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By Stephen W. Paff

The EPA has estimated that there are over 3,000 sites across the United States contaminated with lead. Techniques to remediate these sites include standard stabilization/disposal technologies, reclamation of lead using secondary lead smelters, soil washing, and biological removal technologies. In this paper, the current technologies used for lead remediation will be reviewed. Factors affecting the use of each technology, such as range of applicable concentrations, soil types, interferences from other contaminants, economics, and current technology status will be assessed. The paper will also focus on the results of a recent study completed by the Center for Hazardous Materials Research (CHMR), in conjunction with a major lead smelter, which demonstrates that secondary lead smelters may be used economically to reclaim lead from a wide range of lead-containing materials frequently found at Superfund sites. Such materials include battery case materials, lead dross, and debris containing between 3 and 70% lead. The results of development work completed by CHMR on the Acid Extraction Treatment System (AETS), which has been demonstrated to extract Lead from soils containing up to 30,000 mg/kg lead, will also be presented. The use of these technologies will be compared with other options for the remediation of sites.

Jan 1, 1994

By D. M. Dabbs

A static dew point technique has been used to evaluate the solubility of arsenic in ?slag and its dependency on P02 at temperatures of 1458 and 1523K. The ferrous-ferric ion ratio of the slags ranged from 3.9 to 23.8. These values correspond to partial pressures of 02 ranging from 10-8 to 10-12 atm. The solubility of arsenic in slag was found to be independent of? P02? The data indicate that elemental arsenic exists in silicate ?slags. This result was further substantiated by mass .spectrometric analysis of doped slag specimens.

Jan 1, 1983

By V. I. Lakshmanan

Crown ethers are gaining importance in separation technology specifically for rare earth elements (REE, La to Lu plus Y) and precious metals (Au, Ag, Pt, Pd, Rh and Ir) due to their specific binding ability, metal complex stability and high extraction efficiency. The selectivity of crown ethers in extraction of these metals depends on different factors, including the cavity diameter and nature of a donor atom of the crown ether, size and charge of the metal ion, diluents and counter ion. Demand for strategic REE and precious metals are consistently increasing in the world while the separation of these metals is most challenging tasks. In this paper, the use of crown ethers in separation of REE and precious metals, reaction mechanisms and simplified process flowsheets will be elucidated. New reagents with high selectivity for the separation of these metals are further expected to produce high purity metals.

By J. Wong

We report a successful use of x-ray absorption spectroscopy to probe the chemical and structural environment of trace elements in coal. When applied to vanadium in coal, it was found that vanadium exists in at least two environments: a trivalent site 6-fold coordinated by oxygens at ca. 2.0~ and a tetravalent site 5-or 6-fold coordinated also by oxygens, one of which forms a short V=O bond at ca. 1.6a. No evidence of nitrogen (porphyrin)1'or sulfide environment was found. It was also found that the vanadium environ-ments in the raw coal did not survive unchanged in a liquefaction process. These findings have implications for coal cleaning processes and for trace element release into liquefaction process streams.

Jan 1, 1982

By René Winand

A new process was studied at large laboratory scale at Université Libre de Bruxelles, under contract with Metallurgie Hoboken-Overpelt. A two cathodes (1m long ; 0.2 m high) channel cell was used at 2000 A/m2, with an electrolyte flow rate up to 1.8 m/sec. The main results may be summarized as follows : cathodes are electro¬refined grade in analysis ; metallographic structure and surface roughness are kept under control up to 1.3 cm (one side deposits) ; silver in cathode is controlled by CI and Br ions in solution ; organics must be used at very low concentrations (in the range of 0.1 mg/1, with a consumption of about 0.01 mg/lh).

Jan 1, 1987

First, a classification of the various primary sources of feed materials for the production of cobalt is presented from a mineralogical point of view : sulfides, arsenides, sulfo-arsenides and oxide minerals. Each of these cate- gories will be characterized by its behaviour towards concentration methods, taking account of the presence of the associated minerals of other metals and of the nature of the gangue minerals. Then, for each category of cobalt bea- ring ores, typical flowsheets of treatment will be presented and discussed and the characteristics of the cobalt concentrates produced will be under- lined having in view their subsequent processing by pyro - and (or) hydrome- tallurgical methods.

Jan 1, 1988

By Luiz A. Teixeira

A process is described whereby worn, deffective or crystallized photoconductive Se-As layers can be stripped off from aluminium photocopier drums, using hydrogen peroxide solutions in conditions such that the aluminium substrate is preserved from chemical attack. The process allows the stripped drum to be recoated with a new photoconductive layer, and to be put again in use.

Jan 1, 1990

By V. E. Antonov

Hydrides of iron and iron-based alloys are thermodynamically stable only at hydrogen pressures in the gigapascal range and rapidly loose hydrogen under ambient conditions. At low temperatures, however, these hydrides can be retained in a metastable state at atmospheric pressure after being cooled under the high pressure to liquid nitrogen temperature. This review will discuss the current state of studies on phase transformations in the Fe-H and related systems and also on the composition, crystal structure and physical properties of the hydrides, both under high hydrogen pressures and in the "quenched" metastable state at ambient pressure. The studies at ambient pressure include magnetization measurements, X-ray and neutron diffraction, Mossbauer spectroscopy and inelastic neutron scattering. In the sections on Mossbauer and structural investigations of hydrides of Fe-Cr and Ni-Fe alloys new experimental results will be presented.

Jan 1, 2002

By L. R. Verney

A number of interrelated factors influence the economics of the sulphide smelting of copper, lead, zinc and nickel. This paper discusses these factors, mainly from a US point of view, and shows how they affect the cost of construction and operation of new and existing plants. The paper shows how metallurgical plant construction costs and the consumer price index have increased at a much faster rate than metal prices thereby making some metal mining and production operations within the USA, Canada and the EEC less profitable than operations elsewhere. This in turn inhibits new "grass roots" metallurgical developments. It is explained how retrofit of existing pyrometallurgical plants can be a more viable development than the construction of "green field" plants, especially if such retrofit improves, energy efficiencies, overall operating costs and reduces emissions of sulphur and other toxic wastes. Some aspects of metallurgical plant operation are examined, especially for copper and nickel, to show how changes in operating practices may develop in order to improve overall smelting economies, especially when developed in conjunction with objective retrofit. The paper also examines some financial aspects, especially insofar as the disparity between terms for loans offered to third world countries and the USA and the EEC are concerned and also comments upon the need, especially within the USA, for legislation to permit rapid depreciation of capital. Specific comments are made about environmental aspects, including the lack of uniformity of pollution control legislation and how environmental considerations may have some bearing of the location of future smelting operations.

Jan 1, 1983

By Larry M. Southwick, Phillip J. Mackey, A. E. (Bert) Wraith, Albert Pelletier

In 1881, the first commercial pneumatic Bessemer-type converter treating copper matte was successfully introduced by Pierre Manhes at the Eguilles copper plant near Vedène in France. This development followed over a year of testing on a smaller scale at a foundry in Vedène, during which the vertical tuyeres of the conventional Bessemer converter had been successfully replaced by horizontal tuyeres in an effort to avoid the freezing of copper which had occurred in the bottom of the vessel having vertical tuyeres. The Manhes Converter, as it became known, was the first successful large-scale adaptation of the Bessemer concept of using compressed air blown into a melt for metal refining and treatment. Within a few years, Manhes Converters utilizing horizontal tuyeres in either the original type of vertical converter, or a later and more enduring horizontal barrel converter, were in operation at over a dozen copper smelters around the world. It was this process that Messrs Peirce and Smith essentially improved with the introduction of the larger converter which bears their name and the development celebrated at this Symposium. The present paper briefly traces the original development by Pierre Manhes in the early 1880s and which set the stage for the later Peirce-Smith adaptation. The paper observes that the original development by Manhes was in part driven by the need to reduce coal (energy) consumption and hence the production cost in order for Eguilles to remain competitive with the larger plants in Swansea, Wales, where a ready supply of cheap coal helped keep smelter treatment terms of the day low. These themes are eerily resonant of today where booming copper production in China has impacted the industry, and also where energy consumption, closely linked to today’s more familiar theme of ‘climate change’ remains an important challenge currently confronting the entire industry. The paper concludes with comments on these seemingly parallel situations today and offers some thoughts for the future.

Jan 1, 2009

By N. L. Piret

Reprocessing of low zinc-bearing residuals with a zinc content of less than 10%, originating from the iron and steel industry, has been given more and more attention in the last few years, due to the potential landfill liability and the increasing cost of disposal by dumping. Whereas, recycling of hazardous electric arc furnace dust is already being performed commercially on a large scale in the U.S., Japan and Western Europe, almost no reprocessing takes place in the case of these low grade zinc-bearing materials. In blast furnaces and basic oxygen furnaces dusts and / or sludges are generated at a rate of 1 to 2 % of the respective production. The technologies for the retreatment of these types of materials, either commercially available or still being developed are briefly described hereafter. They involve internal recycling, upgrading by physical separation methods, separate hydrometallurgical processing and pyrometallurgical treatment. Their scope and limitations are critically assessed in terms of technological applicability, economic feasibility and environmental compatibility. Since, the possibtlity of achieving economic profitability is unlikely with this type of material, the main criteria for acceptability of the treatment process are: generation of a iron-rich material, suitable for treatment by the iron/steel industry, acceptance of the non--ferrous metal-bearing sub-product by zinc smelters, generation of non-hazardous waste materials.

Jan 1, 1992

By Patrick R. Taylor

A non-transferred arc thermal plasma assisted cyclone reactor has been designed, built and operated to evaluate its use in vitrification of wastes. Simulated waste (liquid, slurry or fine particulate) is injected near the plasma flame, where nearly instantaneous dehydration and calcination reactions happen. A non-transferred arc plasma torch was attached tangentially to the cyclone and is utilized as both an enthalpy source and to provide the gas velocities required to generate the cyclonic gas flow patterns. The closed top cyclone flow sends the solid particulates to the wall, where they are captured by a thin film of molten glass that is injected as a powder at a position lower in the reactor. The molten glass is then collected in a crucible. The feasibility of simulant injection directly into the flame zone and its effect on electrode lifetimes has been studied. Several candidate refractory systems have been evaluated for their suitability for extended use under the demanding conditions present in the cyclone reactor.

Jan 1, 2002

By N. L. Piret

Primary and secondary copper smelting dusts are being generated in varying quantities with very dissimilar characteristics due to the different compositions of feed materials and the type of process utilized. After categorizing the multitude of dust types, the criteria for on-site and off-site recycling of smelter dust in terms of type and concentrations of the accompanying elements are established. Thereby, consideration is given to the important aspects of: ? optimization of copper recovery ? quality of copper product ? valorization of accompanying elements ? elimination and disposal of deleterious impurities ? minimization of impact on operation ? effects on operating costs ? environmental impact of dust treatment on overall process Existing commercial, emerging and proposed copper smelting dusts, pyrometallurgical as well as hydrometallurgical, treatment schemes are reviewed and evaluated technically, economically and environmentally in an attempt to streamline the vast number of proposed options. Thereby, the high selectivity achievable in hydrometallurgical dust processing due to it being complementary to the smelting process is expected to be given increased consideration.

Jan 1, 1995

By Mariana H. Staia

The present communication reports the results obtained by applying different concentration methods, at laboratory level, to the black sands from Estado Bolivar, Venezuela, with the aim of obtaining an adequate ilmenitic concentrate for the subsequent chlorination process. Sizing analysis was performed and plasma emission spectroscopy method was used to determine the chemical composition. It was found that from the two hydrogravimetric methods used, the Humphrey spirals is much more effective than Wilfley tables, leading to a 85% recovery. The most convenient particle size group for these concentration methods was the one corresponding to ASTM 40-140 mesh. When magnetic concentration was applied to the concentrate, obtained as a product from Humphrey spiral, a recovery of ilmenite more than 90% was obtained in the first step. It has been shown that the ore would respond to the separation techniques employed, giving individual minerals: ilmenite, zircon and silica as concentration products.

Jan 1, 1995

By Hongbo Yang, Tongbo Zhang, Ting Huang, Jingshe Li, Fangfang Song

"Liquid core length is a very important parameter of the process of continuous casting, which directly reflects the cooling status in secondary cooling zone and solidification rate of the slab. In this paper, the billet caster in some steel plant in China was chosen as the prototype of simulating. A numerical simulating model for calculating the liquid core length of continuous casting billet was built by ProCAST software, which was verified reasonable and accurate by pin-shooting technique. Based on the model, the relationships between casting speed, casting temperature and liquid core length of casting billet were found, which was very practically useful for the workers on sit to improve casting billet quality. IntroductionContinuous casting process developed very rapidly because of the high metal yield, energy saving, and low-cost 111• And the quality requirements of continuous casting billet for customers became higher and higher with the fast development of economic121• Internal defect usually is the major quality problem for continuous casting billet[3•61 , which is influenced by the solidification process of casting billet, especially the solidification process of liquid core17•81 • So it is very important to study on the relationship between casting parameters and the liquid core length which means the distance between the crystallizer meniscus and the casting billet solidification end-point. In practical production process, the workers usually control the quality of casting billet according to the liquid core length."

Jan 1, 2013

By P. A. Botha

Most sinter producers prefer to use a range of iron ores with the aim to optimize their sinter blends. ISCOR is however limited to the use of ore from two deposits, namely Sishen and Thabazimbi. Only sinter produced from Sishen ore is described in this report. The Sishen iron ore deposit provides high-grade hematite ore with a mean iron content of 65 per cent. Three major ore types are developed: massive, laminated and conglomeratic. The main ore mineral is hematite with minor to trace amounts of quartz, mica, phosphates and, in places, carbonates. A sinter product is characterized by its mineralogical composition and metallurgical properties. The production rate also plays an important role in the economic evaluation of sinter quality. Sinter-pot tests were conducted with varying basicities, given as the ratio of CaO to SiO:< and coke content. The results of these tests were characterized by mineralogical and metallurgical methods. Basicity of a sinter mix directly influences the mineralogical composition and metallurgical properties. The content of calcium ferrite and calcium silicate increases with increasing basicity, thereby increasing the reducibility and cold strength of the sinter product. Experiments performed during this study provided a model for the optimization of the sinter mix with respect to its mineralogical and metallurgical parameters.

Jan 1, 1991

By Patrick R. Taylor

Coatings of TiCIFe have been produced by Reactive Plasma Spraying using ilmenite ore concentrate as the feedstock powder and methane as the reactive gas. A free energy minimization analysis of the ilmenite-methane system is presented. The coatings have been characterized by x-ray diffraction and SEM. The microstructure of the coatings indicates good interparticle cohesion. The composition of the coating is deficient in iron compared to the initial Fe to Ti ratio found in ilmenite.

Jan 1, 1998

Al2O3,-WC Composite powder for cutting tools was synthesized by self-propagating high-temperature synthesis using A1 powder as a reducing agent. WC, W2C and Al2O3 were concurrently formed in WO3Al-C system. It was found that the complete reaction was achieved with excessive addition of carbon and appropriate processing parameters such as degree of dilution, particle size of aluminum, compaction pressures of green pellets and carbon source. The final product which was leached by 50% HN03+HF diluted solution was consisted of Al2O3-55wt% WC having 2-3um of mean particle size.

Jan 1, 1999

By L. Lü, M. O. Lai

"Mechanical alloying is a dry, high energy ball milling process which has been used to synthesize metallic powders in the solid state. The present study use this technique to synthesize Cu-base shape memory alloy powder from commercial Cu70Zn30, Cu86Zn14 and element AI powders. The evolution and formation of shape memory alloy powder were monitored using X-ray diffraction and microscopy. It was observed that shape memory alloy powder started to form after 1.8 ks of mechanical alloying. ? phase was clearly detected after 3.6 ks of mechanical alloying. The intensity of X-ray diffraction of the y phase increased when mechanical alloying duration was prolonged indicating an increase in the amount of y phase. Microstructure observation showed different stages of formation of alloyed powders: welding between powders and formation of layered structure, deformation and fracturing of layered structure, and finally the formation of alloyed powders.IntroductionMechanical alloying (MA) is a process used for producing powders with controlled and extremely fine microstructure. It was original developed in 1966 (1) to produce aNi-based superalloy combining oxide dispersion strengthening with gamma prime precipitation hardening. In recent years this technique has been used in producing a wide range of materials including intermetallic compounds (2, 3), amorphous materials (4-6) and other materials (7-9). In MA, a blend of powders is subjected to highly energetic compressive collision. The powder panicles are welded and fractured during ball milling. Therefore, it is essential that at least one of powders should be ductile to act as combiner. It has however been found that brittle components without soft element can also be mechanically alloyed (10), even ceramic powders (11).The present work aims to study the mechanism of formation of shape memory alloy powder during MA."

Jan 1, 1994

By Guoqiang Lv, Xi Yang, Wenhui Ma

Cast multicrystalline silicon ingots are widely used in photovoltaic manufacturing. A key issue to achieve high solar cell efficiencies is to attain an optimized temperature field during directional solidification (DS) process. This paper reports numerical investigation of multicrystalline silicon (mc-Si) ingot production using two major types of DS furnace. Specific examination is made on thermal distribution, interface shape and stress field. Evaluation is performed for the applicability of thermal system design to reduce thermal stress, improve crystal quality and enhance energy efficiency. The effects of procedure parameters and geometric configuration on temperature distribution are discussed as well to provide the viable solutions for systems optimization.

Jan 1, 2015