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By R. Trammell, O. Eterigho-Ikelegbe, S. O. Bada

In response to the enormous amounts of coal discard generated during coal mining and preparation, the development of an efficient and sustainable strategic use of this resource is essential. Furthermore, the rising urban population over the next decades is confronted with the depletion of quality raw materials for building components. To this end, this study reports new information on the morphology, water absorption, and flexural strength properties of ceramic composites produced from three different coal discards and polysiloxane pre-ceramic polymer (PCP) resin. In addition, test results relating to the continuous operating temperature, chemical resistance, and efflorescence potential of the composites are presented. The results show that the water absorption and flexural strength of the coal composites, up to 1.94% and 36.46 MPa respectively, exceed the requirements for ceramic and clay roof tiles. The continuous operating temperature of composites is found to be more thermally stable than conventional roofing tiles (concrete and ceramic) between ambient temperature and 600°C. In addition, the excellent chemical resistance of the composites (94.43%−99.98%) compared to conventional roofing tiles (67.82%−99.97%) eliminates the need for additional external coatings. The interesting results documented so far suggest that this technique could be used to produce low-temperature application building products such as bricks, panels, roofing tiles, etc. This new recycling technique offers an excellent opportunity to eliminate enormous volumes of coal discard and to advance the circular economy in the coal industry.

Aug 2, 2022

By J. Hines

Traditionally, fuel oil or diesel was the collector of choice in coal flotation, but in recent years these materials have come under increased scrutiny because of concerns about the toxicity of some components. In response to these concerns, Georgia-Pacific Chemicals LLC has commercialized a patent pending coal collector (Talon® 9400 reagent) that is 100% derived from the pulping of trees. This study presents a comparison of yields and recoveries for different coal collectors, including the one derived from the pulping of trees.

Jan 1, 2011

By T. N. Matveeva, T. A. Ivanova

"The article presents the results of the research aimed at development and testing of new effective reagents – collectors and green modifiers for more complete extraction of gold and platinum to concentrates at reduced loss with waste products. The main deposits of Au and PGM ores of Russia and abroad are presented by refractory raw material with the non-uniform finely-interspersed sulfide mineralization, submicron gold and platinum, the low metal content, non-uniform distribution of valuable minerals. and show low indicators of recovery. The main losses of precious metals (up to 15 %) at flotation are associated with thin slam tailings because of inefficiency of standard reagent modes.In the paper, the new trends in design of collecting agents for extraction of gold and PGM sulfide minerals and their application in flotation tests are substantiated. The original technique for obtaining the modified collector reagents – dithiocarbamate, dithiophoshpinate and dithiazine, incorporated non-ionic compounds that are able to generate stable complexes with gold and platinum has been developed. A novel class of collectors – cloud point polymers showed high flotation recovery of fine particles of gold and platinum. The original technique to create the mineral samples of natural sulfides with ""invisible"" or sub-micron gold on their surface designed helped to indicate the mechanism of selective adsorption of novel agents on Au and Pt-sulfide minerals. Extractive UV spectrophotometry, potential measurements, X-ray phase and spectral analysis, scanning electronic microscopy (SEAM), laser SIM and AFM microscopy were applied to analyze the adsorbed layer of modified reagents on the mineral surface. Selective hydrophobic covering on the surface of micro- and nanoparticles of noble metals provided an increase in their extraction during flotation. New reagent modes of modified collectors and green modifiers were tested in scaled-up laboratory flotation and the results obtained demonstrated the increased quality of the concentrates in terms of gold content by 1.5 times and higher gold recovery by 1.5-5%. The studies have been supported by Grants of the President of RF “Scientific School of Academician Chanturiya” NSh-220.2012.5; NSh-748.2014.5."

Jan 1, 2018

By Lawrence Nordell

A Conjugate Anvil-Hammer Mill (CAHM) has the potential to replace conventional crushers and SAG mills, with their respective conveyors and stockpiles, in a SABC circuit. It may improve comminution circuit efficiency by 100%. CAHM compresses rock in a more efficient way, similar to 19th century stamp mills, which follows the fundamental research of Schönert (1990 & 1996). CAHM efficiency is being proven through the use of ROCKY (2011) Discrete Element Method (DEM). ROCKY features allow it to simulate realistic comminution. CAHM is customizable with many geometries that are rock-property specific. ROCKY?s wear modeling compliments the structural integrity of the design.

Jan 1, 2012

By M. Kerr, Petra Lampinen, Jinming Zhang, Petra Brodin, C. Hull, Nils-Johan Bolin, R. Asmatulu

"According to Darcy’s equation, the rate of dewatering varies as inverse square of the surface area of the particles to be dewatered and is proportional to the pressure drop across a filter cake. Thus, the difficulty in dewatering fine mineral concentrates can be overcome by using high-pressure filters. When treating ultrafine particles, however, it is often necessary to further dewater the filter cake using a thermal dryer. In the present work, novel dewatering aids that can reduce the pressure requirement have been developed. The reagents are designed to reduce surface tension, increase particle hydrophobicity and increase capillary radius, all at the same time. They were tested for dewatering mineral and coal concentrates in both laboratory and pilot-scale tests. The results show that the use of the novel dewatering aids can substantially reduce cake moistures and, at the same time, increase throughput. In this communication, the case history of using the reagents commercially at the Garpenberg concentrator is given. The use of the novel dewatering aids allowed the operators to use a vacuum filter to obtain desired cake moistures and obviate the need to use a thermal dryer.INTRODUCTIONDewatering is an integral part of mineral and coal processing operations, as it is necessary to remove water from concentrates (or clean coal) to minimize shipping costs, meet contract specifications, and recycle the process water. In general, the cost of dewatering increases with decreasing particle size, which can be attributed to the difficulty in removing the water trapped in the pores (or capillaries) formed between the particles constituting a filter cake.The various parameters affecting the process of dewatering, including the effect of particle size, can be understood in view of Darcy’s equation (Darcy, 1856):"

Jan 1, 2005

By Dale Ramsey

Emulsion explosives have become the product of choice for many blasting applications and are not limited to just extreme wet hole conditions or special application environments as in the past. Today’s novel emulsion technology has evolved over many decades, allowing a great diversity of formulations, Emulsion explosives can be effectively designed to produce very high energies, cap sensitive high explosive cartridges to bulk blasting agents, with varying viscosities, stable VOD’s, excellent water resistance, long shelf life and sleep time. They are also conducive to the mixture of emulsion, An/F0 blends in varying proportions and are amenable to any type of sensitizer. The key to a stable, reliable and consistent emulsion formulation is the careful mixing of the internal phase, which consists of a solution of oxidizer salts suspended as microscopically fine droplets, with the surrounding continuous fuel phase. There are few blasting applications today where some form of an emulsion explosive cannot fit the application. In massive, hard rock, dense, tightly jointed and fine grained rock types, the emulsion explosives are the best choices in creating new fracture networks for good fragmentation with a few alternatives. In such environments, emulsions with expanded drill patterns often result in better economics than the use of straight AnLFo. This paper will cover emulsion formulations, sensitizing options, product testing, material handling, and blast optimization, Emulsion explosives characteristics have also proven to reduce adverse environmental effects such as noxious fumes, ground vibration, and airblast while still remaining cost effective.

Jan 1, 2000

Two new inorganic-organic hybrid polymers, Al(OH)3-polyacrylamide (Al(OH)3-PAM) and Mg(OH)2-polyacrylamide (Mg(OH)2-PAM) were synthesized and successfully applied for the treatment of oil sand tailings. The results indicate that both Mg(OH)2-PAM and Al(OH)3-PAM were unaffected by the change in pH, and could be applied to oil sand tailings with varying sand-to-fine ratio (SFR). The optimum dosages for the Mg(OH)2-PAM and Al(OH)3-PAM were about 330 g/ton and 650 g/ton, respectively for SFR 3.75. The flocculated oil sand tailings dewater quickly producing 66-68% solids. The flocculated tailings produced similar filtration rate before and after shear. Mg(OH)2-PAM treated oil sand tailings produced twice the filtration rates (220 ml/min) compared with Al(OH)3-PAM. This study clearly indicates that Mg(OH)2-PAM and Al(OH)3-PAM is a viable solution while decreasing the mass-production of tailings and increasing the rate of water-recycle.

Jan 1, 2012

By P. A. Dimas

A new family of sulfide flotation collectors has been developed in our laboratory. These formulations are comprised of novel renewable materials combined with conventional reagents. The resulting diversity permits tunability of collector chemistry to meet a range of flotation problems. Several attributes of the new collectors are presented.

Jan 1, 2012

By J. Kallioinen

Theoretical considerations, experimental results and plant experience have lead to a new design concept called the unit reactor approach. It has been successfully implemented to the largest flotation cell on the market, the 4000 cu ft OK TankCell. The work has also lead to a new operating idea called size specific flotation. The paper discusses these concepts in the view of full scale field experiments. In large scale porphyry copper flotation experiments conducted in Chile the new large TankCell with its new low energy input Free Flow mechanism out-performed the more conventional designs. The recovery was substantially better, especially in the coarse fractions. In some experiments the difference in total recovery was up to 10%-units and the savings in total energy consumption at the same time over 40%.

Jan 1, 1995

By F. J. Tavera, J. A. Finch

A probe suitable for on-line measurements of gas hold-up in industrial flotation systems has been developed. It is based on an open cell for measurement of slurry-gas conductivity and a novel syphon cell for measurement of slurry-only conductivity. The desired behaviour of the two cells was demonstrated and estimates of gas hold-up were shown to be in good agreement with independent measurements. The gas hold-up probe was used as a diagnostic tool to assess the operation of flotation columns. Differences in gas hold-up between baffled sections in two industrial columns were detected

Jun 18, 1905

By Adil Aledresse, Louis Mercier, Laxman Amaratunga

"The development of high capacity adsorbents with uniform porosity denoted, MP-HMS (Mercaptopropyl – Hexagonal Mesoporous Structure) using nanotechnology, and their ability to extract gold from solution, is presented. The preparation of highly effective heavy metal ion adsorbents by the incorporation of thiol moieties into the pore channels of mesoporous silica molecular sieves has been the subject of many nanotechnology research investigations. The unique feature of these nanoporous adsorbents is their ability to adsorb gold ions from ultra-low concentration solutions like mine effluent as well as from leached solutions in gold mills. The preliminary studies from laboratory simulated gold solutions show that the adsorption capacities of these materials are also among the highest reported. MP-HMS has shown the capability to adsorb 370 mg gold per one gram of the nanomaterials from Tetrachloroaurate solution (up to 37% of their weight). Experimental studies indicated that the maximum adsorption of gold (as high as 99.9% recovery). The current studies will be extended to investigate the interaction of ionic gold complexes with nanomaterials. Future development of this work may lead to either to replace the conventional CIP/CIL processes or use nanomaterials in tandem with the former, suggesting plausible use of mesoporous material in pulp, MIP or in leach, MIL, as a novel gold extraction process.INTRODUCTIONGold typically occurs at very low concentrations in ores less than 10 g/t or 0.001% (mass basis). At these concentrations the use of aqueous chemical (hydrometallurgical) extraction processes is the only economically viable method of extracting the gold from the ore. Typical hydrometallurgical gold recovery involves a leaching step followed by the separation of the gold bearing solution from the residues, or adsorption of the gold onto activated carbon adsorbent. After elution from the activated carbon the gold is further concentrated by precipitation or electrodeposition."

Jan 1, 2008

By Phillip R. Mulligan, Kevin Gantz, Aaron J. Ward, allen shirley, Sean Treadway

Understanding the impulse transferred into a structure by the coupled two-phase loading produced by an explosive charge buried in soil is of interest for various applications. The most common impulse measurement technique involves a buried explosive charge and a steel plate/test structure suspended above the charge. Upon detonation of the charge, the soil and overpressure heave the plate into the air. The plate’s trajectory and velocity provide the necessary information to calculate the total impulse transferred from the charge configuration.

Jan 1, 2016

By G. L. Smith, B. Genc, V. Morar, U. Govender

This paper presents a novel holistic healthy human framework for C-suite executives and senior leaders in the minerals industry. The value-add of the framework centres around the integration of inner holistic health and interpersonal holistic health to support and enhance environment, social, and governance transformation, with a focus on the social enterprise. The framework unpacks key components of holistic health and their interlinkages to environment, social, governance, and stakeholder engagement. Insights were gleaned from interviews with 10 C-suite executives, each with over twenty years of experience in mining or business leadership. By applying the holistic healthy human framework, industry leaders can strengthen the social licence to operate and positively transform the industry's public image. Broader application to other sectors is underway.

Oct 2, 2025

By J. Bas A. F. Smeulders

Traditional laboratory lubrication tests, including those for cold rolling lubricants often involve measurement of neat oils. To achieve increased levels of test severity, such tests are often carried out at high temperatures and prolonged durations. However, we found that the levels of lubricant degradation and wear in these tests can be much higher than in the field. Moreover, steel rolling is not done with neat oils, but with emulsions, where the presence of water influences film formation, surface chemistry and oil composition in the roll bite. To better approach the situation in the field, and thus to be able to develop rolling oils with improved lubrication performance, several lubrication tests were developed for emulsions: direct measurement of film formation and measurement of Stribeck curves, in which the emulsions can be assessed in terms of their boundary lubrication and elastohydrodynamic behaviour. The key innovation is that also another test method was developed, which focuses on boundary lubrication and wear, and the role of extreme pressure and anti-wear additives. Realistic levels of test severity are achieved in the tribometer by mimicking frictional power intensities and flash temperatures for typical cold rolling or tinplate mills. Test conditions can be adapted according to the mill stand or pass number and other cold rolling process parameters. The emulsions are kept at normal operational temperature. Clear differences could be observed between emulsions of various concentration and composition. The viability of the method is illustrated by a number of field cases, in which a good correlation is demonstrated between the laboratory tests and the performance in a pilot or production mill.

Jul 30, 2018

By T. Wang, R. G. Reddy

"The corrosion of stainless steel SS316L in a low melting point novel LiNO3-NaNO3-KNO3- NaNO2 eutectic molten salt mixture was investigated at 695K. After long-term isothermal dipping corrosion experiments, the SS316L samples were analyzed using scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS) to determine the topography and corrosion products. Dense and protective lithium iron oxide scale formed on the surface and prevented the SS316L sample from further severe corrosion. Therefore, SS316L is considered to be suitable construction material for solar thermal energy storage materials containers.IntroductionMolten salt mixtures have been considered as potential candidates for thermal energy storage and heat transfer media in solar energy applications. To apply the molten salt in the energy transfer process, the standard pipes made of stainless steel must be utilized to carry the molten salt mixtures in parabolic trough system of solar power production. The pipes encounter continuous flow of hot and cold molten salt every day. Thus corrosion of stainless steel in molten salt mixtures becomes extremely essential for the long-term utilization of the thermal energy storage media. The corrosion of passivity materials inside high temperature molten salt systems have been studied which gives fundamental understanding of basic mechanism about the corrosion process [1-8].The corrosion behavior of Fe-Ni-Cr alloys in an equi-molar LiNO3–NaNO3–KNO3 mixture was studied [9]. According to the XRD analyses, the major phases in the oxide scales were identified as LiFeO2, Fe3O4 and Cr2O3. A HITEC® salt mixture (NaNO3–NaNO2–KNO3) was also tested as a corrosion medium for stainless steel [10] and the corrosion rate was found to be affected by the protective oxide layer. In most cases, the alloys having more than 10wt% chromium show high resistance to corrosion in molten salts."

Jan 1, 2014

By J. W. Shield

Refractory sulfide flotation or gravity gold concentrates are coated onto a sized support matrix and placed in a heap configuration for biooxidation. The surface coating is typically less than 0.05 in. thick and the support matrix is preferably composed of 0.375 to 0.75 in. diameter material. The exposed thin coating of sulfides reduces biooxidation rate limitations due to oxygen mass transfer. The large spaces between matrix particles reduce resistance to fluid percolation and aeration in the heap. The capital and operating costs for this biooxidation configuration are significantly less than for concentrate biooxidation in stirred tanks. After 30 to 90 days of biooxidation, sub- sequent gold recoveries exceed those seen in whole ore heap biooxidation and are comparable to recoveries obtained from stirred tank biooxidation processes. Results from laboratory and pilot testing indicate that this technology is a viable alternative for pretreating sulfide refractory gold ores.

Jan 1, 1997

By Constantin D. Pitis

Similarly to notions of constant capital/expenses in business or magnetization power for electric motors an energetic base load (E0) is always necessary to set up a mining process. Denominated as ?non-productive energy? or base load, (E0) is a constant component of the entire energy consumption of the process, while another component the ?productive energy? (Ep) is variable, being function of the production/throughput (M). By using these new concepts, the author creates an energetic model proposing a new method of assessing changes in mining processes (throughput) that can reveal possible energy savings (DSM component) or energy losses. Proposed mathematical model of assessing (E0) and energy savings by using ?Marginal Energy Usage Index? (MEUI) enables creation of historical benchmarks and direct on line energetic (efficiency) assessment of mining processes and/or equipments. The paper analyses the case of assessing possible energy savings that can be obtained by: ?? Improving efficiencies of various equipments (by retrofit) ? reducing E0 ?? Improving the process control or other process changes ? reducing Ep ?? Monitoring persistence of the adopted Energy Conservation Measures (ECMs). For the new plant design, the proposed method enables prediction of Customer Baseline in various mine/process configurations. The method could become part of a ?preventive action? in design process by offering a reliable tool of assessing additional financial effort (Incremental cost) when choosing various higher efficiency equipments and/or processes.

Oct 1, 2009

By Piet Halliday, Ellina Kharatyan

Conventionally, emulsion matrices (unsensitized) need to be sensitized to become detonable explosives. This is done either chemically or mechanically. Both methods have their advantages and disadvantages. Mechanical sensitization involves the addition of microballoons (plastic or glass) to the emulsion matrix, in order to create hot spots during detonation. This is usually done at the manufacturing site and poses a safety risk in terms of the storage, transportation and handling of a 1.1 type explosive. Many countries throughout the world make use of chemical sensitization as opposed to mechanical sensitization as this allows for the storage, handling and transportation of two 5.1 type products rather than the 1.1 type explosive. Chemical sensitization involves the addition of a small amount of a chemical that reacts with a component of the emulsion matrix causing the formation of gas bubbles that act as hot spots during detonation. The disadvantage of this is the lack of accurate density control (due to various factors affecting the reaction) and the lack of comprehensive understanding of the operators of the reaction. This can easily result in poor blast performance. Due to these disadvantages a pumpable, non-detonable (5.1 type) mechanical sensitizer was researched and developed. This product allows for pumping at a 50:50 volume ratio with the emulsion matrix, when loading into blast holes. The significance of this is that a 1.1 type explosive is formed in the blast hole. As such, the security and logistical issues of the transportation and storage of the 1.1 type explosive are eliminated. Another advantage is accurate density control of the final product, specifically in small diameter long hole applications. A cost effective, unique mini pumping system has been developed for the loading of this product. Moreover, this system can easily be used for secondary blasting applications and the on-site packaging of cartridged explosive products.

Jan 1, 2015

Thermo Fisher Scientific is the worldÆs leading supplier of analysers for laboratories and process industries. The companyÆs X-ray fluorescence (XRF)-based slurry immersion probes were originally developed by the acquired Amdel Instrumentation. These analysers have found limited application within wet beneficiation plants for measurement of iron. The recent trend of renewed efforts to maximise recovery from existing resources and lower costs has increased industry interest in online analysis. In the mid-1990s the company developed online analysers (the light element slurry analyser û LESA) for slurry applications using the prompt gamma neutron activation analysis (PGNAA) method. The company has successfully installed LESA for the direct measurement of lighter impurity elements in Brazilian plants using flotation for rejection of silica. A case study is presented. The PGNAA technique has the unique ability to provide elemental analysis of bulk materials on a conveyor belt. The company released its eighth generation cross belt Omni analyser using PGNAA in 2007. Results from a recent project with sinter are presented. The Niton range of hand-held XRF analysers is also supplied by Thermo Fisher Scientific. These handy devices are finding widespread use in the mining industry to provide quick and easy analyses in exploration settings. In contrast to PGNAA this is a surface technique. A prototype for light element analysis is being tested for iron ore.

Jan 1, 2007

By C. Keefe, O&apos

Measurements of the quantity of entrained air within processes have challenged instrumentation developers for years. This is particularly true in the unique and demanding operating environment and applications seen in minerals processing. In minerals processing applications, entrained air plays a role in errors seen within nuclear density gauge measurements and in pumping efficiency. It is also the major component of flotation processes. The measurement of the quantity of entrained air, known as the gas void fraction, can now be performed from the outside of a process pipe through CiDRA?s patented passive sonar array-based technology. Within column cells, the need for a robust, no maintenance, accurate means of measuring the entrained air, known as gas holdup, has resulted in a submersible version of this technology. CiDRA?s meter technology calculates the gas void fraction by first measuring the speed at which naturally occurring sound in the process slurry propagates past an axial array of sensors. These sensors are incorporated in a band that is wrapped around the outside of the pipe, resulting in no process downtimes for installation and unprecedented reliability. A known relationship between this speed of sound and the entrained air captured in the form of bubbles within the slurry is then applied in CiDRA?s meter to calculate the gas void fraction. This paper will present the measurement technology, its operation, its calibration and its application in a variety of gas void fraction and gas holdup measurement situations such as pumping efficiencies, hydrocyclone operation, external sparging, and column cells.

Jan 1, 2008