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By B. Fang

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment, The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate, The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By Erwin Stötzer, Renato Fiorotto, Wolfgang G. Brunner, Manfred Schöpf

"Deep mixing methods can be used economically for the construction of cut-off or excavation support walls where other systems such as traditional soldier beams and lagging walls would yie ld unsatisfactory performance, where the installation of vibrated or driven sheet piles could cause vibration induced settlements and where concrete diaphragm walls would be time consuming and expensive. The new CSM method can largely replace the more conventional single or multiple auger methods of soil mixing or jet grouting. The cutter tool is similar to a cutter used in diaphragm walls or cut-off walls and is operated with a Kelly mounted on a drill rig. With this system much deeper walls can be installed and even hard soil layers can be penetrated. CONVENTIONAL SOIL MIXINGIn 1962 Norman Liver patented an auger-based soil mixing technique that has become the basis for the world's current technology.The deep mixing method (DMM), as it is known today, is an in situ soil treatment and improvement technology where the soil is blended with binders and/or other materials that are introduced in a slurry or dry form.Typically one or more hollow, rotating mixing shafts tipped with some type of cutting tool are mounted vertically to the mast of a base carrier and are driven into the ground by hydraulic or electrically powered rotary heads. The shafts above the cutting tool may be further equipped with discontinuous auger flights and/or mixing paddles. The binder is injected through the hollow shafts to nozzles located near the cutting tool where it is mixed with the ground to form columns of treated soil.Individual column diameters range from 0,6m to 1,5m and may extend to 40 m in depth. They can be arranged individually or in contiguous or secant patterns to produce a wide range of treated soil structures on both land and marine projects. Typical configurations are: Single elements, rows of overlapping (secant) elements, grids, lattices and blocks (Fig. 1 )."

Jan 1, 2005

By Yi Luo, Jeremy Slagley, Arunkumar Rai, Steve Guffey, Syd S. Peng

Research was conducted to study the characteristics of longwall mining machine noises and to develop engineering controls for the reduction of noise exposure at longwall faces. Time-motion noise dosimeter data was analyzed and compared with existing databases. Experiments were conducted above ground on a stage loader/crusher to explore the potential of using active noise control (noise cancellation) in reducing the noise levels. A 5-7 dBA reduction in recorded stage loader noise was achieved. This paper presents the equipment, procedure and results of the noise surveys, as well as the active noise control experiments.

Jan 1, 2005

Surface Plasmon Resonance (SPR) spectroscopy, combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithio-phosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as-300 mV (vs SHE). Keywords: flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.

Jan 1, 2005

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By Yi Luo

The efforts to mitigate longwall subsidence influences on various residential and farming structures by many coal mining companies have been successful in the recent years (Luo, et al, 2003). The successes were largely dependent on the accurate subsidence predictions, correct assessments of potential influences, appropriate design and implementation of the mitigation measures. However, such efforts for protecting large industrial structures are still very rare. In this paper, the successful assessment and mitigation of the subsidence influences associated with a very intensive dynamic longwall subsidence process on a large workshop are presented.

Jan 1, 2005

By J-P Franzidis, E V. Manlap

Froth transportation characteristics have a significant impact on the flotation recovery especially in large flotation cells. The probability of an attached particle being recovered into the concentrate depends strongly on the location where it enters the froth phase. A mathematical model for froth transportation in industrial flotation cells was proposed (Zheng et al, 2004). The model has been tested on the experimental data obtained from testwork conducted at the Western Metals Hellyer lead/zinc concentrator. The results show that the model fits the experimental data well, especially when the froth is well developed (ie for a deep froth). The model fitting can be significantly improved by incorporating an air dispersion factor. However, the models encounter some limitation, ie inconsistent prediction at different froth heights, due to change in froth viscosity which cannot be modelled at the present time.

Jan 1, 2005

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005

By Melissa L. Trapani

Keywords: Copper, Taphole, Flow Instability. ?Blister spitting? is a flow irregularity where the molten blister copper stream ? or part thereof ? sprays from the taphole exit rather than following a regular flow profile to the collection box. As well as being a general ?housekeeping? issue, the unpredictable nature of the flow is a threat to operator safety. Also, the aggressive flow pattern may contribute to the mechanical wear of the taphole refractory, compromising the integrity of the taphole. This paper brings together a collection of first-hand observations and reports from process personnel, and suggests some theories as to the causes of blister spitting.

Jan 1, 2005

By Rob Farnfield, Charlie Adhock

The measurement of near-field shock has always been an attractive proposition for those working in the field of explosive and blast performance. The most commonly employed technique involves the use of piezoelectric accelerometers. Although highly effective, these complicated devices are relatively expensive and are often destroyed in the blast event. This paper describes the development and field-testing of a shock sensor of sufficiently low cost to enable it to be routinely used in product blasting. This new device is based on piezoelectric wafer technology and does not require any external signal conditioning. The device is housed in a small cylindrical package with approximate dimensions of 30mm (1.2”) length and 5mm (0.2”) diameter. It has been determined that the most effective way of fixing the device to rock is in a small diameter hole with epoxy glue. Alternatively the sensor can be simply placed in holes filled with either water or bulk emulsion explosive.

Jan 1, 2005

By Ron Glowe

This paper shows the potential of a new computer model, using the Glowe-Tech (GT) Tonnage Analyzer program to compare drilling and blasting results. This model uses the crushers and conveyors as measuring tools in aggregate quarries in the USA and Canada. All data is collected using commercially available kilowatt transducers and an analog input/output automation module. There are two areas of measurement used to compare results. The first area is the tonnage moved by key conveyors to show the split in products produced and the actual rate of production. If belt scale readings are not available then the Glowe-Tech Tonnage Analyzer can be used to convert kilowatts from the conveyor motor to tonnage. The second is the tons of rock crushed per kilowatt hour of energy consumption by the primary and secondary (optional) crushers. This modeling process works best if blasts are mucked and crushed in sequence. There are many other variables such as crusher types, crusher settings, screen sizing and actual geology in the pit that can influence the results, however if variables can be standardized then definite trends can be seen when comparing drilling and blasting results

Jan 1, 2005

By L. Jeffrey

The Waterberg Coalfield has vast potential to become a significantmining and industrial centre in South Africa. Its future developmenthinges on a number of critical decisions that must be made jointly by government, power utilities and industry, and on some technical and economic challenges that must initially be overcome. Sufficient water is the primary key to enabling exploitation, together with an adequate market for the large volumes of low-grade coal. As the most likely consumer of this coal will be either a power station or a petrochemical complex, the need for additional energy will be a driving force in the development of this coalfield. Conventional mining methods can exploit the shallow coal resources in both the Grootegeluk and the Vryheid formations, but alternative technologies such as coalbed methane extraction and underground coal gasification are the only currently known technologies that may be able to exploit the deep Grootegeluk Formation resources. However, extensive research is still required into these procedures, particularly with respect to the Waterberg coals. Transport infrastructure to the region is currently not sufficiently well developed to support large-scale exploitation of the region?s coal resources. In particular, the railway line would have to be extensively upgraded to allow the increased export of coal. Alternative transport methods such as pipelines would also have to be pursued to serve a large Sasol-type petrochemical complex or coal gas extraction. The road network would also require improvement, as only the roads between the main commercial centres are currently tarred. Dr Con Fauconnier, Kumba CEO, concluded his presentation to the Investing in African Mining Conference 2004 with the words: Again, it?s all about infrastructure? when it?s there, it enables the development of bulk mining projects which attract the resultant economic benefits for the region and country as a whole. These words aptly sum up one of the stumbling blocks to the future development of the Waterberg Coalfield.

Jan 1, 2005

By R. M. Goktan

Rock brittleness plays an important role in the cutting action of picks on rock surfaces. It controls the ease with which cracks can propagate through the rocks. Although rock brittleness is known as a property that contributes to the cuttability of rocks, despite considerable research effort, there is still much uncertainty about the relation between rock brittleness and rock cutting efficiency. This fact can be attributed to the lack of a universally accepted brittleness concept and a brittleness measurement method. The existing publications of some researchers have, in a way, tended to confuse the understanding of brittleness in the general field of rock excavation where it is expected that the energy consumption of cutting should decrease with increasing brittleness of rock, other conditions being equal. However, this sometimes conflicts with the brittleness concept commonly used in rock mechanics, where the more brittle the rock the higher its mechanical strength. The ratio of rock compressive strength to tensile strength is considered by many authors to give a valuable brittleness index for drag pick operations. Hence, in this contribution the ratio of uniaxial compressive strength to tensile strength BI is considered as an index of rock brittleness, and a new methodology is proposed for its use in rock cutting efficiency analyses of drag tool operations. Validation of the suggested approach is supported by available experimental data in the literature. Contrary to the conclusions reached previously by other authors, it is shown that an increase in rock brittleness is accompanied by an increase in the cutting efficiency, other conditions being equal. Keywords: brittleness index, rock brittleness, cutting efficiency, specific energy, rock excavation.

Jan 1, 2005

By J. Martinovic

The large proportion of gangue minerals present in platinum bearing ores in South Africa provides challenges to the flotation and downstream processes. In order to take effective measures to reduce their recovery in flotation, an understanding of the mechanisms and factors influencing their behaviour is needed. Typical gangue minerals are pyroxene, feldspar, quartz, chromite and talc. Of these, talc is a naturally hydrophobic mineral and although it is present in relatively small quantities, it has a disproportionate effect as it has a strong froth stabilizing effect, increasing the recovery of other gangue minerals by entrainment. Talc recovery is effectively reduced with the addition of polymeric depressants. Although the other gangue minerals are assumed to be hydrophilic and their recovery by entrainment is expected to follow the water recovery, there is some evidence that they may be activated by the typical reagent suites used. Reagents such as copper sulphate, added as an activator, and collectors are used to selectively induce hydrophobicity on the sulphides. It has been shown that some of these gangue minerals can be activated. This research work investigates whether inadvertent copper activation is mineral specific and evaluates the mechanisms and factors affecting the reversal of activation with the addition of the depressants using electrokinetic measurements, adsorption and microflotation tests. Results are presented that show that the selected minerals do respond differently and that the reversal of activation is dependent on mineral type, depressant type, dosage and ionic strength of the electrolyte.

Jan 1, 2005

By S-E. Vandat

The goal of this work was to select an appropriate electrode for dummy load of diesel engine in fully salt-water in the DESA factory. The electrochemical corrosion rate of general structural steel, commercial pure aluminum and cathode copper calculated as weighting, volumetric and commercial in fully salt-water by city power. After several tests and then applying the fuzzy logic method, it was determined that general structural steel is the best selection for this purpose.

Jan 1, 2005

By R J. Goldfarb, A B. Christie, D I. Groves

Small orogenic gold deposits have the same deposit-scale geological and geochemical features as those that characterise giant orogenic gold systems (>16 Moz Au). Therefore, a broader-scale approach is needed to identify the critical controls on giant deposits and their disproportionate distribution throughout time and space. Ages of giant gold systems cluster around well-defined periods of lithospheric growth at continental margins, and it is orogen-scale processes during these Late Archaean, Early Proterozoic and Phanerozoic times that determine gold endowment of a province.   A critical factor for giant orogenic gold provinces appears to be asthenospheric upwelling at the time of gold mineralisation to most effectively transfer the thermal energy required to initiate and sustain high hydrothermal fluid flux. The extent of this fluid flux should be related to thickness of the lithosphere beneath a province at the time of gold mineralisation, such that giant gold deposits are much more likely to develop in orogens with oceanic or thinned continental lithosphere. A proxy for the latter is likely to be a short premineralisation crustal history such that thick subcontinental lithospheric mantle was not developed. Conversely, orogens with protracted premineralisation crustal histories are more likely to have a thick subcontinental lithospheric mantle, which is difficult to delaminate and, hence, such provinces will normally be poorly endowed. The nature of the lithosphere also influences the intrinsic gold concentrations of potential source rocks, with back-arc basalts, transitional basalts and basanites enriched in gold relative to other rock sequences. Thus, segments of orogens with thin lithosphere may be defined by conjunction of giant-scale fluid flux through gold-enriched sequences.   Although the nature of the lithosphere plays the crucial role in dictating which orogenic gold provinces will contain one or more giant deposits, the precise siting of those giants depends on the critical conjunction of a number of province-scale factors that control fluid conduits, traps, and seals in tectonically and lithospherically suitable terranes within accretionary orogens.

Jan 1, 2005

By Robert B. Bittner

The Sutong Bridge across the lower Yangtze River in China will have, when completed, the longest span (1,088 m) and the highest towers (306 m) of any cable stayed span in the world. The foundations for this record setting span will also be record setting. They are located in water depths exceeding 30 m with maximum flows exceeding 3 m/sec. The soil at the site of the main pylons consists of layers of silty sands and silty clays extending to bed rock at 270 m below river elevation. This paper describes the innovative methods used by the team of foundation designers and constructors to support this record setting bridge at this very challenging site. This paper covers three specific topics related to the foundations of the Sutong Bridge: ? Design and construction of the 131 drilled shaft (2.8/2.5 m diameter and 114/117 m long) under each of the two main pylons, ? Design and construction of the scour protection for the two main pylons, ? Construction methods used to construct the waterline pile caps (113.8 m by 48.1 m by 13.3 m deep) under each pylon.

Jan 1, 2005

By Chang-Yu Ou, Shao-Chi Chien, Hsuan-Hsiang Chang

"A field test was performed to investigate the applicability of electroosmosis with the injection of saline solution of Taipei silty clay. The calcium chloride solution and sodium silicate solution were used as the saline solution for the injection in this test. The results of this study indicate that injection using calcium chloride solution and sodium silicate solution during the electroosmosis to increase drained water from cathode and electro-chemical reaction can greatly improve the effect of electroosmosis and shorten the time of treatment. The results of field vane tests showed that the undrained shear strength after treatment increased an average of approximately 120% for a treatment period of 24 days.INTRODUCTIONThe first field application of electroosmosis in soil was demonstrated by Casagrande in 1939. Since then, more complete field applications of electroosmosis such as Bjerrum (1967), Fetzer (1967), and Lo et al. (1991b) have been made.The results of field electroosmotic work for a period of 120 days were presented by Bjerrum et al. ( 1967). The mean undrained shear strength, Su, increased from 18 to about 40 kPa, with a uniform surface settlement of about 0.5 m. Lo et al. (1991b), with a more sophisticated installation and a relatively larger spacing, also had positive results. For a 3 m electrode spacing during the treatment of a period of 33 days, the mean Su increased from 18 to about 25 kPa. Although the effect of the electroosmosis could be applied in the field based on the above examples, the response remained slow. For actual field work, the application of electroosmosis will be limited due to short project schedules and request of the effect of improvement."

Jan 1, 2005

By P. K. Hofmeyr

Base Metal (Cu, Ni, Mo, Zn, Co etc.) analysis traditionally has been very slow in conventional analytical laboratories which can lead to additional costs being incurred in waiting time of drill rigs or mining excessively off-reef. Recent developments in the automation of analytical laboratories now allow for very rapid turn-around times for base metal analytical data which can help reduce such costs as well as reduce the unit costs of the analyses themselves. 2.0 CONVENTIONAL ANALYTICAL LABORATORY PRACTICE Conventional analytical laboratories are necessarily are very manual. Sample preparation is slow and laborious, samples are moved from stage to stage manually and, typically, all samples are processed in batches so a sample which is the first to be, say, milled has to wait for the complete milling of the batch before it advances to the next stage eg. mixed with wax prior to pelletising for XRF analysis. Inevitably this results in long sample data turn-around times for laboratories handling large numbers of samples. Manual sample preparation can only be accelerated by increasing staff which increases costs and can lead to additional errors being introduced. Cleaning of sample preparation equipment, eg. crushers and mills, between samples is essential to avoid cross-contamination between samples and this is slow and labour-intensive. In manual sample preparation the correct sample numbers staying with the samples is totally dependent on the efficiency of laboratory operators. It is extremely difficult to detect when errors have occurred due to the switching of sample numbers during the sample preparation stages. Running duplicates and QC samples at best is only partially successful in detecting when sample number switching errors have occurred. Errors of this nature and cross-contamination problems due to incomplete cleaning of sample preparation equipment tend to occur when laboratories are working at pressure due to high sample numbers and when supervisors are not present during 24/7 laboratory operations which is often required on plant process control laboratories. These problems are common to all conventional analytical laboratories and their magnitude is dependent on the level of control and efficiency of QC systems practised by individual laboratories. The disadvantages of conventional manual analytical laboratories can be summarized as follows:- 1. Labour-intensive which is costly especially when multiple shifts have to be used during 24/7 operations.

Jan 1, 2005

By Donald W. Stever

In 1995 I was asked to participate in a litigation matter between a corporation and its insurance carriers concerning insurance coverage for remedial costs at a large, environmentally contaminated closed-down former industrial facility. One of the buildings on this site became known to the lawyers representing the company as “the infamous Building 8”. This building housed millions of documents retrieved from various locations at the facility while it was being shut down. It became apparent that the facility management had no document destruction policy, and thus Building 8 contained internal memoranda, notes, copies of correspondence, permits, operating records, inventory records, and the like from fifty years of operation. Needless to say, some of these documents, all of which were subject to discovery by the insurance companies in the litigation, contained material that was less than helpful to the company’s case. Of course, there were also a few helpful documents, but the overall usefulness of these records was outweighed by the negative impact they had on the conduct of the litigation. A second example involves e-mail. Several years ago, acting on an anonymous complaint that we later discovered was made by a disgruntled former employee who had been fired, a small army of federal environmental investigators descended on a client’s operating facility and, armed with a search warrant, literally commandeered the facility’s EH&S department. The investigators impounded the computers of the EH&S personnel and extracted all of the data from the hard drives of those PCs, as well as all EH&S related files from the hard drives of several servers used by the facility. These computers contained many years’ worth of stored e-mails, draft letters and memoranda, and other documents that provided grist for a four and one-half year criminal grand jury investigation of the facility and its EH&S staff. Both of these companies would have benefited from following a rigorous, enforceable, corporate records policy. Here is a third problem. My client had, during the 1960s, made a brief, and unprofitable foray into the nuclear fuel processing business. It ultimately sold the subsidiary, and was forced to give the purchasing company a broad indemnity against future liability. As might be expected, years later the facility was found to have considerable soil and ground water contamination both by chlorinated solvents and low-level radioactive material. Several years into the remediation program, my client discovered a tractor-trailer load of files, apparently removed from the subject facility, sitting in a parked trailer in a company-owned lot 300 miles away from the facility, where they had been for nearly thirty years. These documents were not helpful to the client, but had to be reviewed, at considerable cost, by paralegals. Moreover, several of the boxes turned out to have been mildly radioactive, setting off a chain of health and safety issues that consumed tens of thousands of dollars of legal expenses before they were resolved. Today, formal, enforceable corporate records management programs have become an extremely important element of overall corporate management. What was for most of the last century little more than a low level warehousing function is now a critical, actively managed, operating function that affects every level of corporate management. The rapid assimilation into corporate culture of electronic document management and the prevalence of e-email as the primary means of internal communication have created records management complexities the likes of which were not even conceived of fifteen years ago. Record preservation and destruction are no longer matters that can be handled on an ad-hoc decision making basis. Because of regulatory requirements affecting various classes of documents and the litigation consequences of ad hoc retention and destruction of corporate business records, and the need to have the ability to quickly retrieve documents in either a litigation or business negotiation context, a set of records management norms have evolved over time that have become the core elements of virtually every corporate records program. However, notwithstanding the existence of a set of norms (which are the basic elements of a

Jan 1, 2005