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By R. Simkus, J. K. Gowans

Polaris Operations, a Cominco Ltd. lead-zinc mine, is located on Little Cornwallis Island, Northwest Territories, at Latitude 75°23' N and Longitude 96°75' w. When the Polaris Mine went into operation in late 1981, it became the world's most northerly base metal mine.The Polaris Concentrator, housed in a unique process barge, is a basic lead-zinc concentrator where flotation is used to produce the lead and zinc concentrates.The paper describes the ""coarse lead"" flotation feature incorporated in the concentrator flowsheet and describes the start-up problems and continuing operation of this circuit.

Jan 1, 1984

By M Davies, G Theletsane, A H. Gray

Recovery of gold from gold ores has been driven by the available technology and its configuration in the process plant flow sheet.Conventional practice in test work programs has the ore being ground fine (to 106 or 75 microns) to ensure liberation ahead of leaching or flotation. This paper identifies that, in many cases, gold and gold sulfide carriers will liberate and be recovered to a concentrate at much coarser sizes.There is an exponential increase in energy consumption relative to particle size reduction. This impact becomes extreme when comparing crushing a product to 1 mm against grinding to 75?microns.The resultant reduction in energy consumption when liberating and separating at 1 mm or coarser compared to grinding to 75 microns can be in the order of 15 kWh/t or 60 per cent of energy in the comminution circuit.Recovery of free gold and gold sulfide carriers by preconcentration (using continuous gravity devices such as the InLine Pressure Jig), combined with flotation of the fine gold and gold carriers, can result in significant power savings.There are multiple locations within the flow sheet that can be targeted using this process, including recovery in the cyclone underflow of existing plants, preconcentration ahead of the plant or complete greenfield, low-energy process plants designed from first principles based on data from a Gekko developed test work regime.We will describe the process of defining mineralogy in the laboratory and the decision-making process through to actual applications in the field.Several examples will be provided, including a South African Witwatersrand gold ore, several Australian gold ores and others, indicating the benefits of this process and where it has been brought to commercial reality.CITATION:Gray, A H, Davies, M and Theletsane, G, 2014. Coarse liberation and recovery of free gold and gold sulfide carriers for energy reduction in process plants, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 117–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By E. T. Tuzcu

Microscale information about single particle fracture can be incorporated into the macroscale model of the whole size reduction process in the mill. The ultrafast load cell (UFLC) device provides a substantial amount of information about fracture characteristics of a particle under impact loading. UFLC captures high-resolution compressive force signals during particle breakage. The measurement of the compressive force at the instant of fracture of the particle allows computation of a number of comminution-related particle properties, as well as the energy absorbed during fracture. In the current study, limestone particles 50 mm in size were fractured to obtain specific fracture energies. Then, based on the experimental data, two models were proposed to quantify the fracture process. The specific fracture energy distribution of the particles in the range of 6 to 50 mm was defined by the well-known Weibull distribution. The other model is a probabilistic fracture model. This model is a link between energy events occurring in a grinding mill and the breakage rates of particles. The impact energy spectra or energy events occurring in a grinding mill can be obtained with a discrete element method (DEM) simulation. One can model the breakage rates of the mill material by combining the energy spectra with the probabilistic fracture model. This novel approach for the modeling of breakage rates via DEM and UFLC is shown here.

Jan 1, 2011

By E. T. Tuzcu

Microscale information about single particle fracture can be incorporated into the macroscale model of the whole size reduction process in the mill. The ultrafast load cell (UFLC) device provides a substantial amount of information about fracture characteristics of a particle under impact loading. UFLC captures high-resolution compressive force signals during particle breakage. The measurement of the compressive force at the instant of fracture of the particle allows computation of a number of comminution-related particle properties, as well as the energy absorbed during fracture. In the current study, limestone particles 50 mm in size were fractured to obtain specific fracture energies. Then, based on the experimental data, two models were proposed to quantify the fracture process. The specific fracture energy distribution of the particles in the range of 6 to 50 mm was defined by the well-known Weibull distribution. The other model is a probabilistic fracture model. This model is a link between energy events occurring in a grinding mill and the breakage rates of particles. The impact energy spectra or energy events occurring in a grinding mill can be obtained with a discrete element method (DEM) simulation. One can model the breakage rates of the mill material by combining the energy spectra with the probabilistic fracture model. This novel approach for the modeling of breakage rates via DEM and UFLC is shown here.

Nov 1, 2011

By J. B. Sabey, V. R. Degner, D. MacGillivray

"Hydrodynamics principals are applied to the design of a natural air ingestion flotation machine for coarse solids applications. Preliminary laboratory test data and subsequent operating plant flotation kinetic performance evaluations are reviewed. INTRODUCTIONThe concentration of potash (sylvite, KCI) from halite and other salts using flotation is well understood and practice a with much success. Reagent schemes and plant circuitry for obtaining the desired product recovery and grade have been established with proven performance. These flotation circuits normally process the medium and finer size particles, less than 30 mesh (600 microns).However, often the potash market trends specifically demand a coarse product size. This emphasis, accompanied by the existing high losses of coarse (+30 mesh) potash in flotation circuits, creates the need for development of a flotation machines specifically designed for coarse potash beneficiation.This technical challenge was undertaken by the WEMCO Research and Development Group. The specific objectives of this flotation machine development program were ( l) to achieve an ""Ultra Coarse Flotation Machine"" capable of adequately suspending and transporting particles in the 4 - 30 mesh (4.75 - 0.6 mm) size range at solids concentrations of 30% or greater and (2) ascertain metallurgical performance of this machine.This paper covers the development (both theoretical and mechanical/ hydrodynamic), the field test program and results, a discussion of applicable flotation kinetics, and conclusions of this ""Coarse Potash Flotation Machine"" development project."

Jan 1, 1986

By N Maistry, C Carelse, A Singh

Banded Iron Formations or more commonly known as BIF are sedimentary rock formations with alternating silica-rich layers and iron-rich layers that are mainly composed of iron oxides (hematite and magnetite), iron-rich carbonates, and/or iron-rich silicates. Considering the depletion of highgrade iron ore reserves in South Africa, there is a need to maximise resource utilisation through the exploitation of low-grade/uneconomic resources particularly BIF material, which makes up more than 65 per cent of current reserves. Previous test work conducted by alternative BIF sources globally indicates the need for fines processing in order to produce a concentrate. South African BIF however is amenable to coarse and fines processing producing an on-grade product or blended feedstock. C-Type material within South Africa’s Northern Cape Province grading at approximately 33 per cent Fe was supplied for research purposes. Top size optimisation via gravity Heavy Liquid Separation (HLS) tests was conducted. The laboratory results being perfect separation (Ep=0) were modelled to predict pilot performance, the results of which were tested on a pilot scale for the finest size fraction (-1 mm). It was observed that a top size of -2 mm provided optimum results in terms of upgrade and recovery, with crushing finer not necessarily producing superior results. At a target grade of 60 per cent Fe, recoveries of 65.6 per cent were achieved on the laboratory scale, whilst recoveries of approximately 58 per cent were achieved on the pilot scale. Targeting higher upgrades of 63 per cent would inevitably result in lower recoveries of 57.2 per cent on a laboratory scale and approximately 54 per cent on a pilot scale. This is in line with grades and recoveries achieved globally for BIF material albeit at finer grind sizes.

Sep 18, 2023

By D. R. Wardrop, G. Walton

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. A description is given of the approach that has been taken to the design of the 550 000 000 t superquarry with a planned life of 60 years that is proposed for development. The quarry has been designed to replicate a corrie and a sea loch and will include excavated slopes more than 570 m high. The main geological and physical controls on the layout and the choice of development method are outlined. The operation phasing is presented and the geotechnical constraints on slope design and the feasibility of alternative quarry limits are discussed. Environmental considerations have been dominant in planning and the quarry has been specifically designed for closure

Jul 1, 1996

By A. H. Mokken

Failed attempts at amalgamation of a gold/osmiridium concentrate, recovered behind pebble mill liners during re-lining, led to the discovery that the gold particles were coated and that nitric acid only could remove the coatings. Following this treatment amalgamation was rapid and resulted in a complete recovery of the gold that otherwise would have been lost in plant residues. Investigations into the nature and formation of the coatings led to the realization that the coatings were impregnations of harder elements, associated with the gold during grinding and driven into the softer gold surface by high pressure, impact and attrition. It was further realized that this phenomenon could be part of gold ore milling, world-wide. With these thoughts in mind the question is asked whether concentration down to micron sizes prior to cyanidation, should not play a greater role in gold recovery.

Jan 1, 1999

By Edwards A. B

A table concentrate obtained experimentally by the New Occidental Gold Mines N.L. has unusual interest on account of the presence in it of abundant coated or "black" gold. The concentrate was obtained from ore from the New Cobar mine, Cobar, New South Wales, by feeding the oversize product from a "Dorr Bowl classifier to a Card table.Its assay value was 129 oz. of gold and 52 oz. of silver per ton, yet practically no free gold could be seen on panning.When, however, the concentrate was digested in hydrochloric acid fine rusty gold could be obtained by panning.The following chemical analysis was carried out by the mining company on a similar sample of concentrate.

Jan 1, 1941

By I. Hilerio

Chromium Nitride (CrN) thin films were deposited on AISI steel 316 substrates by means of the reactive magnetron sputtering method. CrN films were produced under two different conditions. In the first one, the substrate was heated by a DC source. For the second coating a negative substrate bias voltage was applied. X ray diffraction, quantitative energy dispersion and scanning electron microscope were employed to characterize the two different phases, their chemical composition as well as their microstructure. In addition, a microhardness test was carried out. The results show that a better phase formation of CrN thin films was achieved when a heating source was present (first case). Both coatings presented homogeneous surface. Their compositions show differences even when the gases flowing are the same in composition. Regarding to the hardness test results, there can be found a higher value when using a heating source.

Jan 1, 2009

By M Scott, J J. McEwan

Silver and silver alloys tarnish readily by the formation of tarnish on the surface when exposed to a wide range of sulphur-containing atmospheres. This tarnish is unsightly and undesirable and can be removed either with a silver polish or a chemical dip. Polishes are, however, not suitable for irregular and embossed surfaces such as on coins, medallions and jewellery items, because of uneven removal of the tarnish layer and excessive wear. Successful tarnish protection can be achieved by either storing the items away from the aggressive atmosphere or by coating/treating the exposed surfaces with a protective layer. Storage is feasible for collections but is not suitable for items that are handled or worn regularly, such as jewellery. A number of commercial coatings and treatments have been developed, but to date there has not been a systematic evaluation of tarnish protection. This paper details the performance of a range of generic coatings in an accelerated tarnish test. The degree of tarnish was evaluated by means of loss in reflectivity and change in colour. Four coatings/treatments improved the tarnish resistance of silver by more than tenfold. These include an organic lacquer, rhodium electroplating and an organic self-assembled monolayer (SAM) conversion coating. Research is continuing to optimise these coatings. Keywords: silver alloys, tarnish resistant coatings, silver polishes.

Jan 1, 2006

By John V. Beall

BROMO Seltzer blue has gone to war. The blue of the Bromo Seltzer bottle is a product of cobalt, the Nation's No. 1 strategic metal. When the National Production Authority, on Nov. 21, 1950, ordered a 70 pct cutback in domestic use of cobalt, a stab of pain was felt in the hearts of the glass, porcelain enamel, steel, paint, pottery, and electrical and electronic equipment industries. The reason: A full-scale wartime economy with astronomical requirements for jet engines, high velocity projectiles, armor plate, electronic equipment, and the many products needed to win a war. There is little potential comfort for cobalt users in nonessential manufacturing, and the military will be pinched for optimum supplies of the metal. However, if proper measures are taken immediately and current plans are completed, in two years there will be far more cobalt available than ever before. When normal times return, cobalt supplies should be sufficient to meet peacetime military requirements, and greatly expanded domestic requirements that will result from new technological development for wartime but adaptable to peacetime products. The pres-

Jan 1, 1951

By Bryce Clark

Cobalts history from the 14th Century is outlined, with a look at its various sources over that period. The present sources and quantities are given, when in 1994 it is an equal co-product of copper in Africa and nickel elsewhere (Canada, Australia, Russia). Future trends in this scene are also examined. The final section deals with cobalts uses in superalloys, magnets, colours, electronics, chemicals, and examines trends in its markets. Supply and demand in co-product cobalt are shown, based on the latest production figures.

Jan 1, 1995

By W. Jilowa, C. Nguni, M. Simukoko, C. Nampungwe

The upsurge in cobalt price and demand is propelled by high demand from the electronics and electric vehicle industry. Konkola Copper Mines has cobalt occurring with copper in the ratio 1:10 in ore. The ore is treated in the concentrator and recovered at the smelter as an alloy (Cu 70%, Co 4%–7%, 15% Fe). Subsequent processing of the cobalt alloy is challenging, with very few plants able to treat it, leading to marketing challenges. Konkola Copper Mines sought to improve the cobalt alloy by producing a slag that is easier to handle and process in subsequent processes. Cobalt alloy (3.60% Co, 85.4% Cu) was re-melted in a copper bath four times the mass of the alloy. Silica and lime were added for phase separation and fire refining commenced. Following completion of fire refining and after holding the temperature at 1200°C, cobalt-rich slag was skimmed and blister copper was cast into anodes for electrorefining

Jan 1, 2023

By G. J. van Tonder

The use of Molecular Recognition Technology (MRT), a highly selective separation technology using specifically designed ligands (such as macrocycles), has been demonstrated to be an effective treatment process for removal of several ions that are commonly found in many hydrometallurgical circuits as well as in environ-mental treatment operations. Ions removed by MRT include base, heavy and transition metals, precious metals, halides, and alkali/alkaline earths. A MRT pilot plant run was conducted at Zincor to demonstrate the cobalt/nickel purification of zinc electrolyte, and to recover saleable pure cobalt/nickel sulphate solution. The MRT process holds various advantages, which include the elimination of a catalyst such as arsenic trioxide, conventionally used in cobalt and nickel cementation. SuperLig® 138 can be used to remove cobalt and nickel from120?170 g/l Zn-solutions at pH 1?2. The Zincor MRT application demonstrated its capability of concentrating large volumes o copper barren impure solution at low cobalt and nickel concentration levels in the feed, to small solution volumes at high cobalt and nickel concentrations. Around 99.5% of the cobalt was removed from solution with cobalt impurity levels in feed varying between 10 mg/l and 26 mg/l.

Jan 1, 2002

By Michael L. Sorokin

The behaviour of cobalt during processing of nickel raw material is analysed within the Ni-Co-Fe-S-O-SiO2 system using the computer model. For this purpose the thermodynamic parameters for "three-suffix" Margules's equations in Co-Fe-S and Co-Fe¬Ni-O-S1O2 systems were computed! Phase and iso-activity diagrams for Co-Fe-S system, and phase diagrams for the systems Co-O, Co-Fe-O, Co-Ni-O, C-oO=SiO2 and Co-Fe-O¬SiO2 are calculated using the developed computer programs and identified parameters. The diagrams are used to analyze cobalt behaviour at smelting and converting.

Jan 1, 1995

By Andrea R. Kim, Ramana G. Reddy

Electrodeposition of cobalt from cobalt chloride using the urea and the choline chloride ionic liquid (2:1 molar ratio) was studied to search the optimized parameters for the higher current efficiency. The cyclic voltammetry was tested with 0.2 MCoCl2 using various scan rates to determine the reduction potential in Urea/ChCl at 323 K. Based on the data from cyclic voltammetry test, the transfer coefficient and the diffusion coefficient were calculated as 0.22 and 3.38 × 10−6 cm2/s, respectively. The parameters for electrodeposition of cobalt were various temperatures (323 –383 K), applied potentials (2.4 –3.3 V), and concentration of CoCl2 (0.2–0.5 mol/L). Current efficiency and energy consumption were calculated to investigate the optimal condition for the electrodeposition of cobalt. The highest current efficiency (95%) was obtained under the temperature 323 K, the applied voltage 2.7 V, and concentration 0.5 mol/L of CoCl2. Scanning electron microscope (SEM) and X-ray diffraction (XRD) were used for the characterization of cobalt deposits.

Mar 1, 2017

By Mark A. Koestel

Cobalt-sulfide mineralization can he found in potentially economic quantities where permeable, basal Cambrian formations "pinchout" against Precambrian pal eotopographi c highs. These environments are common around the Saint Francois Mountains of southeastern Missouri and they share many similarities with the geologic environments of Zambia and Zaire in South Africa. Exploration for this type of deposit involves test drilling targets identified by trend analysis from past drilling, geophysics, geochemistry and a comprehensisve study of regional geology and isopach maps. Innovative ideas, new exploration concepts and insoluble residue geochemical methods may provide the necessary "edge" needed to complement basic geologic understanding leading to ore discovery.

Jan 1, 1987

By L Nicholls, A Parbhakar-Fox

Reprocessing Queensland’s historical copper tailings for critical minerals is an opportunity to circularise the state’s mining industry by converting waste liabilities into assets. Mine waste valorisation enables economic rehabilitation of legacy mining sites, improves environmental outcomes, and can establish a secondary resources sector that produces a sustainable supply of critical minerals to supplement growing global demands (Australian Government, 2023). The North-West Queensland Minerals Province (NWQMP) hosts numerous copper mines with known cobalt mineralisation (Degeling, 2020). Cobalt is a critical metal essential for green energy and battery technologies, however its global supply is at risk due to geopolitical and ethical concerns (Rachidi et al, 2021). Historically mining in the NWQMP has focused on copper, leaving cobalt to theoretically accumulate in the mine waste. First-pass geometallurgical characterisation of waste repositories by the Sustainable Minerals Institute identified Capricorn Copper as a key site for further investigation into cobalt deportment and recovery potential.

Aug 2, 2023

By S. A. Shuey

The present industrial practice used to separate aqueous cobalt from nickel is multistage solvent extraction processing. This paper describes a different but simpler treatment technology. The proposed technology has been applied to cobalt/nickel hydroxide intermediate solids produced from the treatment of Electrochemical Machining (ECM) waste sludge, The process consists of dissolving the cobalt/nickel hydroxides in basic cyanide solutions. Cobalt and nickel form aqueous .solution metal cyanide complexes. Nickel can be selectively precipitated from the solution as a nickellic hydroxide solid. Cobalt can be recovered from the leach solution by precipitation of a cobaltous/cobaltic cyanide double salt. The double salt product can then be subsequently treated to produce an appropriate cobalt product. The process chemistry, proposed fiowsheet and preliminary reagent costs are presented and discussed.

Jan 1, 1998