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By M. S. Greenfield, E. Cocchiarella, S. Chubbs

"At Dofasco sNo.4furnace a variation of the basic oxygen steelmaking process, Klockner Oxygen Bottom Maxhutte (K-OBM), is used to produce steel. Large amounts of hot gases and particulate are evolved during the oxygen blowing phase. A quencher and a venturi scrubber are used to collect over 99.5% of the particulate. In 1990, the authors investigated the effect of foamy slag on the particulate emissions from the furnace. The amount of lime added early in the oxygen blowing cycle was reduced, making the slag more viscous and foamy for a six minute period. Instantaneous particulate emissions were monitored throughout the blow by analyzing quencher and venturi scrubber water samples. Particulate emissions were reduced up to 59% during the foamy slag period.IntroductionThe reduction of the amount of waste generated or control of emissions at source is at the top of the ""3R"" hierarchy of waste management (Reduce, Reuse, Recycle). Process and operating practice changes are often the most economical ways to control emissions. At Dofasco, they investigated the effect of operating practice changes, specifically the formation of a foamy slag, on particulate emissions from steelmaking furnaces. They wanted to determine if a foamy slag changed the quantity and nature of the fume evolved from the K-OBM furnace over the oxygen blowing phase.The Basic Oxygen Steelmaking ProcessesThe basic oxygen steelmaking process (BOP) generates large quantities of very fine metal oxide fume during the production of steel. In this process, scrap steel and molten iron (hot metal) from blast furnaces are charged into a steelmaking furnace. Then pure oxygen is injected and a lime flux added . The oxygen reacts with carbon dissolved in the molten iron to form carbon monoxide. Oxygen lances can have secondary nozzles which introduce oxygen above the bath. This secondary oxygen, known as post-combustion, bums some of the carbon monoxide radiating the heat back to the bath. Particulate and gases rich in carbon monoxide are ejected from the furnace during the oxygen blowing phase and are collected by a gas cleaning system. Typically, more than 99.5010 of the particulate is scrubbed from the gases by high energy venturi scrubbers or electrostatic precipitators. The oxide sludge or dust collected may have elevated zinc and lead which is unsuitable for recycle to blast furnaces. Due to the presence of these undesirable elements, treatment and disposal of steelmaking oxide dust is difficult and costly."

Jan 1, 1993

Some crystal chemical properties of several apatites from Brazilian deposits and occurrences were determined; the samples had different origins (igneous, metamorphic and sedimentary). The aim was to establish relationships to their froth flotabilities behaviour. Detailed X-ray diffraction studies were carried out, to determine precisely the unit cell parameters and the degrees of crystallinity of the apatite samples. A thorough chemical analysis of these minerals was also conducted. Microflotation studies were carried out, using sodium oleate and dodecylammonium chloride as collectors. The crystallinity levels were determined for all samples studied, with the establishment of a crystallinity index, which varied from 10.0 to 4.5, on a normalised scale. A marked dependence was observed between this crystallinity sequence and flotability; for both collectors, flotability dropped drastically for crystallinity indices lower than 8.0. Also, the low crystallinity apatites showed a decrease in floatability, for longer conditioning times.

Jan 1, 1993

By Taner Sumer, H Altay Guvenir

Fragmentation in rock quarries is tried to be achieved by changing the specific charge, drill pattern and bore hole diameters by different experts. This paper is a brief summary consisting of the utilization of practical experiences of the other group on cost optimization procedure that takes into account blasting, transportation and crushing as a whole process and optimize the cost by defining the optimum gelatin based explosives to be used as a main primer of anfo in three different limestone and granite quarries, with similar rock characteristics.

Jan 1, 1993

By Ralph H. Nafziger

The feasibility of smelting a Ni-Co-Cr-bearing laterite ore from southern Oregon was evaluated by the Bureau of Mines. The objective was to prepare a master alloy for subsequent stainless steel production. A mixture of the ore with suitable reductants and fluxes was smelted in a 50-lb-capacity single-phase ac electric furnace under sub- merged arc conditions. The smelting tests produced a metal in which most of the nickel was concentrated. High-chromium recoveries required an excess of carbon. The resulting metal alloys contain sufficient nickel for some stainless steels. Ferrochromium additions would be required to attain suitable chromium levels. This research was conducted under the Oregon Metals Initiative in cooperation with Walter B. Freeman.

Jan 1, 1993

By J. D. Miller

The sedimentary western phosphate deposits of Idaho, Montana, Utah, and Wyoming tend to be calcareous and generally carry a significant amount of dolomite along with collophanite. In some cases, such as the Smokey Canyon Mine, Afton, Wyoming, the ore will also contain mudstone, and in this case the aluminosilicate minerals (clay, feldspar, etc.) together with some dolomite are floated from the collophanite in column flotation cells with an amine in order to meet product specifications (31 % P205) (Service et al.). In other cases, such as the SF Phosphates Limited Mine, Vernal, Utah, the ore is treated by traditional fatty acid flotation of the collophanite with mechanical flotation cells (Weber, 1986). Preliminary tests have now been conducted to evaluate air-sparged hydrocyclone (ASH) technology for the flotation of western phosphate ore. For this preliminary study, samples were taken from the hydrosizer overflow stream (18-21 % P205) at the SF Phosphates Limited Plant in Vernal, Utah for scavenger flotation testing with the 2-inch ASH system in laboratories at the University of Utah. Selected design and operating variables are being studied, and the initial results show that satisfactory separations can be achieved by high-capacity ASH flotation at appropriate operating conditions. For example, with single-stage ASH flotation 80% recovery can be obtained with a scavenger concentrate grade of about 26% P2O5. These results are comparable to, or better than, those obtained at SF plant operations with conventional flotation cells and suggest that ASH flotation technology can be used to good advantage in the phosphate industry. Of course, research should be continued to consider other process streams, optimize the separation efficiency, and evaluate larger diameter ASH units.

Jan 1, 1993

By E. F. Paski

Geological materials are likely the most complex and challenging substances to quantitate by ICPOES (inductively coupled plasma optical emission spectroscopy). For complex materials having widely varying compositions, spectral overlap interferences govern detection and quantitation limits attained by ICPOES based analytical methods.

Jan 1, 1993

By Nickolas J. Themelis

The flash oxidation and smelting of mineral sulfides is a very prominent metallurgical achievement of the second part of this century. Its initial industrial implementation owes much to the work of Petri Bryk, in Finland, and Paul Queneau, in Canada. However, attempts to develop flash reduction pro- cesses, such as the reduction of iron oxide concentrates with hydrogen, have not yet been successful. The author, on the basis of experimental studies on both kinds of flash reaction systems, examines the respective rate controlling phenomena and the relative rates of flash oxidation and flash reduction.

Jan 1, 1993

By Xuanxue Mo, Zengqian Hou

"Abstract -Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcano­ genic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and back­ arc spreading during its evolution and formed a complete trench-arc-basin system, i.e., the Ganzi­ Litang suture zone, forearc basin, outer arc, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate fault­ bound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.Ali VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is two­fold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. Ali deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asyrnmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe_The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerais (Groups I and II) formed during intensifying stages of hydrothermal activity, and the majority of serni-yellow-ore minerals (Group III) formed during a thermal maximum . There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kuroko­ type VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By R-H Yoon

The MicrocelTM column flotation technology has been developed based on the fundamental understanding that the first-order flotation rate constant increases approximately as the inverse cube of bubble size. In this technology, bubbles in the range of 100-400 pm are generated by pumping aerated slurry through an in-line static mixer. The high-shear agitation provided by the in-line mixer produces small air bubbles without requiring large frother additions. This column has been tested successfully for processing a variety of non-metallic minerals including kaolin clay, graphite, phosphate, and feldspar.

Jan 1, 1993

By J. Klemenic

This paper presents an analysis of gold production and prices over an extended period. Production patterns are provided for the world as a whole and for the five major producing countries. Gold prices as a function of interest rates, as measured by municipal bond rates, are given for the period 1947 to the present. World gold production has had a phenomenal increase since 1980, with the exception of South Africa, all major producing nations participated in this increase, even though the price of gold generally has been decreasing since the high level attained in 1980.

Jan 1, 1993

By F. A. Schinner

The present study has investigated the leachability of cadmium sulfide minerals by Thiobacillus ferrooxidans and the electrochemical reactions involved in the process. Using a cyclic voltammetric technic and carbon-paste-CdS electrodes, it was found that the bio-oxidation of semiconductor cadmium sulfide minerals consisted of a number of intermediate electrochemical reactions. The overall reaction was found to be controlled by solid state diffusion as suggested by the chrono-amperometric and chrono-potentiometric measurements. The activation energy of solid state diffusion was determined by the Sand's method to be AE=24.3 kJ. A generalized mechanism was proposed for the bacterial oxidation of cadmium sulfide by T. ferrooxidan and an explanation given for the importance of high redox potential of leach solution versus the decomposition potential of the sulfide mineral. Furthermore, the effects of n-type or p-type character of CdS substrates relative to their bioleachability was discussed.

Jan 1, 1993

By Nicol SK, Engel MD

Ion flotation involves the adsorption of ionic species, in association with surfactant molecules, at the surface of rising gas bubbles, for the purpose of recovering and concentrating those ions. The objective of this study was to optimise the ion flotation process using a heap-leach liquor, containing gold cyanide, and the surfactant cetyl trimethyl ammonium bromide (CTAB). The aim was to minimise the surfactant reagent dose, maximise the throughput of feed liquor in the process, and satisfy the dual constraints of a high gold recovery and a high volume reduction factor. Development of a first order model of the ion flotation process formed the theoretical basis for the test program procedure and the interpretation of the results. Batch tests were used in order to determine the ultimate recovery curve for the heap leach liquor-CTAB surfactant system. The results indicated that a surfactant dose of about 0.083 g/l would be necessary in order to achieve a satisfactory gold recovery. Continuous tests were then performed on a small-scale pilot plant at the Newcastle Laboratories. The optimum result achieved was a gold recovery of 85 per cent, a volume reduction factor of ten, and a feed throughput of 2.3 m3/m2-h. Recent work also indicates that very much higher volume reductions can be achieved using a larger diameter vessel. The improvement may be a consequence of a reduction in wall effects and hence an improvement in foam drainage.

Jan 1, 1993

The Mahakipawa gold deposit is located 21 km northwest of Blenheim. It became the site of a small hardrock gold rush in 1889 following nearby alluvial gold discoveries in 1888. The study investigates the geology of the area of hard rock mining in the vicinity between Cullens and Waikakaho Creeks. The Marlborough Schist which hosts the gold depos, it consists of polydeformed greenschist facies quartzofeldspathic psammitic, pelitic and volcanigenic schist.

Jan 1, 1993

By Ranklin W. J

The mechanism and rate-limiting step of carbonaceous reduction of zinc from slags was investigated in the laboratory. Disks of graphite were rotated in ZnO-containing slags at various speeds for fixed periods at 1250 to 1325¦C. The mass loss was used as a measure of the amount of ZnO reduced. Application of the Levich equation indicated that at rotation speeds at which it is valid, the reduction was chemically controlled with an activation energy of 27 kcal/mol. At zero rotation speed the reduction of ZnO by carbon appeared to be slag-phase mass transfer controlled with an activation energy of 38 kcal/mol. An increase in the FeO content of the slag increased the rate of reduction while an increase in sulphur content decreased the rate of reduction. When FeO was present in the slag, reduction appeared to occur by a combination of indirect reduction of ZnO by carbon and by reduction by FeO with reduction of Fe203 back to FeO by carbon. The effect of sulphur was consistent with a surface blockage mechanism due to the surface active nature of sulphur in slags.

Jan 1, 1993

By D. W. McDonald, N. A. Duke, R. L. Hauser

"Abstract- The NERCO Con Mine is situated in the amphibolite facies aureole of the Western Plutonic Complex overprinting the Yellowknife Greenstone Belt. Metamorphic grade of the upright monoclinal basaltic succession decreases from hornblende-amphibolite facies along the border of the batholith to greenschist facies. Metamorphic isograds, subparalleling the faulted margin of the batholith, transect volcanic stratigraphy and coincide with major gold­ bearing shears.Gold mineralization is confined to north-striking, west-dipping shear zones where hanging­ wall amphibolite facies mineral assemblages retrogress to chlorite-carbonate-sericite-sulfide bearing schists hosting multiple generations of quartz-ankerite veins. The gold-producing portions of the Con and Campbell Shears occur where these structures transect an east trending thermal corridor. The corridor is defined by granitic plugs and a number of related breccia bodies, that can be traced outwards from the batholith across the greenstone belt.Prograde reactions of greenstone during amphibolitization effectively liberate fluids that partition metals. With retrograde reactions at shear zones, gold is precipitated with quartz due to the destabilization of sulfide and arsenic complexes. The coupling of regional prograde metamorphic and restricted retrograde metasomatic overprints suggest mineralization is temporally related to emplacement of the Western Plutonic Complex. Economic gold concentrations within the intrusive corridor indicates enhanced metamorphic overprint of hornfelsed greenstones enveloping satellite intru sives peripheral to the main batholith."

Jan 1, 1993

By Samuel J. Kosa

The Monotube is a uniformly tapered high-strength steel shell pile manufactured for friction pile applications. The Monotube pile was developed in the early 1920's in Canton, Ohio. Its first commercial installation was an Ohio railroad trestle in 1926. The Monotube has been manufactured in the same Canton plant since its inception. The Monotube is produced in four diameters, 12, 14, 16 and 18 inches, with U. S. Standard Gage wall thicknesses of 9, 7, 5 and 3. The uniformly tapered Monotube section can be manufactured in one of three rates of taper.

Jan 1, 1993

By J. H. Meza V

La Caridad operated at only 65% of design capacity during the first five years of operation. After the first major shutdown and repairs to the furnace in mid- 1992, the smelter quickly reached 95% of design capacity. Converter operation is now more efficient; blowing times have decreased from about 1.7 to 1.2 min/ton of matte. Anode copper production is now 15000 tons/month. The increased efficiency provided by better coordination and scheduling ensures La Caridad's ability to operate at present and expanded production capacity while simultaneously meeting environmental control standards.

Jan 1, 1993

By Neill A. O, Worth I, O&apos

The formation of Kalgoorlie Consolidated Gold \lincs 1't% Ltd hati pla,xd all the major the gold producing areas adjacent to the city of Kalgoorlie/Boulder under one management, enabling the development of the 'Super Pit'. This has facilitated the economic optimisation of the resource. Optimisation has been achieved by the timely collection and presentation of data and the use of these data to reduce costs and improve planning procedures.In particular the following issues have been addressed:ò the reduction of the impact of the mining activity on the adjacent urban population centre,ò implementation of safety procedures for mining through underground voids,ò the determination of the optimum bench height and mining method for ore production benches and blast design. This system is fundamentally based on maintaining a high degree of selectivity while achieving a balance of relatively low unit operating costs,ò assessment of the comparable benefits of contractor versus owner operated earth moving equipment, andò the development of effective ore body models, production reconciliation and the long term mine planning procedures to facilitate effective strategic planning.

Jan 1, 1993

The demand for minerals will grow strongly to satisfy the needs of an increasing world population for materials and energy. The technical problems involved in producing these minerals will be daunting and the engineers who will have the responsibility for designing and controlling the mineral production processes must have a high level of skills. This will place a heavy responsibility on the education system. A small number of large, well equipped university departments dedicated to mineral processing and having a close working relationship with the mineral industry, and an international orientation, will be much better placed to meet the needs than a large number of small ill-equipped departments which find it difficult to remain viable in modem universities. Courses in mineral processing must be designed to meet the scientific and technological needs of industry and full use must be made of innovative educational techniques such as video conferencing in delivering the courses. The concept of a major international network of major mineral processing departments which is designed to make best use of scarce academic resources is important and should be considered by the International Committee of the IMPC.

Jan 1, 1993

By Muller GP, van Deventer JSJ

A mineralogical analysis has shown that in the Hartebeesfontein ore studied, uranium is associated mainly with uraninite, sulphides such as pyrite and to a lesser degree carbonaceous material such as thucolite. Little could be learned from the literature regarding the mechanism of flotation of these uranium-bearing minerals. A wide variety of reagents were used so that conditions enhancing the flotation of either the sulphides, carbonaceous material, oxides like uraninite, or combinations thereof, were created. As could be expected, the xanthate based floats gave-better selective recovery of sulphides than oleic acid. A substantial fraction of the uranium is associated with pyrite, so that addition of oleic acid to a xanthate float did not enhance the recovery or grade of uranium. After a pre-leach with sulphuric acid in which the pH and Eh were controlled so as to destroy the uraninite, higher uranium recoveries were obtained for the combined float (xanthate, DTP and oleic) and the DTP float. This was most evident when iron was added before flotation. Roasting, which destroyed the sulphides and thucolite, caused a significant decrease in uranium recoveries. The uranium liberated in this way was obviously not flotable in the same way as the uranium liberated from uraninite. A small amount of iron (2 kg/t) added before milling resulted in slightly higher grades and recoveries of sulphur for xanthate based floats. Higher iron additions had a detrimental effect on sulphur recoveries. Even in the case of oleic acid the addition of small amounts of iron had a positive effect on the recovery of sulphur and uranium.

Jan 1, 1993