Search Documents

By Huanhuan SU, Jianqiang Zhang, Zhongyuan Liu, Junwei Ma

The high-sulfur bauxite in Henan Province was used as raw material. The grinding fineness, pH value and collector dosage on its desulfurization performance, and industrial flotation desulfurization process were studied. The best flotation desulfurization conditions were grinding fineness of 75%, pH of 8.5, and collector of 600 g/t. “One coarse, one cleaning and one sweep” closed-circuit flotation was established as the industrial flotation desulfurization process. After the closed circuit test, the sulfur content of aluminum concentrate with the yield of 93% was 0.23%, and the sulfur removal rate was 83.16%, and the sulfur content of tailings (sulfur concentrate) was 15.09%. Keywords：High-sulfur bauxite under coal mines, flotation, desulfurization

Jan 1, 2020

By A. J. H. Newell, K. Doherty

A copper-gold project has required a number of trade-off studies underpinned by test work to settle on pragmatic flowsheets and throughputs to support a pre-feasibility study that provides a compelling financial case. The primary trade-off studies were based on the mine schedule, ore type feed-grade recovery relationships, likely concentrate grades and typical marketing terms as well as the estimated capital and operating costs for a range of throughputs and mining strategies. Secondary trade-off studies were conducted for specific circuits and additional processing options. Although the details of these studies are not presented, the technical options and subsequent flowsheets are discussed. While the flowsheets will be optimised during the feasibility study stage, the basis is now fixed for the four ore types that would be mined from the copper-gold orebody. The ore types, resulting from a strong weathering profile, exhibit a wide range of copper mineralisation and gold associations, as well as gangue types. They display a range of characteristics that necessitated a nuanced approach to flowsheet development. The primary separation techniques that have been employed include gravity, classification, flotation and leaching while a range of comminution methods have been selected to suit the properties of the ore types. While technical issues are important factors in terms of maximising the quality of separations, recoveries and revenues, attention to material handling, equipment characteristics, the mine schedule, and capital and operating costs are equally important considerations for settling upon a suitable and robust flowsheet. Keywords: Flowsheet, testwork, studies, saprolite gold, native copper, chalcocite, chalcopyrite

Jan 1, 2020

By P. K. Jain

A spiral concentrator is a density separation device used for the beneficiation of coal and various minerals such as iron ore, chromite ore, gold, beach sand minerals etc. The flow pattern developed in the equipment is complex and unique, yet the operation is very simple, with low capital and operating expenditure. Spirals are applied for beneficiation of material in the size range finer than 2 mm and are capable of recovering heavy minerals as fine as .01 mm. The understanding of the unique flow pattern has kept researchers engaged over the last few decades and attempts are being made to explain such flow patterns so that they can be controlled and modified to improve the operating efficiency, Ep (Ecart Probable Error, also known as probable error in separation) and acceptability of spiral concentrators for processing of fines and slimes - currently being discarded and dumped in the tailing ponds. An attempt has been made in this paper to explain the generation of complex flow patterns with application to classical solid mechanics in the fluid and slurry system. The same has been used to explain the selective separation of particles in different zones in a cross-section on the spiral trough. The paper also discusses the application of a force balance model to explain the generation of secondary circulation. Due to the presence of laminar and turbulent flow regimes in the spiral concentrator, varieties of equations have been proposed in the literature, consisting of different equations for different zones. An attempt has been made to present a unified flow equation for calculation of flow velocity at different positions on the spiral trough. Keywords: Secondary circulation, spiral concentrator, density separation, fine particle processing

Jan 1, 2020

By Y. Cao, C. Li, A. Song

Bubble size plays a key role in determining flotation efficiency. Bubbles can be formed by passing air through pores. Bubble detachment from a pore is driven by lifting forces including buoyancy force and momentum force. Enhancing the momentum force is the key to accelerate bubble detachment and to minimise bubble size. Recent studies show that replacing steady air with oscillatory air supply could significantly decrease bubble size by enhancing the momentum force. To date, the underlying mechanism for the improved momentum force with oscillatory air supply is not yet clear. This work, for the first time, developed a qualitative model for the momentum force as a function of frequency, on/off time ratio and gas flow rate. It was found that the momentum force was positively correlated with the frequency as well as the air flow rate, and was negatively related to the on/off time ratio. The relation between bubble size and these operating parameters was also investigated. Keywords: Flotation, bubble size, momentum force, modelling, oscillatory air supply

Jan 1, 2020

By G. Akdogan, C. Dorfling, L. Bumhira

Hydrometallurgical recovery of rare earth elements from phosphors obtained from end-of-life fluorescent lamps involve leaching followed by extraction of dissolved metals from solution. The similar properties of rare earth elements make selective recovery of individual elements challenging. The aim of the paper was to investigate the extraction of primarily Ce and Tb from a hydrochloric acid leach solution also containing other REEs (Y and Eu) as well as impurity metals (Ca and Al). Batch solvent extraction tests were performed with di-(2-ethylhexyl) phosphoric acid (DEHPA) at various extractant concentrations, pH conditions and organic-to-aqueous ratios. Extraction isotherms and separation factors for the range of conditions tested in the project are presented in the paper. Separation of individual REEs was not possible at the conditions investigated, but a mixed REE product can be obtained in a single extraction stage operated at a pH of 0.5 using 1 M extractant at an O/A ratio of 1; these conditions resulted in complete Y and Eu, 95 % Ce and 99 % Tb extraction with Ca and Al coextraction below 7 %. A better quality mixed REE product can be produced by operating at lower pH and extractant concentration conditions, but this would require a larger number of extraction stages. Keywords: Cerium, fluorescent lamps, phosphors, rare earth elements, solvent extraction, terbium

Jan 1, 2020

By L. Cheng, Y. Liu, Z. Shen, H. Shang, Y. Li

The pre-concentration process of magnetic coarse particles can discharge waste rock or liberated gangue before milling, which is an effective means to reduce cost and increase the efficiency of the concentrator, but the weakly magnetic ore doesn’t have the effective separation method of coarse particle such as hematite, limonite, ilmenite and so on, Because the composite iron minerals contain both strong and weak magnetic elements, the pre-concentration process cannot be applied, or the existing pre-concentration process has problems of complicated configuration and high operation cost. By researching a new type of external magnetic separation technology, the pre-concentration process of composite iron ore was realised by single equipment, which can have a good recovery rate with simple arrangement. In this paper, the separation principle and structure characteristics of the external magnetic separator were researched, and the magnetic circuit characteristics of the external magnet were analysed. The laboratory tests of vanadium titanium magnetite were conducted, and the test results proved that the external magnetic separator can be applied for the pre-concentration process. The industrial application shows that a product of TFe 24.76% with 90.08% recovery, TiO2 10.10% with 91.78% recovery can be achieved from the feed of TFe 20.67%, TiO2 8.33%. Keywords: Coarse particle pre-concentration, composite iron ore, external magnet, magnetic separator

Jan 1, 2020

By J. J. Cilliers, J-A. Lamamy, J. N. Rasera, K. Hadler

Production of oxygen on the moon can be achieved by reduction of lunar soil. One such reduction technology, hydrogen reduction, favours a high proportion of ilmenite in the feedstock. Ilmenite is present in lunar soil as a minor mineral phase, but it can be upgraded using electrostatic separation. This study presents the results of a preliminary investigation into the operating parameters and sensitivities of a free-fall electrostatic mineral separator for lunar applications. Samples of ballotini and ilmenite as well as simple binary mixtures of the two were tribocharged on copper and passed through a uniform electrostatic field. The field is varied to change the electrostatic force acting on the particles. The proportion of material reporting to the positive electrode collectors, negative electrode collectors or the central collector was measured to determine the separation performance. The data confirmed that the charge transferred from the tribocharger to each species is in agreement with the triboelectric series; ballotini was found to charge positively on copper and ilmenite negatively. Particle-particle contacts were dominant, however, resulting in a somewhat symmetrical particle distribution in the collectors. These findings indicate that the copper tribocharger design requires optimisation in order to substantially increase particle-wall contacts. Four binary mixtures with feed grades of ilmenite ranging from 5% to 20% were prepared and tested. This study found that a higher ilmenite head grade resulted in a higher concentrate grade (26.3% from a head grade of 20%) with low recovery (3.4%). In contrast, the lower feed grade resulted in a low concentrate grade but higher recovery. The mass yield of ilmenite was 1.4 times greater for the highest-grade feed than for the lowest. A subsequent study into the reprocessing of middling fraction found a nearly constant relationship between cumulative grade and recovery. This is the first investigation into the effect of feed grade on the concentrate grade and recovery for lunar mineral processing. Keywords: Lunar resources, beneficiation, electrostatic, SRU, ISRU

Jan 1, 2020

By G. Bueno, L. M. Tavares, T. M. Campos

Iron ore pellet feed pressing has been one of the first and most successful applications of High- Pressure Grinding Rolls (HPGR) in the minerals industry. Vale S.A. has been one of the pioneers in this application, currently with six HPGRs in operation in the pelletising plants of the Complexo de Tubarão (Brazil). In spite of the important advances in the technology, risks still exist when scaling-up the process from small-scale information. The present work takes advantage of the recent advances in the mathematical modelling of the HPGR performance, using the population balance model to evaluate the modified Torres and Casali model prediction in iron ore pellet feed pressing for different scales of operation. Results are presented that compare the HPGR performance in different operational scales for iron ore pellet feed pressing, demonstrating the confidence of this model-based approach for scale-up to full-scale HPGRs used in pressing iron ore concentrates. Keywords: Scale-up, HPGR, pellet feed, modelling, simulation

Jan 1, 2020

By L. Morgan, M. Le Roux, Q. P. Campbell

Dry coal processing is becoming increasingly favoured as a fine coal beneficiation technique. The decline in suitable good-quality coal, as well as the ongoing decrease in usable process water, makes dry beneficiation of the fine coal fraction even more crucial. Dry fine coal beneficiation is a relatively young process with most of the methods still in the developmental phase. Additionally, many of the dry processing options available are better suited for coarser (+6 mm) and easy-to-beneficiate coal. Air winnowing for fine particles has been established in both agricultural and pharmaceutical industries, which indicates that the method can be used to separate smaller particles on a density basis and therefore, may prove effective in the coal industry as well. A proof of concept study was conducted using both computer-based simulations (which do not form part of this paper) and physical experiments. The initial winnowing unit consisted of a closed box with a horizontal air stream flowing through the top section. Coal particles were injected into the air stream and displaced horizontally across a distance (x), depending on the particle size and density, thus actuating a separation based on these two parameters. For this study particle sizes of 6, 4 and 2 mm were used all with a density ranging from 1200 kg·m-3 to 2000 kg·m-3. The simulation in Star CCM+ confirmed the findings of the mathematic behavioural model and provided a virtual representation of the separation using streamlines and particle tracks. The coal tests prove that size separation can be achieved at an airflow velocity of 21 m·s-1 and the density cut-point can also be predicted by using the prediction matrices constructed as part of this study. The results show efficiency values (EPM) of 0.11 and 0.09 at density cut-points of 1400 kg·m-3 and 1500 kg·m-3 respectively. The data obtained from the study indicates that air winnowing can be used to separate fine coal particles based on both size and density. However, in order to achieve an efficient density separation, a narrow size range is required. With some improvements to the model, simulation, method and design, the separation efficiency can also be improved. The next phase of testing will include the upscaling of the process to a demonstration plant, optimising the separation unit and testing the method on different qualities of coal. Keywords: Dry processing, fine coal, winnowing, simulation, tracers, demonstration plant

Jan 1, 2020

By G. Akdogan, S. M. Bradshaw, M. I. Isaacs, P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached in order to remove base metals from a concentrate containing platinum group metals (PGMs). This paper investigates the atmospheric leaching process, in order to develop a better understanding of the leaching behaviour of the base metals; in particular Cu, Fe, Ni, and the PGMs in particular Ru and Ir with key process variables, acid concentration, copper concentration under oxidative leaching conditions. Higher initial acid concentration resulted in a higher copper, iron and nickel extractions, as well as higher leaching rates together with faster Cu, Ru, Ir precipitation occurring. On the other hand, a higher initial copper concentration resulted in more nickel but less iron being extracted. Keywords: PGM, converter matte, leaching, precipitation

Jan 1, 2020

By H. Han, Z. Gao, Y. Gao, W. Sun, J. Wang

Strategic Ca-bearing minerals like scheelite and fluorite are usually separated by flotation, yet the separation is quite difficult due to their similar surface Ca active sites. Compared with the conventional strong collector sodium oleate (NaOL), lead nitrate-benzohydroxamic acid (Pb-BHA), complex collector shows a better selectivity for scheelite, yet its high cost hinders its wide application. Therefore, a novel collector (Pb-BHA-NaOL complex) was initially developed in this work to overcome the abovementioned dilemma. The flotation results of a single mineral showed that Pb-BHA-NaOL had a better selectivity for scheelite than Pb-BHA. Under the conditions of sequential assembly of Pb, BHA and NaOL at the molar ratio of 240:120:1 and pH 9.0, selective separation of scheelite from fluorite could be achieved without adding any depressants. In addition, for the same preferred scheelite recovery, Pb- BHA-NaOL could also save approximately 20% Pb and BHA compared with Pb-BHA. The analyses of the zeta potential measurement and X-ray photoelectron spectroscopy indicated that Pb-BHA-NaOL showed stronger adsorption on scheelite relative to fluorite. Meanwhile, Pb-BHA-NaOL showed more adsorption modes and higher utilisation of Pb and BHA on scheelite than Pb-BHA, which was due to the accelerator, NaOL. Keywords: Scheelite, fluorite, lead nitrate, benzohydroxamic acid, sodium oleate, flotation

Jan 1, 2020

By B. Oladipo, E. Govender-Opitz, T. V. Ojumu

Bioleaching, one of the several important processes of biohydrometallurgy is an accepted technique for the extraction of desired metals from sulphide ores. Although the mechanism is well understood, the slow metal extraction rate due to passivating layer and ferric ion precipitation, especially in a typical chalcopyrite leaching, impact negatively on the overall efficiency of the process. Iron precipitates are common in many biohydrometallurgical operations and these precipitates represent the exit route for undesired iron, alkali ions or sulphate ion from the processing circuit. While there have been reports on approaches to slow the formation of these precipitates by manipulation of various operating conditions such as pH, redox potential and temperature, the precipitates become highly significant over the long term in the continuous operation of bioleaching and may render heap impermeable. Although there is evidence supporting the nature of the passivation to be precipitates of iron, their scavenging mode of reducing extraction efficiency is still not well understood. This paper thus discusses iron precipitation in biohydrometallurgical processes, including its formation and significance on bioleach processes. The paper also details the associated passivating species identified with heap bioleaching of sulphide minerals and provides some insight into sorption mechanism that limits metal recovery in a typical bioleach operation. Keywords: Iron precipitation, bioleaching, chalcopyrite, passivation, jarosite, metal sorption

Jan 1, 2020

By F. K. Crundwell

The rate of dissolution of sulphide minerals is frequently interpreted in terms of the passivating behaviour of a layer of material on the surface. This interpretation has driven research to identify and possibly remove this layer from the surface, and thus yield higher rates of dissolution. The identification of such layers has proved difficult, with different researchers claiming different compositions for possible layers. An alternative framework has been pursued by the author and co-workers, who have argued that the rate of dissolution is governed by the electronic structure of the minerals which give rise to their semiconducting properties. Researchers sceptical of this approach have argued that semiconducting properties are only important in highly pure substances. In this paper, we review the electronic and semiconducting properties and discuss how they impact dissolution behaviour. These properties affect their colour and dissolution properties even though the minerals are not high purity substances. Keywords: Dissolution, leaching, passivation, semiconductor, chalcopyrite

Jan 1, 2020

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy

Attachment of collectors containing thioamide groups to sulfide minerals is interpreted as interaction between NH-acids and sulfides acting as solid bases with the formation of a donor–acceptor reagent–mineral bond. As the acid function of the reagents increases, their sorption optimum is observed to shift to a less alkaline region. The developed concept has enabled us to propose a method for calculating optimal pH values for the sorption of reagents on mineral surfaces depending on the acidity of the reagents and the pH value of the medium. Our estimates correlate well with the experimental data. We studied the spectra of the reagents containing thioamide groups and the spectra of copper salts and their surface compounds on an oxidised copper film, chalcopyrite, and pyrite using the infrared (IR) spectroscopy. Some effective applications are described of reagents containing thioamide groups in the flotation of copper, copper-molybdenum, and gold ores, both separately and in combination with other collectors. It is shown that the flotation performance is maximised by adding two- and three-component collector combinations, including collectors containing thioamide groups. In this case, the increase in the recovery of copper, molybdenum, and gold is up to 2-5% compared to conventional process conditions. A new, high-performing reagent containing a thioamide group is proposed. A commercial pilot batch of the reagent was produced and sent for flotation tests in gold ore applications. Keywords: Thioamide reagents, dialkyldithiophosphate, collectors, flotation, arsenopyrite, chalcopyrite

Jan 1, 2020

By А. V. Aksenov, S. G. Rybkin, А. Y. Senchenko

For gold plants in Russia, it is very complicated and costly to use cyanide leaching for efficient processing of gold refractory ores, where gold is closely associated with sulphide minerals and the significant amount of natural carbonaceous matter present. Oxidative roasting of gold refractory concentrates is a well-known method, making it possible to obtain a high recovery rate of precious metals to a target product. The use of oxidative roasting is limited in general by the expense of capturing and neutralising the harmful components of roasted gas, mainly sulphur (SO2, SO3) and arsenic (As2O3) oxides. This paper addresses testing and development of an optimised technology to process gold refractory gravity and flotation concentrates by means of oxidative roasting which stabilises arsenic as calcium arsenate. The process involves roasting of a gravity or flotation refractory ore concentrate in a mixture with lime and calcium chloride, with a supply of oxygen, and at 600-700°С. During the roasting a carbonaceous matter of the concentrate burns out and sulphide components transform into harmless calcium sulphate (CaSO4) and calcium arsenate (Ca3(AsO4)2), and iron passes into the form of hematite (Fe2O3). After disintegration, the roasting cinder is concentrated on a table to obtain a high-grade gravity concentrate and gravity tailings. The high-grade gravity concentrate is subject to smelting in a mixture with fluxing agents, which results in alloyed gold and slag. The gravity tailings are ground and reported to cyanide leaching. In the case of a flotation concentrate, the roast cinder is ground to minus 30 μm and subject to sorption cyanide leaching. High gold recovery (90-95%) of the target product and environmental safety are typical of the improved technology under consideration. Two national patents were granted for the methods developed to treat refractory concentrates bearing precious metals. Keywords: Gold concentrates, oxidative roasting, cinder, cyanide leaching, smelting, alloyed gold

Jan 1, 2020

By X. Chen, G. Wang, D. Wan

Computational fluid dynamics have been applied for detailed modelling of particle-bubble collisions. The most accurate approach in the previous work is using the point particle method to treat particles and bubbles. Nevertheless, the sizes of particles and bubbles are generally bigger than the Kolmogorov scale in the high turbulence of the flotation environment, which makes the point particle method inappropriate. This paper describes particle-resolved direct numerical simulation on the collisions between particles (denoted as heavy particles) and bubbles (denoted as light particles) in a homogeneous isotropic turbulent flow field, and a comparison with the point particle method.. A largescale stochastic forcing scheme was implemented within the mesoscopic multiple-relaxation-time LBM approach to maintain turbulence intensity at targetted levels. Both kinematic and dynamic collision kernels were evaluated to study the correlation of total collision events and turbulent kinetic energy (TKE) dissipation rate. The results show that collisions between particles increase with the TKE dissipation rate as radial relative velocities between particles increase with it. In the particle-resolved simulations, the dynamic collision kernels were found to not match with the kinematic collision kernels as in the point particle method. Quantitatively, they were approximately 4 to 10 times smaller than the corresponding dynamic collision kernels. Therefore, it is not reasonable to estimate the kinematic collision kernel in particle-resolved simulations as its rationales are not valid. However, the collision behaviour can still be accounted for by means of the dynamic collision kernel since it is obtained from the direct statistical analysis of the collision events. Keywords: Lattice Boltzmann Method; particle-resolved simulation; multiphase flow; collisions

Jan 1, 2020

By D. V. J. W. Groenewald, T. M. Louw, L. Auret, S. M. Bradshaw, A. V. Cherkaev

Unexpected equipment failures lead to financial losses due to production disruption. Time-based maintenance, based on checks over regular time periods, has been employed to minimise disruption. However, the improvements it can offer are limited as it may lead to unnecessary service of healthy equipment or missed failures occurring between service intervals. Condition-based maintenance (CBM) provides a further improvement to equipment reliability by detecting faults and predicting remaining useful life (RUL) based on equipment health monitoring. Its application in the mineral processing industry is hindered due to the high cost of health monitoring equipment. In this study, two stochastic process models, the adaptive auto-regressive model and the gamma process, are compared in their ability to forecast the degradation state and to provide RUL prediction. The gamma process model was found to be effective in both tasks. Due to its simplicity and minimum hyperparameters requirements, it is proposed to use the gamma process as a baseline for comparison with other models. Keywords: Condition-based maintenance, remaining useful life, slurry pump, adaptive autoregressive mode, gamma process

Jan 1, 2020

By M. Pawlik, N. Ghaffari Touran

The interactions between apatite and hematite were studied through zeta potential and stability experiments, for this paper. The zeta potential measurements were conducted in both background electrolyte and mineral supernatants. The difference in electrokinetic properties of minerals in the presence and absence of supernatant was explained in terms of the dissolution of minerals and the subsequent readsorption of dissolved species at the mineral-water interface. The stability measurements in individual and mixed mineral systems were also performed to identify the extent of interaction between apatite and hematite upon their direct contact. The results from stability measurements in individual and mixed mineral systems indicate that there is an interaction between apatite and hematite. Based on the results, the implications for the apatite-hematite separation process were discussed. Keywords: Apatite, hematite, dissolved ions, stability, zeta potential

Jan 1, 2020

By M. A. Reuter, N. J. Bartie

Metals make modern societies function, and increasingly, various high purity precious and special metals endow sustainability-driving technologies with specific functionalities. These metals become heavily intertwined within products, complicating end-of-life treatment. To counteract the resulting downcycling and potential depletion of scarce resources, maximising both the quantities and qualities of materials recovered during primary extraction and recycling, processes should be a priority in the pursuit of sustainable circular economy. Adopting a process simulation approach; a digital twin for the life cycle of cadmium-telluride solar photovoltaic (CdTe PV) modules was created. The system comprises an integrated metallurgical production system that produces, among others, cadmium, tellurium, selenium, zinc, copper, and lead, all of which are required to manufacture PV modules. System-wide resource efficiency and environmental impacts are assessed using exergy analysis and life cycle assessment, respectively. Simulation of this large and complex product life cycle at a high level of detail allows for the evaluation of potential system-wide effects of various production, recycling and residue exchange scenarios aimed at maximising the sustainability of the entire system. It diminishes the need to make arbitrary choices about allocation methods for the distribution of environmental impacts in multipleoutput production systems. Furthermore, it demonstrates the key importance of metallurgy in achieving circular economy. Keywords: Circular economy, sustainability, simulation, metallurgy, CdTe photovoltaics, life cycle assessment

Jan 1, 2020

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals generally have high floatability, but their floatability decreases when surfaces are oxidised under some conditions. Sodium hydrosulfide, NaHS, is known both as an activator and as a depressant for copper minerals. NaHS at low concentrations activates copper oxides by sulfurising surfaces, but at high concentrations depresses copper sulfides by interfering with the adsorption of collectors. In this paper, we applied NaHS to activate oxidised chalcocite and bornite and focused on the conditions of NaHS treatments such as dosages and pH, and the effect of these conditions on the floatability of those minerals. The pure minerals treated with NaHS were analysed using zeta potential analyser and X-ray photoelectron spectroscopy. Analyses indicated that the reactions of NaHS and the products on the mineral surfaces after the reactions (i.e. oxidation, pH change) depended on whether NaHS reacted with copper or iron, and the reactions between NaHS and iron depend on NaHS concentration and pH. Flotation tests using a small column cell were performed with a single pure mineral, and using a Denver-type flotation machine with a copper sulfide ore. The results of each flotation test were utilised to clarify the floatability. The relation between flotation behaviours and analysis results were also discussed. Keywords: Chalcocite, bornite, NaHS activation, flotation, floatability

Jan 1, 2020