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By Russell E. Griffin

The current state-of-the-art of fire and smoke detection technology is reviewed from the standpoint of suitability for use in underground metal and nonmetal mines. Detection modes, fire signatures, and environmental considerations are included. Preliminary results of long-term in-mine tests are presented.

Jan 1, 1979

By Michael Zachariah, Art Miller, David Kittelson, Gib Ahlstrand

This report describes an investigation in which we used iron-doped diesel fuel to generate metal-bearing diesel particles and a subsequent analysis of the particles using transmission electron microscopy (TEM) and energy-dispersive spectroscopy (EDS). For this study, DPM was generated by a 1.5-L diesel engine and the fuel was doped with ferrocene to enhance the level of iron in the system. The exhaust particles were collected on TEM grids and analyzed using the Philips CM12 TEM/EDS instrument. Results show that when the iron-to-carbon (soot) ratio (Fe/C) in the engine is low, the exhaust particles have morphologies similar to those for the undoped case, but at a threshold Fe/C value of 0.013 (for this engine), homogeneously nucleated metallic nanoparticles are formed and begin agglomerating. The number and size of these nanoparticles increase with level of doping. Metal-bearing particles that span a wider size range are also formed. Agglomeration of metallic and carbon particles is observed in two distinct modes: attachment of iron primary particles (5–10 nm in diameter) to carbon agglomerates, and coagulation of iron agglomerates (20–200 nm in diameter) with carbon agglomerates. Results of this work imply that as new engine technologies reduce soot levels in the engine and/or levels of trace metals in the fuel are increased, the generation of metallic nanoparticles may ensue, creating a potential health concern. Keywords: Nanoparticles; Particulate emissions; Metallic particles; Metal emissions

By E. G. Valdez

Three cryogenic systems that utilized liquid nitrogen, dry ice, and methanol with dry ice were investigated in conjunction with crushing and classifying techniques. The systems were used to aid in separating and reclaiming the metallic components contained in insulated wires, shredded automobile nonferrous metal concentrates, small motors, generators, and rubber tires. Wire strands, 2 to 6 inches long and insulated with polyvinyl chloride and neoprene, were chilled at -60° and -195° C, then roll-crushed and processed by water elutriation; this procedure resulted in two products--a sink fraction that was 99 percent metallic and a float fraction that was 99 percent nonmetallic. Excellent separation of zinc die-casting alloys from copper and aluminum contained in shredded automobile nonferrous metal concentrates was attained by chilling at -72° C for 1 minute, crushing in a grateless hammer mill, and screening. From the screened products, 97.2 and 100 percent of the copper and aluminum, respectively, were recovered in the plus Pinch fraction, and 100 percent of the zinc was recovered in the minus 1-inch fraction of over 97 percent zinc die-cast purity. Laboratory experimental results comparing direct and indirect chilling indicated that a sufficiently low temperature could be attained by indirect chilling to permit use of a liquid C02-dry ice system on insulated wires and mixed nonferrous metallic concentrates.

Jan 1, 1973

By Steven J. Schatzel, Robert B. Krog

Frictional ignitions are defined as the ignition of a flammable mixture of methane and air that is initiated by frictional heating. Ignitions created through the addition of energy from open flames and exposed electrical circuits are not included in this analysis. Energy released in a roof fall that creates a spark and ignites a methane mixture would be considered a frictional ignition. Frictional ignitions represent the majority of all ignitions in underground coal mines. Over the study period of 1983 to 2005, a total of 1993 ignitions were reported in underground bituminous coal mines in the United States, of which 1589 were frictional ignitions. Reportable ignitions to the Mine Safety and Health Administration (MSHA) are any unintentional occurrences of flame underground regardless of duration. Frictional ignitions were reported in 155 mines and 13 states. Continuous miners represented the largest source for frictional ignitions with 1090 (68.6% of all frictional ignitions). Longwall mining operations represented the highest concentration of frictional ignitions during this study period with 1365 frictional ignitions (85.9% of all frictional ignitions). The 17 mines with the most frictional ignitions were all longwall mining operations and had 1130 frictional ignitions (307 from the shearer) that represented 71.1% of the total. In 1983, mines with frictional ignitions represented 6.9% of operating underground mines and 36.6% of total underground coal production. The percentage of operating underground mines with frictional ignitions and their total production has increased steadily and in 2005 represented 9.8% of active mines and 46.2% of underground coal production. The three coalbeds with the highest number of frictional ignitions (Blue Creek, Pittsburgh No 8, and Pocahontas No 3) had 1049 ignitions that represented 66.0% of all frictional ignitions. The three states with the highest number of frictional ignitions were Alabama (710), Virginia (247), and Pennsylvania (242) that represented 75.5% of the total. Frictional ignitions peaked in 1991 with a high of 114. In 2005, only 34 frictional ignitions were reported. If only frictional ignitions that occur at the face are considered, there have been no fatalities since 1983. Since this time, there were 33 ignitions that caused 53 workers to lose a total of 2912 working days. When including ground falls, then there have been four frictional ignitions with one incident causing two fatalities and injuring eight workers. From 1983-1991, underground productivity and the number of frictional ignitions increased. However, productivity continued to increase from 1991-2000 while total frictional ignitions fell, thereby disproving this connection between productivity and frequency of frictional ignitions. Ninety percent of all frictional ignitions occurred in underground coal mines that liberated more than 393 L/s (1.2 MMcfd million cubic feet per day) of methane through the main ventilation system. Although methane production is not the determining factor for the occurrence of frictional ignitions, it is a good indicator of the anticipated frequency.

By Joel N. Van Sant

An investigation was conducted to study possible sources of Utah refractory and structural clays that could be used for the manufacture of refractories and light or buff burning heavy-clay products. A field study was made and the clay samples tested to determine their firing characteristics. Results of the Bureau's work indicate many small noncommercial deposits of hypogenic clay occur in igneous rocks. Commercial hypogenic deposits are mostly halloysite clay developed by hydrothermal replacement of limestone. The high firing shrinkage of halloysite precludes its use as a refractory, however, halloysite produced at the Dragon Mine south of Eureka, is used for making oil catalysts. Clays and shales suitable for low heat duty refractory products are found in the Manning Canyon shale, in shales associated with coal bearing rocks, and in the Dakota formation. Some of the clays from the Dakota formation are also suitable for high-duty refractory products.

Jan 1, 1964

By Forrest T. Moyer

INJURY experience in the metal and nonmetal mineral industries during 1964 was better in rates of occurrence but worse in severity rates than in 1963. The frequency rate of injuries per million man-hours was improved at metal mills, nonmetal mines, and sand and gravel operations, and was virtually unchanged at metal mines; however" the rate of occurrence of work injuries at nonmetal mills, stone operations, nonferrous reduction and refining plants, and slag plants was higher than in 1963. The severity rate of injuries during 1964, data for which are presented for the first time in this chapter, was better at metal mills, nonmetal mines, stone operations, and slag plants. However, the severity rate was worse at metal mines, nonmetal mills, sand and gravel plants, and nonferrous smelters.

Jan 1, 1965

By P. C. McWilliams

Theoreticians in soil mechanics have been pursuing a probabilistic approach to the factor of safety of an embankment or darn for the past 10 years. The motivation for this work is in contrast to the current practice of deterministically computing a factor of safety and treating it as an absolute with no regard to its inherent statistical variability. Basic to the probabilistic approach is the selection of an appropriate statistical model to represent the histogram or probability density function (PDF) of the factor of safety values, Rather than simply assuming which PDF is appropriate, the Bureau of Mines collected data at two waste disposal embankments for consideration, This report addresses three candidate models, using the techniques of nonlinear curve fitting, and identifies the "best" model. A propagation of error formula for estimating the variability of Fellenius? factor of safety is also discussed.

Jan 1, 1983

By A. Visnapuu

Excessive noise and high vibration are inherently associated with equipment used in the mining, extraction, and processing of mineral resources. High vibration degrades structural components, often leading to catastrophic failure and loss of productivity, and excessive noise can result in permanent hearing loss. In order to foster efficient utilization of the Nation's mineral resources and minimize occupational hazards associated with mineral processing, the Bureau of Mines investigated the relationship between the microstructures of carbon and alloy steels and cast irons and their damping capacities (ability to absorb vibration). Researchers measured damping capacity and other properties and investigated the effects of carburizing, spheroidizing, and annealing. The investigators found that in carbon and alloy steels, rounded colonies of fine-grained pearlite in a ferrite matrix correlate well with low damping capacity. Steel microstructures that exhibit sharp-faceted pearlite in ferrite matrix and partially or fully spheroidized cementite in ferrite show considerably higher damping. In cast irons, the lowest damping capacity is associated with nodular graphite microstructure, and the specific damping capacity (SDC) increases as the graphite micro-structure progresses from nodular to compacted to flake. Predominant ferrite in cast irons is also associated with good damping. SDC data are presented for selected carbon and alloy steels and cast irons.

Jan 1, 1987

By C. B. Davison

One goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. Consistent with this goal, the Bureau conducted studies on the formation of undesirable cristobalite in seven different fire clays used as refractories. The studies employed scanning electron micrography, chemical and X-ray analyses, and pyrometric cone equivalent determinations to examine the sample clays and determine the effect of thermal history and stablilizing additives on the amount of cristobalite in various calcines. This research has indicated that as fire clay calcining temperatures increased from 1390° to 1,490° C there was a gradual decrease in the percent of cristobalite present in the calcines and a progressive development of mullite crystallization. No cristobalite was found in fire clays calcined above 1,550° C, but cristobalite reappeared when the calcines were reheated to temperatures between 1,400° and 1,500° C. The research also revealed that additions of lithium fluoride (LiF) prevented formation of cristobalite in fire clay calcines.

Jan 1, 1979

By John C. Machisak

The National Safety Competition is sponsored and conducted annually by the Bureau of Mines, U.S. Department of the Interior, to give greater impetus to the building of programs safeguarding the employees of the mineral industries from disabling work injuries. The results of the 1960 National Safety Competition are presented in this publication. Mines and quarries that were awarded the Sentinels of Safety trophy for the best safety record in their competitive group and those mineral operations that ranked second, third, fourth, and fifth in the competition are listed with a summary of their achievements in preventing disabling work injuries. In addition, this publication presents statistical data on disabling work-injury experience in all other mines and quarries participating in the annual competitions.

Jan 1, 1962

By H. E. Powell

A laboratory investigation was conducted by the Bureau of Mines to study the magnetic characteristics and to measure the magnetic susceptibility of the mineral siderite. All susceptibility measurements were made by the method of Gouy on powdered samples and at room temperature. Specific susceptibilities of samples from 15 different locations, domestic and foreign, were determined. Values ranged from 66 to 103 (10-6) cgs electromagnetic units. The relation of susceptibility to mineral composition is discussed in this report. The specific susceptibilities of 76 minerals are tabulated in an appendix.

Jan 1, 1963

By S. H. Ash

For several years considerable activity has been devoted to economic and social factors affecting California metal-mining operations as they relate to accidents and their cost. The reason for this intense interest is that accidents cost this industry annually over $1100,000 in industrial insurance premiums for mines insured by insurance carriers only; during 1924-32, inclusive, they amounted to $3,616,9115. There are several reasons for this high cost, the most important of w rich are the consistently .high frequency and severity rates of injuries occurring in the industry. Coordination of effort, appreciation of a mutual problem, and widespread education are essential if accidents and their cost are to be reduced.

Jan 1, 1935

By H. F. Yancey

About 65 percent of the more than 400 million tons of coal produced annually in the United States is mechanically cleaned to remove the inorganic impurities before being sent to market. The impurities, principally shale and clay with some pyrite, average about 20 percent of the raw coal treated. Nearly 95 percent of the tonnage is treated by wet processes, in which water, suspensions of solids in water, or occasionally calcium chloride solutions are employed. Difference in density of coal and impurity is the basis of these processes. Of major importance in the separation is the competency of the impurities, that is, the resistance of the impurities to size disintegration in water. In general, the impurities are more resistant in geologically older coals or those in effect made older by metamorphism. If the impurities suffer reduction in particle size when immersed in water, the separation of organic from inorganic material becomes more difficult, Recently the Scientific Department of the National Goal Board (Great Britain) undertook fundamental research into the interaction of shale and water and also developed an empirical method of assessing shale breakdown or disintegration. 6

Jan 1, 1962

By H. H. Fields

The Bureau of Mines is in the process of degasifying a virgin area in northern West Virginia from the base of an 839-foot-deep vertical borehole¬. An in situ gas pressure hole 199 feet long, and seven degasification holes ranging in depth from 500 to 850 feet (average 618 feet) were drilled in an 8-foot-thick virgin Pittsburgh coalbed from the enlarged (14-foot-diameter) bottom of this borehole. The in situ pressure at the back end of the hole and the range of gas and water flows from degasification holes as they were completed and closed off were 203 psi, 79,000 to 257,000 cfd (average 160,000 cfd), and 5 to 8 gpm per hole (average 6.8 gpm), respectively. Twenty-four hours after the seven holes were connected through individual water traps to a common collector for natural venting of the gas through pipes to the atmos¬phere, the total gas and water flows and the in situ pressure dropped, respec¬tively, to 971,000 cfd, 1.3 gpm, and 18 psi. Eighty days later the correspond¬ing values dropped to 529,000 cfd, 0.50 gpm, and 13 psi. After 180 days of degasification, 91 million cubic feet of gas had been removed from the affected virgin area. This represents 60 to 70 percent of the gas calculated to be contained in the area of coal affected by the holes.

Jan 1, 1973

By J. E. Chilton, T. Mal

Methane monitoring at the mine face is essential to assure a safe work environment in underground coal mines. Machine-mounted methane monitors must be used to continuously monitor methane levels during mining. Monitors used on mining machines must be approved by MSHA and properly maintained to provide protection for workers (30 CFR 75.342). To provide protection the instrument must give accurate readings of current methane levels. Accuracy is maintained by calibrating the instrument with a standard gas at least once every 31 days. Instrument “response time” determines how quickly measurements will change to reflect current concentrations. At present there are no criteria for measuring the response time for a ma-chine-mounted methane monitor while underground. This study examined a procedure for measuring the response time of a machine-mounted methane monitor. Response times were measured using methanometers obtained from three different manufacturers. The effects of the measurement technique and methanometer sensor head design on response time measurements are investigated. Techniques for reducing variation in response time measurements are discussed.

By David K. Ingram

The Bureau of Mines conducted underground mapping and rock strength tests to describe and analyze mine roof conditions surrounding ancient stream channel deposits (paleochannels) in the Pittsburgh Coalbed in southwestern Pennsylvania. Paleochannels in the study mine consist of sandstone and/or siltstone and affect the Pittsburgh Coalbed through erosion and/or differential compaction. Differentially compacted sediments within and adjacent to channel deposits caused slip planes, faults, clay-dike faults, clastic dikes (clay veins), coalbed rolls, and slumped structures. Paleochannels can be predicted by recognizing these features and associated sediments, which allows for modification of long-and short-term mine planning and development. Mine entries located beneath the paleochannel deposits exhibit less stable roof conditions than entries with normal (nonchannel) roof. Paleochannel deposits comprise only one-fourth of the mapped study area; however, they contain one-half of the hazardous roof. This study deter-mined that rock strength evaluations, including rock quality designation (RQD), unconfined uniaxial compressive strength testing, and point-load testing, must be accompanied by underground observations. Suggested remedial support techniques include angled and/or longer tensioned bolts, steel mats or crossbars, steel sets or cribbing, and roof trusses.

Jan 1, 1987

By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials for removing metal contaminants from waste waters. The beads, designated as BID-FIX beads, are prepared by blending biomass, such as sphagnum peat moss or algae, into a polymer solution and spraying the mixture into water. Laboratory studies were conducted to determine bead sorption and elution characteristics. Batch and continuous tests demonstrated that BIO-FIX beads sorbed arsenic, cadmium, lead, and other toxic metals from acid mine drainage waters collected from several sites. Selectivity for heavy and toxic metal ions over calcium and magnesium was demonstrated. The beads exhibited excellent metal sorption and handling characteristics in stirred tanks, column contactors, and a low-maintenance passive system. The sorption process was reversible, and metal ions were eluted from the beads using dilute mineral acids. Cyclic tests indicated that the beads continued to extract metal ions after repeated loading-elution cycles.

Jan 1, 1991

By Henry C. Meeves

The Bureau of Mines, between 1956 and 1963, examined 18 major pegmatite districts in Arizona, Colorado, New Mexico, South Dakota, Utah, and Wyoming to evaluate their content of beryllium, a material in short domestic supply that has become increasingly important to modern industry. This examination report includes the salient statistics on the production of pegmatite minerals other than quartz and feldspar; and brief descriptions of 170 specific pegmatite deposits.

Jan 1, 1966

By J. M. Kuchta

Bench-scale test methods were developed by the Bureau of Mines for use by the Department of Transportation in the classification of solid and liquid oxidizers. A burning rate test is recommended for evaluating the fire hazard of solid inorganic oxidizers when mixed with a red oak sawdust as the reference combustible. A spontaneous ignition test is proposed for evaluating liquid and solid inorganic oxidizers which may decompose violently or ignite spontaneously when unmixed or mixed with the wood sawdust under unconfined conditions. Test results are compared for various representative oxidizers and a classification system is proposed for use in the government transportation regulations.

Jan 1, 1972

By M. M. Wong

The Bureau of Mines, under a cooperative research program with four lead companies, has investigated a nonsmelting process for the production of lead metal. The process, which would eliminate sulfur dioxide generation and minimize particulate lead emissions, involves ferric chloride leaching of galena concentrate to produce lead chloride, followed by molten-salt electrolysis of the lead chloride to yield lead metal and chlorine. This chlorine is used to regenerate ferric chloride in the leaching solution. The process was tested in an experimental unit with a capacity of 500 lb of lead metal per day. The tests were performed in three 10-day and six 5-day campaigns, during a period spanning 28 mo. The study was carried out using a southeastern Missouri lead concentrate. Typical lead recovery was about 98 pct. Process problems related to impurity buildup and control were studied. When copper and silver impurities were removed from the leaching solution, a lead metal purity of 99.999 pct was obtained. Lead-in-air levels and lead-in-blood levels of operating personnel were monitored. The process has potential for producing lead with minimum pollution, but is not ready for commercial utilization. Operation of a prototype commercial electrolytic cell and a full-scale pilot-plant investigation by industry are needed to evaluate the commercial viability of the process.

Jan 1, 1983