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By B. Q. By

TiO2 is an ideal material for catalytic technology due to its unique properties. In this paper, Sm3+ doped TiO2 photo-catalyst was developed to improve the efficiency of TiO2 and to use the natural light as irradiation source, which was made from Titanium Tetrabutoxide and Samarium Oxide with the Sol-Gel process. The Sm3+-TiO2 photocatalyst was used to degrade reactive orange 4 (RO4) in Azo Dyes. The effects of solution pH, Sm3+ concentration and catalytic time on the degradation rate of RO4 were studied. The characteristics of the catalyst were analyzed with XRD and TEM. The experimental results show that the catalyst has high activity in the degradation of RO4. The Azo bonds of RO4 are active and easily broken by oxidation. The catalytic activity of the Sm3+ doped catalyst greatly depends on the pH of solution. The catalyst has high photo-catalytic activity at both neutral and alkaline conditions. The degradation mechanism of the Sm3+ doped TiO2 photo-catalyst was also discussed.

Jan 1, 2014

By S. Chander

The effect of sample storage in argon and in air on kinetics of oxidation of pyrite from a coal source was studied using accelerated weathering test in laboratory columns. Prior to the weathering tests the samples were crushed, ground, and stored for various time periods in argon and air. The results showed a dramatic difference in the rate of oxidation of the aged samples. The differences were interpreted based on the hypothesis that the aging of pyrite led to the formation of surface coatings which changed with time. The significance of these results in pyrite/reagent interactions in flotation and in evaluating the acid mine drainage potential of pyritic waste materials is discussed.

Jan 1, 1993

By N. S. Aouad

"Gaseous explosions are one of the most hazardous incidents in process and mining industries. Experimental research in this area is shown to be high risk and expensive. Computational Fluid Dynamics (CFD) techniques are reasonable alternatives to experiments; specifically when testing large scale gaseous explosions such as methane explosion in underground mines. The dimensions of a confined space where explosions could occur vary significantly. Thus, the scaling effect on explosion parameters is worth to be investigated using CFD tools. In this research paper, the impact of scaling on the explosion overpressures is investigated by employing two scaling factors. These two factors are the Gas-fill Length scaling factor (FLSF) and the Hydraulic Diameter scaling factor (HDSF). The combinations of eight HDSFs (1, 2, 4, 8, 16, 32, 64, and 100) and five HDSFs (0.5, 1, 2, 4, and 8) will cover a wide range of space dimensions where flammable gas could accumulate. Experiments were conducted to evaluate the selected premixed combustion and turbulence models. Large Eddy Simulation (LES) turbulence model was used because it shows accuracy compared to the widely used Reynolds’ averaged models for the scenarios investigated in the experiments. Researchers also simulated methane explosions in both deflagration and detonation regimes using different numerical schemes. Three major conclusions can be drawn from the simulation results. (1) The overpressure increases with both FLSF and HDSF within the deflagration regime; (2) in an explosion duct with length to diameter ratio greater than 54, detonation is more likely to be triggered for stoichiometric methane/air mixture; (3) overpressure increases as an increment hydraulic diameter of a geometry within deflagration regime. INTRODUCTION The most typical category of gaseous explosion accidents is methane explosion accidents in the mining industry. It normally leads to significant economic loss and massive amount of casualties (McPherson, 1993). It could occur in unconfined spaces, such as combustion due to flammable gas leakage, as well as confined spaces, such as inner-combustion in process equipment and methane explosions in airways of underground mines. Gaseous explosions in confined spaces are more intensive compared to unconfined spaces provided that the total energy of explosives is the same. In addition, explosion characteristics are also affected by the geometry of a selected confined space. The size of confined spaces commonly encountered in process and mining industries could differ as much as an order of four (Catlin & Johnson, 1992). A better understanding of the scaling effect on gaseous explosions could contribute to explosion mitigation and prevent operation activities within high risk regions. This research paper has investigated this scaling effect and its impact on explosion propagation. The approach to investigate explosions is either experimental or numerical. Large scale explosion experiments are often costly and dangerous (Catlin, 1991; Zhang, Pang, & Zhang, 2011). Lab scale experiments and numerical methods are common alternatives. However, it is not yet clear if the findings in lab scale experiments can be used to represent the explosion characteristics or not. On the other hand, CFD modeling has been used to simulate chemical combustions and, thus, can be used to evaluate the scaling effects in methane explosions."

Jan 1, 2015

By J. E. Chilton

The National Institute for Occupational Safety and Health (NIOSH) has conducted research to determine the influence of mining machine-mounted scrubbers on airflows and methane concentrations at the face when blowing ventilation systems are used. Tests were conducted in a full-scale ventilation gallery with a model mining machine that simulated airflow created by a dust scrubber. During the tests, ultrasonic anemometers were used to measure airflow speed and direction at several locations near the face. For the same test conditions, methane was released from the face and gas concentrations were measured at 21 locations above the machine using fixed point methanometers. Changes in airflow speed and direction are correlated with scrubber airflow and the measured methane distribution above the mining machine. The research results showed that operation of machine-mounted scrubbers improved face ventilation when blowing ventilation is used by increasing both the intake flow and the quantity of air reaching the face.

By PERCY E. BARBOUR

SECONDARY copper1 has &come more or less of a bugbear generally. What is its influence is often the subject of heated argument. The inedapable fact usually quoted is that since in 1929 primary production of copper in the United States was 1,026,348 tons and secondary production was 626,550 tons, there- fore, 0.6 lb. of secondary is produced for every pound of primary, and "How can you get around that?" The matter seems very plain, now that I have reached my conclusions, but they are the result of much laborious study and research. I shall show that' the production of secondary copper is not 0.6 per lb. of primary, in spite of statistical appearances; that the production of secondary is a function of primary production rather than of price; that secondary production has 'only a sub-. ordinate influence on the price of copper and then only in abnormal times; that there is not an accumulating reservoir of secondary from which the country is some- time to be drowned in copper, as is believed by some, or a reservoir from which we are going to draw much needed and more or less inexhaustible stores in the future, as is believed by others; and finally, that the United States always produces more copper than it uses and exports the surplus. These are all controversial points, and for that reason and to anticipate argument I have set forth my reasoning in considerable detail.

Jan 1, 1931

By Liu Xinghua

Yuanjiacun iron ore located in Shanxi province of China has finely disseminated grain size and contains refractory iron-bearing silicate gangue minerals such as chlorite. Therefore, a large amount of secondary slime (the content of -10µm fraction was up to 32.92%) was produced inevitably in fine grinding process, and chlorite was also enriched in concentrate from the content of 4.3% to 14.8% after high intensity magnetic separation. These two characteristics result in the difficulty to deal with Yuanjiacun iron ore by flotation. In this test work, contrast tests between single reverse flotation and selective flocculation desliming-reverse flotation were conducted on Yuanjiacun iron ore. The test results show that after selective flocculation desliming, the iron grade of cationic reverse flotation concentrate increases by 6.15% and the recovery increases by 7.25%; the iron grade of anionic reverse flotation concentrate also increases by 2.15%. Furthermore, analyses of grain size composition and mineral composition were carried out on separation products, the results indicate that selective flocculation desliming plays a dual role of optimizing grain size composition of flotation feed and removing iron-bearing silicate gangue minerals (chlorite) effectively.

Sep 1, 2012

By E. Nejati, S. Khoshkooei, V. Firouzdor, M. Akbari, F. Khomamizadeh

In this study the effects of Si content on mechanical and thermal fatigue properties of Al-Si casting alloys were investigated. Repeated heating and cooling cycles were applied on the samples at 230°C to develop thermal fatigue cracks. Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy. Thermal fatigue behaviors were improved successively by increasing of silicon content up to 7wt%. However, addition of more than 9wt% silicon decreased the thermal shock resistance of the alloy. Silicon contents of about 9wt% presented the best mechanical and thermal fatigue resistance in the alloy.

Jan 1, 2006

By M. B. Shongwe, G. Freemantle, M. Botha, S. Brill, J. D. Steenkamp

During steelmaking, one important factor for production efficiency is the free opening of the ladle nozzle during continuous casting. Free opening occurs when the well filler sand and the steel flow freely when the slide gate is opened. Well filler sands are used for the slide gate of a ladle to separate the slide gate refractory and the molten steel. The well filler sand is partially sintered by the heat of the molten metal, which can result in the ladle nozzle failing to open if the sand is not sintered to an appropriate extent. It is therefore of great importance that the sintering behaviour of well filler sand is understood. We studied the effect of the well filler sand chemistry on its sintering properties. Samples of well filler sand with various chemical compositions were sintered in a high-temperature chamber furnace. Quantitative X-ray diffraction (XRD), inductively coupled plasma optical emission spectrometry (ICPOES), and wavelength dispersive spectrometry (WDS) by electron microprobe analysis (EMPA) were used to analyse the various well filler sand mixes. Points of analysis were indicated on backscattered electron (BSE) micrographs. Quantitative element mapping was undertaken by energy dispersive spectrometry (EDS). Thermodynamic calculations in FactSage predicted the percentage liquid phase present for the various well filler sand compositions at equilibrium conditions. The results of this work show that the degree of sintering of chromite-silica well filler sand depends strongly on the silica content. The amount of liquid phase formed increases with increasing silica content.

Feb 2, 2022

By F. Chiesa, Jeremy Carignan, B. Duchesne, D. Levasseur

"Aluminium A206 (AlCu4) is one of the strongest aluminium casting alloys with tensile properties approaching those of ferritic ductile iron. If the specification on the silicon content (< 0.05%) is easy to achieve during alloy ingot production, it is not the case in a foundry, where returns are used which are not perfectly cleaned from the silicate containing molding sand (Olivine). In alloy A206, the Si content is controlled in order to avoid the formation of a low melting point intermetallic phase (such as phase Q Al5Cu2Si6Mg2); these phases will melt during the solutionizing heat treatment to which alloy A206 must be subjected to develop its outstanding mechanical properties. This incipient melting may deteriorate the mechanical properties of Alloy A206 if the solutionizing treatment is applied at the standard temperature of 530°C.In the present study, a lower temperature solutionizing (520°C) was applied to a high Si content 206 alloy in order to reduce or eliminate the possible incipient melting. This was carried out on a complex shape industrial casting weighing 14 kg (31 lb) and 560x410x250 mm (22x16x10”) in size poured in aluminum 206 with a high silicon content (0.22% vs 0.05% max for alloy A206). Twenty ASTM E8 subsize tensile specimens were excised from two locations in the casting in order to compare the tensile properties for the two solutionizing temperature used (530 and 520°C). Optical and SEM microscopy allowed to investigate the causes of the differences in the properties observed between the 2 zones of the casting studied for 3 different heat treatments. INTRODUCTIONIn spite of their “textbook” outstanding mechanical properties (Up to twice the strength and elongation of the widely used A356 alloy), aluminum-copper alloys of the 2xx series are seldom used because of their propensity for hot tearing [Li, 2011], the segregation of copper [Cho, 2003], and their sensitivity to stress corrosion cracking [Jean, 2009, p. 113)]. Also, because of their wide freezing range and high thermal conductivity, a wide mushy zone makes feeding difficult, unless strong temperature gradients are created by liberal use of chills and risers in the critical zones of the part. Because they are prone to hot tearing, grain refining of Al-Cu alloys is particularly important, titanium playing a major role in the process [Sigworth, 2003]; grain refining has also been shown to be beneficial to fatigue strength [Jean, 2009, p. 103]. The practical basis of foundry practices pertaining to these alloys is outlined in an AFS webinar [Weiss, 2014]."

Jan 1, 2016

By H. D. Newell

THERE has been much research and commercial development in recent years in the use of chromium and nickel in steels of various types, including those intended for high-temperature service. By "high-tem-perature steels" are meant those specifically designed for service at ele-vated temperatures in steam plants, oil refineries and other industries where high-temperature operations are conducted. This paper is devoted to some preliminary data on the effect of silicon on certain of the most popular chromium-molybdenum steels now being used in quantity by the refining industry and includes a short statement on the influence of copper in steels intended for high-temperature service.

Jan 1, 1937

By Zhiqiang Zhou, Shengnan Zhou, Zizong Zhu, Yuchuan Ding

The effect of silicon on removal of phosphorus from high phosphorus Si–Mn alloy was investigated at 1673 K by CaO-based slag. It was found that the dephosphorization efficiency increases significantly as increasing the silicon content, which is due to the reaction between silicon and CaO at slag/alloy interface. The relation between silicon content with oxygen activity and phosphorus activity coefficient of Si–Mn melt was determined respectively as follows: lg aO = -1:55xSi - 1:67; ln rP = 9:26e xSi 0:0433 + 11:0839 The carbon content in Si–Mn melt decreases continuously with the increasing silicon content, meanwhile, the decreasing rate of carbon content becomes rapid when the mole fraction of silicon is about 0.32. Si addition is beneficial for both dephosphorization process and low carbon Si–Mn alloy production.

Mar 1, 2017

By Champoux. G., E. Ghali, W. Zhang, G. Monteith, A. -M. Lafront, G. Houlachi

The efficiency of the electrowinning process of zinc depends on the performance of oxygen evolution reaction, anode quality and corrosion resistance of lead anodes. Original surfaces of rolled commercial lead-silver anodes were examined using conventional polarisation methods in acid zinc sulfate electrolyte with manganese sulphate at 38 °C. The self-discharge method (potential decay) following 5 h polarisation at 50 mA cm-2 was considered to evaluate electrochemical activity, oxygen overpotential and anode stability. The influence of silver content is compared to that of the microstructure, the fabrication process and the composition of the corrosion products. Polished anode samples have also been examined for microstructural and corrosion performance studies. The experiments show that the duration of the plateau at 1600 mV versus SHE, the potential level (active corrosion state/stationary state) and the rate AEco/At during the decay could be a good indicator to compare the corrosion rates of the anodes in industrial zinc electrolytes.

Jan 1, 2008

By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By Mingming Zhang, Marshall S. Coe, Marcelo W. Andrade

To supply iron units and flux burden in blast furnaces, sinter basicity is one of the vital parameters for sinter plants. The sinter basicity also plays an important role in sinter quality since it imparts the formation of different mineral phases in sinter. Pot-grate sintering tests were carried out with low and high basicity to investigate the effects of sinter basicity on sinter mineralogy, properties and productivity. It was found that with an increase in sinter basicity, both sinter productivity and reducibility (RI) increased. Tumbler index (TI) and low temperature degradation index (LTD) of high basicity sinter were comparable to low basicity sinter. Softening and melting tests showed that sinter with 3.5 C/S basicity had slightly higher softening temperature comparing to lower basicity sinter with C/S 2.6, acid and fluxed pellets. XRD analyses confirmed the formation of silico-ferrite of calcium and alumina (SFCA) and calcium ferrite (CF) in the tested sinter samples.

Jan 1, 2015

By Robert H. Hafner, Irvin R. Kramer, Stewart L. Toleman

IN his paper on the calculation of hardenability from chemical composition, Grossmann1 discussed the effect of most of the alloying elements used commercially. The purpose of the work reported in this paper was to determine the effect of several other elements on hardenability-arsenic, antimony, beryllium, cobalt, columbium, germanium, tellurium, tin, aluminum, and titanium-and to extend the range of composition of some of the elements studied by , Grossmann-chromium, copper, manganese, molybdenum, nickel and silicon. EXPERIMENTAL METHODS To determine the effect on hardenability, suitable amounts of the alloying elements were added to experimental heats and the hardenability determined by means of end-quenched hardenability specimens. The steels were melted in a high-frequency induction furnace with a basic crucible, using ingot iron as a base for some of the heats and S.A.E. 1015 for others. The alloying additions were made as ferroalloys or as metal, depending on the &apos; alloying element. Hundred-pound heats were split and poured into square, tapered, cast-iron ingot molds with hot tops. Aluminum was not used as a deoxidizer in most of the heats. The ingots were homogenized for 12 hr. at 1260°C. (2300°F.) , and forged into rounds of 1 ½ in. diameter. These bars were normalized twice from 840°C. (1550°F.) before machining into Jominy bars. The composition of the steels was deter- [ ] mined in most cases by samples taken from the end-quench hardenability specimen. As suggested by crafts,2acid-soluble

Jan 1, 1943

By Luiz Henrique Accorsi Gans

First, this works carries an experimental evaluation for austempered ductile iron (ADI) as a gear material. And second, in order to provide a better understanding of the microstructural effect on the stress state of subsurface regions, a finite element method approach was considered using the submodeling tool in ANSYS 11.0. For this, ADI gears were produced from continuous cast iron bars, heat and thermochemical treated and tested in FZG test rig. The results were compared to those of carburized steel AISI 8620 and induction hardened steel AISI 4140 gears. The wear experiments were performed at the temperature of 90ºC with two torque stages: 135 N.m (running-in) and 302 N.m (steady-state). The time for pitting and spalling on the gears surfaces were measured using image analysis. The results showed a very good potential of using ADI for manufacturing gears, replacing induction hardened steels. Also, the ADI gear with smaller nodules showed higher life for pitting. In contact fatigue tests with severe load, the carburized AISI 8620 steel proved more adequate than the austempered ductile iron, showing that the mechanical properties are critical in the resistance to damage in gear contact. The austempered ductile iron with smaller nodule size showed to be very competitive with wear resistance similar to AISI 4140 steel induction hardened. With ANSYS, it was verified that the nodule size affects the gears life independently of the mechanical properties of the matrix. The results showed that the nodules indicate the presence of a concentration stress, but their size doesn’t affect the contact fatigue life as much as the total amount of nodules, regardless of the ductile iron microstructure. The size and number of nodules affects both the nucleation and the propagation stage of cracks. ADIs with higher amount of nodules have a greater wear resistance. Also, compared to the Hertz contact theory (isotropic material), the presence of graphite nodules indicates a non-isotropic material and made the maximum shear stress point moves toward the surface.

Jul 31, 2018

By Anil Saigal, Mark H. Shooter, Michael A. Zimmerman

Liquid Crystalline Polymers (LCPs) provide favorable dielectric properties for extremely high frequency (30–100 GHz) radio frequency device packaging and printed circuit board substrates. The material studied in this work is a proprietary, thermotropic LCP composite developed and manufactured by iQLP (Woburn, MA, USA). Dielectric constants measured in the flow direction of the post-processed materials differ between the two processes, 3.51 in injection molded plaques, and 4.23 in cast films. This investigation sought to determine the cause of process-induced variation in the dielectric constant between injection molded and cast film extruded LCP. The complex thermomechanical environment present during processing of LCPs creates a through-thickness hierarchical structure, simplified in this study as a skin and core layer. The volume fraction of skin layer of the post-processed LCP was determined to be the differentiating factor, and responsible for the difference in dielectric constant between the injection molding and cast film extrusion processes. The resulting dielectric constant is a function of this volume fraction with a near linear relationship.

Mar 1, 2017

By S. G. Kumar

Experimental studies on high carbon steelmaking through LD Converter - Vacuum Arc Degassing - Bottom Pouring route to produce low oxygen steels were carried out. The results indicated that it is possible to produce steel with a total oxygen content of less than 15 ppm. Thermodynamic and mass balance calculations are made on low-carbon steels that are treated by a complex deoxidation practice based on primary deoxidation of aluminum, manganese and silicon additions; followed by secondary deoxidation of vacuum degassing with simultaneous additions of aluminum. The results showed that primary deoxidation is mainly due to aluminum and the effect of carbon under reduced pressures on deoxidation of molten steel that is already killed by aluminum is negligible. The effect of process parameters on total oxygen content of steel, like carbon content, slag composition and inert gas purging, are discussed.

Jan 1, 1994

By R. H. Eric, A. Chaendera

Gas jet was blown through bottom nozzles of a 1/5th scale CLU model in the presence and absence of slag. Kerosene and water were used to simulate the slag and metal phases respectively. Mixing time increased with increasing bath height and with a decrease in the gas flow rate. It was related to bath weight, bath height and gas flow rate. Slag increased mixing time by about 16% and the mass transfer values by about 32%. Mass transfer rates were higher near the bath surface and in the gas-liquid plume region. They increased with increasing gas flow rate and with a decrease in bath height. A relationship showing the dependence of derived mass transfer coef ficient on the gas injection rate was established. Turbulence characteristics inside the bath liquid were established to vary with location, vessel geometry and gas injection rate.

Mar 1, 2017

By T. Innmi

The potential of the nickel matte anode was measured during the matte electrolysis in the commercial cell. The slime layer consists of elemental sulfur and was found to greatly influence the potential of anode. The measurements of porosity and permeability of the slime suggest that the voltage drop of the slime layer dominates the potential. Furthermore, the diffusion of the electrolyte through the slime layer is also one of the factors to determine the potential. In addition, the copper content of the nickel matte anode was found to affect the change in the anode potential during the electrolysis. The role of copper on the anodic dissolution of nickel matte is discussed in this work.

Jan 1, 1988