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By Amanda de Angelis Vitoi

A nitretação do aço inoxidável endurecível por precipitação do tipo 17-4PH foi estudada comparativamente pelos processos de Plasma-DC e de Tela Ativa. Os resultados mostram que os dois processos são eficientes em promover a formação da camada nitretada de elevada dureza superficial, cerca de 1300 HV0,025. Entretanto, diferenças importantes são observadas. No processo de Plasma-DC a camada nitretada é composta, além da martensita acicular saturada em nitrogênio, de nitretos de ferro e cromo precipitados pela supersaturação. No processo de Tela Ativa a precipitação de nitretos de cromo é praticamente suprimida e predominando os nitretos de ferro. Esta diferença na sequência de precipitação de nitretos é inferida como sendo causada pela oferta de nitrogênio. Em Plasma-DC a oferta de nitrogênio é suficiente para a precipitação do nitreto de cromo, o que não ocorre em Tela Ativa. A maior profundidade de camada e de endurecimento transversal confirma a maior difusão de nitrogênio em Plasma-DC. Ainda, em ambos os processos a dureza de partida do substrato envelhecido é preservada após o ciclo de nitretação.

Aug 16, 2017

By Fathi Habashi

Nitric Acid has been used for over 50 years in the uranium industry and in phosphate fertilizer manufacture. Its application in the treatment of sulfide concentrates is relatively recent. A review of recent developments is given.

Jan 1, 1999

By P. Altinkaya, O. Celep, H. Deveci, E. Y. Yazici

"Copper-bearing gold ores have proved difficult to treat in conventional cyanide leaching process owing to prohibitively high consumption of cyanide by readily soluble copper minerals interfering with gold extraction. Cyanide leaching of gold from copper-rich ores can be improved by intensive cyanidation or application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting and leaching). In this study, nitric acid leaching of a copper-bearing pyritic concentrate (0.3% Cu, 62 g/t Au and 110 g/t Ag) as pre-treatment prior to cyanidation was investigated. The mineralogical analysis of the concentrate has revealed that it is composed of mainly quartz (25%), pyrite (32.7%), sphalerite (5.37 %), galena (2.12 wt %) and anglesite (1.13 %). Arsenopyrite, chalcopyrite, covellite and bournonite were also detected as minor phases present. Previous studies carried out by the authors showed that direct cyanidation (1.5 g/L NaCN) of the as-received concentrate (d80: 80 µm) produced low gold (45% Au) and silver (46% Ag) extractions. Nitric acid pretreatment of the as-received concentrate was performed for 5 hours at 1-5 M HNO3 and 80oC. In these tests, 65% Cu/Pb and 94% Zn were leached. The nitric acid pre-treatment improved the extraction of gold and silver in subsequent cyanide leaching (1.5 g/L NaCN) to 82% Au and 87.5% Ag with a concomitant decrease (up to 54%) in cyanide consumption. It can be inferred from these findings that the removal of copper from the concentrate and the liberation of the occluded gold by nitric acid leaching as pretreatments can be appropriately employed for the treatment of the copper-bearing pyritic concentrate with high gold/silver content. INTRODUCTION Refractory ores are often characterized by their low amenability to cyanide leaching resulting low (often <80%) Au/Ag extractions (Bhappu, 1990; Celep et al., 2009; Marsden and House, 2006). One of the most common causes of refractoriness is the physical or chemical encapsulation of submicroscopic or fine-grained gold in sulphide minerals such as arsenopyrite and pyrite (La Brooy et al., 1994; Vaughan, 2004). To render refractory gold ores/concentrates amenable to cyanide leaching, the decomposition of sulphide minerals within a pre-treatment process to expose the encapsulated gold grains to the action of cyanide is required. In this regard, roasting, pressure oxidation and biooxidation are commercially used processes for pretreatment of arsenopyrite/pyrite gold ores/concentrates ahead of cyanide leaching (La Brooy et al., 1994). Presence of cyanide-soluble copper minerals in the ore leads to low gold recoveries and high cyanide consumptions under conventional cyanide leaching conditions. High cyanide concentrations (CN:Cu>4) should be employed to achieve high gold recoveries from copper-rich gold ores/concentrates. This may require recovery of cyanide from effluents. In this regard, SART Process (sulphidisation-acidification-recycling-thickening) employed industrially for recovery of cyanide and copper as a by-product. This process simply relies on the addition of sulphide (as Na2S, NaSH or H2S) to the leach solution prior to the acidification to pH 4-5. This results in the precipitation of copper as Cu2S and occurrence of free cyanide which is recycled to the leaching circuit after S/L separation (Dai et al., 2012)."

Jan 1, 2018

By Dairo E. Chaverra, Carlos Argumedo‑Jimenez, Oscar J. Restrepo‑Baena

This paper presents the results obtained by processing a gold and silver telluride mineral concentrate from a mine in Colombia. An acid wash, also known as acidification, was carried out, followed by oxidation with nitric acid as a pretreatment. Cyanidations of the pretreatment residues were carried out and the results were compared with results from cyanidations of base materials. The removal of carbonates in the acidification, a tellurium extraction close to 90% during the pretreatment, and a 30% improvement in the gold recovery compared to the conventional process were achieved.

Nov 8, 2023

By D. S. Davies

Further development of the Nitric-Sulfuric Leach (NSL) process has led to an improved design of the leach and nitric acid recovery steps. NO produced in the leach step is reacted with oxygen, regenerating N02, which is sparged directly into the leach reactor. Leaching is simplified to two steps and the nitric acid plant is replaced with an oxidation recycle gas sys-tem. Laboratory work substantiated the concept and led to selection of operating conditions. The lab work also pointed to improved process control compared to use of nitric acid as the sole oxidant. Recovery of copper from purified pregnant liquor is modified to use air agitation electrowinning improving cathode quality and lowering tankhouse costs. Economic evaluation shows reduction of capital requirements from $2400/AT to $2000/AT in 1978 dollars for 50,000 TPY of copper production.

Jan 1, 1978

By D. S. van Vuuren

Titanium bearing resources can selectively be chlorinated at temperatures below 200°C if the Ti02 in the feed is nitrided before chlorination. However, the nitriding reaction is highly endothermic, requires highly reducing conditions, is only thermodynamically favourable at elevated temperatures, and is affected by mass and heat transfer restrictions. At the required processing conditions, problems might also be experienced with sintering and with melting of slag forming components in the raw materials. A test programme was undertaken to study the effects of raw material type, temperature, gas composition, bed depth, carbon to raw material ratio and residence time in order to simulate conditions required for scaling up a nitriding process. In contrast to previous experience with low-grade titanium-bearing slag containing about 30% Ti02, ilmenite and chlorinateable slag do not form melting phases under the studied nitriding conditions and hardly sintered at all. Both feed materials can readily be nitrided with conversions in excess of 90% at temperatures around 1300°C and using bituminous coal as reducing agent with fixed carbon in excess of 1.1 times the stoichiometric requirement. The conversion decreases as the bed depth of the feed material increases and the N2/CO ratio in the gas decreases. Analysis of the relative rates of mass and heat transfer into the reacting beds of ilmenite and slag showed that the heat transfer rates are more limiting than the mass transfer rates. In order to increase the throughput that can be achieved in a kiln, it would be necessary to take special measures to enhance the heat transfer rates into the mass of reacting material. One such a measure is to pre-form the mass of reacting material into thin-walled, hollow brick shapes prior to introducing it into a kiln. Depending on bed depth, temperature and N2/CO ratio, required residence times in the high temperature zone of the kiln can vary between about 6 and 10 hours. Keywords Titanium dioxide, titanium nitride, carbo-thermic, reduction, ilmenite, slag, tunnel kiln, residence time.

Jan 1, 2011

By B. Stettner, J. Asante, S. Abraham

The levels of nitrogen in steel produced in various metallurgical vessels vary significantly. For example, the tap nitrogen levels in steel produced in the BOF are around 4Oppm, as compared to 70-100ppm in both DC and AC electric arc furnaces. Given the pressing need to reduce nitrogen levels in steel to satisfy customer demand, IPSCO Inc. has gained considerable experience in controlling nitrogen levels in steel over the course of the last three years. Hence, a cost effective process has been developed through an intensive nitrogen control program from steel melting in the EAF through to the continuous slab casting stage. This paper describes the practices employed at each stage of the steelmaking process that have enabled IPSCO Inc. to reduce and control nitrogen levels in steel.

Jan 1, 2004

By Jacques F. Abrahamse, Kevin A. Bahe, T. Arthur Palm, Gregory E. McCluskey, Stephen L. Bessinger

Introduction Basis For System San Juan Coal Company (SJCC) is a subsidiary of BHP Billiton. Until recently, BHP Billiton operated three surface mines in northwestern New Mexico: Navajo, San Juan, and La Plata. The San Juan and La Plata Mines supplied the San Juan Generating Station operated by Public Service of New Mexico. Stripping ratios at those operations were increasing, and by 2000 a feasibility study was underway to develop SJCC’s vast underground reserves as a replacement. Early in the evaluation and planning phase for the San Juan Underground Mine, it was determined that the target seams (Fruitland #8 and #9) had a high propensity for spontaneous combustion. Spontaneous combustion was identified as a risk, both to personnel and equipment, and to the ability of SJCC to reliably fulfill its obligation to the power plant. In the last 20 years, several western US coal mines suffered underground spontaneous combustion events and/or mine fires. Included in this group were Colorado Westmoreland’s Orchard Valley Mine (1987), RAG’s Willow Creek Mine (1998 and 2000), Oxbow’s Sanborn Creek Mine (1999), the West Elk Mine of Arch Coal (2000), Arch’s Skyline Mine (2002), Western Fuels’ Deserado Mine (1996), and the West Ridge Mine of Andalex Resources (2003). The cause for the majority of these fires was spontaneous combustion. Fighting the fires required injection of an inert gas or foam. Nitrogen and carbon dioxide were the predominant choices of inert gas. In all cases, the gasses had to be trucked in from considerable distances. Before the inert gas could be used, injection holes had to be drilled into or near the suspected fire locations. This drilling and trucking caused costly delays in the timing of the fire fighting effort, and was not as precise as desirable. Emergency purchasing of gas and pumping services was extremely expensive, running as high as $70,000 per day at one mine. As a result of the experience of other western US coal operators, and the risk inherent with spontaneous combustion at SJCC, it was decided to pursue installation of a nitrogen delivery facility on-site at SJCC. This decision was later expanded to include a continuous supply of nitrogen.

Jan 1, 2005

By H. G. Oltmann

The equilibrium nitrogen solubility in the CaO-SiO2system was studied by a slag-gas equilibration technique, in graphite crucibles at 1823K under a CO-N2 atmosphere. The nitrogen content of the slags was determined by the Kjeldahl method. A reliable technique was used to obtain an initial nitrogen content in the master slags, from the addition and pre-melting of silicon nitride. Reduction of silica by graphite was found to occur during the equilibration experiments, resulting in compositional changes of the slags. The results were extrapolated to equilibrium by kinetic evaluation of the data. The nitrogen solubility showed good agreement with the result of Suito and Sano, while Fruehan?s results were lower. However, the results of the present study do not support the maximum nitrogen solubility values found by Sano.

Jan 1, 1999

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019

The National Mining Association’s (NMA)MINExpo International ’96 is shaping up to be the organization’s largest. About 30,000 mining industry business and technical professionals are expected to descend on Las Vegas, NV Sept. 9-12 to take part in the 25 technical sessions and visit the more than 900 exhibitors who will be showing off their products and services. MINExpo will be the largest mining equipment and services exposition in the United States this year. Exhibits at MINExpo will fill the Las Vegas Convention Center, parking lots and part of the Hilton Center, located next door to the convention center. NMA estimates that this year’s show will cover more than 46,450m2 (500,000 sq ft) of exhibit space. Some of the exhibits on display will include haultrucks, hydraulic shovels and excavators, conveyors, continuous miners and tunneling machines. In addition, an array of computer equipment and software will be demonstrated. A new feature this year will be a helicopter pavilion, located in the Hilton Center. Helicopters and fixed-wing aircraft have become indispensable to many remote mining operations. NMA said that at least one full-size helicopter will be on display.

Jan 1, 1996

By D Kilkenny

This paper discusses the use of a mechanised shaft sinking machine Herrenknecht Vertical Shaft Sinking Machine (VSM) – to conduct the 93 m presink for the Wira Hoisting Shaft at the Prominent Hill Mine in South Australia. This technology has been widely used in the global construction industry, however, this was the first time it had been used in Australia and the second time in a mining application. The non-entry shaft sinking system eliminates risks associated with a traditional manual method and allows all shaft construction operation to take place from surface. The geology in the upper 100 m at the Prominent Hill mine is conducive to mechanical excavation, with expected rock strengths below 130 MPa. This enabled an alternative shaft construction methodology to be considered. The Herrenknecht VSM system was selected due to its extensive work history and demonstrated performance in similar ground conditions. In collaboration with the operations and design team, the shaft collar and surface configuration were modified to suit the requirements of the VSM, additional equipment, and loading jacks that support the pre-cast lining. Dedicated concrete moulds were designed in Germany and built in Italy. The concrete segments were cast in Adelaide and road freighted to site. This paper outlines each stage of the presink – refurbishment, transportation, logistics, establishment, operation and demobilisation. Selecting this shaft presink excavation methodology, delivered through positive collaboration and communication despite some challenges, shows the benefit to the mining industry of applying new technology and innovation to improve safety and productivity.

Mar 29, 2023

By S Christensen

In August 2001 the Minister for Conservation declined an application by GRD Macraes for an access arrangement to enable work at the Globe Progress Mine near Reefton. In her decision, Ms Lee said:æI have considered whether potential compensation and the proposed safeguards against some of the adverse effects are sufficient to outweigh my concerns as to the loss of conservation values, consistency with the objectives of the Conservation Act, the purposes for which the land is held by the Crown and, to a lesser extent, the North Westland Regional Management Plan. I do not think they are sufficient. To my mind, my concerns as to the consistency with the objectives of the Conservation Act, the purposes for which the land is held and the loss of some conservation values in particular, outweigh any potential compensation and possible mitigation of adverse effects.Æ Commenting on the MinisterÆs decision Guy Salmon of the Ecological Foundation stated that the Minister should have invited the applicant to provide a 10 000 hectare pest-free wildlife sanctuary as part of the æpriceÆ for obtaining that access. However,æfor many people of green persuasion, it has become fashionable to say no every timeàthose who really have the well-being of the environment at heart, will want to look carefully at the bigger picture of environmental restoration needsàThe deciding criterion: the mining company should show that its involvement on conservation land would produce a net conservation gain. That is a criterion that creates the right incentives for win-win-win solutions on conservation land.ÆThis paper considers whether the concept of off site mitigation is one which fits within the current legal regime. Two questions arise:Can such mitigation/compensation be legally considered in access arrangements or required as a condition of resource consents? Is this a realistic option for industry to be pursuing?

Jan 1, 2002

By Edmonds W, Jeffcoat R

The completion of the first two open hearth furnaces in the new No. 2 open hearth plant at Port Kembla will increase Australian production of steel by 350,000 tons of ingots per annum.The paper gives an outline of the essential features of open hearth design and auxiliary equipment required to operate the two modern open hearth furnaces at present being installed.INTRODUCTIONThe increasing demand for steel required by Australian secondary industries led to the decision to construct and operate No. 2 open hearth plant at Port Kembla. Two basic open hearth furnaces of the most modern design are under construction and it is anticipated that these units will be commissi.oned in September 1956. Australian steel capacity will thereby be increased by approximately 350,000 tons of ingots per annum.PLANT LAY-OUT AND CONSTRUCTIONIn the design and lay-out of this plant the emphasis has been on efficient material handling with simplicity of design and operation. Overseas methods were studied and these studies, together with experience gained at Newcastle and Port Kembla open hearth shops, enabled this plant to be built to a standard which compares favourably with any other in the industry.Initially two furnaces, each of 2,75 tons capacity, have been built, but provision has been made in. the design and lay-out to enable expansion to six furnaces.The location of the new plant in relation to the existing units will be noted in Fig. 5. It is one of the first units to be built in an area which will dovetail into a pattern for...

Jan 1, 1957

With the sinking of the No. 3 Shaft at North Broken Hill Limited, it was necessary to construct adjacent to the shaft a new changehouse for mining and surface personnel.It was also probable that as the older sections of the North and British leases were worked out, all employees at present working in these sections would be transferred to the No. 3 Shaft area. This could ultimately result in all personnel employed by North Broken Hill Limited being concentrated in this area, requiring the construction of new administration offices, workshops, mine store, etc., also in this area.

Jan 1, 1957

To finalise the arrangement and details of the headframe to be erected over the new No. 3 Shaft, the haulage and winding equipment requirements were first determined, then tentative designs were prepared to cover the needs of general shaft servicing work for men and materials, mullock and ore handling, and the probable requirements of a breaker station to be built adjacent to the headframe, which would provide for the crushing of the run-of-mine ore down to a size which would be suitable for feeding on to the concentrating mill.

Jan 1, 1957

With the sinking of the No. 3 Shaft and the erection of a changehouse nearby, a sub-brace level structure was provided incorporating a time office, underground foremenÆs office and lamp room, in conjunction with a covered walkway, ambulance room, fire station and waiting brace.

Jan 1, 1957

The sinking of the new No. 3 Shaft being mainly concerned with providing for the continuation of mining operations north of the existing workings, requirements for the shaft and haulage equipment were assessed, having in mind the anticipated needs of the Company in future years, the .available knowledge and probable future trends of the orebody, and also that the shaft would be required to act as a downcast airway for the ventilation system associated with the northern underground workings.

Jan 1, 1957

By H. Ikeda

The new Onahama N0.3 tankhouse was put into operation early in 1973. This new tankhouse, which has a capacity of 90,000 metric ton cathode per year, is distinct in many important respects from conventional tankhouses. The major objectives in design were to simplify the construction and ope- ration for reduction of the costs for labor, interest and depreciation and also to reduce the copper inventory in the tankhouse by the use of conti- nuously-cast anodes. As a result, the investment cost was decreased by approximately 30% and the inventory cost by approximately 600, while the production per unit area of the tankhouse was increased by 80 - 100% as compared with the existing conventional-type tankhouses at Onahama. By abolition of cell inspection and maximum mechanization of materials handling the labor cost was decreased by as much as 80%. On the other hand, the new system has some disadvantages, such as increase in anode scrap ratio and increased cost of anode casting. The No.3 tankhouse system is, however, still at its starting point, while conventional methods have been continuously improved over the past years of operation. It is expected that the innovational ideas behind this system will serve as bases for a more efficient electrolytic refining system in future.

Jan 1, 1976

With the sinking of the new No. 3 Shaft and the increasing depth and northward movement of the mining operations, improved ventilation of the mine workings became necessary and it was decided to sink a new upcast ventilation shaft midway between No. 2 Shaft and No. 3 Shaft.The shaft is finished to 16 ft. internal diameter and connects with the mine workings at the 2,600-ft. level. It is lined with unreinforced Concrete approximately 12 in. thick. The shaft sinking routine was drilling, blasting and mucking by hand using a 27-cub. ft. capacity bucket. The concrete lining was poured in conjunction with the sinking and was normally finished within 30 to 50 ft. of the shaft bottom.

Jan 1, 1957