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By Y. M. Jubeli

"Gamma-ray spectrometry, an effective tool in geological mapping, was used to de?ne boundaries between various lithological formations in three adjacent areas of Central Syria, namely, the Syrian Desert, Ar Rassafeh Badiayat and the Northern Palmyrides mountains.This paper describes the role of an airborne gamma spectrometric survey which was originally undertaken to assist uranium exploration. Interpretation of the total count data obtained through the survey has led to signi?cant modi?cations and corrections to the previously published distribution map of the palaeogene phosphate rocks.Another important result of the survey is the discovery of four previously unknown phosphorite horizons in the Rasm Al-Aawabed area of the Northern Palmyrides. In addition, previously unknown phosphatic horizons are outlined in the other study areas. The importance of this technique as an effective prospecting method, not only for U but also for exploring for the economically important phosphorite formations in Syria, is emphasized. Furthermore, its role in geological mapping is stressed, especially in areas that lack suf?cient geological data."

Jan 1, 1997

By M. J. Laurila

On-line analyzers have made possible the use of Fuzzy Logic Control (FLC) for local control applications in coal preparation plants. This includes FLC control of complete circuits such as heavy media vessels, cyclones and froth flotation. These circuits can be controlled in real time in a feedback control loop with an on-line analyzer. Control strategies can be readily developed using Statistical Process Control (SPC) techniques which are first applied off-line in manual mode through the use of control charts and then this process is brought on-line using FLC in conjunction with an on-line analyzer to fully automate the circuit. This paper outlines the types of control strategies employed and presents examples of automatic verses manual control.

Jan 1, 1997

By Andreas Nolte

This paper includes a comprehensive report about the metallurgical utilisation of reusable products from electronic scrap recycling, car shredding industry, used glasses an various waste products, such as slimes and flue dusts, generated in a secondary copper smelter. Depending on the copper content, the type of copper compounds and the characteristics of accompanying substances, the materials are treated by smelting in furnaces, operating under reducing or oxidizing conditions. HKs pyro- and hydrometallurgical processes, blast furnaces, converters anode furnaces, tin lead alloy plant and tankhouse will be outlined. The reusable products are categorized according to the origin of the materials and then presented in the form of quantity and quality balances. Processing methods, process able quantities and quality requirements of inputs are described. The utilization degree of the most important metals (copper, tin, lead and zinc) is described with graphics. The report is rounded by information on operating licence according to the environmental regulations of the Federal Republic of Germany and data concerning supply and contracts

Jan 1, 1997

By Rafael C. Castro, John Overton, Gregg Sherry, David A. Sutter

This paper presents an innovative ground support solution developed to construct a tunnel cross-passage for the MUNI Metro Turnback (MMT) Project. A “soft center” jet grouting approach was designed to provide solid ground support while maintaining a soft center to allow for hand-mining of a 2.44 m (8 ft.) wide, 3.66 m (12 ft.) tall and 4.6 m (15 ft.) long cross-passage through soft Bay Mud. Prohibitive costs and schedule impacts associated with mining under compressed air (at the time being used for main tunnel construction) were the catalysts to search for alternative methods for cross-passage construction. Limited surface disruption, relatively low costs, ease of subsequent excavation, nominal schedule impacts and proven local success of jet grouting were key factors in selecting and designing this method of ground support.

Jan 1, 1997

Madison Enterprises Corp. and Matu Mining are currently ex- ploring the Mt. Kare property in Papua New Guinea. The Mt. Kare gold prospect has had a short but very active history, since the first discovery of gold in the area in 1986 the property has sccn: a 3 year gold rush during which 10,000 alluvial miners re

Jan 1, 1997

By Pertti Paavola, Hikki Rasanen

This paper describes a very exacting tunneling project. Planning and technical realization of this service and transportation tunnel was especially difficult as a matter of vibration control, because the tunnel is situated only a few meters under Maria Hospital, which is one of the most busiest hospitals in Helsinki. In this hospital there are many departments for bedpatients, research and treatment with high-tech equipment, operational surgery and a big laboratory. Besides access tunnels are situated near several apartment buildings. The functionality of the tunnel required the placement of the access tunnels to be straight towards these apartment buildings for which special care for blast induced air pressure had to be taken.

Jan 1, 1997

By John G. Oldsen

During the last several years, implementation of trusses, in lieu of wood cribs, has been successful for supplemental tailgate support in the Pittsburgh seam. This paper reviews the truss support system provided by the new high strength 0.6" tensioned cable truss, which is now also being used in cribless tailgates. Cable loading and roof deformation were monitored to evaluate roof and floor performance. The test results indicate that the cable truss system successfully controlled the roof and floor during the first and second panel extraction. This paper will describe the advantages of cable trusses and their load transfer mechanism as well as mine evaluation.

Jan 1, 1997

By Daniel W. H. Su

The importance of incorporating fundamental principles of rock material response and failure mechanics into a pillar strength design model has been demonstrated. To accurately assess pillar strength, a model should account not only for the characteristics of the coal, but also for those of the surrounding strata. The interactions between the pillar and the surrounding roof and floor dictate ultimate pillar strength. Confinement, or the lack thereof, provided by roof and floor frictional end-constraint is one of the most significant factors in the strength of very wide pillars. The best conditions for end-constraint occur with ideally strong roof and floor. In this paper, it will be shown that weak roof and floor may decrease the ultimate pillar strength by as much as 30% compared to ideal conditions. Field observations confirm this pillar strength reduction in the presence of weak roof and floor. Furthermore, rock partings within the coal have a variable effect on pillar strength, depending on the parting strength. A competent shale parting within the coal reduces the effective pillar height, thus increasing the ultimate pillar strength; a weak claystone parting slightly decreases the strength. Imposed load distribution also has a significant effect on pillar strength, such that asymmetric pillar loading, similar to that observed in pillars adjacent to high extraction mining, reduces the ultimate pillar strength below that of equivalent pillars subject to uniform load distributions.

Jan 1, 1997

By Brian W. Stump, David P. Anderson, John Wiegand

Mining explosions are designed for a variety of purposes including the fragmentation and movement of materials. The blast design is dependent on the particular application intended and the material properties of the rock. The range of mining applications from hard rock quarrying to coal exposure to mineral recovery leads to a great variety of blasting practices.

Jan 1, 1997

By Michael D. Justason

This paper details the static and Statnamic load testing on a 600 mm square pre-stressed concrete pile. The pile was located at Pier 15 on the 20 million-dollar Bayou Chico Bridge Project in Pensacola, Florida. The pile was 10.5 meters long and had a design load of 1.3 MN. Three static load test cycles were performed in November, 1996. The Statnamic load test was performed in January, 1997. The Davisson Failure load of the first cycle of the static test was 3.7 MN, and the Davisson Failure load of the Statnamic test was 3.2 MN. The load-displacement curves for the two types of tests were very similar, indicating that the Statnamic load test performed well in the sandy soils. Strain gauges embedded in the pile showed 35% skin friction and 65% end bearing for both test methods. Strain gauges were located at equal spacing at five elevations in the pile. A toe accelerometer verified the rigid body assumption of the Unloading Point Method currently used in the analysis of Statnamic load tests. The data collected from the pile instrumentation was of excellent quality and represents some of the best research to date comparing static and Statnamic load tests.

Jan 1, 1997

By G. Van Weert, A. van Sandwijk, O. W. J. S. Rutten

"Cathodic and anodic reactions in an acidic nitrate medium were studied in reference to the production of electrolytic manganese dioxide from pyrolusite' (Mn02) ores by reductive leaching. Two USA ores were investigated. The reductant for the pyrolusite ore is produced cathodically in an electrolytic cell and can either be nitrous acid (HN02) or nitric oxide gas (NO). In this work emphasis was placed on the nitrous acid leach. In a high-temperature leach in a nitrous/nitric acid medium, manganese and silver are solubilized and iron is not. Anodic electrowinning of manganese dioxide from the acidic manganese nitrate electrolyte yields flaky y-Mn02, similar to that produced from sulfate and chloride electrolytes. Cathodic regeneration of nitrorts acid was studied in a membrane cell in 1.0 M nitric acid and 0.0 to 0.1 M nitrous acid on a' platinized titanium cathode. At cathode potentials ranging from +950 to +700 mV (SHE), cathodic reduction to nitrous acid takes place, at cathode potentials < +700 mV, cathodic reduction of nitrous acid to nitric oxide takes place. A conceptual process is presented and discussed.IntroductionManganiferous-silver oresLarge reserves of manganiferous-silver ores are present in the Southwestern United States and Latin America. These ores are generally refractory to hydrometallurgical methods of treatment, due to the insolubility of the higher oxides of manganese (Mn 4+) in all common lixiviants such as cyanide solutions, dilute sulfuric acid, nitric acid, ammonia, salt solution, thiosulfates, etc. The silver is either bound by the insoluble manganese, or is rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization.Higher oxides of manganese will dissolve if they are first reduced pyrometallurgically to manganous oxide (Mn2+). This is a widely used pretreatment for manganese dioxide ores and subsequent dissolution in sulfuric acid is common. In order to avoid the pyrometallurgical pretreatment with its large energy requirements and gaseous emissions, fully hydrometallurgical processes have been proposed. These processes are based on the presence of a reductant in solution, in order to reduce the insoluble higher oxides of manganese to soluble lower oxides. Aqueous S02 has been proposed and tested on industrial scale by the U.S. Bureau of Mines. After washing, silver could be extracted by cyanidation. The neutralization of the pulp prior to cyanidation however causes problems in filtration and the reagent consumptions are high [1]. More recently, acidified thiourea and bacteria were proposed for the solubilization of both manganese and silver in a single leach step. High extractions were obtained, but drawbacks of these methods are high reagent consumption or slow kinetics [2,3]. For the options of manganese recovery from the leach filtrate, precipitation with persulfate or ammonium carbonate and ion exchange have been proposed. The proposed options for silver reclaim are precipitation with either zinc or Na2S and adsorption onto activated carbon."

Jan 1, 1997

By C. E. Semler

A multiyear program involving online, in-vessel exposures at Barrick Goldstrike Mines Inc. (BGMI) has provided information and experience about the materials and designs for brickwork linings in pressure oxidation autoclaves. A variety of brick and mortar products was evaluated. Properties before and after exposure were used to document the performance. Some benefits include the development of a new silicate mortar, a better understanding of brick requirements and increased autoclave operating time between maintenance shutdowns. BGMI operates six pressure oxidation autoclaves at its Eureka County, NV gold operation. These autoclave process 15.8 k/ld (17,500 stpd) of gold ore. Figure 1 is a flowsheet of the six autoclave circuits. The gold ore is refractory, in which the gold particles are mineralogically encapsulated on a micro- and submicroscopic level. The autoclaves are 4.4- m- (14-ft-) diam and 26 m (85 ft) long (tip-to-tip). Inside of each is a full brickwork (brick plus mortar) lining that divides the vessel into five compartments. Each compartment has a motor-driven agitator that keeps the slurry suspended and disperses the oxygen to enhance reaction. During autoclave operation, the conditions are steady state at 210° to 232° C (410° to 450° F) and 61 to 62 kPa (420-430 psi). As shown in Fig. 1, there are other accessory vessels (splash and flash towers) in the autoclave circuits that are also brickwork-lined. The linings used to date, other than small test sections, have all been acid-resistant fireclay bricks, bonded with alkali silicate mortar, PbO- based mortar and/or vinyl ester mortar, but mainly alkali silicate mortar.

Jan 1, 1997

By C. H. Ash

"The Red Chris Cu-Au deposit (522.7 Mt at 0.35% Cu and 0.27 g/t Au), northwestern British Columbia, is one of several pre-accretionary porphyry systems in the Cordillera of westernCanada. It is hosted by an Early Jurassic hornblende monzonite to quartz monzodiorite porphyry which forms part of a suite of dikes and stocks that intrude Late Triassic volcanic strata. Major and trace element chemical data suggest that these Early Jurassic intrusions have compositions which fall on the boundary between alkalic and calc-alkalic compositions. Alteration and mineralization in the Red Chris deposit are more typical of calc-alkaline porphyry systems with abundant potassic, sericitic and argillic assemblages and quartz-rich stockworks. It lacks Na- and Ca-bearing silicate assemblages which characterize the alkalic porphyry deposits of British Columbia. One of the more unusual features of the deposit is the abundance of carbonate alteration and veins which occur throughout the hydrothermal history of the deposit. This type of alteration and veining is more typical of alkalic porphyry deposits.The composition of the carbonates vary both temporally and spatially with different alteration zones. Potassic zones, which are characterized by orthoclase±albite±quartz±chalcopyrite±bor-nite±magnetite±hematite and Au/Cu ratios of 1:1 (g/t Au:% Cu), contain minor siderite veins and alteration. Quartz-sericite-carbonate (QSC) zones overprint earlier potassic alteration and comprisequartz+ankerite+sericite+pyrite+chalcopyrite with Au/Cu ratios of 0.5:1 (g/t Au:% Cu). Ankerite isthe main carbonate in this stage but has a variable composition with a more Fe-rich variety associated with mineralized veins. Localized chlorite-carbonate alteration zones, characterized by chlorite+carbonate+quartz±kaolinite±pyrite±gypsum and high Au/Cu ratios [2 to 3.5:1; (g/t Au:% Cu)],contain predominantly calcite. Late stage carbonate-gypsum veins have an ankerite to dolomite com-position which is very similar to the regional carbonate alteration and veins."

Jan 1, 1997

By H. Soto, J. Jara, F. Nava

A method has been developed to recover cyanide and copper from solutions containing copper complexes and thiocyanate. Copper is precipitated as copper thiocyanate or as copper cyanide depending on pH and the concentrations of thiocyanate and cyanide in the effluent. The copper precipitate assays over 50% copper and presents good dewatering characteristics. After settling it can be separated from the effluent by filtration. The solution containing the bulk of the cyanide is then oxidized with ozone to transform the remaining thiocyanate into cyanide. This results in a regenerated solution rich in free cyanide that can be recycled to the cyanidation process. Careful control of the pH of the solution is required. First, pH of the effluent is lowered to optimize the precipitation and oxidation stages, then the pH is restored to an alkaline value to regenerate the cyanide solution. Recoveries of over 96% copper and cyanide were obtained in laboratory tests using industrial solutions. With this procedure, cyanocidic gold/copper ores could be treated economically by heap leaching, since the cyanide consumed by the copper impurities could be regenerated at very low cost (most of the cost of cyanide regeneration would be compensated by the copper credits). In order to achieve this, a bleed of the barren solution could be treated by the proposed method, and then recycled to the leaching step. The volume of solution to be treated should be large enough to keep a cyanide/copper molar ratio higher than 3:1. This would assure that copper does not cause undue interferences in the leaching or the carbon adsorption stages. If the thiocyanate content is low, the oxidation stage can be avoided, and the solution can be recycled to the leaching stage directly after the solid-liquid separation stage.

Jan 1, 1997

By Guo Chang Jiang

In order to improve the IIAZ toughness of X-60 pipe steel, the intragranular ferrite plate (IFP) technology was used. The characteristics of IFP is claimed to be much fine ferrite plates appear inside the original austenite grains. By means of suitable Re, Zr, Ti additions in a bath with a higher initial oxygen potential, a good control of the peak temperature and the cooling rate during welding simulation, one can get a %IFP in volume over 50%, and the toughness gets up from 55 J to 160 J. It was found that the inclusions most effective in nucleating IFP are some deformable complex silicates which either entrap Re, Zr, Ti oxides or contain these elements. The greater the number of the evenly distributed and effectively nucleating inclusions, the more the %IFP in volume, and the finer the microstructure of the HAZ, so the better the relevant toughness. Generally, these silicates bahave as fine spheres along a line. The present authors revealed that these fine spheres result from the remelting of the shuttle- like silicates due to heating in the process of welding simulation. These silicates used to get a higher sulphur capacity, so MnS deposits might be observed on the periphery of the silicates. IFP was proved to be directly rooted in the [Mn] depleting zone which locates beside MnS deposits.

Jan 1, 1997

By A. Aftabi

To evaluate geochemical aspects of sheared zones, 35 samples of granitoid rocks from an area of shearing >5 km2at Derehamzeh, Iran were studied geochemically. Relatively unaltered samples within the shear-zone area average 38 ppm Cu, 1.45 ppm Mo, 4.6 ppb Au, 0.21 ppm Ag, <1ppm Re, 46 ppm Zn, 28.5 ppm Pb, and 0.34% S. Bleached, hydrothermally-altered samples areanomalous in Cu (>896 ppm), Au(>59.5 ppb), Ag(>24.4 ppm), Re(>1.28 ppm), Zn (>164 ppm), Pb(>218 ppm), and S(>0.9%). Some samples from bleached sheared zones that are highly anomalous in Cu (5000 ppm), Mo(23 ppm), Ag(74 ppm), and Au(200 ppb) are characterized by a typical sericitic alteration assemblage consisting of sericite, pyrite, chalcopyrite, and granular quartz. The main anomalous zone extends over about 0.4 km2in the southern part of the area. The strong Cu-Mo-Au-Ag association in the sericitic shear zones suggests a possible relationship to porphyry cop-per mineralization, similar to that found in northern Chile. Further studies on drill-core samples in the southern sericitized shear zones are required to determine if more extensive porphyry-type sul?de mineralization is present.

Jan 1, 1997

By A. D. Davis

This project took a watershed approach in the evaluation of water-quality impacts from past mining activities and current restoration projects in the Bear Butte Creek basin, a small and well defined drainage in a heavily mineralized area of the northern Black Hills. The basin contains numerous inactive and abandoned mines as well as a currently active heap-leach surface gold mine. Bear Butte Creek normally loses all of its discharge to sinkholes in the Madison Limestone aquifer and thus can affect the water quality of this regionally important water resource. Water-quality data were analyzed, stream surveys were conducted, and two abandoned mine restoration projects were monitored to evaluate the effectiveness of the watershed approach and to identify practical remediation techniques that could be applied to other watersheds. A geographic information system (GIS) was developed to organize information on stream quality, abandoned mine locations, and other geologic and hydrologic data. The watershed approach toward assessing and reclaiming abandoned mines appears to be effective when compared to a point-source approach that might improve water quality at specific sites but not result in significant overall improvement to the watershed because of adjacent sources.

Jan 1, 1997

By D N. B Skinner

Changes in the configuration of late Cenozoic volcanic arcs related to Pacific-Australian plate convergence in northern New Zealand may have localised large-scale epithermal gold-silver mineralisation to a particular part of the volcanic arc system, the Coromandel Volcanic Zone (CVZ). The history of arc-type volcanism in northern New Zealand began with the development of the continental margin Northland Volcanic Arc from early-mid Miocene (26-15 Ma). From 18-15 Ma the Northland Volcanic Arc extended south into the northern and western part of the CVZ where it is dominantly composed of andesite with lesser dacite and very minor rhyodacite. In the south, centre and east of the CVZ, younger andesite-dacite volcanism overlapped in space and time (14-5 Ma) with voluminous rhyolitic volcanism associated with rift-hosted calderas and minor basaltic eruptions. This change to bimodal rhyolitic-basaltic volcanism and extensional tectonics was a result of southwest (SW)-directed propagation of the Colville-Lau oceanic island+ arc into the north-northwest (NNW) trending Northland Volcanic Arc and its underlying continental crust. The extensional tectonic regime created in the collision zone between the two arcs is also the site of the 14-6 Ma Coromandel epithermal gold-silver province, which contains some 50 separate deposits and has a production (1862-1996) of about 300 t Au and 1150 t Ag. Extensional tectonics facilitated the emplacement of silicic magma at shallow crustal level and led to reactivation of deep basement faults. The resulting enhanced heat flow and fault-focused fluid flow localised large hydrothermal systems and associated extensive low-sulphidation epithermal gold-silver deposits in the southern part of the province, as at Waihi, Golden Cross and Karangahake.

Jan 1, 1997

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By G. M. Card, K. D. Card, B. V. Sanford

Abstract-The Canadian Shield and its extensions are traversed by an orthogonal system of northwest and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches influenced patterns of sedimentation and tectonism in the intervening epicratonic basins and marginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structures also triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997