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By L. Hanschar, C. Bwalya, E. Mokola, K. Musonda, A. Makayi

This paper describes the installation, commissioning and operation of porous plugs featuring nitrogen gas purging in both Anode Furnaces at the Kansanshi Copper Smelter (KCS), a greenfield copper smelter which commenced operation in March 2015. The decision to install porous plugs was taken in November 2016 and the facilities were successfully commissioned on both anode furnaces in October 2017. The project was successful and has demonstrated the following process improvements: 12.2% reduction in main burner fuel consumption Larger average charge size, due to fewer accretions; 17 minute decrease in average refining cycle times Improvements in slag skimming operations Improved casting rates INTRODUCTION Porous plugs The application of porous plug technology in copper smelter anode furnaces is well established around the world. Vukovic and Gamweger (2017) and Wallner (2004) noted that the stirring and mixing action induced by the injection of inert nitrogen gas into the molten copper via porous plugs has potential benefits in the following areas: Homogenization of the temperature and composition of the molten copper resulting in Reduced fuel consumption Less tendency to overheat slag (reduced risk of refractory attack) Less slag produced with a lower degree of oxidation (lower rate of refractory wear) Less tendency for buildups to form Improved environmental performance (produce low sulphur blister at Peirce Smith converters) Elimination of buildups inside the furnace and potential for larger charges per cycle Reduced processing times and potential for shorter cycle times More efficient skimming of anode slag Shorter skimming time Less copper carry over to Peirce Smith converters Very little slag remaining in the furnace (reduced potential for buildups to form)

Jan 1, 2019

By S. Hunt, D. de Vries

Kansanshi Copper Smelter began operation in March 2015. The smelter features a single Isasmelt furnace for smelting, one 6-in-line electric furnace for matte-settling and slag-cleaning duties, four Peirce- Smith converters and two rotary anode furnaces. A 1,450 t/day oxygen plant and a 4,085 t/day sulphuric acid plant are included in the smelter operations. This paper gives an overview of the operational performance to date with summary data for each smelter section. Challenges such as an unforeseen refractory failure in the Isasmelt furnace in 2016 are discussed. Design improvements around the electric furnace are mentioned. Plans for potential future improvements are put into context. A consistent focus on operations, maintenance and continuous improvement has seen the smelter easily achieve its nameplate capacity of 1.2 million tonnes per annum of copper concentrate throughput. The smelter now operates consistently at a concentrate throughput rate of 1.38 million tonnes per annum of copper concentrate. INTRODUCTION The smelter was commissioned in March 2015. Design and commissioning of the smelter have been discussed by de Vries, Hunt, Hanschar and Louie (2016). The smelter rapidly ramped up to achieve nameplate production (1.2 million tonnes per year concentrate) and in 2018 operated consistently at the rate of 1.38 million tonnes per year concentrate. This paper presents major operational data for each section of the plant and describes significant events and improvements during the first four years of operation. The smelter flowsheet is shown in Figure 1.

Jan 1, 2019

By G. Stokreef, B. R. Davis, M. Kadiyski, Alvear Montenegro, H-P. Loock, V. Montenegro

An optical probe for burner monitoring in copper flash smelting, first developed at the University of Concepcion, is being industrially tested in a collaboration between Kingston Process Metallurgy, Aurubis AG, and Queen’s University. The sensor uses fibre-optics and optical emission spectroscopy to analyze the light emitted from combusting particles in the furnace reaction shaft. Information that can be extracted from the emission spectrum includes the temperature and brightness of the flame, as well as emission lines or bands from excited atomic and/or molecular species. Laboratory proof of concept testing of the sensor was first completed in a continuously fed drop tube reactor using O2/S stoichiometric ratios between 0.8–4.0. These O2/S stoichiometries capture the industrial operating condition, which is typically less than 1. The results from lab testing justified a plant trial of the optical probe, which was done in the Aurubis Hamburg flash furnace in September 2018. From this trial, approximately 31 hours of spectral data were collected and synchronized with furnace operating data. The results from both drop tower test work and the plant trial are discussed with implications for process monitoring in the commercial furnace. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process. It is used to treat copper sulphide concentrates and small amounts of secondary materials, such as dust generated by the process. O2 enriched air and the concentrate blend are fed into the furnace reaction shaft through the concentrate burner. As the particles fall through the reaction shaft, they heat up and ignite, causing rapid, exothermic reactions that oxidize the iron sulphide, some copper sulphide and impurities in the feed. Reacted particles fall into the settler of the furnace, melt and separate into a matte and slag, while the SO2 enriched off-gas is carried out of the furnace for heat recovery and H2SO4 production. Operation of the furnace is achieved by adjusting a limited number of control variables. The main variables are the blast feed rate, blast oxygen enrichment, SiO2 flux feed rate and CH4 combustion rate (CH4 is used when the chemical energy of the concentrate is low) all measured relative to a set feed throughput. (Davenport & Partelpoeg, 1987; Davenport, King, Schlesinger & Biswas, 2002) The batch tapping nature of flash furnaces makes operation difficult because these control variables impact each other, and product quality can only be measured when matte and slag are tapped from the furnace. This means that operation of a furnace is based on feedback control from matte and slag assays. Because of the time-delay associated with understanding product quality, there is interest in using technology to monitor the combustion reactions that happen in the furnace reaction shaft.

Jan 1, 2019

By Z. Q. Liu, J. M. Du

"On the basis of analyzing current design and applications, the structure form, working loads and design principles of shaft sinking headframe are summarized in this paper. To overcome the insufficient bearing capacity and geometry size of the finalized shaft sinking headframe in China, a series of new large shaft sinking headframe were developed under vertical shaft construction conditions of maximum net diameter of 12.0 m and maximum depth of 1200 m. The new series shaft sinking headframe include two sets (with single sheave platform and double sheave platform), three dimensions (optimum shaft diameter <8.0 m, 8.0-10.0 m, and 10.0-12.0 m, respectively) for each set, and has innovation and optimization on structure of the sheave wheel platform (MU type) and bracing frame (REN and ZHONG type). The largest new shaft sinking headframe can arrange up to 4 hoisting equipment simultaneously and has bearing capacity more than 10000 kN. Two of the new shaft sinking headframe were successfully applied in practical engineering, such as the Hulusu auxiliary shaft, the Dahaize 1# auxiliary shaftand Sishanling auxiliary shaft. These applications showed that the new shaft sinking headframe has sufficient bearing capacity and reliable applicability. The new shaft sinking headframe could provide an effective guarantee for safety and efficiency sinking of deep-large shaft in the future.INTRODUCTIONShaft sinking headframe is one of the basic shaft sinking structures and it is mainly for hanging hoisting containers and sinking facilities in sinking a vertical shaft (Yu & Shi, 1991; Wang, Jing, & Liu, 2007). Currently, 7 types of steel pipe sinking headframe are used in China, which are mainly finalized by the Ministry of Coal Industry of China (Wang, 1988). As shown in Table 1, V-type is the largest of them and it is only suitable for sinking shaft of diameter less than 8 m and depth less than 1 000 m(Yang, 1982). However, with the increase of mining depth and scale of mineral resources in China, the diameter and depth of newly built vertical shaft are increasing continuously (Xie, Zhou, Xue, Wang, Zhang, & Gao, 2012; Qi & Pu, 2013). At present, the maximum net diameter of vertical shaft is close to 12 m, and the maximum depth is more than 1600 m (Yang & Chen, 2015; Xu, Yang, Liu, & Qin, 2015). The shaft sinking headframe has become the main restrictive factor for the development of sinking equipment, such as the height of muck discharging platform cannot meet the usage requirement of hydraulic umbrella driller, the size of sheave wheel platform is difficult to arrange the increasing hoisting and suspension equipment, the bearing capacity is insufficient to meet the needs of multiple hoisting loads in sinking a deep-large shaft, etc. Therefore, development of new shaft sinking headframe for deep-large shaft (>1000 m in depth and 8~12 m in diameter) is urgently required for China and also the whole world."

Jan 1, 2019

By A. Thatcher, C. Day, C. Meyer

The purpose of this paper is to provide general information about the bioaccessibility of metals and specific information about the use of bioaccessibility in risk assessments (human health risk assessments [HHRA] or ecological risk assessments [ERA]) and a list of sites where regulatory agencies have approved the use of bioaccessibility data in risk assessment. The memorandum also cites current U.S. Environmental Protection Agency (USEPA) guidance as well as state specific guidance where applicable. BRIEF HISTORY OF METAL BIOACCESSIBILITY TESTING AND METHODS The bioaccessible fraction of a constituent is that fraction that dissolves or desorbs from its matrix (e.g., soil) in the gastrointestinal tract and is available for absorption (USEPA 2007a; ITRC 2011; ITRC 2017). This is different from the bioavailable fraction, which is the percentage of the amount of an element that an organism is exposed to that is absorbed by that organism during a given time under defined conditions (USEPA 2007a). The bioaccessibility factor is the percentage of a metal that is potentially available for absorption and, therefore, is a conservative estimate of the bioavailable fraction since all that is available for absorption may not ultimately be absorbed into the organism’s system. Currently, there are two main techniques for estimating bioavailability of metals within a medium: in vivo animal studies (time-consuming and often cost-prohibitive), and in vitro tests that simulate human, or animal digestion in a laboratory setting. In vitro and in vivo test methods and protocols have been extensively evaluated by numerous researchers (Ruby et al. 1996; Rodriguez and Basta 1999; Sips et al. 1998; Sips et al. 2001; Molly et al 1993; Oomen et al 2002; Kelley et al. 2002; Oomen et al. 2003; Furman et al. 2006; Drexler and Brattin 2007; Basta et al. 2007; Wragg et al. 2009; Wragg et al. 2011; Chaney et al. 2011; Bradham et al. 2015; Bradham et al. 2018). The most recent scientific literature demonstrates that protocols used to estimate the bioavailability of metals to mammals also predict bioavailability of metals to birds as well (Beyer et al., 2016).

Jan 1, 2019

By J. Poplawski

In mineral processing plants, cyclones typically perform the classification duty prior to the downstream recovery process. Particle size distribution of the cyclone overflow is an important parameter and can be viewed as the product of the comminution process. Too coarse of a product will likely have poorly liberated valuable minerals and make recovery difficult. Too fine of a product may represent a missed opportunity to increase plant throughput and/or also result in low recovery due to poor kinetics. “Near-line” particle size measurement instrumentation has been in place for several decades, its availability and low measurement frequency have typically been inadequate for reliable use in automatic control. CiDRA Minerals Processing has developed a novel and robust technology that provides a highly reliable and low maintenance system for “on-line” measurement of the particle size in the overflow of individual cyclones. The system is based around a wetted sensor design with no moving parts and provides a real-time trend of the desired target grind size parameter. The system does not require sampling and associated sample transfer piping that is prone to plugging, thus avoiding high maintenance requirements. Plant data and benefits realized from the latest installations of the CYCLONEtrac PST will be presented. INTRODUCTION Impact-based real-time hydrocyclone particle size measurement Acoustic impact-based particle size tracking is a unique method for measuring and controlling the particle size in cyclone overflow streams. The implementation of this technology is centered upon a sensor probe that is inserted into the overflow slurry stream via a two-inch (50 mm) hole in the overflow pipe (Figure 1). Particles within the slurry stream impact the surface of the probe generating travelling stress waves within the probe. A sensor converts these travelling stress waves into an electrical signal and proprietary signal processing techniques convert these signals into a particle size measurement that is output every four seconds. The sensor is constantly in contact with many particles in the slurry stream, thus obtaining information from orders of magnitude more particles than traditional sample-based technologies. The sensor has no impact on cyclone performance because it is located downstream of the hydrocyclone and the presence of an air core ensures there is no change in the back pressure seen by the hydrocyclone.

Jan 1, 2019

By R. Stach, S. Gola, P. Zgrzebski, K. Soroko

"At the moment climatic conditions are a primary problem of the exploitation of copper ore. The efficiency of preventive actions in order to improve climatic conditions is connected with the knowledge of changing air in underground excavations. This article demonstrates the analysis of types of ventilation dams which are used in sealing abandoned areas on the maintenance of climatic working conditions in excavations has been conducted at the exploitation in Polish copper ore mines. INTRODUCTION The basis for mining activity performed by KGHM Polska Miedz S.A. is mining copper ores from the deposit lying at depths between 600 and 1,200 m below ground level. Activity has continued since 1963. The copper ore deposit is mined in ‘Lubin’, ‘Rudna’ and ‘Polkowice-Sieroszowice’ mines, where difficult climatic conditions occur. The major factor moulding the climatic conditions in headings is the original temperature of rocks, being the result of geological conditions of the lying of the deposit and the existing geothermal degree. In the faces of present opening-out and preparatory headings, driven from mining areas of ‘Rudna’ and ‘Polkowice-Sieroszowice’ mines in order to open out deeper parts of the deposit, the original temperature of rocks reaches 45°C. Excluding the original temperature of rocks, the following are additional factors affecting the deterioration in the climatic conditions: • thermal properties of deposit rocks, • employed room-and-pillar mining systems, which are characterised by a large surface of exposure of rocks, • using self-propelled mining machines with diesel drive, • a high concentration of mining works, • setting up high-power electrical equipment in headings, • complex structures of mine ventilation networks, • a limited number of ventilating shafts, • constantly longer air-transport routes, • a significant accumulation of water increasing the humidity of supplied air. According to the valid Polish provisions (§21, 2013), the primary criterion of assessment of a climatic hazard is the occurrence at a workstation in an underground mining heading of an equivalent climate temperature of more than 26°C, which temperature is determined according to the following dependence:"

Jan 1, 2019

By Jerry C. Tien, Yingjiazi Cao

"Coal spontaneous combustion (SponCom) is a natural phenomenon in underground operations, which can either happen naturally or be triggered by human activities. For underground operations, espe-cially in coal, SponCom can happen frequently as a result of air leakage, although its incubation period may vary depends on types of coal and surrounding environment, resulting in uncertainty in control. In China, most of the underground coal operations now use longwall mining method because of its superior safety, high productivity and efficiency. With an increased popularity, there is also an increasing necessity to study spontaneous combustion, its occurrence and management. There have been many theoretical analysis and experimental studies over the past half century hoping to understand the occurrence of coal combustion and its control measures to better understand the occurrence and to design controlling measures to limit the dam-age it causes. In this paper, research on coal spontaneous combustion fundamentals from these three aspects will be reviewed, gaps highlighted and possible directions for future studies. INTRODUCTION The history of anthropic development is the history of human's energy utilization progress. From the first usage of fire, people have been continuingly seeking energy resources on earth. Coal, as an abundant, economic and convenient source of fuel quickly became indispensable and made significant contribution to economic growth worldwide. With technology and societal development, people are becoming more and more coal-dependent, but at the same time, problems of fossil fuel combustion came into sight. In global coal mining industry, spontaneous combustion has now presented one of the most challenging safety issues, it is also believed that it has contributed significantly toward the climate change. It is essential that more effort be invested to examine the cause of SponCom and its control measures. Coal SponCom is a complex process, with both physical and chemical inter-actions among various interrelated factors such as local airflow distribution, ventilation pressure, methane emissions (if any), and physical surroundings underground. With the advent of powerful computers, simulation techniques and af-fordable modelling packages in recent years, significant advances have been made in understanding sponta-neous combustion. But because of the complex nature of combustion and varying underground conditions, there are still areas that need further examining. This paper will focus on illustrating the current research of coal spontaneous combustion and addressing research gaps and future study areas."

Jan 1, 2019

By D. M. Ziebarth

"Normal sequence of operations to develop a new underground mine is: construct and outfit headframe for shaft sinking, sink shaft, construct and outfit shaft sump, develop shaft station and shaft bottom steel. In an effort to reduce the overall project schedule, an innovative plan was developed to install service shaft steel below station level, prior to the completion of the shaft sinking effort. To better evaluate the construction of this substantial steel tower, a preliminary constructability evaluation was conducted, including the best method of supporting the main tower; from the bottom, middle or top of the tower. The design criteria and plan involved: •,Develop access from existing service shaft, 25 km underground •,Use of materials to maximize strength while minimizing corrosion exposure •,Estimating the location of the shaft centerline •,Over excavating the station and shaft below station to allow future shaft steel repositioning •,Designing the tower steel for modular installation •,Incorporate commissioning considerations, such as suspension of the cheese weights during steel installation •,Provision for covered stair access to shaft bottom •,Enclosed shaft envelope with open panels to allow visibility and ventilation The design approach was innovative and this paper will describe the design principles and challenges encountered while providing insight into the solutions developed and implemented; especially the modular construction and installation methodology. INTRODUCTION In an effort to expand the mining operations, a plan was developed to construct a new service shaft closer to the new mine workings and convert the existing service shaft to a production shaft at the Potash Corporation of Saskatchewan Inc. (PCS now Nutrien) Rocanville Potash mine in southeast Saskatchewan. The new service shaft required a multi roped friction hoist operating a cage / counterweight, rope guided conveyances to support the operational requirements. The service shaft is an integral part of the mining infrastructure as it provides access to the underground workings, transport personnel and materials underground for operation and maintenance of the mine. The shaft also allows for services required for safe operation of the underground mine, power supply, controls, communication, dewatering and fresh water supply."

Jan 1, 2019

By U. Caliskan, S. Miskovic

Gravity separation is a technique that depends on the difference in density of minerals for their separation. Although this method is one of the oldest separation techniques, it is still preferred in the industry because of its low capital and operating cost while it is environmental-friendly. In this paper, we present a new numerical methodology that can be used to investigate dynamics of dense slurry flows in gravity separation systems. A simple channel with a set of riffles is selected as a test platform in order to observe the effect of the riffle shape on segregation profile of particles with different densities. It is believed that the riffle shape would affect the slurry flow and possibly cause one class of particles to segregate within the riffle zone. The turbulence, as a disturbance effect within the riffle zone, causes heavy particles to displace the light, that is, the heavy particles will be trapped in riffles, while the lighter particles are carried by water to the end of the channel, which is an example to uninterrupted suspension. MP-PIC model in OpenFOAM is used to study the effect of riffle shape and slurry percentage of solids in this simple gravity separator on particle segregation profile of four discrete mineral density classes, which are Quartz/Clay (SG 2.6), Pyrite (SG 4.2), Chalcopyrite (SG 5.1), and Gold (SG 19.32). Gold particles are found to be readily captured and retained in the riffles because of their high density, while particles with the intermediate densities are more influenced by the flow. The developed model framework has been proven robust and capable of providing physical results even for the flows with a very high percentage of solids, characteristic for mineral processing operations. INTRODUCTION Gravity-based ore concentration techniques make use of differences in density of minerals within an ore to enable separation of valuables from the gangue. As some of the oldest techniques used for ore beneficiation, they are known to offer a range of benefits such as low specific energy consumption and low capital and operating costs (Burt, 1999; Falconer, 2003; Holland-Batt, 1998), however, they suffer from low selectivity, poor separation efficiency, and low capacity. Gravity separation techniques are common practices in the mining industry and are employed widely for the precious mineral concentration, iron ore recovery and coal preparation (Kroll-Rabotin, Bourgeois, & Climent, 2013; Laplante & Spiller, 2002; Williams, 1997). For example, gravity separation systems are highly applicable for precious metal enrichment operations by being included in primary grinding circuits, shaking table tailing separation, pre-concentration of leach feed and flotation concentrate enrichment for both flash and conventional flotation purposes (Burt, 1999; Falconer, 2003; Holland-Batt, 1998; Laplante & Spiller, 2002; McAlister, 1992). Gravity separation can be employed in the copper processing circuits by being integrated into the pre-flotation circuit to capture the gravity recoverable gold (GRG) and any free copper aiming to enhance the gold and copper recovery of the plant. When native copper and GRGs are present in the deposit, this integration not only facilitates plant overall performance via removal of the valuables early in the circuit, but it also reduces downstream operational expenditures due to less retention time of coarser copper particles in the system.

Jan 1, 2019

By R. Viljoen, K. Manns

"The mining industry instinctively follows rule-of-thumb design velocities often based on very simplistic theoretical “economic velocity” optimization calculations to determine airway sizes. Although these are important building blocks in ventilation planning it should be recognized that mines are far more complex and various, often opposing factors, are at play. Therefore, it is important that each ventilation situation be analyzed on a case-by-case basis to determine the best-fit solution for an operation. The ventilation design process should not necessarily be constrained by theoretical optimal economic velocities that become rules-of-thumb. In some cases, this could lead to unrealistic infrastructure requirements and exorbitant capital expenditure. This type of design often lacks corporate support leading to a scenario where no ventilation upgrades are implemented. Economic velocities typically consider the cost of power, development costs and operational risk. These typical rules-of-thumb work reasonably well as a starting off point when considering feasibility of greenfield projects. For established mines that are looking at expansion these rules may not be appropriate due to capital expenditure constraints or geotechnical ground conditions. The theoretical optimum should be reviewed in the case of an established mine where existing infrastructure could perhaps be maximized. For example, the geotechnical risk of large diameter raises at depth may require multiple small diameter raise to maintain the theoretical economic velocity. If a mine has a life of less than 5 years, then the cost of power is an insignificant proportion of the total owning cost. For these mines, operating the ventilation raises at an increased velocity to avoid a complicated and expensive capital upgrade might be the more appropriate option, even though it opposes the traditional rules-of-thumb. Mines which are capital constrained may be better off accepting a higher operating cost for the interim or settle for minor infrastructure upgrades rather than run the risk of the entire ventilation upgrade not being approved at all. This paper explores a number of examples derived from case studies undertaken by the authors for several deep mechanized mining projects in Australasia. The examples explore conditions under which higher than the economic norm would be applicable."

Jan 1, 2019

By J. A. Scott, K. Moreau, H. Shang

"Trials of automated technology at underground mine sites around the world have reported increased production and the potential for lower energy consumption. Autonomous mining eliminates a range of delays related to operator downtime and travel to the workface and facilitates continuous operation in conditions that are unsafe for workers. Automation also introduces complexities and safety hazards arising from equipment–personnel interactions; automated processes must be isolated from other stope-cycle–related activities such as production drilling, development, loading, and backfilling, poten¬tially requiring changes to the mine design to maintain an efficient and safe operation. This paper reviews and discusses the implementation of automated equipment in deep underground mining operations and the challenges and advantages associated with the technology. ¦ KEYWORDS Automated equipment, Emissions reduction, Energy, Productivity, Sustainability, Technology, Underground mines RÉSUMÉ Des essais de technologies automatisées dans des sites miniers souterrains aux quatre coins du monde ont indiqué une production accrue et la possibilité de réduire la consommation d’énergie. L’exploitation minière autonome élimine tout un éventail de retards liés aux temps d’immobilisation des opérateurs et aux déplacements vers le front de taille, et facilite l’exploitation continue dans des conditions qui s’avèrent peu sécurisées pour les travailleurs. L’automatisation introduit également des complexités et des risques pour la sécurité, qui surviennent en raison des interactions entre l’équipement et le personnel. On recommande d’isoler les procédés automatisés des autres activités liées au cycle des chantiers telles que le forage de production, le développement, le chargement et le remblai, ce qui pourrait entraîner des changements au niveau de la conception de la mine afin de préserver rendement et sécurité dans l’exploitation. Cet article examine et aborde la mise en oeuvre de l’équipement automatisé dans des exploitations minières souterraines profondes, ainsi que les enjeux et les avantages associés à cette technologie. ¦ MOTS CLÉS durabilité, énergie, équipement automatisé, mines souterraines, productivité, réduction des émissions, technologieINTRODUCTION As the mining industry continues to exhaust easily accessible orebodies, the need for efficient, deep (typically below 2,500 m) mine operations increases (Atlas Copco, 2013a); however, the mining process can become economically infeasible at great depths because operation costs drastically increase. This has resulted in investigations into automating mining operations as the industry strives for improved productivity (Schunnesson, Gustafson, & Kumar, 2009) and ways to remove personnel from hazardous work areas."

Jan 1, 2019

By Kyle Wagner, William Joa, Colter Angell, Catherine Johnson, Marty Langenderfer, David Doucet

The goal of any business is to seek the maximum profitability for the organization through optimization the use of resources, processes and the application of new technologies. An analysis of various case studies demonstrate that blasting can have positive impacts on the crushing and milling processes resulting in increased profitability for the mining industry (Grundstrom, Kanchibotla, Jankovich & Thornton, 2001). This paper describes the case study of two copper mines in Peru producing Cu-Mo and Cu-Au concentrates, which together with their strategic partner, have implemented a project focused on the improvement of rock fragmentation. The project was based on techniques of pattern size reduction, the use of high energy explosives and the technology of electronic initiation. Combined, these techniques were shown to have significantly impacted the efficiency of downstream processes.

Jan 1, 2019

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By T. E. Wakefield

"Final Galloway (stage) designs for vertical drill and blast shaft sinking projects evolve from complex thought patterns which integrate operational processes, systems and methods of communication, power supply, drilling, blasting, ventilating, mucking, supporting, surveying, dewatering, sealing, concrete lining and shaft furnishing. Attention to ergonomic design detail at the shaftsman / structure interface is at the heart of safe and successful multi-deck working platforms. For economy the end product must have a low mass to reduce suspension rope end loads to be able to use smaller suspension hoists and have lighter headframe structures, be robust to withstand concussion damage, be easily constructible on site, be maintainable in the shaft barrel, and comply with safety and legislated standards. This paper’s ambition is to describe a systematic design framework and sequenced thought process that delivers a product that is engineered with excellence, illustrated by making use of two designs that evolved during recent Galloway projects, one destined for a large diameter man/material shaft, the other for a ventilation shaft. The stage engineering iterative process starts with mapping permanent and sinking hoisting layouts, followed by laying out horizontal deck plans, mostly constrained by the permanent shaft purpose and configuration, whilst maximizing openings to enable muck to be removed rapidly for the best sinking cycles. Concurrently the designer needs to understand the chosen sinking methodologies in conjunction with crewing to determine the number of decks and fix their spacing. Insufficient access to move and line up formwork, set reinforcing rods and pour concrete in the confined spaces of the stage is an inherent major risk to be mitigated. An iterative and integrative process follows for the primary configuration which delves into increasing design detail, accommodating all other methodology influences, resulting in 3D layouts for further risk assessment, review and fine tuning by seasoned shaftsmen. INTRODUCTION Documented colliery shaft sinking practice from the late 1800’s makes reference to purpose built walling (bricked lining) cribs with floors suspended in sinking shafts, thereby allowing shaft lining to proceed concurrently with the excavation. Improvements were made by Sir William Galloway who introduced two decks supported at the corners by angle irons. The sinking stage, or Galloway, has developed substantially over time to be the in-barrel heart of the sinking operation, with overwhelming complexity for those who have to design one for the first time."

Jan 1, 2019

By B. M. Kunar, C. S. N. Murthy, B. Rao K

Rock particle size has a very important significance in the mining industry, starting from blasting till the mineral processing. The present study was carried out to understand the particle size distribution in various sieves after conducting the ball milling process. The time of the grinding process was varied at different intervals. It was observed that 80% of the particles of both granite and marble rock samples passed through the 4800 μm sieve when subjected to grinding time of 40 minutes. Also, it was observed the number of particles that were retained in the smallest sieve of <75 μm was higher in the case of granite sample when compared to a marble sample. INTRODUCTION India is a major exporter of granite and marble stones. The major use of marbles and granites are constructing walls and floors. There are several machining processes that are applied before it is used as floors and walls. During this process, wastes are produced these wastes are used in various ways. These include use of powders for clay products (Segadães, Carvalho, & Acchar, 2005), as an additive in cement production (Aruntaş, Gürü, Dayi, & Tekin, 2010), to enhance the properties of brick ceramics (Saboya, Xavier, & Alexandre, 2007), in constructing bricks (Bilgin et al., 2012) and as an additive in concretes (Aliabdo, Abd Elmoaty, & Auda, 2014). Usually, the powder form of marble and granites are used as an additive in the above-mentioned applications. Powders of marble and granite are obtained through the grinding process. One such process of grinding is the ball milling process. In the ball milling process, a quantity of samples along with the charge quantity consisting of steel ball is subjected to a grinding process within a closed chamber as shown in Fig. 1. An even particle size can be obtained through sieving the material after subjecting it to grinding. The present study is planned to understand the particle size distribution in various sieves due to varying time and charge quantity in the experiment. Only time was varied to understand the amount of particle distribution in the case of granite and marble rock samples and a comparison is drawn. A statistical model was developed for marble rock specimen considering the data obtained by varying time and charge quantity in the ball mill experiment.

Jan 1, 2019

By David Newman

"Horizontal stress can have a profound effect on the stability of an underground limestone mine. The presence of horizontal stress is usually determined once the mine has been developed and the orientation of headers and crosscuts are well established. Multiple attempts are typically made to control roof falls without re-orienting the mine. Once the decision has been made to change the orientation, pillar centers, mine opening widths, and the question of how to determine the correct orientation must be answered.A case history is presented to illustrate how geologic structure, ground conditions and roof falls in adjacent mines, the World Stress Map (Heidbach et al., 2016), in-mine measurement of “cutter” roof orientation, the orientation of strata offset (cats eyes) within borescope holes, and the diametral deviation method of determining horizontal strain from drill core were used to establish the most likely range of horizontal stress.The main headers were re-orientated in a direction parallel to the median of the range of horizontal stress. The crosscuts were angled 60° to the headers to avoid being perpendicular to the horizontal stress direction. Pillar centers and opening widths were increased in the favorable stress direction of the mains and decreased in the less favorable crosscut orientation. The major principal horizontal stress magnitude was estimated using the strain measurements from the diametral deviation method and elastic modulus obtained through testing.INTRODUCTIONOver the past decade, there has been a significant increase in the number of underground stone mining operations in the United States. As stripping ratios at surface quarries become uneconomical and reach the extent of the mineral boundary, coupled with the encroachment of urban development on previously rural mining operations, the remaining mine reserves are best accessed through underground development.Although the majority of underground limestone mines in the Midwest are in relatively flat lying deposits with minimal geologic structure, many Appalachian mines are in folded and faulted environments. Tectonic horizontal stresses associated with multiple orogenic episodes are locked in the formation and are released as the underground mine is developed.A common misconception is that horizontal stress impacts are more prevalent at shallow depths where the ratio of horizontal to vertical stress may be high. However, field observations and academic research indicates that horizontal stress conditions may be encountered at any depth due to the tectonic compression of the limestone formation (Esterhuizen et al., 2007; Dolinar and Esterhuizen, 2007; Iannacchione et al., 2003; Slaker, Murphy, and Miller, 2017; Kuhnhein and Ramer, 2004). This paper outlines mine design and layout guidelines for the mitigation of horizontal stress impacts on underground stone mining operations through a case history example. This approach to mine planning and the ability to anticipate horizontal stress can significantly improve future production of multiple levels (Newman and Newman, 2019). As underground stone production continues at deeper depths and in more geologically and geometrically complex mining conditions, an emphasis on ground control and the anticipation of horizontal stress can provide safer and more productive single and multiple level mining operations."

Jan 1, 2019

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

In this project, low grade copper ore samples were obtained from two mining sites in the US, and they were chalcopyrite-rich (sample A) and conichalcite-rich (sample B) ore. Copper grades were 0.6% and 0.4% for the two samples, A and B, respectively. Leaching experiments were conducted by bottle roll tests for 24 hours, and various lixiviant systems were applied. Methanesulfonic acid (MSA) and glycine were used as alternative lixiviants to sulfuric acid. Oxidants including ferric ion and hydrogen peroxide were tested. The results showed the copper extraction of sample A increased after adding 1 g/L ferric ion in sulfuric acid and MSA solution, from 20% to 36%, but further increase was not observed with higher ferric ion concentration. The copper recovery increased significantly with H2O2 concentration, and over 80% copper recovery was obtained with 10% H2O2. For sample B, the copper dissolution kinetics were relatively fast and reached the maximum value in five hours. Around 60% copper were extracted in sulfuric acid and MSA solution. Copper recovery slightly increased after adding ferric ion and H2O2. Glycine is a weaker lixiviant for both samples, the copper extractions were 36% and 4% respectively. INTRODUCTION Chalcopyrite is the most abundant copper sulfide mineral on earth, and it is one of the most refractory copper minerals regarding chemical processing. The declining copper grade and depletion of copper oxide deposits stimulate the development of hydrometallurgical process to extract copper from chalcopyrite. The dissolution of chalcopyrite by ferric ion is normally illustrated as Equation (1) and (2) (Dutrizac & MacDonald, 1974): CuFeS2 + 4Fe3+ → Cu2+ + 5Fe2+ + 2S0 (1) CuFeS2 + 4Fe3+ + 3O2 + 2H2O → Cu2+ + 5Fe2+ + 2H2SO4 (2) However, slow kinetics are usually observed from chalcopyrite leaching at ambient temperature and pressure. Researchers attribute the slow kinetics to passivation during chalcopyrite dissolution, and different passivation products are also proposed (Klauber, 2008). In recent years, many efforts have made to develop new methods to extract copper from chalcopyrite, such as utilizing bacteria or stronger oxidant (Zhao et al., 2015; Ruiz-Sánchez & Lapidus, 2017).

Jan 1, 2019

By G. Hu, P. Chang

"As hydraulic fracturing is forbidden in some countries due to its accompanying environmental pollutions, microwave fracturing was proposed as a substitute technology to enhance coal seam permeability. Its mechanism includes: on the one hand, thermal stress caused by non-uniform microwave heating leads to fracture development in coal body, which increases coal seam permeability for gas; on the other hand, moisture within the coal body that hinders gas desorption and diffusion is removed during this process. To study the effect of moisture content on fracture development under microwave irradiation, high resolution photographs were taken before and after microwave treatment. These photographs were then binarized and skeletonized. Based on the processed photographs, the total area were calculated using ImageJ. The results showed that coal samples with 0% and 25% water saturation have more variation in fracture development as compared to that of samples with 50%, 75% and 100% water saturation. This study can be very useful in gas drainage and gas control in coal mines. INTRODUCTION Coalbed methane (CBM) is a clean energy source as well as a natural hazard to underground mining (Kurnia, Sasmito, & Mujumdar, 2014; Ranathunga, Perera, & Ranjith, 2014). One of the main goals of mine ventilation is diluting methane and removing underground contaminants (Xu, Huang, Nie, Chalmers, & Yang, 2017). Coalbed methane (CBM) has to be extracted prior and during underground mining to avoid methane outburst and explosion accidents. However, with the increase of mining depth, the coal permeability decreases significantly, which makes it hard to extract the methane (Huang, Xu, Hu, Kizil, & Chen, 2018). To enhance the coal seam permeability, many CBM recovery methods have been applied on-site, such as hydraulic fracturing and enhanced coalbed methane (ECBM). However, hydraulic fracturing is restricted due to environmental concerns and ECBM is only suitable for the coal seam with relative large permeability (Bustin, Bustin, Chikatamarla, Downey, & Mansoori, 2016; Huang, Xu, Chen, & Chen, 2018; Huang, Xu, Hu, et al., 2018)."

Jan 1, 2019

By L. Vollert

In-situ recovery of metals is presently experiencing a revival not seen since early applications in amenable copper oxide deposits, uranium and generally applications where neither, porosity and permeability, nor process chemistry have been prohibitively difficult. With ever decreasing grades in current mining operations or Greenfields projects and ever increasing capital and operating costs, in-situ recovery is looked to as the processing option that will both unlock these deposits as well as potentially derive revenue from mineralised waste remaining in the ground once traditional mining and processing methods become uneconomical. In-situ recovery is also being looked to as a mining method that minimises the environmental impact sustained in the application of traditional energy and water intensive mining and processing operations where millions of tonnes of ore are mined from the earth, processed on surface and then disposed of in both waste dumps and tailings facilities. The key challenge facing companies like Newcrest is that these low-grade deposits or remnant mines are generally hard rock applications that require costly methods to liberate the valuable minerals. A further challenge includes identifying suitable chemistries that both facilitate the economic recovery of gold and copper and that may be considered environmentally acceptable. This paper presents a desktop study whereby the issues of access creation and chemical extraction are discussed and evaluated with a view to driving future research in the area and unlocking this application as a real processing option. INTRODUCTION Mining companies are increasingly challenged by low grade, deep and complex ore deposits which are no longer economically exploitable by current methods. The large footprint of current open pit operations can present obstacles for permitting and social acceptance. For these reasons in-situ recovery (ISR) technologies are receiving renewed attention as a technology which could be used to exploit these more complex deposits economically and with less environmental impact. The environmental impact may be further reduced if emphasis is placed on use of renewable energy sources rather than traditional grid power, gas turbine or diesel generators are employed to drive the operation. A potential renewable energy driven ISR mine of the future is shown in Figure 1.

Jan 1, 2019