced at approximately 11.0m along the length of the battery. The columns transfer load to ground through individual foundations resting on competent subsoil strata.Two sets of foundations for the rail track beam support and dust extraction pipe support are adjacent to deep underground junction house of coke carrying conveyor. The depth of the pit for the junction house is 12m. The layout and arrangement of the foundations in this region around the junction house (JH-1) is shown in the “Figs. 1a, 1b”."

Jan 1, 2017

By M. R. Haibach, M. L. Shema, J. M. Silvis

"Since 2005, longwall coal mine operators in Pennsylvania (US) have been required to collect extensive hydrologic and biological data to document pre- and post-mining conditions of aquatic resources (streams and wetlands) overlying the subsidence control plan areas. Continued operation of the longwall mine is dependent upon empirical data demonstrating that the undermined aquatic resources have either been maintained or restored to an accepted range of pre-mining conditions. This study used quantitative hydrologic methods and comparative biological metrics to examine response of aquatic resources to longwall subsidence at the Bailey Mine located in Greene County, Pennsylvania. This study analyzed data from over 25 miles of streams and over 8 acres of wetlands that traverse the 4,779-acre study area. Hydrologic analysis of flow intermittency suggested that there are variable degrees of change to headwater streams immediately following mining; however, the majority of the effects are reversible through streamflow mitigation measures. Furthermore, the post-mining discharge from streams can be restored to within the range of pre-mining conditions the majority of the time. Biological assessments showed that greater than 95% of assessed stream length has maintained its ability to support benthic macroinvertebrate communities following mining and intervention (i.e., mitigation). Comparative metrics of the benthic macroinvertebrate communities showed that the biological community in 48 of the 50 sample sites is being maintained or restored across both high- and low-gradient streams. The effectiveness of intervention was further substantiated by the similarity in recovery times between streams having no intervention (median = 2.1 years, 95th percentile = 4.9 years) and streams with intervention, when recovery times were measured from the date of the intervention (median = 1.7 years, 95th percentile = 4.7 years). Changes to individual wetlands were observed between the pre- and post-mining assessments, but cumulatively a net gain of 7% in wetland acreage was realized. Hydrologic assessments were used to infer whether there was a potential that streams had been affected by mining; however, the ultimate test of stream recovery is based on biological metrics that establish the relative quality of the biological communities following mining. Overall, the hydrologic balance is being protected and the aquatic life use of streams is being maintained within the Bailey Mine’s subsidence control plan areas."

Jan 1, 2017

By J. Zollinger, J. R. Kennedy, J. H. Park, D. Daloz

"In order to improve the properties of cast Ti-Al alloys to replace Ni-based superalloys past the low pressure stages of aircraft engines investigations into inoculation for grain refinement were carried out. Previous work showed isomorphic self-inoculation using Ti-Al-Nb particles was effective for grain refinement, however the relatively fast diffusion of Nb in Ti-Al make it difficult to observe the mechanism of nucleation. An alternative alloy was developed in the Ti-Ta system for isomorphic self-inoculation, maximizing the Ta content to improve the particles survivability in the melt. The powder processing produced comparatively small inoculant particles which dissolved, however larger particles were seen to survive solidification. The density difference between the inoculant particles and melt resulted in an inhomogeneous mixing of the particles and the melt with larger particles found near the outer edges of the ingots. Variations on particle size and interaction time between the inoculants and the melt resulted in the Ti-Ta inoculant reducing the as-cast equiaxed grain size by a factor of two compared to non-inoculated samples as well as increasing the equiaxed fraction in the ingot.INTRODUCTION Lightweight metals are of particular interest in aerospace applications. The hot sections of turbines are dominated by blades made of nickel based superalloys. Recently the GEnx turbine introduced TiAl blades in the last low pressure stage of the turbine to reduce weight and improve fuel efficiency (Kim & Dimiduk, 1991). In order to carry these benefits deeper into the turbine the high temperature (>800oC) properties of the alloys must be improved. Current grain refinement methods to improve properties rely on boron additions which may not be applicable for all blades as brittle precipitates may be formed during processing (McCullough, Levi, Mehrabian, & Hyman, 1991). A novel grain refinement process was previously introduced called “isomorphic self-inoculation” using Ti-Al-Nb particles to successfully grain refine TiAl (Kennedy, Zollinger, Bouzy, & Daloz, 2016). In order to better understand the mechanism of this process an investigation was carried out using the same process but with a Ti-Ta alloy which is more stable in the TiAl melt than the Ti-Al-Nb."

Jan 1, 2017

By Fernando J. A. S. Barriga

"Recent concerns over the availability of many mineral raw materials, and newly available technological developments, produced renewed interest in deep-sea mining. However, environmental concerns, with variable degrees of justification, are raising opposition to the concept. The forecast for the behavior of consumption versus availability of many raw materials, nearly all critical metals, arguably show that consumption will grow much faster than resource discovery onshore. Finding new sources of raw materials seems inescapable. The deep seafloor stands out as the only likely candidate.Sea Floor Mining and the EcosystemMarine mining has already started, decades ago, for diamonds, currently up to depths near 400m. Although the industry recognizes there is a footprint, it considers the footprint quite minor, because the area mined is small: in Namibia, where offshore diamond mining is now 70% of the country’s total, only 3% of the concession of 3,700 sq miles (9600km2) have been mined. As plans to mine deep-sea massive sulphide deposits and polymetallic nodules progress, the environmental concerns grow. Some of these concerns are as follows:?The deep-sea ecosystems are composed of long-lived species, with low rates of reproduction. The environment may not recover from mining on a human time scale;"

Jan 1, 2017

By G. Ofori-Sarpong, A. -S. Adam, R. K. Amankwah

"In the application of the BIOX® technology, high tailings grade (2-16 g/t) may be generated with a decrease in overall gold recovery, which sometimes make it economically unattractive. This paper investigated the causes of the high tailings grade by using samples from the Bogoso BIOX plant. Partial chemical analysis, diagnostic tests and cyanidation optimisation studies were conducted to invoke understanding into the high tailings grades. Diagnostic study on the tailings showed 48.34% of gold in carbonaceous matter, 17.12% in quartz, 13.40% as liberated gold, 11.51% imbedded in sulphides and the remaining 9.65% in carbonates. Optimum cyanidation recovery of 90.4% was established for the BIOX concentrate at 7 kg/t NaCN, 40-50 g/L activated carbon and residence time of 40 hours. The recovery was sensitive to carbon and cyanide concentrations but additional cyanide was not economical. High preg-robbing indices of 72.7% and 64.4% were recorded for the BIOX product and the flotation concentrate respectively. This confirms the inability of the BIOX process to deactivate carbonaceous matter, which remains a serious precursor for low overall gold recoveries and high CIL tailings. INTRODUCTION Gold ores may be broadly classified as refractory and non-refractory. Non-refractory ores are easy to treat but refractory materials require complicated flowsheets for metal extraction (Hausen and Bucknam, 1985; Schmitz et al, 2001; Marsden and House, 2006). As near surface non-refractory gold deposits are getting depleted, the increasing price of gold and increasing demand for gold, have encouraged many gold producing companies to treat refractory ores for gold recovery. The refractory behaviour of these ores may be due to the presence of sulphides, tellurides, cyanicides and/or carbonaceous matter. Refractory ores do not respond well to conventional cyanidation as the gold is either occluded by or in solid solution in sulphides, or is in association with cyanicides (Marsden and House, 2006). Further, carbonaceous matter preg-robs gold during leaching (Osseo-Asare et al, 1984; Hausen and Bucknam, 1985; Schmitz et al, 2001). The two major causes of refractoriness are the presence of sulphides and carbonaceous matter, and these render the ore double refractory (Nyavor and Egiebor, 1992). Oxidative pre-treatment processes such as high pressure leaching/oxidation; biological oxidation, ultra-fine grinding and roasting are required to render refractory ores amenable to conventional cyanidation (Marsden and House, 2006). Biological oxidation, however, has become the preferred pre-treatment route because it is more environmentally friendly and convenient even where only partial oxidation is required. Comparative tests have demonstrated that bioleaching can achieve the same or better results than roasting or pressure leaching in terms of gold recovery (Yannopoulos, 1991; Brierley, 1997). Further, biological treatment processes are more cost-effective, environmentally friendly and safer."

Jan 1, 2017