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By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

In this study, the dissolution behavior of copper and arsenic from five different copper concentrates containing 21-34.7 %wt. of Cu, 1.3-7.3 %wt. of As and 15.6-27.5 %wt. of Fe were investigated under high pressure oxidative leaching conditions. Leaching experiments were conducted using different leaching reagents such as ferric sulfate, sodium chloride, deionized water, sulfuric acid and ferric sulfate-sodium chloride mixture in order to compare the effectiveness of each on the dissolution of copper and arsenic from copper concentrates. The effects of ferric sulfate (0.1-1 mol/L), sodium chloride (0.1-0.5 mol/L) and leaching temperature (100-180C) were investigated under 1 MPa autoclave pressure , particle size >45 m, pulp density of 100 g/L, stirring speed of 750 rpm and leaching time of 60 min. Results showed that the most effective leaching reagents for the dissolution of copper are 0.34 M NaCl and a mixture of 0.1 M Fe2(SO4)3 - 0.34 M NaCl, in which As extraction did not exceed 7%. The copper concentration in the pregnant leach solution obtained after leaching using 0.1 M Fe2(SO4)3 - 0.34 M NaCl was 13-30 g/L, while the concentration of As and Fe were in a range between 0.3-1 g/L and 0.2-10 g/L at 160C. INTRODUCTION Copper sulfide minerals, such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and covellite (CuS) are used for the production of copper in mining and metallurgical industries worldwide. The conventional pyrometallurgical processing followed by electrorefining is a common process for the production of high purity copper (Moskalyk, & Alfantazi, 2003; Padilla, Aracena, & Ruiz, 2012). However, the degradation of copper content and an increase in the amount of metal impurities, especially arsenic (As), antimony (Sb) and bismuth (Bi) in copper concentrates cause serious problems to the production of copper and environmental pollution (Basha, Selvi, Ramasamy, & Chellammal, 2008; Long, Peng, & Bradshaw, 2012). Hydrometallurgical processes are used to recover metals from refractory ores, concentrates and tailings by leaching (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018). During the last decades, hydrometallurgical processing for the recovery of copper from enargite-bearing copper ores and concentrates has been extensively investigated due to its relatively more environmentally benign and less capital costs than the conventional pyrometallurgical processes (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018; Choubey, Lee, Kim, & Kim 2018). However, several issues facing the hydrometallurgical processing are incomplete extraction of copper associated with the coprecipitation of iron compounds, difficult stabilization of toxic impurities and production of a contaminated copper product (Dreisinger, 2003; Safarzadeh, Moats, & Miller, 2014). Hence, a number of studies have been conducted on the selective dissolution of copper from copper ores and concentrates or selective removal of arsenic leaving a clean copper residue using various leaching reagents or lixiviants (Safarzadeh, Moats, & Miller, 2014; Mihajlovic, Strbac, Zivkovic, Kovacevic, & Stehernic, 2007; Tongamp, Takasaki, & Shibayama, 2009). More extensive studies on the selective extraction of copper from enargite- bearing copper ores and concentrates are much needed to improve copper recovery.

Jan 1, 2019

By H. Huang, H. M. Chen, W. B. Xie

Cu-0.8Cr-0.1Zr alloy were prepared by atmospheric melting. the microstructure and properties of the CuCrZr alloy after first cold rolled, solid solution, second cold rolled and aging treatment were analyzed by using optical microscope, electrical conductivity analysis and Vickers hardness tester. The results show that with the increase of the first cold rolled deformation, the grain breakage becomes more serious, and the cold hardening becomes more obvious and the hardness increases. The conductivity and peak hardness of the first cold rolled (reduction of 30% and 60%) alloys after solution, secondary cold rolled and aging treatment reaches 81 %IACS and 187 HV, respectively. However, the conductivity in the CuCrZr alloy with a higher rolling degree (reduction of 90%) after solution, secondary cold rolling and aging treatment is significantly higher, and the conductivity and peak hardness is 85.8 %IACS and 178 HV, respectively. INTRODUCTION CuCrZr alloy has been widely used in domestic industry for its excellent comprehensive properties such as high strength and high conductivity, especially in the contact wire and lead frame of high-speed railway (Sun, Tao, & Lu, 2015; Mishnev, Shakhova, Belyakov, & Kaibyshev, 2015; Zhang et al., 2016; Fu et al., 2017). In recent years, a lot of research has been done on how to improve the strength and conductivity of CuCrZr alloy. However, the high strength and high conductivity of copper alloys are contradictory characteristics. On the one hand, the addition of alloying elements is conducive to solution strengthening and aging strengthening; on the other hand, too much alloying elements in copper alloys cause defects in the lattice of copper matrix, resulting in a serious decline in the conductivity of copper alloys (Martienssen & Walirmont, 2005). How to obtain high strength and high conductivity at the same time is the main problem. At present, the main research methods are adding microalloying elements, thermomechanical treatment and severe plastic deformation to study the electrical conductivity and mechanical properties of CuCrZr alloys. For example, Xie et al. (2011) added trace Ag to the Cu-0.26 wt%Cr-0.08 wt%Zr alloy, and the size of precipitated phase Cr and Cu4Zr became smaller and the mechanical properties of the alloy were improved. Su, Dong, Liu, Li, & Kang (2004) found that the addition of trace Mg in CuCrZr alloy inhibits the growth of precipitated phase and reduces the internal stress around the precipitated phase. At the same time, the size of precipitated phase becomes smaller and the peak aging strength of the alloy is improved. Pang et al. (2013) found that adding trace Ni and Si to the CuCrZr alloy could improve the peak hardness, softening resistance and precipitation morphology of the alloy. Experiments shows that the grain size was significantly refined by equal channel angular extrusion combined with aging treatment, while the strength of the alloy was increased, and the electrical conductivity of the alloy did not decrease (Vinogradov, Patlan, Suzuki, Kitagawa, & Kopylov, 2002; Saray, 2016); Kermajani, Raygan, Hanayi, & Ghaffari (2013) showed that the strength of CuCrZr alloy can be improved by rolling at 500 °C. After 150 minutes of aging treatment, the strength and conductivity of the material increased to 431 MPa and 81 %IACS, respectively. Takata, Ohtake, Kita, Kitagawa, and Tsuji (2009) noted that the strain hardening, uniform elongation and tensile strength of the nano-precipitates produced by the mechanical heat treatment process can be notable enhanced. The mechanical and electrical properties of CuCrZr alloy can be improved by combining large plastic deformation with aging treatment in the test process (Gao, Huttunen-Saarivirta, Tiainen, & Hemmila, 2003; Huang et al., 2003; Xia et al., 2012; Zel’dovich et al., 2014).

Jan 1, 2019

By Marko Lampi, Ross Andrews, Jouni Pihlasalo, Robert Matusewicz

With widespread discussion on reducing carbon, sulphur and other emissions, use of sustainable energy sources and the pivotal circular economy theme, consideration needs to be given to pyrometallurgical operations broadly and more specifically, non-ferrous metallurgy. These themes present a number of challenges in terms of current operations and the view of processing the metals which are largely taken for granted in day to day living. This paper considers how these themes will impact pyrometallurgical flowsheets using the non-ferrous base metals as an example. It will examine the flowsheet chain to offer views on the boundaries of flowsheet optimization and the application of available tools to meet these future goals and challenges. INTRODUCTION The themes of reducing footprint through lowered CO2, S and other emissions, together with process sustainability (e.g. lowered energy) and links to the circular economy are well known to everyone in the metals industries. Whether it is reducing greenhouse gas emissions or analysing the importance of metals recycling in the circular economy, all these themes carry with them the fundamental premise of any change being considered; how can you best optimize a system to meet your aims? Of course, this depends on the available tools and the approach used for optimisation.

Jan 1, 2019

By E. Lehtila, J. J. Talja, R. Jahila

Kopar Oy is acknowledged for engineering and manufacturing of robust systems for bulk material handling, especially at power plants and non-ferrous smelters. We have over thirty years of experience with systems specifically designed for hot and abrasive conditions, aiming at low cost of ownership, low operational expenses and high availability. Although Kopar has numerous applications in mechanical conveying, there is an increasing number of pneumatic conveying applications at copper smelters. They relate to conveying of concentrate, and primary and secondary flue dusts. Challenges of pneumatic conveying for concentrate are mechanical and do relate to broad particle size distribution and high abrasivity of the concentrate and the silica. Therefore, special attention shall be paid to system design and ceramically lined bends in the pipeline. Challenges of pneumatic conveying of primary flue dust relate predominantly to material stickiness and poor flowability which are mainly due to fine particle size and formation of sulphates and furthermore, crystalline water. Additional challenges of secondary dust, the white converter dust, are primarily due to the extremely fine 0.1–1.5 µm particle size and problems which come with this. Effect of material characteristics like size distribution, morphology and chemical composition in pneumatic conveying are discussed in detail. INTRODUCTION Fine materials like concentrate, feed mix, flue dusts (from waste heat boiler and electrostatic precipitator) and secondary dusts need to be conveyed at smelters. Both horizontal and vertical conveying and combination of those are used. For the purpose, both mechanical and pneumatic conveying are applied. Most widely used equipment are drag chain conveyors and various combination of pneumatic systems, e.g. air lift, dense-phase and dilute phase pneumatic conveyors. Kopar has 30 years’ experience with multiple material handling systems. Furthermore, acquired companies like Elmomet Oy and SITE Oy (both currently fully merged and integrated into Kopar Oy) have even longer history, especially in pneumatic conveying. It is commonly known that the finer the dust the more difficult it is to be conveyed pneumatically. Sulfates with crystal water makes it all even more difficult, if not ineligible. Challenges related to pneumatic conveying of various fine materials is discussed in detail in the paper.

Jan 1, 2019

By Paul Voigt, Mike Hourn, Glenn Stieper

Sable Zinc Kabwe Limited ("Sable") is a base metal processing plant, two kilometres south of Kabwe Town in Central Province, Zambia. The region has a rich history in mining and minerals production, being a major lead and zinc producer from the 1900s up to the mid-1990s. In 2006, a copper plant was built at the Sable processing site to treat third-party copper and cobalt oxide ores and concentrates. The oxide leaching plant included whole ore leaching, solvent extraction and production of 8,000 tpa LME Grade A copper cathode. The plant was placed on care and maintenance in 2014, and Glencore Plc ("Glencore") took the opportunity to convert the plant using a minimal budget, to an Albion Process™ plant to treat local refractory copper concentrates unsuitable or uneconomic for smelting. The Albion Process™ plant comprises an M100 IsaMill™ operating in acidic conditions such that raffinate from the downstream process is recycled back to slurry the concentrate delivered to site thus maximising copper tenor in solution and reducing water consumption. The finely ground concentrate feeds an oxidative leaching plant using the existing stainless steel oxide leach reactors converted to Albion Process™ duty by fitting HyperSparge™ supersonic oxygen injectors and gas dispersing agitators. The leached slurry is then directed to the existing solid/liquid separation equipment, and the PLS is then sent to the existing SX/EW plant. The plant also allows for cobalt recovery from the raffinate. The plant was designed based on testwork on regional copper concentrates. The plant was designed to toll treat a range of concentrates, and so the design was flexible With the flexibility of the Albion Process™ being one of its distinct advantages, the plant was ideally suited for tolling regional concentrates. The plant was commissioned and ramped up in six weeks using low-grade Zambian copper concentrate, and produced exclusively LME Grade A copper with over 99% leach recovery in the Albion circuit. INTRODUCTION The Sable Zinc Kabwe Limited ("Sable") process plant is located 2 km south of Kabwe town and 140km north of Lusaka in Central Province, Zambia. In 1902, rich deposits of zinc and lead were discovered with mines and processing plants operating in and around the town until mid-1994. In 2000, the Kabwe Mine tailings dams were sold to Sable, a newly established company, as part of a purchase deal for other plots and facilities. Up until 2004, Sable produced zinc cathodes in an SX/EW plant treating wash plant tailing material. In 2004, Sable was acquired by the South African mining company Metorex Limited ("Metorex"), and in 2006 a copper/cobalt SX/EW plant was built to produce copper cathode from malachite ore supplied from the Democratic Republic of Congo. In 2011, Jinchuan Group International Resources Co. Ltd acquired Metorex and Sable was in turn sold to a subsidiary of Glencore Plc ("Glencore").

Jan 1, 2019

By John Babcock, Bryan C. Smith

In a partnership between Luck Stone Corporation and Loudoun Water, a 42” (1.067m) steel pipeline was constructed along the perimeter of an extensive permitted reserve of diabase rock Luck Stone was about to begin mining. Loudoun Water provides drinking water and wastewater services to over 75,000 households in Loudoun County, Virginia. In discussions to establish the 30-foot (9.1 meter) easement for Loudoun Water within the permitted reserve of diabase rock, Luck Stone and Loudoun Water agreed on the following basic conditions: • Luck Stone could execute production blasting as close to the easement as physical conditions of overburden depth permits. We estimated the minimum distance to be about 75-feet (22.86 meters) from the centerline of the pipe. • Loudoun Water would install strain gauges on the pipe every 500-feet (152.4 m) along the entire length of the future reserve area. This resulted in the installation of 18 strain gauges. • Luck Stone would contract a third-party vibration monitoring company, agreed to by Loudoun Water, to monitor the strain gauges and provide seismograph reading at appropriate locations along the pipe as mining progresses. All information would be provided to Loudoun Water. • Luck Stone’s blasting will be conducted in a manner that ensures the recommended strains are not exceeded.

Jan 1, 2019

By H. R. Bullis

"A 2003 paper discussed the idea that as gold mining companies grow larger it becomes more difficult for them to discover or acquire new gold deposits large enough to replace extracted reserves on an annual basis. Deposits of the size required to replace annual production of very large gold producers (VLGPs) are statistically few. An update in 2005 reviewed VLGPs with respect to production, reserves, and reserve life and observed recent changes in the gold mining industry. Now, more than 12 years later, this paper explores how those VLGPs have fared and how the gold mining industry has changed. KEYWORDS Gold, Gold price, Production, Reserves, Very large gold producer (VLGP) RÉSUMÉ Un article de 2003 examinait le concept selon lequel, à mesure que les sociétés d’exploitation aurifère se développent, il leur devient de plus en plus difficile de découvrir ou d’acquérir de nouveaux gisements aurifères suffisamment grands pour remplacer les réserves qu’elles extraient annuellement. Statistiquement, il existe très peu de gisements de la taille requise pour remplacer la production annuelle des très gros producteurs d’or. Une mise à jour de l’article en 2005 se penchait sur la production, les réserves et la durée de vie des réserves des très gros producteurs d’or ; elle portait sur les récents chan¬gements au sein de l’industrie de l’exploitation aurifère. Aujourd’hui, plus de 12 années plus tard, cet article explore l’évolution et les résultats de ces très gros producteurs d’or, ainsi que les changements qu’a connu l’industrie de l’exploitation aurifère. MOTS CLÉS or, prix de l’or, production, réserves, très gros producteurs d’orINTRODUCTION In 2005, the world’s top five gold producing companies were Barrick (after purchasing Placer Dome; 9.1 million ounces; Barrick Gold Corporation, 2005; Placer Dome, 2005), Newmont (8.2 million ounces; Newmont Mining Corporation, 2005), AngloGold Ashanti (6.2 million ounces; AngloGold Ashanti Limited, 2005), Gold Fields (4.2 million ounces; Gold Fields Limited, 2005), and Harmony Gold (3.0 million ounces; Harmony Gold Mining Company Limited, 2005). During the years leading up to that point, there had been a flurry of activity in the gold sector directed at consolidating production and reserves to create very large gold producers (VLGPs). As defined in Bullis (2005), a VLGP is a mining company whose primary busi¬ness is gold production and that has annual gold production more than 5 million ounces. A stated corporate goal of several of the VLGPs at the time was to become the largest gold producing company in the world."

Jan 1, 2019

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019

By David deVries, James Rajith, Paul Mascrenhas, Nurzhan Dyussekenov, Lawrence Hanschar

Kansanshi Copper Smelter commenced operation in March 2015. The smelter features four Peirce- Smith Converters (PSCs) operated in a three hot, two blowing configuration. This paper describes some of the process automation and design features implemented to maximize operational and environmental performance. To ensure that the converters were easy to operate, efficient, and were protected in emergency situations such as power failures or loss of tuyere air supply a significant focus was placed on automated sequences initiated by “one button” operator commands or otherwise automatically by the Distributed Control System (DCS). Examples include: main converter roll-in and roll-out sequences; emergency roll-out in the event of power failure; and the charging sequences for reagents (silica and reverts). Other automated features configured for the PSCs were specifically aimed at maximizing converter capacity and reducing the environmental impact from fugitive emissions. These features include: “one button” in-stack charging; automated restriction of blowing rate based on the available acid plant capacity; and fully-automated control logic for the Secondary Ventilation System. In-stack charging allows anode furnace oxide slag to be poured into the PSCs while the converters are still blowing and still sending off-gas to the acid plant. PSC Secondary Ventilation control logic was configured to require minimum input from the operators while ensuring maximum utilization of the available draft from the ventilation system. Highly automated PSC controls contribute to high utilization, averaging 41.2 in-stack hours per day. INTRODUCTION Kansanshi Copper Smelter (KCS) is located near Solwezi at Kansanshi copper mine in Zambia's Northwestern province. The smelter treats concentrate produced at Kansanshi mine as well as Sentinel mine located 150 km west of Solwezi. Four Peirce-Smith Converters (PSCs) are installed at KCS. The nominal capacity of each converter is to treat 350 t of copper matte and produce up to 250 t of blister copper per batch. Normally three PSCs are hot, with two able to operate (produce off-gas), and the third converter on hot standby. The fourth converter is normally under cold repairs. The blister charge size is relatively low for the matte charged due to the unavailability of tank house or other high copper scrap.

Jan 1, 2019

By H. S. Venkatesh R. Balachander, G. C. Naveen

During the construction of a 1020 MW underground hydroelectric project in Bhutan a huge rock fall took place in the Downstream Surge Chamber (DSC) during March 2016. The total quantity of rock in the fall area is estimated to be about 1,50,000m3 (2.6 billion cubic feet), out of which about 25,000m3 (0.44 billion cubic feet) of muck was removed. The removal of muck was stopped apprehending that the cavity formed due to the rock fall may get further aggravated leading to widening and destabilising the adjacent transformer hall cavern or it might day light as the top cover was about 190m (623 feet). As the fall has virtually blocked the 314m (1030 feet) long cavern and divided it into two different chambers (south and north), and that the muck cannot be disturbed, it was decided to erect concrete wall on either side of the fall up to the cavern roof and then later address the filling of the cavity with appropriate fill material. As the access to the DSC was there for the southern side it was decided to extend a cable tunnel which was terminated at a distance on the north side of the cavern by D&B so that once it gets punctured into the north wall of the DSC it can be used to access the fall from this front too. This is a unique situation where in every blast approaching the DSC, the parting between them is diminishing and hence the tunnel blast will be exerting axial load on the parting wall leading to dynamic transient loading conditions and buckling may take place on the northern wall of DSC. This paper describes the various drill blast combinations adopted for successful excavation of this tunnel.

Jan 1, 2019

By Christopher Jon Preston, Troy Williams, Daniel Roy

There has been significant progress made with narrow vein gold mines in which a second option for crushing has begun to attract attention. To ensure the profitability of a mine that has based its economics on the absence of a crusher station, more than just best blasting practices are required. Using a blasting operation itself as a primary crusher would undoubtedly save enormous capital costs as well as eliminate some of the costs of crushing ore with the result that considerable savings might be realized. The challenge would be to define the conditions necessary to make this type of operation feasible by providing consistent blasting methods that result in a significant paradigm shift with respect to both blasting and current underground crushing methods. A break model has been developed and applied as a technique in designing blasting patterns based on a unit charge blasting geometry and stress reflection from free faces. There are four components to this model and these are 1) unit charge, 2) thermodynamic/energy, 3) stress reflection, and 4) radial break. Some important changes in timing between holes and rows based on rock properties and the percentage of burden moved were also used. On-site testing at a narrow vein gold mine in Quebec Canada, provided measured parameters for the model. No underground crusher was planned - relying only on the fragmentation profile generated by ring blasting. The specification for muck was that the fragmentation profile needed to be 100% < 400 mm (16 in) with no overbreak - with dilution less

Jan 1, 2019

By C. -G. Berg, J. T. Tuominen

Since the beginning of the 20th century, energy efficiency in copper smelting has been improved by a factor of 30 as a result of adopting autogenous smelting processes with more and more efficient waste heat recovery systems, increasing use of oxygen enrichment and countless smaller improvements. Nevertheless, energy in the form of electricity and fuels continues to be the biggest contributor to smelter operating cost. Metallurgists around the world are under constant pressure to find ways to save those precious megajoules wherever they can. One area that is often neglected is the removal of water contained in concentrates. Copper flotation concentrates, as delivered to a smelter, typically contain some 8–12% moisture. This moisture must be removed and the only way to do this is by evaporation, which consumes a lot of energy. Several studies have shown that the most efficient way of removing this moisture is to use a steam- heated indirect dryer—the least efficient way being the feeding of wet concentrate directly into a smelting furnace. Even in the most efficient smelters that employ modern steam drying, the energy needed to remove the moisture from the concentrates constitutes over 15% of the total energy consumption of a smelter – acid plant complex. The major steps that have been taken in the past to lower the energy consumption of moisture removal are the use of drying in general and the adoption of steam drying. The energy efficiency of concentrate drying has been improved by 25% over the last 20 years. The latest giant leap in this area, the Kumera Heat Recovery Dryer, is the result of Kumera’s long-term development in improving the efficiency of concentrate drying. The Heat Recovery Dryer is a novel application of steam drying that uses the waste heat from dryer exhaust gas for drying concentrates, thus, cutting the energy consumption by a further 30%. This paper discusses energy consumption in copper smelting in general and analyzes the energy consumption of concentrate drying in detail. Different dryer types are compared especially from the perspectives of energy consumption and environmental emissions. Applicability of different energy sources for drying is evaluated and discussed. The principle of the Kumera Heat Recovery Dryer is presented along with results from extensive continuous pilot plant tests. Potential applications and the feasibility of Kumera Heat Recovery Drying technology are discussed.

Jan 1, 2019

By Shila Jafari, Mari Lundström, Aleksei Kritskii, Pia Sinisalo

A typical process adopted at nickel plant is the processing of nickel-copper mattes and converter mattes using the following technology: pressure oxidative leaching (POX), solvent extraction (SX), electrowinning (EW), cobalt recovery, and solutions purification. As a result of multi-stage atmospheric and autoclave process leaching, copper-nickel separation is achieved. Cobalt and nickel are further separated by SX. Copper in the process can be removed as copper cake (Cu-cake), which is a by-product with high content of valuable metals. In the current paper, a method combining atmospheric and pressure leaching of Cu-cake in sulfuric-acid media is discussed. Suggested method allows to obtain high copper extraction (>98%), with leach residue containing precious metals and PGMs. Sulfuric acid media was chosen to make the suggested technology adaptable for the primary POX-SX-EW circuit. The initial Cu-cake was analysed and a range of process parameters (t = 25–190°C; PO2 = 0–7 bar) investigated to achieve the optimal conditions for leaching process at the ambient as well as at increased pressure. As a result, an initial process block diagram for the treatment of Cu-cake with high copper leaching efficiency and low metal losses is provided. INTRODUCTION The conventional technology for nickel sulphide ore processing includes the following main stages: froth flotation, matte smelting and converting. The subsequent processing of nickel converter matte is possible using fundamentally different approaches - hydrometallurgical (Llanos, Queneau & Rickard, 1974; Rademan, Lorenzen & Van Deventer, 1999; Kshumaneva, Kasikov, Neradovskii & Belyaevskii, 2009; Dutrizac & Chen, 2013) and pyrometallurgical (Tsymbulov, Knyazev, Tsemekman & Golov, 2007). Hydrometallurgical approach in comparison with pyro-process has several advantages, such as reduced environmental load, reduced PGM losses, increased copper and nickel extraction. Typically, hydrometallurgical technologies include leaching, solvent extraction as well as nickel and cobalt recovery in metallic form by electrowinning or hydrogen reduction or as valuable metal salts via crystallization process (Crundwell, Moats, Ramachandran, Robinson & Davenport, 2011).

Jan 1, 2019

By Yan Jie

A series of production technologies are described for gold recovery from complex gold concentrate blended with copper concentrate treated in the SKS smelting process comprising: 1) Feed preparation and proportionate feeding of complex gold concentrate and copper concentrate; 2) SKS smelting gold recovery operation and process control technology developed based on reaction mechanism, process simulation and slag formation optimization study; 3) a dry-process quenching arsenic collection technology developed during de-bottlenecking severe restriction of SO3 in the off-gas on As collection system by suppressing and eliminating SO3 in off-gas as a result of optimizing SKS smelting process conditions and spraying caustic soda absorbent so as to reduce off-gas dew point temperature; 4) electrorefining of impure anodes; 5) technology for recovering such precious metals as Au, Ag, Pt, Pd, etc. from high-Sb copper anode slime produced as a result of gold recovery from complex gold concentrate by using SKS smelting process. INTRODUCTION Gold concentrate resources in China are mainly found in Shandong province, Henan province and the Inner Mongolia Autonomous Region, etc. Currently, recovery of gold is based on pre-oxidation (roasting) cyanide leaching process. This process produces a large amount of cyanide-containing wastewater, cyanide leaching residue and relatively high SO2-bearing flue gas during production, which can cause increasingly more serious environmental pollution issues. Besides, this process route suffers from a relatively low precious metals recovery (70–80%) found when treating refractory gold concentrate and carbon-bearing gold concentrate. These issues have severely restricted the development of the precious metals processing industry in China.

Jan 1, 2019

By Scott Thayer, Michael Murphy, Natalie Cope, Gabriel Esterhuizen, Anthony Iannacchione, Tim Miller, Brent Slaker

"The Subtropolis room-and-pillar mine extracts the Vanport Limestone (Allegheny Formation, Pennsylvanian System) near Petersburg, Ohio. Strata instability problems associated with excessive concentrations of lateral stress caused the mine operator to implement a change in layout design. This mining method has been identified as a stress control layout, which has been used by other underground stone mines in the past with varying degrees of success. Practical experience has shown that entry headings advance in the direction of the principal lateral stress, producing lower stress concentrations with better mining conditions. It is important to minimize stress concentrations along the mining front, so an arrow-shaped advance is recommended. This technique advances more developments (headings) in a “good” direction and reduces developments (crosscuts) in a “bad” direction. As is expected, the stress control layout enhances the potential for shear failures in crosscuts. It is, therefore, important to focus crosscut engineering interventions that either: (a) lower stress concentrations (for example, an arched roof) or (b) enhance strength of the strata containing the shears (for example, rock reinforcement). This study focuses on observing strata conditions on a regular basis and monitoring the response of this strata to changing geologic and mining conditions through 3D Dynamic LiDAR scans.INTRODUCTIONProject AimsThe Subtropolis Mine is extracting the Vanport Limestone in northeastern Ohio. Since the start of mining in 2006, ground conditions have been significantly affected by excessive lateral stress condition. In some other mining districts with this hazard, certain mine layouts have been shown to lessen the potential for unstable ground conditions. The term “lessen” is used to state the realization that stress concentrations are not eliminated but instead occur in less frequency and intensity, and their locations can be projected.The stress-control mine layout, specifically for large-opening room-and-pillar stone mines, naturally evolved at mines suffering from excessive lateral stress problems. These mines will typically experiment with methods to mitigate adverse impacts, thus developing best practices for their conditions. These practices have evolved into a basic framework for the stress control mine layout. For example, Jack Parker was able to write about personal experiences at the White Pine Mine in Michigan (Parker, 1966, 1973). Various researchers at the U.S. Bureau of Mines (USBM), the Mine Safety and Health Administration (MSHA), and the National Institute for Occupational Safety and Health (NIOSH) have studied the effectiveness of stress-control mine layouts over a wide range of geologic conditions (Emery, 1964; Mark and Mucho, 1994; Iannacchione et al., 2003). While the stress control layout design approach has proven successful in many categories, it can be difficult to implement. For example, excessive stress conditions in crosscuts can put the ground control focused intervention at odds with ventilation and haulage constraints, thus limiting optimal crosscut size, shape, and location. Therefore, more information on the effectiveness of this approach is needed."

Jan 1, 2019

By M. Girard, C. Farsangi, N. Singh

"Canadian Royalties Inc. owns and exploits the Nunavik Nickel Project: a copper and nickel deposit in Nunavik, Québec. The nickel and copper concentrates are filtered by plate and frame filter presses, and are transported 100km north to Deception Bay by truck. As the site is situated in the far north, extreme weather can be detrimental to production: roads can close for significant periods of time, resulting in the concentrator using all its storage capacity. During the winter of 2017, this accounted for over 100 hours of unplanned mill downtime. Different solutions to this problem were evaluated and the most economically viable combination of solutions was determined to be the use of concentrate storage containers and upgrading the plate size of the existing nickel filter press. By satisfying new, increased utility requirements, the cycle times would not change, but produce 30% more filter cake. Simulations were developed to determine the number of concentrate containers needed in conjunction with the upgraded press to eliminate unplanned downtime due to road closures and secure production through the winter. This paper summarises these simulations, the commissioning and start-up of the upgraded filter press, container loading procedures, and how this was put together to achieve a record 2018 winter season with a 90 percent reduction in downtime. The payback period of the project was 4 months. A specialised side-tipping trailer emptied the containers during the fall of 2018.INTRODUCTION The Nunavik Nickel Project is a nickel/copper mining project located in Nunavik, Québec. The nickel and copper concentrates are stored in stock tanks after thickening and are then filtered by plate and frame filter presses at the concentrator before being transported 100km to the shipping port at Deception Bay by trucks. The region is prone to periods of extreme weather during the winter, with winds that can reach +100km/hr and blizzards that severely limit visibility. The roads to Deception Bay are often affected by this weather, causing closures that last an average of 18hrs and as long as 72hrs. Additionally, there is a 15% chance that road closures occur within 24hrs of the last event. This has been an issue for the concentrator team since start-up in 2013, causing unplanned mill downtime every winter (Table 1) due to filling concentrate storage capacity during prolonged closures of the roads to Deception Bay."

Jan 1, 2019

By Tristan Worsey, Nathan Rouse

The Florida legislature allocated funding for the Florida State Fire Marshal (FSFM) to review the applicability of the United States Bureau of Mines (USBM) Report of Investigations (RI) 8507 blast vibration limits with respect to Florida and its soils. The study also discusses whether the current blasting vibration limits set by statute are still appropriate, including a review of measured vibration amplitudes and frequencies, structure responses, and theoretical analyses of material strength and strains.

Jan 1, 2019

By O. Benavente, M. C. Hernández

Selenium is obtained mainly from copper anode slimes, which is a by-product of the copper electrorefining process. Selenium is present in copper anode slimes as silver and copper selenides. Traditionally, selenium has been obtained by pyrometallurgical processes; however, hydrometallurgy has now been incorporated either full or partial to the conventional process. Some hydrometallurgical processes are been developed and used at laboratory level an industrial scale. This document describes theoretical background and results of characterization and dissolution of selenium from a decopperized anode slimes in an alkaline oxidizing system. The results have indicated that the oxidizing leaching process reaches a practically complete dissolution of selenium (up to 90 %); the undissolved portion is due to the generation of a AgCl around the particle surfaces that delays the progression of the reaction. The results indicated that 90% of selenium extraction can be obtained by dissolution under moderate conditions of pH, temperature and reagent concentration in oxidizing medium. INTRODUCTION Selenium is distributed in the earth's crust in most rocks and soils. Selenium is essential, as it has wide range of applications in the medical and food industries as well as, used in semiconductor, sensors and photochemical devices. Selenium is rarely found in the native state, 90% of selenium is obtained from copper anode slimes, which is a byproduct of the copper electrorefining process (Lu, Chang, Yang, & Xie, 2015; Xiao et al., 2017; Yang et al., 2018). In anode slimes, selenium is present as an intermetallic compound, as Ag-Cu selenides. Currently, selenium is recovered from the anode slimes via hydrometallurgical and pyrometallurgical processes (Lu et al., 2015). The traditional pyrometallurgical method recovers selenium effectively, but faces difficulty as a result of increased energy costs and strict environmental regulations associated with the process (Li, Yang, Jin, Chen, & Tong, 2017). Therefore, hydrometallurgical processes are proposed in oxidizing medium such as nitric acid, alkaline leaching with sodium nitrate, wet chlorination and pressure leaching, amongst others (Hait, Jana, & Sanyal, 2012; Kim & Wang, 2010; Xiao et al., 2017; Yang et al., 2018).

Jan 1, 2019

By Erik Westman, Brandon Stables, Benjamin Mirabile

"Standing support is often used in conjunction with underground retreat mining. Knowledge of the load-displacement behavior of standing support and loading induced by the mine opening is critical to proper support selection. The NIOSH STOP database contains load-displacement laboratory test data for most commonly used standing supports. Hydraulic load cells currently used to measure in-situ loading of standing supports have exhibited leakage under load, producing irregularities within the dataset. An improved hydraulic load cell eliminates leakage and produces more consistent data.INTRODUCTIONA hydraulic load cell, more commonly known as a flat jack or JackPack, is a device installed to determine the loading characteristics of the roof-to-floor supports. These standing or roof-to-floor supports include, but are not limited to pumpable cribs, cans, wooden cribs (4-point, 9-point, etc.), metal props, wood timbers, concrete donut cribs, and other variations of these standing supports.Flat jack devices have been used previously to determine the loading of such roof to floor supports. The most commonly used load cell for standing supports is based on a design intended for pre-stressing standing supports, not load measurement. Preloading helps to keep the supports, such as timbers props and cribs, in place during the dynamic loading associated with blasting (Barczak and Tadolini, 2004).Flat Jacks are manufactured in various shapes and sizes depending on the application; common shapes are square and round that are 25.4 mm (1.0 inch) thick when collapsed, as shown in Figure 1. These load cells are produced in South Africa and can be formed into several different shapes depending on the application (Barczak, 2003). The sheet metal that makes up the bladder is comprised of 19-gauge or 1.11 mm (0.04 inch) thickness; the top and bottom pieces of sheet metal are resistance-seam welded around the perimeter. There are two different ports installed on one of the bladder skin corners of the flat jacks; these ports allow fluid to fill the unit, and the other port has a relief valve. The fill port is comprised of a check valve. The pressure relief valve is located in the second port; preset to 1,724 kPa (250 psi), the pressure relief valve keeps the load cell from bursting. Bursting of these load cells typically causes a small tear in the metal skin allowing the fluid to leak out without a large catastrophic failure.The effective inflation range of these load cells is between 25.4 mm (1.0 inch) to 254.0 mm (10.0 inches) thick. Different types of fluids can inflate these load cells but the most common and easily accessible fluid for testing applications is water. Water pressure from the mine supply line can inflate these load cells to the desired load. Depending on the pre-stressing requirements, a pneumatic powered pump, hydraulic pump, or hand pump may be required to inflate the load cells."

Jan 1, 2019

By J. Coffin, R. Multani, C. Deredin

Glencore’s Strathcona Mill has recently evaluated a pyrrhotite depressant combination of diethylenetriamine (DETA) and sodium metabisulfite (SMBS) to improve its overall plant pyrrhotite- pentlandite (Po-Pn) selectivity, with the aim of producing a higher quality nickel concentrate. In a previous paper, key findings from a comprehensive lab-scale program (completed at the XPS Centre) were summarized where, of the depressants tested, DETA/SMBS combination was found to be the most effective in improving the Po-Pn selectivity. The present paper describes the metallurgical program recently completed at Strathcona Mill; DETA/SMBS evaluation on select plant “grab” samples as well as the major results of three DETA/SMBS plant trials conducted on several plant ore feeds (long-term testing). Interestingly, it was found that there was variable success in using DETA/SMBS depressants on the different plant ore feeds; DETA/SMBS (dosage: 25/50 g/t milled feed) on lower Cu feeds demonstrated a ~2% Ni recovery increase at the same Ni grade. On the other hand, higher Cu feeds demonstrated virtually no benefit from DETA/SMBS at the same plant dosage, suggesting that higher DETA/SMBS dosage (at specific locations) than that tested is required to overcome the increased Cu-DETA complexation for these particular feeds. Glencore Nickel – Sudbury Integrated Nickel Operations owns and operates Strathcona Mill which has been processing Ni-Cu ores from the Sudbury Basin since 1968. The valuable sulfides are pentlandite (Pn) – (Ni,Fe)9S8 and chalcopyrite (Cp) – CuFeS2, majority of the sulfide gangue is pyrrhotite (Po) – Fe(1-x)S [0 < x ≤ 0.125] which is present in two forms: hexagonal Po (Fe9S10) and monoclinic Po (Fe7S8) (Multani & Waters, 2017; Lawson et al., 2014). Currently Strathcona Mill processes ore mined from two primary sources from the Sudbury area and produces two concentrate streams: (1) nickel-copper concentrate that is sent to the Sudbury Smelter; and (2) copper concentrate that is shipped to the Fonderie Horne (Glencore Copper, Rouyn-Noranda).

Jan 1, 2019