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By Yoshinao Kobayashi

he removal of oxygen from titanium and zirconium is important for use in application because it significantly affects the mechanical and physical properties such as ductility and toughness. However, thermodynamic properties of oxygen in molten titanium and zirconium have not been clarified and the effective deoxidation process of molten titanium and zirconium has not been established. In this study, the standard Gibbs energy of reaction of oxygen and yttrium in molten titanium and zirconium have been measured by a chemical equilibrium technique. Molten titanium, zirconium, and their alloys with aluminum were equilibrated with a Y2O3, A12O3, or Zr02 pellet in a cold crucible. The results are summarized as follows:

Jan 1, 2000

By B. Swarbrick

Today’s mining occurs in a dynamic world of conflicting objectives. Mining companies have to look further than a traditional cash flow analysis to determine the potential value of developing a mine. In particular, proposals for new mine developments undergo rigorous scrutiny by a variety of stakeholders including regulators, NGO’s, and the local communities. From a business risk perspective, how mining companies address stakeholder concerns can have a dramatic impact on the success of the project. In today’s mining environment mining companies must continue to ‘walk the talk’ to stay in business, particularly during downturns in the business cycle. Falconbridge’s Raglan Mine is an example of a project that was successfully developed in a region that is sensitive from many perspectives, including environmental, socio economic, and regulatory. Close working relationships with local stakeholders along with strong environmental management systems are necessary elements of continued success for the project.

Jan 1, 2000

By D Craw, L C. Kerr, P Wopereis

Gold placers in the Nokomai and Nevis valleys are dominantly Quaternary in age. They occur mainly in western tributaries of the upper Nevis, eastern tributaries of the middle and upper Nokomai, and in the trunk valleys themselves. Placer gold in both valleys is dominantly a-phase Au-Ag-Hg alloy. Au-Ag alloy is absent or rare in most of the deposits, except in the lower Nokomai. Alpha-Au-Ag-Hg alloy is typically coarse-grained (up to 2 cm), angular, and rarely flattened or folded. Crystalline texture, quartz intergrowths, and psuedo-hexagonal crystal-pluck cavities are common. Fluvial transport distance predicted from the maximum Flatness Index ofAu-Ag-Hg alloy particles is typically less than 10-20 km. Coarse (up to 2 cm) cinnabar is commonly associated with the Au-Ag-Hg alloy, and both were probably derived from hydrothermal sources in western tributaries ofthe upper Nevis and eastern tributaries of the upper Nokomai. Minor secondary Au-Ag-Hg alloy occurs locally in the lower Nokomai, where it coats or cements detrital a-phase Au-Ag-Hg and Au-Ag alloy particles. Au-Ag alloy dominates over Au-Ag-Hg alloy in the lower half of the lower Nokomai alluvial plain and gravel of a raised channel incised into semischist basement adjacent to the plain. The Au-Ag alloy is rounded and commonly flattened and folded. Crystalline texture, quartz intergrowths, and pluck cavities are rare, and a fluvial transport distance of 25-40 km is estimated from maximum Flatness Index ofAu-Ag alloy particles. The Au-Ag alloy, three types of gamet, magnetite, clinozoisite and well foliated schist boulders in the abandoned channel are not found in the pumpellyite-actinolite facies bedrock in the Nokomai. These components were derived from greenschist facies schist and sedimentary sources in Otago, many tens of kilometers north of the Nokomai catchment. They were transported to the Nokomai either in Wakatipu Glacier till or fluvio-glacial outwash that entered the valley via Nokomai Saddle, the confluence with the Mataura, or both.

Jan 1, 2000

By F. Russo-Bello

TauTona Mine (the renamed Western Deep Levels East) is using a longwall mining method with stability pillars to extract the Carbon Leader Reef at a depth ranging from 2097 metres to 3456 metres below surface. Seismic activity and the complexity and hazards associated with negotiating geological features at great depth pose the most severe hazard to deep level gold mining in South Africa. It impacts negatively on safety and the profitability of the mining. The critical success factors in longwalling at depth are: ?Sound mining strategies and face shape control ?Ensuring follow behind development infrastructure is kept up to date ?Support system design as a strategy to effectively limit the serious effects of damaging seismicity. This paper describes the following: ?Implementation of the required mining strategies ?The evolution of a new stope support system and problems associated with its development and implementation. How this support system was adapted for the successful negotiation of major geological features with known seismic potential and problems encountered ?Current initiatives to optimize follow behind development infrastructure ?Current initiatives in designing a new gully support system and problems experienced with its development and implementation. Finally, this paper will deal with the way forward, briefly covering areas like the above-mentioned gully support system, the proposed phased introduction of technology, and the use of alternative mining layouts.

Jan 1, 2000

By Z. Smieszek, W. D?browicz, J. Pawlowski, G. Krawiec, J. Czernecki, J. Por?mbski, S. Gizicki

Rapid development of the automotive industry and motorization has been observed in Poland over the last decade. This phenomenon has increased the amount of used car batteries requiring recycling and has thus posed new challenges for their processing. Orzel Bialy" S.A, is the major secondary lead smelter in Poland. Ibis paper describes the program for smelting technology modernisation and productivity increase through the application of oxy-fuel burners, which has been implemented at "Orzel Bialy'' S.A. The main objective of smelter modernisation, which was to increase the furnace productivity by 20%, has been achieved. This paper outlines the previous and present state of the lead acid battery scrap smelting technology at the "Orzel Bialy" S.A. Specifications of the burners and of oxygen installation are given. Industrial tests with the modernised smelting technology and optimisation of the process parameters are described, and the results obtained are discussed.

Jan 1, 2000

The economic viability of many Southern African massive mining operations is threatened by excessive dilution. In many operations currently in progress, some stopes are experiencing as much as 115 per cent waste ingress reporting to drawpoints. This paper examines the magnitude, causes and types of dilution and presents a set of general principles for the control of dilution in massive stoping operations.

Jan 1, 2000

By D. C. Kaliampakos, A. G. Benardos

The existence of quarries near or even within the boundaries of urban centres is the cause of many environmental problems, despite their significant contribution to the cities’ development. Hence, the question arises as to how quarrying activities can be compromised within the spirit of sustainable development in big cities. In the case of Athens, two dominant, though opposite opinions have been formed. The first argues that all quarries must be forced to suspend their activities as soon as possible; the second presses for the continuation of quarrying. Consequently, the question is transposed on the dilemma between improved environmental conditions and economic development. This paper demonstrates that if a complete redesign is employed to specific, nonvisible quarrying sites, the continuation of quarrying activities is acceptable. It is a good compromise between the economical demand and environmental protection.

Jan 1, 2000

By I Mason, A Wellington, J Hargreaves

Many people are familiar with the use of marine echo sounders which are used by fishermen to monitor water depth and locate schools of fish. Similar technology has recently been used in some West Australian mines to provide detailed maps of ore contacts and other geological structures. Whilst drillhole intersections provide details of the location of a contact at a point, echo sounding can be used to obtain a continuous profile of the contact. A series of profiles together with drillhole intersection data can be used to build a more accurate geological model than can be inferred from drillhole intersections alone. The benefits of this are more complete ore extraction, less dilution and the ability to make more informed financial decisions. This paper presents a case history which demonstrates the successful application of the technology.

Jan 1, 2000

By R J. Norris, D J. MacKenzie

Gold-bearing veins have formed at a wide range of depths throughout the uplift history of the Otago Schist. The earliest gold mineralisation occurred during the later stages of Mesozoic metamorphism. This mineralisation was characterised by diffuse wall rock alteration with greenschist facies metamorphic or retrograde metamorphic mineral assemblages, and gold occurs in this altered rock. Quartz veins formed in .steeply dipping extensional fractures associated with this mineralisation type strike north to northeast. The Macraes mine exploits this deposit type. The present northwest strike of the mineralised zone at Macraes is a result of post-mineralisation deformation of the schistosity-parallel mineralised shear zone which hosts northeast striking extensional veins. This combination of schistosity-parallel shear zone and steeply dipping northeast striking veins may exist elsewhere in Otago, and this deposit type is most prospective. Steeply dipping quartz veins formed during post-metamorphic un-roofing of the Otago Schist strike northwest to west and occur as clusters of near-parallel structures in east and central Otago. These veins consist mainly of massive quartz, although some prismatic quartz occurs also. Breccia fragments in veins are common and these are generally silicified, with some gold. Wall rock alteration is negligible, and vein margins are sharp. A set of middle Tertiary veins occurs in northwest Otago. Most of these also strike northwest and dip steeply, but some strike northeast. These veins contain abundant ankeritic carbonate as well as quartz. The carbonate pervades adjacent wall rock as veinlets, but gold mineralisation is confined to veins. Quartz is commonly prismatic and vuggy, and contains gold, which is commonly coarse grained especially in silicified breccia zones. Associated veins contain stibnite. This vein type formed close to the paleosurface (>2 km). Mineralised veins in Marlborough currently strike northwest, but these have been rotated from northeast strike during Alpine Fault displacement of Marlborough from Otago. Some of these veins were formed under late metamorphic conditions and are similar to the north to northeast striking veins in Otago. As in Otago, this type should be considered to be most prospective if they have associated schistosity-parallel shears.

Jan 1, 2000

The 115-year history of the Hall-Heroult process for production of aluminium has been characterised by a sustained technology-driven improvement in costs and productivity. In the past decade the industry has effectively transferred best practice into older technology with improvements through computer control of the process, and redesign of cell linings using computer modelling . Incremental development is now at the point where diminishing returns will apply for further technical improvement effort however, until the gap between technical limits and current best practice is addressed through major process redesign. The process remains a long way short of its technical limits in energy consumption, carbon anode consumption, cell life and product purity. Investment cost in new capacity is very high, supporting the retention of older and less efficient technology and hence limiting the application of best practice in environmental performance and occupational health exposure. The industry is a major emitter of greenhouse gases yet the process has the potential to release oxygen as the primary waste. All of the above issues will be addressed in the new century, but only through commitment to the necessary long-term research and development that is required to achieve a redesign of the process.

Jan 1, 2000

By Peter Wells, Laxman M. Amaratuga, Todd M. Kanhai

"Certain mining methods (eg. Cut-and-fill) result in the contamination of run-of-mine ore with shotcrete. This shotcrete remains mixed with the ore throughout processing. Experimentation performed by Falconbridge Limited revealed that underground contamination of ore by shotcrete (eg. as little as 1% by weight) has led to ill-effects on the nickel recoveries from the flotation process in the mill. The nickel recoveries of contaminated samples were lower than tests without the shotcrete Contamination.To optimize flotation circuits it is important to know why the contamination has created these effects and also to find a method to abate or remove them. Laboratory testing showed that the age of the shotcrete was a factor in it’s effect on nickel recoveries. Younger aged shotcrete gave nickel recoveries lower than baseline nickel recoveries with no contamination. Older shotcrete gave nickel recoveries similar to the baseline.Literature on other cementitious material contaminations on ore revealed that a possible means of remediating this problem is the use of acid in the flotation. The initial pH in the flotation pulp was designed to be pH 9.2, but with the young shotcrete contamination the pH was in the neighbourhood of 10.5. Acid addition may act as a means of lowering the pH to the optimal operational value. Laboratory test work showed that acid addition brought nickel recoveries closer to the baseline."

Jan 1, 2000

By J. Smolensky, M. Paul

The Nordhalde is a waste rock pile resulting from uranium mining near Ronneburg, Germany. The pile contains over 27 million m3 of waste rock. Typical seepage water has a pH of 2.7 and a sulfate concentration of 10,000 mg/L. Geochemical investigations of the Nordhalde from 1993 to 1996 included drillholes, test pits, ABA and metals analyses, column tests, and a detailed review of the construction history of the pile. In 1996, eight drillholes were instrumented for monitoring oxygen and temperature. Monitoring continued for a fill year. Hourly temperature and pressure readings were taken by automated data recorder. Oxygen concentrations were measured three times per week, and periodic gas samples were obtained for complete analysis. The resulting data set is believed to be one of the most comprehensive of its kind. Effects noted elsewhere, such as thermal convection, are evident. However, unlike other data in the literature, the NordhaIde data shows a strong seasonal effect, with convection dominating oxygen transport only in the winter months. Analysis of the data allowed the amount of contaminants associated with ongoing and historical oxidation to be compared, and results were used to assess the potential effectiveness of proposed remediation measures.

Jan 1, 2000

By R G. Jeffrey

The Northparkes, Endeavour 26 orebody is a porphyry copperûgold deposit and comprises a moderately to well jointed rock mass characterised by gypsum veining, the intensity of which decreases with depth. The top 480 metres of the orebody is currently being mined by block caving, the undercut dimensions measuring 196 metres in length by 180 metres in width. Continuous caving was never achieved after the completion of the undercut thus cave inducement techniques were sought to maintain caving so as to safely sustain production. The use of hydraulic fracturing as a cave inducement tool was successfully trialled in December 1997 using existing exploration boreholes located midway up the current lift. Subsequent fracturing campaigns have enjoyed various degrees of success and have yielded in excess of seven million tonnes of ore at a significantly lower cost than conventional cave inducement techniques. Monitoring of both the hydraulic fracture system and the rock mass response has provided considerable insight into the geometry, growth and influence of hydraulic fracture networks above the Northparkes block cave, and has initiated additional research into the use of hydraulic fracturing in other mining methods.

Jan 1, 2000

By Tobias Hansson

The quality of Lime Cement (L/C) columns is to a great extent dependent on the installation procedure. At a site in the south of Sweden, the client reported problems with the installed columns. To evaluate the operator and equipment dependent part of the installation, Hercules Grundläggning AB was appointed as a competitor to the site contractor. The purpose was to install a number of L/C columns with equal installation parameters for both contractors. A total of 65 test columns were installed in June 1999. The geology is a typical Swedish organic soil profile with a top layer of peat overlying gyttja and clay. Two different binders were used in the comparison; blast furnace slag with cement and lime with cement. After installation, the quality of the columns was monitored by penetration tests and a column sampler for extracting whole columns. The column penetration test were performed 28 and 134 days after installation and extraction 134 days after installation. Inspection and tests of the extracted columns showed that by using a fully computer controlled procedure, the contractor produces columns of superior quality and homogeneity.

Jan 1, 2000

By A. L. Anderson, J. T. Rybock

KEECO has developed the Silica Micro Encapsulation (SME) technology for the treatment of acidic, metal-laden waters. Utilizing a silica-based chemical formulation that entails chemisorption and micro-encapsulation of heavy metals in a permanent silica matrix, encapsulated particles settle quickly and are effectively isolated from the surrounding environment, producing a stable sludge that is characteristically non-hazardous. In a number of independently-verified pilot and full-scale applications (including the Bunker Hill Mine, Leviathan Mine, Wheal Jane Mine, and Meldon Quarry), SME has been proven highly effective. The technology has been featured in a number of mining publications and selected for innovative technology awards.

Jan 1, 2000

The effect of microwave radiation on the processing of Palabora open pit ore has been investigated. Significant reductions in Bond work index are demonstrated for microwave treated samples. Reductions in work index were found to be sensitive to applied power level and method of application. After single stage magnetic separation tests, improvements in recovery of FeO were noted. However, these were curtailed by oxidation of the magnetite species as a result of continued heating. The effects of microwave radiation upon the recovery of copper after froth flotation were also quantified. Small initial increases in recovery of copper were note dafter microwave treatment. However, with prolonged exposure, recovery was found to decrease. Overall recovery of copper was not affected except for samples treated for extended duration. The influence of microwave treatment upon the conventional Palabora grinding circuit has been quantified with the use of USIMPAC software. Conclusions are made regarding the economics of microwave treatment for this ore. Keywords : Microwave; Grinding; Magnetic Separation; Flotation; Economic Analysis

Jan 1, 2000

Sulphide minerals, such as pyrite and sphalerite, are leached by ferric sulphate. This reaction produces ferrous sulphate and other dissolved products. The ferrous sulphate is re-oxidized to ferric sulphate by bacteria. These reactions can be written as: [ ] However, in 1964 Silverman and Ehrlich proposed that this is not the only role that is played by bacteria. These researchers proposed that T. ferrooxidans enhances the rate of oxidation of pyrite above that achieved by chemical reaction with ferric sulphate at the same solution conditions. This enhancement in the rate of dissolution was proposed to occur by direct microbiological action, possibly by the extra cellular secretion of an enzymatic oxidant. Since the Silverman and Ehrlich proposal, different authors have made opposing claims concerning the action of T. ferrooxidanson pyrite. This ?direct mechanism? of bacterial dissolution of pyrite can be given by the following reaction: [ ]

Jan 1, 2000

By Edward J. McNamara

People in the real estate industry are fond of saying that the three most important features of a piece of property are, in order, location, location, and location. This is perhaps the reason that the owners of a well known high-end restaurant chain chose to spend $15 million dollars to renovate 5000 square feet of basement in a 22-story commercial building in the heart of New York City's Time Square. The goal was to create a music club with a stage area and dance floor with a mezzanine level surrounding the dance floor. In order to create the 50' x 40' dance floor and 20' x 40' stage area, 3 concrete columns were removed. New transfer girders were used to transfer the loads of these columns to new steel columns. For the mezzanine, nine columns had to be underpinned. All work continued while the restaurants, shops and offices above carried on business as usual. This paper details some of the means and methods utilized as well as the challenges faced by Underpinning & Foundation Constructors, Inc. in underpinning the columns and installing the new transfer steel.

Jan 1, 2000

The National Mining Hall of Fame will hold its 13thAnnual Induction Banquet during MINExpo International 2000 in Las Vegas, NV. The gala black-tie (optional) event will honor eight legendary leaders of the mining industry. The event will take place at the Las Vegas Hilton Hotel on Sunday, Oct. 8. The induction ceremonies will salute mining greats elected by the board of governors from a list of nominees submitted by mining industry partners and the public. The members of the Class of 2000 will join 151 other inductees enshrined in the Mining Hall of Fame in Leadville, CO. The evening will begin at 6 pm with a cash bar reception followed by the banquet and program at 7 pm. Keynoting the banquet program will be Harrison (Jack) Schmitt. He was the geologist/astronaut of the Apollo 17 mission to the moon in 1972 (see related story on page 26). And he is the only scientist to “kick rocks on the moon.” Schmitt is also a member of the Mining Hall’s board of governors. Schmitt was also the keynote speaker at the First Annual Induction Banquet in Denver, CO in 1988.

Jan 1, 2000

By G. T. Adel, J. D. Miller, C. L. Lin

Washability analysis determines the maximum separation efficiency that can be achieved in the operation of coal preparation plants. Unfortunately, there are no on-line techniques for determining this most fundamental information. It now appears possible to determine coal washability on-line through the use of x-ray computed tomography (CT) analysis. This paper presents the results for the development of a CT-based, on-line coal washability analyzer. The development of appropriate hardware and software necessary to adapt a CT analyzer for use in determining coal washability is discussed. Testing of the analyzer using well-characterized coal samples is presented.

Jan 1, 2000