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By Wayne Bell, Matthew Andriese, Shuqian Xie, Jiann-Yang Hwang, Zhiwei Peng

"Pyrolyzed carbons are generally known as good microwave absorbers and their dielectric properties still remain to be fully explored. In the present study the dielectric properties and dielectric polarization-relaxation phenomenon of a typical activated carbon was investigated. The experimental results indicate the complex permittivity is highly dependent on temperature and frequency. The decrease of permittivity with increasing temperature from room temperature to ~100 °C is probably ascribed to the release of the water vapor adsorbed on the surface of activated carbon, and the variations of permittivity with temperatures between 100 °C and 450 °C in the frequency range of 300 MHz to 3000 MHz are mainly attributed to the decreased relaxation time of dielectric polarization.IntroductionPyrolyzed carbons have been identified as excellent microwave absorbers owing to their high dielectric and electrical loss under microwave irradiations. Among them, activated carbon continues to attract more and more attention from researchers. Due to its special physical properties, the production, modification and regeneration of activated carbon with the assistance of microwave have been widely studied over the last few decades [1-6]. However, only few attempts have been applied to explore the dielectric properties of such materials due to the complexity and variability of their organic precursors and activation processes [7,8]. In order to shed a light on this problem, a typical sample, Norit® A Supra USP powdered activated carbon, was adopted to perform dielectric characterization, which may provide useful information for its wide application in the fields of purification, energy (hydrogen) storage and so on."

Jan 1, 2011

The dielectric properties of practically all oxide and sulphide ore minerals are such that they heat rapidly when irradiated with microwaves particularly at the standard frequency of 2450 MHz. The presence of carbon or low rank coal mixed with the minerals still further enhances the heating rate. Amongst the patented technologies being investigated are: (i) the direct reduction of oxides with or without carbon included in the pellets or briquettes; (ii) microwave precursor heating of composites ahead of smelt reduction; (iii) microwave smelting of ore or concentrate mixtures with carbon, sometimes assisted with oxygen. Microwaves appear to stimulate endothermic reduction reactions as readily as they do exothermic oxidation reactions. Being a method of achieving "bulk" heating, composites or columns of ore-char blends rapidly heat throughout rather than from the outside inwards as in conventional heating. The microwaves of themselves do not generate any gas - the only gases to be cleaned are the products of reaction in the composites or blends, plus the products of oxygen smelting. In the case of sulphide composites, depending on the quantity and type of low rank coal or char present, sulphur may be eliminated, and collected, in the elemental form. Furthermore, reactions seem to take place at lower temperatures than in conventional smelting but no doubt at the "points" where actual reactions are taking place the atomic or molecular vibrations are such as to satisfy the laws of thermodynamics. Examples are given of the production of unusual products of smelting sulphide concentrates and also the alloys produced from refractory minerals such as chromite and ilmenite. The techniques have been used to produce products with as wide a range of melting points as relatively pure tin and tungsten-molybdenum alloys. Special equipment is being designed and evaluated for these new fields of pyrometallurgy.

Jan 1, 1989

By T. Lu

Microwaves have considerable potential as an energy source in both mineral processing and metals extraction. In this research, the utilization of microwave radiation for the heating of a gibbsite type bauxite ore was investigated. Firstly, thermogravimetric studies were performed in order to characterize the dewatering processes of the ore. Secondly, both the real and the imaginary permittivities, which are the fundamental properties that determine the interaction of microwaves with any given material, were measured for the bauxite ore as a function of temperature. The changes in the permittivities were shown to be related to the dewatering processes. Subsequently, the effects of operating variables such as processing time, sample mass, particle size, microwave power, sample bulk density and carbon and magnetite additions on the sample temperature in a microwave field were studied. The results showed that under suitable conditions the bauxite ore could be readily heated. Therefore, there is considerable potential for the application of microwaves for the heating of bauxite ores.

Jan 1, 2007

By X Tian, J Forster, A Olmsted, E R. Bobicki, M Goldbaum, D Boucher, C A. Pickles

As the global demand for metal values expands, it becomes increasingly important to create more sustainable mining operations. Consequently, considerable research and technology development is required to produce processes which are both more energy efficient and have a minimal environmental impact. One potential technology is the utilisation of microwave pre-treatment to reduce the energy requirements in comminution. Microwaves can preferentially heat the valuable mineral phases in an ore and the resulting differential thermal expansion leads to the formation of microfractures along the grain boundaries. As a result of the preferential heating, ore competency is reduced, mineral liberation is enhanced, a coarser grind size can be employed, and plant throughput can be increased. Furthermore, microwave pre-treatment can be combined with advanced ore sorting, to decrease the quantity of gangue material processed downstream and hence reduce tailings production. Previous studies on the microwave treatment of ores over the last 30 years have mainly been limited to low power bench-scale studies and there is a paucity of information on pilot and/or commercial scale studies. In the present research, the microwave heating behaviours of over 40 ores have been studied at the bench-scale. These results were used to generate a database, from which a unique classification system was developed. This system was used to rank the amenability of any given ore for microwave pre-treatment. This knowledge can be employed to predict the performance of the ores in the high-power pilot scale tests and thus can be used as a pre-screening tool. The effects of high-power microwave pre-treatment on grindability and liberation were reported. Additionally, the ore sorting potential was evaluated using a combination of X-ray transmission (XRT) and microwave infrared (MW/IR).

Aug 24, 2022

By J. Y. Hwang

Microwave heating is an attractive alternative to conventional heating methods because heat is generated directly within the microwave absorbing materials. It has potential to be utilized for selective heating and removal of specified components from a materials mixture. This investigation was undertaken to explore the potential of selective heating and burning of binders for foundry sand reclamation. Selected raw materials and binders used in foundry operations were tested to determine their receptivity to microwave heating. Time needed to reach 600°C and/or the maximum temperature achieved for samples irradiated by microwaves for twenty minutes under 800 W microwave power are reported. The microwave heating characteristics of the selected materials are summarized and discussed. The interactions between microwaves and the raw materials used in a foundry. such as silica sand. chromite sand and bentonite (clay) binder were studied. The results showed that chromite sand coupled well with microwave energy at ambient temperature while silica sand did not. This was expected because the major component of chromite sand. iron chromite (FeCr2O4). is a good microwave absorber. while quartz, which is the major component of silica sand, is a microwave transparent material at ambient temperature. Bentonite absorbs microwaves well because it contains a hydroxyl functional group and water molecules in its structure. It was found that the structure of bentonite was changed through microwave irradiation. Microwave heating characteristics of silica sand mixed with different amounts of bentonite binders were investigated. The presence of bentonite in the mixture improved the microwave heating of silica sand significantly. and bentonite was deactivated by the microwave processing.

Jan 1, 1995

By G. Van Weert

ABSTRACT When exposed to microwaves, rocks containing sulphides adsorb energy preferentially over barren gangue and quickly become warmer with minimal energy consumption. This effect makes subsequent machine sorting of ore from waste rocks or overburden possible using infrared sensing. This paper reports on the 2450 MHz microwave response of a variety of sulphide minerals by mesh size and spatial distribution, as they might occur in ore rocks. The implications for infrared ore sorting are discussed.

Aug 1, 2011

By G. Van Weert, O. Wang

ABSTRACT: When exposed to microwaves, rocks containing sulphides adsorb energy preferentially over barren gangue and quickly become warmer with minimal energy consumption. This effect makes subsequent machine sorting of ore from waste rocks or overburden possible using infrared sensing. This paper reports on the 2450 MHz microwave response of a variety of sulphide minerals by mesh size and spatial distribution, as they might occur in ore rocks. The implications for infrared ore sorting are discussed.

Jan 1, 2011

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Likun Li

With the development of the world, the waste tires have been a serious environmental problem. There are about 2 billion waste tires produced all over the world every year and about 500 million waste tires are produced in the United States. Most of the waste tires are land filled, which waste a lot of space. It takes hundreds of years to resolve the macromolecules of waste tire into the standard which does not pollute the environment. Microwave irradiation is a thermal processing way for waste tires decomposition. In this study, the relative dielectric loss factor of the tire at various temperatures was determined to understand the behavior of tires under microwave heating.

Jan 1, 2016

By S. M. Bradshaw

The principles of microwave heating are discussed with reference to dielectric properties, heating phenomena and microwave equipment. Microwave regeneration of granular activated carbon for the carbon-in-pulp process is examined on a laboratory scale, with special attention being given to highlight the problem areas and specific considerations related to microwave heating. Results indicate that microwave regeneration of carbon with 40% moisture on a wet basis by heating to 650°C with steam addition regenerates the carbon to virgin carbon activity levels but with a higher abrasion resistance. A preliminary economic assessment showed that the capital cost for 120 kg/h microwave unit would be R540 000 with an annual operating cost of R 320/t carbon. These figures yield a return on investment of 12%. The aim of this paper is to provide an introduction to microwave heating and to illustrate its application to the microwave regeneration of granular activated carbon for the carbon-in-pulp (CIP) process.

Jan 1, 1998

By Yuzhe Zhang, Matthew Andriese, Jiann-Yang Hwang, Guanghui Li, Zhiwei Peng, Tao Jiang

The microwave power absorption characteristics of iron oxides, including Fe2O3, Fe3O4 and Fe0.925O, have been studied by determining dielectric loss and magnetic loss distributions in 0.05-m-thick oxide slabs irradiated with 1.2-kW, 2.45-GHz microwaves. The results reveal that the dielectric loss is the main factor contributing to microwave absorption in Fe2O3 and Fe0.925O, while the magnetic loss dominates the power absorption in Fe3O4 below its Curie point. Uneven power distributions are observed in the slabs and this phenomenon becomes even worse at high temperatures at which the permittivity increases significantly. Quantification of power absorption in the oxides is of great importance for efficient and uniform microwave heating

Jan 1, 2015

By Farzad Moradpouri, Kianoush Barani, M. R. Azadi

The aim of this paper is to assess the effect of microwave treatment on copper sulfide ore for ball milling and bed breakage. Liberation analysis of ground products in eight size fractions showed that microwave pretreatment liberated more chalcopyrite particles from the bed breakage product than the ball mill product. In bed breakage, microwave pretreatment caused a 2% increase in chalcopyrite liberation on average. Microwave pretreatment produces more elongated particles in ball milling and more rounded particles in bed breakage, respectively. Microwave pretreatment produces coarser chalcopyrite particles with a wide range of sizes. This effect is more significant in bed breakage compared with ball milling. Micro-flotation test results showed that in ball milling, treated and untreated materials have similar metallurgical performance and there is a little difference (1%) between the average Cu recovery values. However, in bed breakage, the average recovery for the treated materials is about 5% higher than the untreated materials.

Jul 8, 2021

By Nikhil Dhawan, Sanjay Pindar

The limited lifespan, ever-growing demand, and significant lithium and cobalt content are responsible factors for the immediate recycling of discarded lithium-ion batteries. Discharged batteries were dismantled, segregated, and size reduced to recover cathode and anode material. The active cathode material comprises LiCoO2 (65.8%) and LiMn2O4 (34.2%) and was carbothermal reduced with recovered graphite in a microwave furnace followed by water leaching and magnetic separation. A Box Behnken statistical experimental design is used for process optimization. Both cobalt and manganese report to magnetic fraction, whereas graphite and lithium carbonate report to non-magnetic fraction and solution crystal respectively. The final product comprises of cobalt 73% and manganese of 14% with process yield of 36% and saturation magnetization of 76 emu/g.

May 16, 2020

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

By Zhang Libo, Li Wei, Peng Jinhui, Guo Shenghui, L. Jing

Partially stabilized zirconia ceramics (PSZ) were prepared by microwave sintering using natural baddeleyite which was obtained by flotation of baddeleyite ore as starting materials. Because of using natural baddeleyite as raw and the process producing no waste, it realized shorter process, energy savmg, environmentally-friendly and non-damage processing. In this work natural baddeleyite stabilized with 3.8wt.% CaO were sintered at 1300°C for 60min in a multi-mode 2.45GHz microwave furnace. Microwave sintering could fast heating and sintering. Besides that, microwave sintering could heat materials wholly, low the sintering temperature, improve the materials properties and save energy. X-ray spectrum displayed the product composed by the tetragonal phase and monoclinic phase that also showed the product was PSZ. Fine and uniform microstructures were observed in the product through scanning electron microscopy. PSZ which was with high density was confirmed by the method of the Archimedes technique.

Jan 1, 2011

By QinGuo, Shenghui Guo, Lei Li, Jinhui Peng, Linqing Dai, Libo Zhang

The ferrous removal process after carbothermic reduction of chromite fines with microwave heating combined with leaching was investigated. Under the following conditions: Reaction temperature: 1150 , Reaction time : 40min, Semi coke ratio: 12% , the iron content of the reduction product : 13.05% . Metallization achieved was 52.7%. Reduced chromite was leached with 8% of H2SO4 and FeCl3 aqueous solution. The results show that: the recovery rate of chromium can reach 88.06%, the mass ratio of chromium to iron is 3.5:1 for leaching 30 minutes with 8% of H2SO4; the recovery rate of chromium can reach 88.91%, the mass ratio of chromium and iron is 2.56:1 for leaching 4h at room temperature with FeCl3 aqueous solution (100g/L). The leaching time of latter is longer but can realize the circulation effectively and reduce the waste liquid processing problem.1

Jan 1, 2016

By John A. Reeves

The unit-train concept of moving raw materials .is considered by many railroad men as the most signifigant contribution to reducing rail freight costs since the introduction of the diesel locomotive. The idea, which involves assigning railroad equipment to only one haul and keeping the equipment rolling results in the maximum utilization of equipment. For example before the unit train was plaged in servige on coal hauled to one of Mid. Continent's customers, about 900 cars and 9 locomotives were needed to move the coal requirements for this plant, compared with. 250 cars and 6 locomotives used by the present scheduling of unit trains. If the economics of unit-train movements are to be achieved, coal companies no longer can use railroad cars as small storage bins on wheels to accumulate their coal in trainload shipments, but, rather, must build large bins which incorporate facilities for the rapid loading of railroad cars in a minimum length of time. In this manner railroad equipment is operated at a high degree of efficiency 'with consequent dollar savings. After negotiations between Mid-Continent, the customers and the Railroad, it was decided a unit train loadout and storage facility at Carbondale was required in order to reduce the delivered price of coal to the customers and thereby contribute to the reduction in the cost of manufacturing steel. Carbondale was selected as the bin site location, because the cost of constructing a railroad to Redstone could not be justified for the tonnages anticipated.

Jan 1, 1969

By AIME AIME

N EARLY 1300 members and guests crowded the halls of the Engineering Societies Building during the winter meeting of the Institute just closed, and more than 600 attended the banquet. In variety of program, quality of papers, interest in discussion, and brilliance of social features, the meeting maintained the high reputation of the past. Nothing elaborate in the way of excursions was attempted, experience having proved that February weather in New York is much too uncertain to warrant extensive field trips. A sight-seeing journey up the Hudson to the Bear Mountain bridge was, however, made despite the snows of the week before and the week after. The annual business meeting, while attended by a minority of the members in the building, was marked by the display of keen interest in the work and called out several interesting discussions. The excellent reports of the committees that had organized their work and directed it along definite lines, emphasized the need of funds with which to support assistants or Fellows who shall correlate and put to the highest use the facilities of the Institute in research along technical lines. This thought was developed at the banquet by the retiring president, J. V. W. Reynders, and it is expected that the Directors will take early steps to collect a fund for this purpose. The number of the individual sessions was too great and the papers and discussions too numerous to permit mention here of all the features of inter- est. A general review only follows. The papers and detailed discussions will be printed and sent to members as promptly as possible.

Jan 1, 1926

By Pratt V, Davis K

Challenges facing middle management in the 1980's and beyond are not confined to business matters such as industrial relations, government and legal constraints, corporate takeovers, and commodity marketing. More particularly they deal with people issues and the interrelationship of corporate/ family relationships. There is a need for corporations to acknowledge the growing conflict between corporate/family roles being brought about by such matters as equal opportunity, double professional marriage partnerships, personal mobility and the increasing stress faced by managers as a result of current demands and expectations being placed on them. While the main responsibility for managing professional life as well as the relationship between professional and private life rests with the individual executive, corporations nevertheless have a major responsibility to assist these executives in this management process. Corporations in Australia are taking steps to address this situation but much more needs to be done. This was highlighted in the March 1985 "Middle Management" course with its associated Spouses Programme presented jointly by Australian Mineral Foundation and The Australian Administrative Staff College. Effective communication is at the heart of the matter but no amount of training on this subject will bear fruit unless there is an associated commitment by executives to improve the effectiveness of their communi- cation process both in their corporate and family roles.

Jan 1, 1986

By Harry R. Price, Behrooz Tahmasbi, Charles J. Roarty

The 2,408 meter (7,900-foot) long Middle Rouge Parkway Interceptor Extension varies in size from 1.52-meter (5-foot) to 2.36 meter (7-foot 9-inch) inside diameter. Most of the sewer was constructed in tunnel through fine sands and silts. Piping of these soils through the concrete liner eventually resulted in a loss of soil support, settlement and/or severe distress of the sewer, and the formation of several sinkholes. The repair and restoration was generally performed in the sewer and included cast-in-place concrete, shotcrete, cured in place pipe, soil stabilization, cement grouting, dewatering, and chemical grouting. As a part of the work, temporary pump stations and flow diversions were required to perform the work while minimizing discharges to the adjacent Rouge River.

Jan 1, 2007

By Kang N. Zhong, Hui H. Luo, Yunan Phosphate Chemical Co., Yi H. Wei, Yao J. Li, Yu L. Wang

"The three kinds of phosphate ores (igneous, metasedimentary and sedimentary) found in China have great differences in flotation flowsheets and reagents suite because of their crystal structure and mineral composition. The igneous and metasedimentary apatites have good floatability with fatty acid as collector and waterglass, sodium hydroxide or sodium carbonate as conditioners. The sedimentary phosphate is very difficult to beneficiate by direct flotation because of their poor floatabilities and relatively high content of MgO and SiO2, even though the dolomite depressants are used sometimes.The differences in floatability of apatites in China are closely related to their differences in specific surface area. The amount of collector to float apatite increases with the specific surface area. Apatite with lower specific surface area showed good floatability at lower collector concentration. Apatite with a higher specific surface area needed a higher concentration of collector. The content of CO3 2- will affect the specific surface area of apatite by distortion of its crystal structure and consequently affect its floatability.Dolomite can be easily rejected from apatite in a weak acidic medium (pH=5), especially in phosphoric acid medium by reverse flotation. Quartz and siliceous gangue in sedimentary apatite can be removed by direct flotation using fatty acid or by reverse flotation using amine. Amine is not practically applied because sedimentary apatite in China is usually very fine and needs fine grinding, which always results in excessive, very fine, stable and non-flowable foam.Based on the floatability of phosphate ore in China, a two-stage flotation process, direct and reverse flotation (D+R), was developed to beneficiate sedimentary ore. For the Haikou phosphate ore containing 25.11% P2O5, 3.46% MgO and 16.5% SiO2, a concentrate containing 31.84% P2O5, 0.48% MgO and 14.8% SiO2 can be obtained through a continuous D+R test at a recovery of 89%."

Jan 1, 2003