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By Nick Salisbury, Alan Howard, Scott Tunison

INTRODUCTION Geotechnical investigations for tunneling projects typically use vertical test borings and, to a lesser extent, angled borings. Horizontal drilling applications were often limited to specialty testing programs and to perform probe drilling from a tunnel boring machine (TBM) as part of production tunneling. The former often involved cumbersome setups with skid rigs and cribbing in a pilot tunnel or shaft. The latter usually was limited to generic probing for rock quality and ground water conditions with no sampling. Neither yielded continuous core at production rates suitable for design and construction planning. Conventional vertical investigations still make sense in many instances, particularly for tunnels planned beneath urban settings where truck access is convenient and where the tunnel horizon is not readily accessible via a portal or shaft. However, equipment is presently available to conduct horizontal geotechnicall investigations at reasonable production rates and cost. Advantages include continuously sampling the tunneling horizon and minimizing “access drilling” to get the zone of interest at the underground construction horizon. Horizontal boring lengths of up to approximately 800 m are considered feasible and those in the range of 150 to300 m are now routine. These capabilities make horizontal borings an attractive option to consider when looking at deep tunnels beneath ridges, especially where access is limited. Fewer drilling staging sites can also mean reduced environmental impacts when investigating tunnels proposed beneath sensitive lands such as public wilderness areas. Investment in early construction packages to develop portals for investigation access and, possibly in excavating test shafts for the same purpose should even be considered. Potential benefits in the form of achieving improved overall project costs using horizontal borings exist because of the significant additional data collected in the tunnel horizon. For this reason they should be considered during the routine cost-benefit analyses generally conducted for planning geotechnical investigations for tunneling. The authors also believe that collection of such data will reduce Geotechnical Baseline Report (GBR) conservatism and lead to lower potential for

Jan 1, 2005

The hoisting system at the Newcrest Telfer mine is designed for a final duty of 7.35 million tonnes per annum at a hoisting distance of 1450 m. In terms of hoisting capacity (t/h) times hoisting distance it is one of the largest friction hoist installations. Initially, the hoist will be equipped for hoisting 6.5 Mtpa from 1100 m depth. This new drive technology is now well proven by ABB for mine hoist applications with the first installation in commercial operation since July 2001. To date 17 systems for medium voltage drives and another five for low voltage drives have been purchased from ABB for mine hoists. This paper will also deal with skip design and powerful data loggers with diagnostics for local and remote monitoring that are installed in the Telfer mine hoist.

Jan 1, 2005

By L. M. Oshinowo

The incorporation of advanced analysis tools, such as CFD, into the process plant design process has become possible through advances in commercially available computational fluid dynamics software and faster computers. Multiphase modeling is now typically employed in the design phase of process plant design at Hatch. The multiphase models include Lagrange-Euler and Euler-Euler treatment of the multiple phases. Additionally, mixture models with interface-sharpening algorithms are applied to the prediction of free-surface flows in complex geometry. CFD is applied to applications where traditional design rules are not applicable. The additional rigor of CFD modeling in 2D and 3D allows process engineers to come closer to realizing true virtual plant design. The objective of this paper is to outline the benefits and pitfalls in the application of multiphase modeling for rigorous design. Several application examples in the hydrometallurgical field will be presented.

Jan 1, 2005

By Laurence G. Britton

Accurate flammability and ignitability data for chemicals form the cornerstone of procedures used to assess the hazards associated with commercial chemical production and use. Since 1967 the ASTM E27 Committee on the Hazard Potential of Chemicals has issued numerous, widely used consensus standards dealing with diverse testing and predictive procedures used to obtain relevant chemical hazard properties. The decision to issue a standard rests solely with the membership, which consists of representatives from industry, testing laboratories, consulting firms, government, academia, and instrument suppliers. Consequently, the procedures are automatically relevant, timely, and widely applicable. The purpose of this paper is to highlight some of the widely used standards, complemented with hypothetical but relevant examples describing the testing strategy, interpretation, and application of the results. A further goal of this paper is to encourage participation in the consensus standards development process. The paper is published in two parts. The first part (in the preceding issue of Process Safety Progress) dealt with the E27 standards pertaining to thermodynamics, thermal stability, and chemical compatibility. The second part, published here, focuses on the flammability, ignitability, and explosibility of fuel and air mixtures. © 2005 American Institute of Chemical Engineers Process Saf Prog 24: 12?28, 2005

Jan 1, 2005

By G J. Massoth, K Faure, A G, R G. Ditchburn, I J. Graham

From modest beginnings in 1996, research into the mineral potential of New ZealandÆs Exclusive Economic Zone has progressed into a major multidisciplinary component of GNSÆs recently funded 6-year æMineral Wealth of NZ and its EEZÆ Programme. In excess of $7.5 M of research funding has been expended, plus $10 M leveraged via collaborations with NIWA (NZ), NOAA (USA), JAMSTEC (Japan), U. Kiel (Germany) and ANU (Australia), whose scientists have contributed hugely to research cruises, as well as subsequent analysis and publication. The 1999 NZAPLUME I cruise was the first research expedition to systematically locate, and chemically characterise, submarine hydrothermal venting associated with arc volcanoes of the southern part the Kermadec intra oceanic arc system. This was followed by the 2002 NZAPLUME II and 2004 NZAPLUME III cruises to the mid- and northern-sections of the Kermadec arc, respectively. Combined, these cruises have surveyed 1300 km of the volcanic chain (from Whakatane to Monowai), including 34 major volcanic centres. Together with concurrent surveys in the Tonga arc, this is now the longest continuous stretch of intra oceanic arc to be surveyed for hydrothermal emissions. Most of the volcanic centres are characterised by simple cones although 30 per cent contain caldera complexes, and compositions range from basalt through to rhyolite. Massive sulphide mineralisation has been recovered from several volcanic centres in the southern Kermadecs (Clark, Rumble II West and Brothers), suggesting the existence of significant Au and base metal bearing deposits along the arc front.

Jan 1, 2005

By O N. Antzutkin, A V. Ivanov, W Forsl

Polycrystalline and surface complexes (at synthetic sphalerite, ZnS, and galena, PbS) of zinc(II) and lead(II) ions with eight different O,OÆ-dialkyldithiophosphate (Dtph) substances have been prepared and comparatively studied by means of 31P CP/MAS NMR spectroscopy. The 31P resonances have been assigned to dithiophosphate groups with terminal S,SÆ-chelating or bridging coordinations in the mono-, bi-, tetra- and polynuclear complexes respectively. The bridging coordination of two neighbouring zinc(II) ions by O,OÆ-dialkyldithio-phosphate ligands was established at the surface of synthetic sphalerite.The adsorption mechanism of dialkyldithiophosphate on synthetic galena includes formation of a surface complex as well as surface precipitation. Principally different coordination modes of the reagent were discovered at the surfaces of galena and sphalerite (ie terminal S,SÆ-chelating coordination to the lead atom).Derivatives of monothiophosphoric and phosphoric acids were displayed as hydrolysis products of dialkyldithiophosphates at synthetic PbS.

Jan 1, 2005

By Purushottam Kumar

Keywords: Magnetostriction, magnetic properties, Pd(Fe,Co,Ni) single crystals Fe-Pd, Co-Pd and Ni-Pd alloy systems show appreciable magnetostrictive strains that are of interest for sensor applications. These systems exhibit congruent melting minima. In this work the magnetic and magnetostrictive behavior of congruent melting Fe-Pd, Co-Pd, and Ni-Pd compositions have been examined. The alloys examined include Fe-54.9 at.-% Pd, Ni-45.4 at.-% Pd, and Co-45 at.-% Pd. The paper describes the growth of bulk single crystals of these alloys using Czochralski technique. X-ray diffractometer was used to obtain rocking curves that were used to determine the [001] crystal direction. Magnetostriction in [001] direction was measured using strain gages. Magnetic properties were measured using a vibrating sample magnetometer. Ni-Pd showed the highest magnetostriction values among the congruent melting compositions. Magnetic and magnetostrictive behaviors of these alloy single crystals are presented.

Jan 1, 2005

By Chen Song

Keywords: Co3O4, Cobalt Compounds, Morphology, Urea, Homogeneous Precipitation Depending on experimental condition, precipitation from cobalt nitrate and chloride solution in the presence of urea yield dispersed cobalt compounds with different chemical compositions and morphologies. The effects of concentration of cobalt solution and urea, agitation, on precipitation morphology were investigated experimentally. Generally in closed systems the particles are identified as cobalt (II) basic carbonate with needle type shape. In open system, spherical and plate-like precipitations of cobalt (II) basic cyanate are formed. The chemical formula of cobalt compounds was confirmed. They are CoII,III(OH)0.83(CO3)0.49 Ay?0.14 H2O (in tightly-capped reactor: A stands for NO3?, Cl?; y[A]molecular weight < 12.9) and CoII,III(OH)0.83(NCO)XAy?0.14 H2O. (in open reactor A stands for: NO3?, Cl?; 42 x + y[A]molecular weight < 44.82). The main reason was that the primary particles had different chemical compositions for the effects of the different kinds of anions and stoichio-chemical compositions of the primary particles. The effect degree of the anions depended on the co-existing anion radius in the reaction solution. According DTA-TG analysis of the cobalt compounds, the latter particles transform to Co3O4 powders on calcining. The shape of the Co3O4 particle with porous character has inheritance with precipitation. In this paper, it concludes that the particle formed by the principle of nucleation-aggregation in aqueous solution. The process of aggregation has played an important role in formation of particles. During calcination, the aggregation would be destroyed partly.

Jan 1, 2005

Andesites are a major source of aggregate for much of the North Island of New Zealand. There are regional differences with respect to some important properties of the andesites. Some are reactive with cement and are designated as potentially deleterious or deleterious by the concrete industry. Other andesites, particularly those that are slightly altered or weathered, have rather high Plasticity or Clay Indices and perform poorly in road construction. &nbsp; The performance of the andesites has been investigated and can be shown to be determined by: +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; the chemistry of the rock which in turn determines the chemistry of the glass in the rock; +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; the presence of large amounts of groundmass glass in the rock; and +&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; the nature of the superimposed alteration processes. Environment of extrusion and how rapidly the rock has been cooled or chilled are also important as they determine the fabric of the rock and how much glass will be present in the rock. &nbsp; There are three main types of alteration that affect the quality of the aggregate: 1. &nbsp; hydrothermal alteration, 2. &nbsp; late magmatic alteration associated with the devitrification of glass, and 3.&nbsp;&nbsp; weathering. &nbsp; Each of these alteration types produces different alteration minerals. In fresh andesites the devitrification of glass has an important affect on the rockÆs properties. The Taranaki andesites are shown to have unusually (in comparison with other North Island andesites) high Na2O contents, held in the groundmass glass, which is the fundamental reason for the high alkali û silica reactivity of these andesites.

Jan 1, 2005

By Wang Shulan

The synthesis process of BaTiO3 from TiO2 and BaCO3 in the molten NaOH-KOH at 350oC was studied by the A.C impedance technique. The A.C. impedance of molten NaOH-KOH (xNaOH = 0.36) and the variation of the conductivity of the salt with time during the synthesized process were measured. The synthesized reaction of the BaTiO3 and the decomposition reaction of BaCO3 are fast and were finished in 10min. The interaction between TiO2, BaO and BaTiO3 and the molten salt was confirmed by the variation of the conductivity.

Jan 1, 2005

Declines for both access and rock haulage are replacing shafts for mining relatively shallow deposits of down to 1000 m below surface. Where the orebody does not outcrop and where surface access may be restricted, it is often necessary to drive long dead end headings before a connection can be made back to surface and a ventilation circuit created. In hot tropical areas and where large diesel powered equipment is used for mining, heat may also be a problem at these relatively shallow depths. The normal design criteria based on statutory limits and good practice used to evaluate ventilation and cooling requirements in terms of air velocity, dust, gases, diesel exhaust dilution, re-entry after blasting and heat stress are described in this paper. These are then used to design and cost alternative auxiliary ventilation systems that include leakage based on general fan performance curves and typical duct systems. The implications of the current European Community recommendations regarding nitrous fumes are also briefly considered. The actual problem relates to a 2100 m long decline that may have to be extended to 3000 m long without a connection to surface or through ventilation and is located in a hot tropical area where the surface wet bulb temperatures may exceed 25¦C for more than a third of the summer period. Once the preliminary ventilation design is completed, the auxiliary ventilation system can be modelled and simulations undertaken that incorporate heat and moisture transfer routines with the objective of determining the cooling load and amount of refrigeration required. Cognisance is taken of cyclic diesel operations and the thermal flywheel effect of the surrounding rock on the wet and dry bulb temperatures resulting from these operations.A suitable modular cooling system located at the portal is described and optimised with capital and operating costs of both the ventilation and cooling systems provided.

Jan 1, 2005

By Dave Deglon, Andrévan der Westhuizen

Objectives ?Survey typical Met Accounting streams at the Zincor refinery ?Determine Precision in Metal Conc?s Measurements for Monthly Met Balance ?Determine the Components of Variance in these Met Acc Values (Sampling, Preparation, Analyses) ??Common plant practice? should be mirrored even though not always in perfect agreement with ?laid down procedures? or ?good practice? ?Mass Measurement and Inventory Measurement was considered in less detail ?not reported here

Jan 1, 2005

By M. Matema

Paper written on project work carried out in partial fulfilment of BSc (Eng.) Metallurgy and Materials Engineering Small and large welded aluminium specimens were tested in fatigue and the results compared with design curves for aluminium in specification BS8118. Metallurgical tests were also performed on the specimens in order to correlate microscopic and macroscopic phenomena. The small-scale fatigue test results were in reasonable agreement with results in BS8118, whereas the large-scale fatigue tests showed that BS8118 is conservative.

Jan 1, 2005

By K. Nielsen

The paper presents a brief overview of the mineral industry in Norway, followed by a description of the mineral policy and relevant legislation including the roles of the Norwegian Directorate of Mining and Geological Survey of Norway in this context. The discussion then proceeds to describe the land use planning framework on a national, regional and local level, the interaction between land use planning and the Directorate of Mining and the Geological Survey respectively, and how this impacts on the mineral industry and the exploitation of mineral resources. Some recent Norwegian examples of land use planning conflicts are also presented.

Jan 1, 2005

By N. Singh

Merensky Reef is mined extensively within the Bushveld Complex. In previously mined-out areas on the Merensky Reef horizon there are pillars, potholes and remnants that have not been mined. These unmined blocks of ground on the Merensky Reef horizon can influence the mining of the underlying UG2 Reef. The extent of the influence will depend on the size of unmined ground and the middling between the two reef horizons. This paper quantifies the influence of partially extracted Merensky Reef on mining of the UG2 Reef, and aims to provide recommendations for mining strategies, as well as regional and local support to achieve efficient and safe extraction of the UG2 Reef, for various middlings beneath the Merensky Reef horizon. In some cases it was found that relatively shallow UG2 Reef mining could encounter conditions similar to those experienced in deep and ultra-deep mining environments.

Jan 1, 2005

By Franz Walchshofer, Mark Kuchta, Nobuharu Isago, Ugur Ozbay, Wolfgang Dolsak

A series of in situ pull test were performed on a new design friction stabilizer bolt with the objective of determining its performance characteristics. The bolt is installed while drilling, thus improving safety and significantly reducing the installation time. An optional expansion element can be inserted into the bolt to provide an end-anchorage, which further increases the bolt’s capacity. In situ tests show that the pull capacity of the 2 m long new design bolt is about 15 tons. When installed with an expansion element, the pull capacity of these bolts becomes as high as 30 tons.

Jan 1, 2005

By Charles M. Wilk

"Solidification/stabilization (S/S) treatment is used to treat hazardous wastes for disposal and in the remediation/site restoration of contaminated land . SIS is also an increasingly popular technology for Brownfield (industrial property) redevelopment, since treated wastes can often be left on-site and to improve the soil for subsequent construction. This paper discusses the applicability of the technology to various wastes, basic cement chemistry relating to SIS, tests used to design treatability studies and to verify treatment, basics on implementation of the technology in the field , and examples of SIS use at brownfield sites, including a former wood preserving site, former manufactured gas plant sites, a former electric generating station, and a shopping mall development.INTRODUCTIONSolidification/Stabilization (S/S) is a widely used treatment for the management/disposal of a broad range of contaminated media and wastes; particularly those contaminated with substances classified as hazardous in the United States. The treatment involves mixing a binding reagent into the contaminated media or waste. The treatment protects human health and the environment by immobilizing contaminants within the treated material. Immobilization within the treated material prevents migration of the contaminants to human, animal and plant receptors. SIS treatment has been used to treat radioactive wastes since the 1950s and hazardous waste since the 1970's (Conner 1990). SIS continues as a cornerstone treatment technology for the management of radioactive waste, hazardous waste, and site remediation and Brownfield redevelopment."

Jan 1, 2005

By R. M. Lamya

The kinetics of copper cementation during atmosphere leaching of a Ni-Cu matte in CuSO4-H2SO4 solution was studied as a function of initial copper ion concentration, initial acid concentration, temperature, stirring rate, particle size distribution and pulp density. It was found that all these process variables influenced the rate of cementation. A two-stage rate of reaction was observed inmost of the experiments, with the rate of cementation in the initial stage being slower than that of the subsequent second stage. The increased rate of cementation in the second stage was attributed to the enhancing effect of the surface deposit. The cementation process was found to take place by two different rate-controlling mechanisms. At a temperature range of 50?70°C, an activation energy of 74.6 kJ/mol was obtained, indicating a surface reaction controlled process. At higher temperatures (70?80°C) a lower value of activation energy was observed (18.2 kJ/mol), indicative of a process controlled by diffusion through surface layers. The structural characteristics of the cemented deposit could not be determined in the investigated system where the deposit was mixed with the leach solid residue.

Jan 1, 2005

By Seung-Kyu Son

This study was investigated about physico-chemical parameter such as water temperature, salinity, inorganic nutrients and total organic carbon (TOC). CTD (Model: Sea-Bird 911 Plus) castings were carried out on two transects in the northeast equatorial Pacific Ocean. As a part of the Korea Deep-sea Environment Study (KODES), inorganic nutrients and TOC were determined at 41 stations located from 131° to 136°W along 10.5°N and from 17° to 5°N along 131.5°W (Fig. 1). We particularly chose KODES Long-term Monitoring Station (St. KOMO) to observe for the annually environmental baseline study in the contract area. [ ]

Jan 1, 2005

By J A. Cowburn

The high intensity zone within the Jameson Cell is the downcomer. It is largely external and separated from the flotation tank. This, together with operation of the downcomer under vacuum, rather than at elevated pressure and the absence of moving parts, allows ready access to the high intensity zone for measurement and analysis. Experimentation was conducted allowing measurements of recovery for residence times of between 20 milliseconds and ten seconds within the downcomer of a Jameson Cell. The affect of aeration rate on the recovery of different particle sizes was also studied.

Jan 1, 2005