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By S. Chander

The results of an investigation to characterize the chalcopyrite/solution interface are presented. Several techniques including galvanostatic and steady state polarization, cyclic voltammetry and impedance spectroscopy were used. The results show that the dissolution of chalcopyrite is incongruent. Initially, at low potentials(<O.34V), iron species are released which give rise to the growth of an iron-deficient sulfide (IDS) layer. The dissolved iron might reprecipitate as a hydroxide layer depending on solution composition. Continued oxidation involves diffusion of species through the product layer. At higher potentials (>O.48V) further oxidation leads to dissolution of copper and sulfur species with a resultant breakdown of the IDS layer. The changes in properties of surface coatings resulting from various electrochemical treatments are discussed.

Jan 1, 1991

This paper is concerned with the blasting of rock in mining. The most common purpose of blasting rock is to cast it or to disrupt its structure sufficiently for effective digging and subsequent removal.

Jan 1, 1991

By A. Kontopoulos

The extraction of nickel and cobalt from low-grade greek laterites by sulfuric acid leaching has been studied. Batch and continuous mini-plant atmospheric leaching as well as pressure leaching techniques were employed. Atmospheric leaching at temperatures as high as 95 OC generally resulted in low Ni extractions (up to 82%), high acid consumption (650-850 kg/t ore or 80-100 kg/kg Ni) and high Fe co-dissolution (30%). Pressure leaching at 260 OC increased Ni extraction to over 98%, with minimal Fe co-dissolution (2.5%); acid consumption was 300 kg/t ore (31 kg/kg Ni). Detailed experimental results and conceptual flow sheets for atmospheric and pressure leaching are presented.

Jan 1, 1991

By Stephen C. Tadolini

"The use of a torque wrench to establish the amount of actual load developed on an expansion anchor bofting system dates back to work completed in the early 1950s. The advent of ultrasonic measurement systems and hydraulic torque wrenches has made it possible for the U.S. Bureau of Mines to perform torque-tension measurements in the laboratory and the field much more accurately. The results indicate that the amount of initial boft preload may be overestimated by amounts in excess of 45% of the expected load using torque wrenches. This inaccuracy is primarily due to the friction that occurs between the bearing plate and the head of the boft. These parameters become extremely important when the support system is being used to prevent joint members from slipping relative to each other or when the boft acts as a heavy spring to clamp two or more sections together. Methods to overcome the frictional losses are presented in conjunction with a laboratory method to determine the actual torque-tension ratios for expansion anchor and combination bolting systems.IntroductionMechanically anchored roof bolts have been widely used in the mining industry since their introduction in 1947. Estimates made in 1989 indicate that out of 85 million fixtures, approximately 49 million bolting fixtures still use applied tension to complete the reinforcement necessary to maintain stable openings. Nearly 85 million bolts are used yearly. The most widely used bolt is the resin-anchored headed rebar, followed by standard mechanical roof bolts, specialty bolts (mechanically anchored, resin enhanced fixtures) , and combination bolts . Po st-tensioned resin rebars, combination systems, and friction stabilizers make up the remaining 10% of the units used (Fig. I).For mechanical, combination, and tension rebar bolts, the bolt tension is the primary means of reinforcing the roof, but in many cases, because of poor installation procedures, the bolts are ineffective. Mine operators recognize the importance of proper installation procedures. Long-term bolt tension measurements are required in the Code of Federal Regulations (CFR)In each bolting cycle, the actual torque or tension of the first tensioned bolt installed with each drill head shall be measured immediately after it is installed. Thereafter, for each drill head used, at least one roof bolt out of every four installed shall be measured for actual torque or tension. If the actual torque or tension of any roof bolts measured is not within the range specified in the roof control plan, corrective action shall be taken."

Jan 1, 1991

Longwall mining originated in the early 18th century in the county of Shropshire in England, where it was known as the longway method. Its name implies the extraction of the seam over a long continuous length or wall of exposed coal. Until the late 19608 and early 1970s the use of the longwall system with a few exceptions was confined to the United Kingdom and Europe. It was not until the early 19708 that the highly productive longwall faces we now know, were developed and the application of the longwall system extended to Australia, South Africa, United states of America and other parts of the world. The modern longwall face has three major components, namely: +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; the machine to break and load the coal +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; the face conveyor; +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; and a system of roof support. &nbsp; This paper reviews the development of longwall mining technology. The parameters directly influencing the production &apos;of a modern longwall face are considered, as are the possible constraints to the further development of the longwall system.

Jan 1, 1991

By M. I. Novgorodova

An overview of the systems Au-Ag and Au-Cu is given. The nature and levels of concentration of various elements occurring with native gold is reviewed. The examples cited are mainly from the USSR. The lack of homogeneity within naturally occurring Au-Ag solid solutions is examined.

Jan 1, 1991

By M. J. Fairweather

"The development of means to maximize the selectivity between galena and sphalerite in lead zinc ores is extremely important to the lead-zinc industry. Two challenging studies recently undertaken by Cominco will be reviewed. The first required an unusually fine grind to achieve liberation between galena and sphalerite. The second contained partially altered galena which resulted in unusual early activation of sphalerite under normal flotation conditions. Means by which lead and zinc separation were optimized in these two ores will be discussed.There are two important factors in the separation of minerals by froth flotation: particle size distribution (grind) and pulp chemistry. Pulp chemistry includes a number of factors including pH, Eh, collector type and concentration, inorganic depressants, organic depressants and activators.Grind is important for two reasons. A sufficiently fine grind is required to optimize liberation. However, if the mineral dissemination is too fine, mineral selectivity in the flotation process is impaired. Due to the hydrodynamic constraints of conventional mechanical flotation cells, flotation works best over the single decade size range between 10 and 100 microns. The majority of new ores treated by Cominco until relatively recently were comparatively simple. The major factor in their treatment was defining optimum grind size. Accordingly, the focus within mineral processing at Cominco was on grind and supporting liberation studies. The relationships between grind, liberation and flotation response are intuitively easy to understand. An idealized relationship is shown in the first figure."

Jan 1, 1991

By P. Verhoeven, G. Hefter, P. M. May

The dissociation (ionisation) constant of hydrogen cyanide, pKa(HCN), has been measured by high precision glass electrode potentiometric titrations in saline solutions containing up to 5 mol/L sodium chloride. The dissociation constant of water that is necessary for the calculation of pKa(HCN) has also been measured. In saline solution, and in contrast to literature values, pKa(HCN) changes considerably at both high and low ionic strengths as a result of changes in activity coefficients. In addition an equation is presented, using literature data, that describes the variation of pKa(HCN) with temperature up to 150°C. The significance of the changes in pKa(HCN) for optimising the pH of alkaline cyanide gold recovery streams is briefly discussed.

Jan 1, 1991

By Aspinall T. O, Bell L. C

Increased awareness and stricter enforcement of regulatory requirements for adequate rehabilitation of surface mining sites has made environmental planning an essential part of strip mine planning. Rehabilitation is site specific and should be based on data which relate to that site. Cost-effective spoil pile design to minimise erosion is an important part of rehabilitation. Spoil pile design is an integral part of strip mine design. QCT Resources Limited has provided a postgraduate scholarship toward research in this area. The controlling factors of spoil pile design are post-mining land use, drainage requirements and degree and rate of erosion. The extent to which mine design is controlled by these factors is determined by regulatory requirements. To plan acceptable rehabilitation programs, erosion processes must be accurately modelled, and a range of erosion prediction models are available. Useful prediction models can be placed in two categories with the first category containing soil loss prediction models which can be used to predict the amount of soil lost from an area over a short or long term basis. Models in this category include the Universal Soil Loss Equation (USLE), Water Erosion Prediction Project (WEPP), Griffith University Erosion and Sedimentation System (GUESS) and Chemical, Runoff and Erosion from Agricultural Management Systems (CREAMS). The second category contains topographic evolution models which give an indication of the long term morphological development of a formed surface subjected to erosion processes. Models in this category include "Topog", Willgoose&apos;s Physically Based Catchment Evolution Model and Areal Nonpoint Source Watershed Environment Response Simulation (ANSWERS). The USLE has been used in the agricultural field for soil loss prediction. To apply the equation to mine sites in Central Queensland, it is necessary to understand the factors affecting erosion at the sites. This understanding should allow the variables of the equation to be quantified. The rainfall factor applied in the USLE is independent of engineering design or soil management techniques. The factor of spoil erodibility is dependent on the material&apos;s physical and chemical properties and can vary from site to site. In the equation, the topographic factor, cover and management factor and conservation practices factor can be varied by design to reduce erosion on rehabilitated areas.

Jan 1, 1991

By Mark Laffoon

Gold Fields Operating Co.-Chimney Creek has conducted numerous ore reserve modeling studies In order to optimize the estimates of the gold grades and tonnage distributions. Improved models continue to be produced for the major pits which Increase confidence levels required by Gold Fields management and provide the basis for more accurate long and intermediate term mine planning. Various kriging and non-kriging estimation techniques are used at Gold Fields -Chimney Creek Mine. This paper reviews the modeling histories and, current procedures used to construct these models with particular emphasis on the North Pit deposit.

Jan 1, 1991

By William J. Almas

Operating uranium mill tailings containment and mill decommissioning activities are regulated by the Nuclear Regulatory Commission (NRC) and the Environmental Protection Agency (EPA) through numerous regulatory mechanisms. Reduction of radon emissions from tailings disposal areas, remedial actions to return groundwater to baseline constituent concentrations, and 200-to 1,000-year stabilization of tailings are major focus areas of regulation. The cumulative economic impact and uncertainty associated with regulation are very significant and will hinder future development of uranium milling facilities.

Jan 1, 1991

By Hendrix J. L, Nelson J. H

A model based on non-steady state has been developed for dissolution and diffusion in porous ore particles. Results from the particular model have been incorporated, as a rate term, into a global, heap-scale model based on a plug flow reactor at unsteady state. The global model can be used to consider leaching by aqueous-phase reagents in equilibrium with a gas- phase component, such as oxygen gas, as well as strictly aqueous-phase reagents, such as cyanide. The flexibility of the model even allows predic- tion of the outcomes of using reagent sideflow injection in large heaps. Data from column leaching tests are compared to the model, and their relationship is discussed.

Jan 1, 1991

By Crook KAW

New sedimentological and biostratigraphic data indicate that the Leron Formation in the Markham Suture Zone, Papua New Guinea (PNG) represented Pleist- ocene alluvial fan-delta deposition in shallow marine to lacustrine environments. The distribution of sedimentary regimes in the Leron Formation indicates that during collision zone evolution, various tectono-sedimentary regimes do not always track the movement of the triple-junction systematically as idealized by Crook&apos;s (1989a) model. The migration of various tectono-sedimentary regimes are also controlled and influenced by the effects of second-order geometric features of the convergent margins. Leron Formation in the Markham Valley represents late to post-collisional marine to fluvial molasse. Foraminifera indicate that the collision and concomitant suturing of the Markham valley occurred after 1.32Ma.

Jan 1, 1991

By Larry Rayburn

Design of cost effective engineered solutions to complex problems requires the team efforts of the owner, the designer and the specialty construction contractor. The basic ingredients of success required to remain competitive and still produce a quality product are creative design based on experience and sound engineering principles, plus practical aspects of constructibility. The three case histories describe creative design/construct approaches that benefited all parties. 1. Introduction The increasing demand placed on specialty contractors to provide cost effective buildable solutions to complex construction problems compels us in the industry to be highly innovative. The practice of geotechnical engineering is considered more of an "art" than perhaps the other disciplines within civil engineering largely because of the basic nature and variability of soil and rock. The geotechnical design engineer must have the knowledge of the components of his design and know the limitations of his equipment and labor force. Thus, for the design/build specialty contractor the potential for creation of unusual solutions to difficult problems is quite high.

Jan 1, 1991

The small scale alluvial gold mining industry in Papua New Guinea (PNG) is c.irrently the only form of small scale mining carried out in this country. It already contributes significantly to the economy with current production estimated at 2 000-2 500kg per year. Until recently, small scale alluvial gold mining has been confined to simple panning and sluicing of high grade alluvial and colluvial deposits. Traditionally the small scale miner in PNG has only worked gravels with gold grades in excess of 500mg/m3. Grades of this order are required to justify the hard physical labour involved ~n hand operated small scale mining methods. .he introduction of higher throughput technologies such as trommels fed by hydraulic excavators has the effect of altering what constitutes an economically viable deposit. Mechanised techniques allow for the consideration of grades of almost half that level. The potential and opportunities for utilising this type of small scale mechanised mining in PNG are enormous with large areas of ground with gold grades running in excess of 250mg/m3 and often up to 2000mg/m3 throughout the country. An assessment of the current operating economics of this technology in the PNG context is the principal objective of this paper. Small to medium scale mechanised mining can potentially contribute significantly to the PNG economy particularly as it lies within the react-, of many PNG businessmen. Its potential is currently somewhat limited by a general lack of infrastructure and is also constrained by socio-political factors.

Jan 1, 1991

By R B. Stewart

Where pasture production is the intended land use of the areas to be reclaimed, the creation of a suitable growing +medium is a major objective. To achieve this land reclaimers require a sound understanding of the proposed mining plan and a knowledge of the physical, biological and chemical properties of materials intended for resurfacing disturbed areas. Where the original soil is not being replaced in its natural state, research is usually required to determine an alternative growing medium. Results from field research conducted on waste material from the Waihi Gold mine are reported with emphasis on the significance of soil depth in relation to pasture production in this environment. &nbsp;Problems in extrapolating field research to large scale operations are also considered. &nbsp; Essentially the requirements for successful pasture production, on surrogate growing medium, are akin to conventional approaches used in New Zealand in the development of unimproved agricultural land. High inputs of fertiliser are initially needed, especially where volcanic soil is used, and careful management of pastures and soils is required to minimise soil erosion and create a sustainable system. In the first three to five years of pasture production, grazing use of the land requires to be dictated by pasture availability and soil conditions and not by animal feed requirements. The use of light stock (young dairy or sheep) is recommended. &nbsp; Successful land restoration requires a team approach by a range of cooperative specialists including engineers, soil scientists, farm managers, agricultural contractors, landscape architects and environmental officers.

Jan 1, 1991

By J. S. Coats, G. E. Patts, N. Hughes

Conventional sampling methods are known to suffer from the variable loss of fine gold by elutriation. Freeze sampling yields representative and quantitative data that, when combined with information on the sedimentology of gravel-bed rivers, may facilitate the development of improved dispersion models for source detection. It is suggested that freeze sampling may have particular application to the orientation stage of a large gold exploration survey

Jan 1, 1991

By P. Creevy, P. F. Mousset-Jones, G. Danko, A. D. S. Gillies

The surface heat transfer coefficient is measure of the rate of heat transfer from exposed rock surfaces to the ventilating air. Knowledge of its value is of particular importance to accurately simulate the early stages of rock cooling after the opening of an excavation. A number of theoretical formulae for the calculation of the coefficient are available for use in mine climate simulation. However, direct determination by in situ measurement is preferred. Instrumentation, which has been developed for in situ mine measurement, and experimental procedures involving measurement at varying air velocities, are described. In a major study covering four Australian underground mines, the system has been used to determine surface heat transfer coefficients. A direct relationship was clearly established between the measured surface heat transfer coefficient and air velocity. Comparison is made between experimental results and those previously measured or calculated by others. The relationship established can be described by an equation and holds for air velocities above 0.4 mls. The derived relationship was con- firmed at all mines tested and is independent of geology and tunnel dimensions found in modern mines.

Jan 1, 1991

By H. Mori

The session chairman, Dr. H. Mori, welcomed the delegates to Discussion Session 8. AUTHORS PRESENTATIONS 1 . G. Price, Building Research Establishment. UK Mr. Price expanded on the content of his paper and presented elements of various case histories of bored piles instrumented by the Building Research Establishment. In particular, the interpretation of data from instrumented piles is critically related to: (i) the construction process (ii) concrete stiffness and variability (iii) the effects on the pile due to installing instruments The main role of the instrumentation in the examples presented was to establish pile performance under service loading conditions. Of particular interest is the mobilisation of skin friction and soil shear modulus.

Jan 1, 1991

By Yates M. G, Rowlands A. T

Most geostatistical techniques applied to the estimation of ore reserves assume relatively unifonn grade and thickness within an ore deposit environment. In shear-hosted mineralisation this rarely occurs. The distribution of mineralisation is controlled by the kinematic and geometric variation within the shear zone. Although the kinematic variation is dependent primarily on the temperature (and consequently the depth) of formation of the deposit, the geometric variation appears to be relatively insensitive to this parameter. Shoot mineralisation is controlled either by the intersection of secoodary shear planes (brittle deformation) or the stretching lineation of the mylonitic fabric (ductile defonnation).Once the shear geometry is clearly identified, it is critical to review the distribution of grade and thickness of mineralisation. The practice of cutting high-grade intersections without reference to the shear model leads to underestimation of the amount of gold in the deposit. High-grade shoots may occur as pipe-shaped bodies within the system; their identification is essential for both resource estimation and mine planning purposes.

Jan 1, 1991