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By T. Grammatikopoulos, C. Gibson, M. Aghamirian

"Lithium is a silver-white alkali metal that has recently become a target commodity for many junior mining companies. Lithium has a wide range of applications including ceramics and glass, lubricating greases, air treatment, continuous cast mold flux powders, polymer production, and primary aluminium production, but the current popularity of lithium can be attributed to an anticipated increase in demand for lithium ion batteries. The most common lithium-bearing minerals occur globally in pegmatites and granites. Spodumene [LiAl(Si2O6)] is the most desirable economic lithium-bearing mineral due to its high lithium content (theoretical Li2O content of about 8 wt%). However, lithium can also be hosted in petalite, micas, tourmaline, and phosphate minerals. In Canada there are a number of spodumene deposits in Ontario and Quebec at development stage that have the potential to help narrow the forecast lithium supply gap stemming from the widespread acceptance and use of electric vehicles. This paper discusses the beneficiation of hard rock lithium deposits, including an in depth review of the use of flotation to upgrade spodumene. A review of the use of dense media separation (DMS), magnetic separation, and roasting as means to process spodumene bearing ores is also discussed. INTRODUCTION Lithium is a soft, silver-white alkali metal with atomic number 3. As of 2015, the end use of lithium was estimated to be as follows: lithium-ion batteries (35%), ceramics and glass (32%), lubricating greases (9%), air treatment (5%), continuous casting mould flux powders (5%), polymer production (4%), primary aluminium production (1%) and other uses (9%) (Jaskula, 2014). Lithium is found in brine lake deposits containing lithium chloride and in hard rock pegmatite deposits. It can be sold in a range of product types; as mineral concentrate, brine, compound (lithium carbonate or lithium hydroxide) and metal depending on its intended end use (Goonan, 2012; Jaskula 2014). In the 1990s the United States and Chile were the largest producers of lithium globally, primarily from brine operations (Ober, 1994). Most of the lithium compounds produced over this period were consumed in the glass, ceramics and aluminium industries. In the 1980s and 1990s there were two major lithium operations in the United States: brine operations at Silver Peak, Nevada, and a spodumene mine and lithium carbonate/lithium hydroxide plant in Kings Mountain, North Carolina. The Kings Mountain operations ceased production in 1991 and were eventually dismantled in 1994. Brine operations were also active in Argentina and Chile, while the largest lithium ore deposit in the world was operated at Greenbushes, Western Australia. During this period it was predicted that major shifts in demand for lithium would come from the success and widespread use of electric vehicles (Ober, 1994)."

Jan 1, 2017

By Donald R. Clark

"Drilled shafts are being used as foundation support for parabolic solar troughs at the Genesis Solar Project being constructed near Blythe, California. Three types of drilled shaft foundations are required for the project. At project build-out, there will be a total of 23,008 drilled shafts installed at the site. Preliminary designs for the axial and lateral capacity of the drilled piers were based on conventional geotechnical engineering methodologies and soil-structure interaction. The drilled shafts and subsurface conditions were modeled through the use of the computer program LPILE v6.0.Conducting lateral load testing of drilled shafts was considered appropriate to confirm or modify the geotechnical parameters used in the preliminary design. The lateral load testing program was conducted to provide site-specific test data that would allow the design engineers (both geotechnical and structural) to predict the actual performance and adequacy of the proposed drilled shaft foundations and improve the efficiency and hopefully reduce project costs.The lateral load testing was conducted within two solar fields at the site. Three pairs of drilled shaft foundations were installed in each field, instrumented, and laterally loaded to determine load-deflection response. A value-engineered option, proposed by one of the drilled shaft contractors, was also load tested. The results of the load-deflection data obtained in the field was used to modify the soil modeling used in the original L-PILE analyses and adjust the production drilled shaft lengths.Based on the results of the lateral load testing, the in-situ moduli of the subsurface soils were significantly increased over that assumed in the preliminary analyses. Based on the final soil-structure interaction analyses, the preliminary drilled shaft lengths were reduced by 2 to 2-1/2 feet. This resulted in an overall reduction of 55,654 feet of drilled shaft construction on the entire project, a savings of approximately 16.5% over the preliminary"

Jan 1, 2017

By Andrew Rietz, Yu Bao, Steven Halewski

"HP-Pile foundations are the most favorable type of foundations for bridges because of their constructability, versatility with regard to subsoil conditions, and settlement controllability. For many years, bridge engineers have puzzled over the most economical way to orient HP-Piles: Should the strong axis be oriented in the longitudinal direction or in the transverse direction? The accurate design of foundations may considerably reduce construction costs. In order to answer this question, 3-D finite element models will be set up to analyze the effects of pile orientation on bridge behavior. Because seismic loading usually controls the structural design in seismic zones, it is important to investigate the effects of pile orientation under such loading. HP-Piles are designed conservatively due to the uncertainty of the dynamic soil-structure interaction during earthquakes. For the bridge substructure, the soil’s stiffness plays an important role in load distribution as the soil and piles act as a combined system to resist the seismic loading. The dynamic soil-structure interaction mechanisms of bridges in both the longitudinal and the transverse directions will be investigated through the use of 3-D finite element models. The numerical models will realistically simulate the soil-pileabutment- wingwall-superstructure system subjected to seismic loads. Nonlinear soil springs will be employed to model the non-elastic soil behavior. The analysis will provide theoretical support to the design practice.IntroductionAs sustainability has asserted itself in the public’s eye, bridge professionals have rushed to develop criteria for sustainable bridges. The three main categories that define and distinguish sustainable bridges are: lower energy input, increased durability, and simplified deconstruction. By optimizing the structural members, the engineer is able to reduce the material quantities for the bridge, effectively reducing the energy input for the bridge (Hunt; Whittemore). A deeper understanding of soilfoundation- structure mechanism will facilitate sustainable bridge design by lowering energy input and increasing the service life of bridges (Rietz et al.)."

Jan 1, 2017

By John A. Rusnak

"This paper discusses the variation of coal strength based on the megascopic coal lithotypes for Central Appalachian high-volatile A coal beds. The composition of coal beds is complex and variable, depending on the depositional environment associated with original plant material, inflow of clastic material, and water level fluctuations in the original swamp/mire environment. Thus, different types of coal and sediment are formed within each coal bed. These differences in coal composition were first classified by Marie Stopes, a paleobotanist, in 1919. The classic coal megascopic lithotypes are vitrain, clarain, and durain, which correspond to bright, bright banded, and dull coal, respectively. Stopes also identified that the lithotype fusain, which is mineral charcoal, has no inherent strength and can act as a plane of discontinuity. In this study, two other coal-bed lithologies are also considered—bone and carbonaceous shale. This makes for a comprehensive suite of coal-bed stratigraphic components apart from rock partings. A total of 1,000 uniaxial compressive strength (UCS) and 440 indirect tensile strength (ITS) tests were conducted on cores from southern West Virginia that were specifically logged and described using the megascopic coal lithotype nomenclature. Statistical analysis is presented showing the results for each lithotype group with mechanical properties correlated to the lithotype. Previous studies have analyzed the mechanical breakage properties associated with coal lithotypes, which correlate well with these results. However, coal rank does appear to be a contributing factor, and this study is confined to only high-volatile A bituminous rank. Application of these results would be well suited to a rock mass classification system to address coal pillar rib stability. This would allow for rib support design and implementation to consider relative coal strength by visual observation of the seam stratigraphy through ongoing observations within a mine. Changes in seam composition can be readily identified, allowing the adjustment in rib support design. Another application would be for the determination of numerical modeling inputs based on detailed seam stratigraphy. However, these results, even with the standard strength reduction criteria, may not be applicable to currently accepted empirical coal pillar design procedures."

Jan 1, 2017

By J. Y. Foley, K. Eden, A. E. Grosz, C. J. Giles, J. E. Grosz

"Portions of the Icy Cape placer Au district have been described and exploited since the early 1900s. Industrial studies of Au-bearing garnetrich intervals established a 3.5 million troy ounce resource in the western half of the district. This estimate is not compliant with CIM and SME definition standards for Mineral Resources and Mineral Reserves. We note high variability in the textures of sediments and their heavy mineral (HM) content and composition in the district, probably as a function of the depositional environment. Sediments are medium- to fine-grained sands with a valuable HM assemblage that averages 26.0% in a range of 1.1– 72.6%. Valuable heavy minerals (VHMs) garnet, magnetite, ilmenite, rutile, and zircon, but excluding Au, average 7.9% in a range of 1.0–37.6% of the HM assemblage. Trace quantities of uraninite, thorite, monazite, xenotime, and others are noted. Garnets have an average Y content of 726 ppm with a range of 0–2150 ppm. Energy-dispersive X-ray fluorescence confirms compositions commensurate with Ca, Al, and Mg silicates. We provide empirical analytical data and note high variability in the textures, HM content, and compositions as a probable function of depositional environment. Icy Cape District land and resources are owned by the Alaska Mental Health Trust Authority and managed by the Trust Land Office (TLO). IntroductionThe Icy Cape Heavy Minerals (HM) District in Alaska subtends more than 200 km2 fronting the Pacific Ocean and backing to the foot of the Robinson Mountains at about 1700 m above sea level. We classify the district into geomorphic provinces; the eastern region as deltaic (Figure 1) and the western region as coastal plain (Figure 2), based on geomorphologic expressions. The coastal plain is entirely built up of unconsolidated outwash sediments and ancient beach sand deposits."

Jan 1, 2017

By L. A. Cisternas, R. I. Jeldres, D. Calisaya

"Flotation of copper-molybdenum sulphide ores in seawater entails critical challenges such as selective recovery of molybdenite, effective pyrite depression, and reducing the lime addition required to reach highly alkaline conditions. It is essential that laboratory flotation tests aimed at solving these problems give reliable, reproducible results and indicate the correct approach for industrial operations. Rougher flotation of coppermolybdenum sulphide ores in seawater was investigated using two different cells: a modified Denver cell and a standard commercial cell. The effect of an organic reagent on the flotation performance was tested, and the fast/slow-floating model was used to describe the results. The modified Denver cell significantly improved the reproducibility of the flotation test results, due to technological enhancements such as the impeller being driven from below without a stator, which enables the whole froth surface to be scraped with a paddle at a constant depth and rate. Organic reagents are a promising alternative to inorganic reagents for depressing pyrite in seawater. However, further studies should be conducted to investigate their impact on molybdenite recovery, as well as to evaluate the possibility of depressing pyrite after molybdenite separation. The fast/slow-floating model was found to be appropriate for describing the flotation kinetics of the copper-molybdenum ores. The parameters are useful for comparing the performance at different conditions. IntroductionOwing to the increasing scarcity of fresh water, the use of seawater mining and mineral processing is becoming increasingly important (Cisternas and Moreno, 2014). Seawater can be desalinated by reverse osmosis, but this involves considerable costs, limiting it to the big mining companies (Akgul et al., 2008; Leidner et al., 2012; Ghaffour, Missimer, and Amy, 2013). Furthermore, desalination has environmental consequences (Lee, Arnot, and Mattia, 2011); for example, a desalination plant designed to process 2.5 m3/s requires an electrical energy supply of around 30 MJ/s. To supply this power demand, a thermoelectric plant burning bituminous/sub-bituminous coal mixtures at a thermal power generation efficiency of 35% might release around 1200– 1500 t of CO2 per day. Furthermore, the effluents from desalination plants are typically discharged into the sea, and their high temperature and ionic content inevitably modifies the marine environment, with unknown consequences. The direct use of seawater is, therefore, more attractive, but it also poses major challenges since seawater contains ions that adversely affect mineral recoveries. In particular, in the flotation of sulphide ores in seawater, the floatability of molybdenite is depressed (Castro, 2012; Laskowski, Castro, and Ramos, 2014)."

Jan 1, 2017

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By J. M. Wempen, M. K. McCarter

"Differential Interferometric Synthetic Aperture Radar (DInSAR) is a satellite-based remote sensing technique capable of measuring centimeter-level surface displacement with high spatial resolution over large areas. Regular monitoring of subsidence due to underground mine development is one potential application of DInSAR, and in this study, the application of DInSAR for subsidence monitoring is evaluated for two mining regions in the mountain west of the United States. In general, DInSAR has potential to identify the shape and extent of subsidence; in some cases, magnitudes and rates of subsidence can be defined. Importantly, the effectiveness of DInSAR for subsidence monitoring depends on the radar band (wavelength), the subsidence rate and the time between image acquisitions, and the topographic and vegetative surface characteristics. INTRODUCTION Differential Interferometric Synthetic Aperture Radar (DInSAR) is a satellite-based remote technique that can be used to measure small surface displacements. Under good conditions, centimeter-level displacements can be measured with subcentimeter accuracy (Buckley, 2000; Massonnet and Feigl, 1998). Additionally, DInSAR data have relatively high spatial and temporal resolutions. Pixels in Synthetic Aperture Radar (SAR) images can have a ground resolution as small as about 3 m, and images often include tens to hundreds of thousands of pixels and cover tens of kilometers. Regions are imaged regularly, and periods between images typically range from weeks to months. In DInSAR, phase measurements from two radar images acquired over the same region at different times are used to precisely measure relative distances (Rosen, 2014). Surface deformation, topography, and changes in the satellite position all contribute to differences in the length of the path that the radar wave travels in each image. SAR sensors use radar with relatively long wavelengths; L-band (24 cm wavelength), C-band (6 cm wavelength), and X-band (3 cm wavelength) radar are used most commonly. Because the wavelengths are long, small changes in the path length of the radar signal can be quantified by measuring the change in the phase of the radar signal between the images. In general, changes in the path length due to changes in the satellite position and topography are known or can be estimated, and centimeter-level changes in the path length due to deformation are measurable. This study evaluates the effectiveness of DInSAR for measuring subsidence in two mining regions in the mountain west of the United States. L-band data from the Advanced Land Observing Satellite (ALOS) and X-band data from the TerraSAR-X mission are evaluated. Imaging characteristics, including the radar band and the time between image acquisitions, are important for effective subsidence monitoring."

Jan 1, 2017

By M. B. Kime, A. T. Kaniki

"Grinding tests were conducted on an oxidized copper-cobalt ore using a pear-shaped ball mill. Twelve mono-sized ore fractions were prepared and wet ground batchwise. The mill was run for 0.5 to 30 min intervals. The shortest interval provided data more closely related to the breakage function (B) because less secondary breakage was hypothesized. Some selection function (S) and B parameters were determined. Remaining parameters were estimated using a population balance model simulator. To evaluate the kinetics model, an unsized ore sample was also milled. Predicted and measured particle size distributions (PSDs) agreed well, suggesting that S and B parameters can be used for continuous operation mass balances.RÉSUMÉ Des essais de broyage ont été menés sur un minerai oxydé de cuivre-cobalt à l’aide d’un broyeur à boulets piriforme. Douze fractions de minerai de dimension unique ont été préparés et broyés en voie humide en lots. Le broyeur était mis en route à des intervalles de 0,5 à 30 minutes. L’intervalle le plus court fournissait des données plus étroitement liées à la fonction d’abattage (B) car d’après l’hypothèse avancée, le besoin d’abattage secondaire était moindre. Certains paramètres de la fonction de sélection (S) et de B ont été déterminés ; les paramètres restants ont été estimés à l’aide d’un simulateur de modèle d’équilibre de population. Pour évaluer le modèle de cinétique, un échantillon de minerai non calibré a également été broyé. Les compositions granulométriques (PSD, de l’anglais particle size distributions) prévues et mesurées correspondaient bien, ce qui laisse penser que l’on peut se servir des paramètres S et B dans le cadre d’équilibrages massiques en fonctionnement continu. INTRODUCTIONSize reduction of solids is a very energy intensive and highly inefficient process. It consumes approximately 5% of the electricity produced worldwide (Rhodes, 1998), and more than 50% of the total energy used in mineral processing plants (Walkiewicz, Lindroth, & Clark, 1996). An increase in grinding efficiency can therefore result in significant reductions in operating costs. This often amounts to determining the optimal design configurations for milling an ore sample in a laboratory mill under standard conditions. Prior to optimizing the milling stage, the requirements for downstream processing in terms of particle size distribution (PSD) need to be understood because low liberation and overgrinding will lead to future problems. Once this is done, it is also important to clearly understand the breakage properties of the ore. The kinetics of size reduction in tumbling mills are often determined using two probabilistic functions: selection and breakage (Austin & Luckie, 1972). Knowledge of the selection and breakage functions also enables the prediction of the PSD for a given ore sample."

Jan 1, 2017

By Shreyas Giridharan, Fursan Hamad, Sujith Gowda, Christian Moormann

"Pile installation in soil is a dynamic process which exhibits large deformation in the soil region. Experimental investigation of pile installation is both time and resource intensive. Numerical investigation can be a helpful tool for the analysis of the installation process. Furthermore, numerical analysis allows simulating various soils and loading conditions with ease. Finite Element Method (FEM) – a widely used framework for numerical simulations - fails to perform well for soil mechanics where large deformation and heavy material movement exists. In order to alleviate this shortcoming, Material Point Method (MPM), advancement to FEM has been used. In MPM, material points (particles) are used to represent the domain which carry the information and move over a fixed computational mesh where the governing equations are solved.In the present work, a variation of MPM, called CPDI (Convected Particle Domain Interpolation) is utilised which handles large deformation problems better than the classical MPM. Here, the material points are represented by a spatial domain which deforms according to the particle deformation. This eliminates stress oscillations while particles cross the grids. Implementation is validated and applied to pile installation in dry and saturated soil conditions. A 2D axisymmetric model is chosen, with penalty function method being used for evaluating contact between soil and pile. Sand is modelled via the hypoplastic constitutive description that takes into account large deformation, as well as small strain stiffness. From these simulations, various parameters like stress, void ratio and friction angle are studied.INTRODUCTIONOffshore piling is challenging in terms of testing and execution. Before the execution, predicting an efficient installation method requires study of various parameters, like soil conditions, type of loading, force requirement etc., and are the minimum parameters to be known beforehand. To obtain these parameters, testing a real scale prototype under different conditions is not feasible. Scaled model tests in lab can support in making certain decisions, but fail to replicate real behavior fully. Therefore, the need for a numerical simulation technique emerges, which can provide early predictions easily and accurately. This later can be extended to real scale tests, reducing the number of experimental investigation required.Simulation of displacement pile installation in sand involves large deformation due to penetration process, thereby making the application of FEM impossible, where large deformation causes heavy mesh distortions. Due to this, meshless methods are developed to treat large deformation in a better way. Among various meshless methods, Material Point Method (MPM) shows more applicability to geomechanical problems. This is mainly due to the ease of handling soil, structure and water in a unified manner."

Jan 1, 2017

By Michael Arnold, Bob Faulhaber, Joe Nichols

"Center Hill Dam is a critical part of the infrastructure controlling floods at the Caney Fork River and reducing flood levels at the Cumberland, lower Ohio and Mississippi Rivers. The Center Hill Dam Foundation Remediation Project was necessary to address Karst features in the foundation rocks and observed signs of distress of the dam. From 2011 to 2014 BAUER Foundation Corp. (BFC) performed deep foundation works for this project. The executed features of work include the installation of two walls. The first wall extends throughout the clay embankment into the underlying rock to provide encasement during the construction of the second wall. Its width of 7.4 feet makes it the widest diaphragm wall ever installed. The second wall is the actual seepage barrier and provides a continuous 2- feet wide wall. It extends through the first wall into the underlying rock and is up to 300 feet deep. The paper introduces the project, the requirements specified by United States Army Corps of Engineers (USACE) for encasement and barrier wall and the approaches taken by BFC. It discusses the ground conditions and describes the excavation equipment as well as the excavation methods used. A special focus is put on the steering capabilities of the hydrocutter equipment and the verticality performance.PROJECTBeginning in 2011, BFC was tasked by the USACE with the installation of a seepage barrier/cutoff wall at the Center Hill Dam Foundation Remediation project under a partially performance based specification. The remediation was necessary due to karst features in the foundation rocks and observed signs of distress, which led USACE to rate the dam with the most critical dam safety action classification (DSAC I). The executed features of work include the installation of two walls. The first wall, an encasement wall, extends vertically through the clay embankment and is embedded minimally into the underlying bedrock to provide embankment stability during the construction of the second wall, the barrier wall. The encasement wall is constructed of overlapping panels 7.4 feet (2.25 m) wide, which is the widest diaphragm wall ever installed, and up to 210 feet (64 m) deep. The second wall is the seepage barrier and provides a continuous 2 feet (0.6 m) wide wall consisting of overlapping panels. It extends through the encasement wall into the underlying bedrock and is up to 307 feet (93 m) deep. BAUER BC40 and BC50 hydrocutters mounted on MC96 and MC128 foundation cranes were used to perform the majority of the works (Figure 1). Excavations were performed under bentonite slurry (encasement wall) and water (barrier wall) and concrete was poured with the tremie method. Adding to the challenges, the project had to be executed in an environmentally sensitive area. Based on the high risk, a special focus was put on monitoring, quality control and geometric accuracy. The WallTracker information management system was used to share all relevant data between BFC and USACE (Roff et al. 2014)."

Jan 1, 2017

By M. S. Safarzadeh, V. Agarwal

"The solvent extraction of cerium(III) and samarium(III) from mixed solutions of all rare earth elements (REEs) except promethium using PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), an acidic extractant, was investigated. The effects of aqueous equilibrium pH, various acids (sulfuric acid (H2 SO4 ), hydrochloric acid (HCl) and nitric acid (HNO3 )), initial metal ion concentration and extractant concentration on the solvent extraction of Ce(III) and Sm(III) were systematically studied. From the experimental results, HNO3 and HCl were found to be the preferred aqueous media for the solvent extraction of both Sm(III) and Ce(III). The most promising experimental conditions of pH, PC88A concentration and metal ion concentration were identified for the extraction of Ce(III) and Sm(III). Separation results showed that H2 SO4 at pH 2 provided the best separation between Sm(III) and Ce(III). IntroductionIn recent years, demand for rare earth elements (REEs) has increased significantly because of their many commercial applications. REEs have especially important high-tech applications owing to their unique physical and chemical properties, and they are used in a wide range of areas such as catalysts, ceramics, magnets, lasers, glass, neutron absorption and alloys. As REEs have very similar physicochemical properties, their separation and purification from each other is challenging and gaining significant interest. Samarium (Sm) and cerium (Ce) are found in different REE minerals, including bastnäsite ((Ce,La,Nd(CO3)F), xenotime (YPO4) and monazite ((Ce,La,Nd,Th)PO4) at major production sites in the United States and China, as listed in Table 1 (Bleiwas and Gambogi, 2013). The most common acidic organophosphorous extractants used for REEs extraction and separation are DEHPA (di-(2-ethylhexyl)phosphoric acid), PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), Cyanex 272 (bis-2,4,4-trimethylpentyl phosphinic acid) and Cyanex 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid) (Sarangi, Reddy and Das, 1999; Surampally et al., 2012; Tian, Jia and Liao, 2013). Out of these extractants, PC88A is known for providing higher separation factors (Acharya, Mishra and Misra, 2015). El-Hefny et al. (2010) investigated the kinetics of the solvent extraction of Sm from chloride media using sodium salt of Cyanex 272 and reported the extracted species to be Sm(OH)A2•2HA. Lee et al. (2005) investigated the solvent extraction of Sm(III) with PC88A and saponified PC88A from chloride solutions and found the stoichiometry of the extraction reactions to be 1.5 with PC88A and 3 with saponified PC88A."

Jan 1, 2017

By Billy Rosseau, Mike Cammack, Richard O’Meara, Gustavo Azpilcueta

During the summer of 2014, the U.S. Army Corps of Engineers (USACE) sought proposals to vastly improve and expand the small boat harbor in Valdez, Alaska. It would be a multi-year project, and construction was scheduled to begin in the spring of 2015. One aspect of the project was the construction of a 3,100 feet (1000 m) rubble-mound breakwater to protect a mooring basin. An estimated 208,500 tons (190,000 t) of rock, ranging in size from 160 to 3500 lbs (73 – 1600 kg), were needed to build the breakwater. The Glacier Point Quarry was selected as the rock source due to its proximity to the project and the quality of the rock meeting all of the USACE rock standards.

Jan 1, 2017

By X. Baolin, R. Guru, M. Peiravi, M. K. Mohanty, Z. Qian, R. Ma, Z. Yude, L. A. Ackah

"Acid mine drainage (AMD) is produced when exposed pyrite (FeS2) reacts with air and water to form an acidic solution that usually contain contaminant levels of heavy metal ions. AMD can potentially contaminate surface water and soil if not treated. The primary objective of this study was to investigate the removal of dissolved aluminum, iron and zinc metal ions from natural AMD using water treatment residue (WTR), a low-cost adsorbent. WTR sorbent generated as waste material in drinking water treatment plants (WTP) was characterized and utilized for the sorption of Al, Fe and Zn in AMD collected from an abandoned coal mine site in southern Illinois that generates approximately 20 gallons per minute of AMD. Sorption experiments were performed using batch technique to obtain rate and equilibrium data. The effects of various parameters on sorption capacities of WTR were observed by varying contact time, pH of the AMD and WTR dosage. The adsorption studies showed rapid uptake in general for the first 80 minutes for Fe and Zn but much earlier for Zn. Further increase in contact time did not show significant change in equilibrium concentration indicating the onset of adsorption equilibrium. After the batch treatment of the AMD water with the WTR, the removal of Al, Fe and Zn were 99.8%, 99.85% and 95.5% respectively. The pH of AMD increased from 2.64 to a near neutral point of 6.74 after treatment. The laboratory results show that the low-cost WTR, which is an abundantly available industrial waste, has proven potential to significantly reduce the high metal ions in acid mine drainage. INTRODUCTION Mining activities provide the basic raw materials needed for infrastructure development and economic growth world-wide. However, it is well recognized that mining activities have been the cause of a variety of environmental pollutions, including AMD. Water seeping out of an old abandoned mine is generally characterized by low-pH with heavy loads of dissolved sulfates (SO4) and metal species such as Fe, Al and Zn among other dissolved elements categorized as toxic metals. The Bureau of Land Management’s Abandoned Mine Lands (AML) program reported the existence of about 46,000 abandoned mines in the United States. Several environmental problems have been reported to be associated with these mined out sites such as heavy metal poisoning, loss of vegetation, air pollution etc. (Boulanger & Gorman, 2004)."

Jan 1, 2017

By Charles M. Wilk, Lori Tiefenthaler

"Information presented in this paper can be used to support deep soil mixing, subsurface grouting and slurry wall technology as sustainable construction technologies. Ordinary Portland Cement (OPC) is the default cementitious material used by Deep Foundation Institute (DFI) Members for geotechnical work. Owners, engineers and contractors can contribute to the sustainability of a geotechnical project by increasing the use blended hydraulic cements and industrial byproducts to replace some of the OPC in mix designs. Sustainability is defined as the quality of not being harmful to the environment or depleting natural resources. Production of cementitious materials consumes natural raw materials and energy while also generating air emissions and waste. Life Cycle Assessments can be used to compare the relative environmental impacts of one cementitious material to another. Blended hydraulic cements (BHCs) are interground (or blended) mixtures of Supplementary Cementitious Materials (SCMs) with OPC. Commonly used SCMs include fly ash, ground granulated blast furnace slag (GGBFS) and limestone. Examples of industrial byproducts commonly used in geotechnical work include coal combustion residuals (CCR) (aka fly ash), and ground granulated blast furnace slag (GGBFS). Much of life cycle impact of these SCMs and industrial byproducts have already been borne by the industries that generated them. There is increasing awareness to LCA and sustainability of different materials used on projects. This is evident in the application of the Leadership in Energy and Environmental Design (LEED) program. The savings in environmental impact with the use of SCMs and industrial byproducts can make proposed use of these materials in a geotechnical project more attractive in terms of sustainability. This paper presents (a) information that compares published life cycle assessment data of OPC, BHCs, and slag cement (SC) to illustrate the potential benefits to sustainability and (b) general strategies for positioning a geotechnical application, use, project design or cementitious material mix as a more sustainable alternative"

Jan 1, 2017

By R. Venugopal, V. K. Saxena, S. K. Tripathy

"This study was carried out to understand the impact of variation in material morphology on the efficacy of microwave pretreatment. Three different types of mineral matter – coal, iron ore and manganese ore – were treated with microwaves at different energy levels, from 180 to 900 W, for different time durations of one to five minutes. The treated samples were subjected to microscopic, milling and liberation studies. Coal is a porous and amorphous material with low dielectric constant, and grinding of the microwave-pretreated coal samples resulted in an 18.18 percent reduction in the 80 percent of passing particle size, or d80, and a 17.1 percent increase in carbon recovery. The microwave-pretreated soft and friable manganese ore samples showed a 47.82 percent reduction in d80 during grinding and higher manganese recovery of 42.46 percent during liberation analysis. The microwave pretreatment and milling of hard and banded iron ore reduced the d80 by 20.83 percent, but no improvement was observed in mineral liberation. Coal showed better results during treatment at lower energy levels of 180 W for one to three minutes, whereas the minerals needed higher energy of 900 W for five minutes. Particle size analysis indicated rapid size reduction up to an energy input of 25 Wh. This effect diminished with increased energy input.IntroductionComminution is an important unit operation in mineral processing plants for the purposes of size reduction and mineral liberation. But most comminution technologies are energy inefficient and only a small amount of energy is consumed in real size reduction, with the rest wasted. High-grade mineral resources have been exploited on a large scale for the last century, and the upgrading of low-grade resources is now required to fulfill the needs of industry. Pretreatment methodologies for comminution will play a crucial role in the upgrading of low-grade mineral resources. Researchers have studied various pretreatment methods to develop an energy-efficient and techno-economically viable solution to improve mineral liberation and product fineness with minimum energy consumption. Most of these studies were focused on the use of chemical additives, thermal, ultrasonic and microwave treatment, and electric disintegration (Klimpel and Austin, 1982; Norgate and Weller, 1994; Gaete-Garreton, Vargas-Hermandez and Velasquez-Lambert, 2000; Wilson et al., 2006; Kumar et al., 2010; Wang, Shi and Manlapig, 2011; Singh et al., 2012)."

Jan 1, 2017

By Alan Diaz Butron, Eng. Thierry Bernard

"In tunnel blasting the most challenging objective is definitively obtaining the maximum advanceassociated to a minimum overbreak. Achieving 100% of advance with no overbreak is the targetchallenge by Chavimochic Consortium. Chavimochic Special Project is an irrigation system that extends throughout much of the coast of the La Libertad Region, on the north coast of Peru. In 2012, it began management for construction of the third and last stage of CHAVIMOCHIC to irrigate lands of Chicama Valley, North of Trujillo. This project of 13 Km (8 mi) of various tunnels, it's a combination of technology and daily optimization by experienced people, which allow to accomplish the objective. Achieving this advance with no overbreak provide a huge saving on time. This paper describes the method, technology used, and the results obtained on more than 600 blasts done with conventional initiation system on the first 3 km (1.86 mi)."

Jan 1, 2017

By P. J. Mehrfert

"Recovery of mineralized coarse particles is notoriously low in conventional concentrators that treat copper porphyry ores. The application of coarse particle flotation techniques has the potential to achieve comparable metallurgical performance at significantly coarser primary grind sizings. ALS Metallurgy has been conducting both internal research and commercial test programs to investigate the potential of Eriez HydroFloatTM technology on copper sulphide ores. Test data indicates that significant improvements in the recovery of copper sulphide bearing particles between 200µm to 850µm can be achieved using Hydrofloat technology compared to conventional flotation techniques. This paper summarizes the results from a selection of test programs that includes recovery by size data from both conventional flotation and HydroFloatTM tests. An explanation of the apparatus and test procedure will be given. Mineralogical analyses of the test products and characteristics that limit metallurgical performance will be discussed.Description of Apparatus and Test ProtocolThe HydroFloatTM laboratory cell is a clear plastic column with an internal diameter of 14 cm. Water and air are introduced to the cell through a circular manifold located in the lower portion of the cell. The cell has a conical bottom which directs slurry to a pinch valve that controls the discharge of tailings. Feed solids are introduced to the upper portion of the cell in slurry form. The cell is operated in a manner such that the manifold water creates a teeter bed zone of suspended solids in the middle portion of the cell. Tailings exit the bottom of the cell at a high pulp density, and most of the introduced water overflows the top of the column and is collected in a launder. Particles with a hydrophobic surface may attach to air bubbles that percolate through the teeter bed, rendering them sufficiently buoyant to be transported to the overflow launder.Three significant features of this arrangement enhance the potential to recover coarse, low grade particles by flotation techniques. Firstly, the hindered settling conditions created by the rising column of water allow coarse particles to become buoyant once attached to a modest sized air bubble. Secondly, the flow conditions within the cell are relatively quiescent compared to a conventional flotation cell that utilizes an agitator. This allows particles that have limited hydrophobic portions of their surface, due to a low content of exposed sulphide mineral, to maintain a somewhat fragile attachment to air bubbles long enough for successful recovery to the overflow. Finally, the absence of a froth phase at the top of the cell allows particles attached to air bubbles to immediately exit the vessel, reducing the potential to drop back into the pulp phase as bubbles burst or coalesce."

Jan 1, 2017

By Dario Libano, Franz-Werner Gerressen

"Diaphragm walls are known as underground structural elements commonly used for retention systems and permanent foundation walls or elements. Of course they can also be used as deep groundwater barriers. This paper will focus on the construction work in an urban area like Sao Paulo. The Line 5 of Metro Sao Paulo is one of four network expansion projects undertaken at the same time. The projects will cover various areas of the city. The Line 5 on São Paulo’s south-side will be extended 7.1mi (11.5km) to serve 770,000 riders per day, stretching a total of 12.4mi (19.9km) along 17 stations. The extension line will facilitate access to the city’s central section and the commercial and hospital districts located along the line. The Brooklin Station, subject of this paper, had to be carried out in a special five shaft shape design, shaft diameter 131ft (40m) each, without using ground anchors. A focus will be taken on the special requirements of the installation of the arrows as well as on the specialties of installation for the shaft shaped layout. Therefore, it was required to install a 3.3ft (1,000mm) diaphragm wall using a specific layout especially in the connecting sections of the shafts, the so called arrows, to provide a bearing area for the struts. Maximum wall depth was about 121ft (37m); the total volume was about 20,060 cubic yard (15,337m³). The paper will describe the construction method and the sequence of activities required for the construction of this diaphragm wall using a combination of hydraulic grab and trench cutter system.INTRODUCTIONThe Line 5 Extension, in the city of Sao Paulo/Brazil, is currently the most important investment in public transport by Sao Paulo state’s government. It will connect the south part of the city to the city center, crossing through four other major METRO lines and stations, all currently in operation. The extension includes a new parking yard for the trains and 11 new stations. The Brooklin Station is one of the new stations and has a unique geometry of five secant shafts. The station should open and operate in 2016.The original design included constructing five secant shafts stabilized by two plastic slurry walls using conventional grab technology. One of them was to contain the contamination plumes in the neighborhood and the other for temporary support to enable the excavation of the shafts. The final retaining wall design was reviewed and changed to a concrete structural diaphragm wall. The reason of design change was as well the reduction of construction time of the shafts by half to meet the schedule as to avoid dewatering effects in a geological region characterized by Quaternary sediments and environmental contamination plumes. It was the first time that a trench cutter (hydromill) was used in such a situation in Brazil. The cutter increased the quality of the joints by overcutting, and decreased the probability of having seepage into the shafts. The cutter created a seepage barrier and avoided movement of contamination."

Jan 1, 2017

By Reda M. Bakeer

"Measurements obtained during load testing of two steel H-piles driven at a site in Northeastern Mississippi are discussed. The general site conditions, equipment used, testing procedures and results of the pile load tests are presented. Both piles were tested in compression and one of the piles was subsequently tested in tension. The piles were instrumented with strain gauges and extensometers to measure the mobilized soil resistance and pile movement. Three different “zero strain” conditions were used to determine the mobilized soil resistance and residual loads due to driving or a load cycle. It was concluded that the effect of residual loads on driven piles could be significant. Driving residual loads influenced the magnitude and distribution of the load transfer curves more than those due to a load cycle. Results of the tension test were impacted by the residual loads from the previous compression test performed on the same pile.INTRODUCTIONSeveral factors affect the performance of a deep foundation system including the subsoil conditions, loading settings, pile type and installation method. Residual stresses develop in piles particularly due to pile driving, but they are typically not accounted for in the analysis (Fellenius 2002). Siegel and McGillivray (2009) presented an assessment of residual loads measured during load testing of instrumented auger-cast-in-place (ACIP) piles. The magnitude and distribution of residual stresses along the pile shaft and toe depend on the pile installation method, previous load cycles and time effects. Poulos (1987) reported that residual load due to driving at the pile toe is independent of pile driving equipment and may significantly affect the results of a pile load test. Hunter and Davisson (1969) reported results of pile load tests performed in compression on fully instrumented piles driven in cohesionless soils along with a discussion of the effects of residual loads. Tension loads of about 445 kN (100 kips) were measured at the pile toe after driving. Unloading residual compression load at the toe was detected as “apparent” tension since the instrumentation was zeroed prior to the test. The researchers suggested a graphical approach to obtain the “corrected” load distribution curves considering that residual load will dissipate following the tension test. Holloway et al. (1975) conducted a study on the effect of residual stresses due to pile driving and developed a computer software that accounts for residual loads. Briaud and Tucker (1984) suggested a method to account for residual loads based on the results of 33 pile load tests performed in mostly cohesionless soils."

Jan 1, 2017