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By Patricia J. Leonard - Mayer

A Bureau of Mines surface resistivity method has been used to determine the joint strike and coefficient of anisotropy of jointed , nearsurface formations at five study areas . The field studies demonstrate the use of rotated , or azimuthal , Wenner-Lee arrays for determining the strike of predominant joint sets . The results of the field studies include the following : in a formation having a predominant , vertical joint set , the maximum value of the apparent resistivity ( pa ) occurs in the same direction ( azimuth ) as the joint strike ; the polar coordinate graph of pa for such a formation is approximately elliptical ; the coefficient of anisotropy ( ^ ) can be calculated from the field data , and values of λ for jointed formations are in the same range of values reported for layered formations ; values of λ are higher at mined sites than at unmined sites . The azimuthal resistivity method and horizontal profiling were used at a site in Pennsylvania to delineate a zone of intensely jointed and fractured bedrock that provided a flow path from a surface stream to a mine . Analysis of the data has been based on a simple model of a jointed formation having a single joint set ; the success achieved to date indicates the need for a more complex model and additional field data .

Jan 1, 1983

This report, 27th in a continuing series1, describes Bureau of Mines research and technologic work on coal and related investigations during 1962. While the brief discussion in each section of the report presents only the highlights of Bureau work during the year, details of many investigations can be found in publications cited in this text. Other work, reported here for the first time, will be covered in greater detail in later publications. Recent trends in coal research and technology both at home and abroad were reviewed in several publications2. Bureau research, as in the past3, continued to stress improved methods of mining, preparing, processing, and using coal. The program included a wide variety of applied and basic studies for developing information useful to the coal mining industry and the coal consumer while promoting wise conservation and utilization of our coal resources.

Jan 1, 1963

A preliminary program dated April 25, 1974 was prepared for Development Engineering, Inc. (D.E.I.) on research and development, laboratory; field and other engineering studies for the disposal of retorted oil shale. This program was revised and published as a final document dated December 17, 1974. The document included a discussion on the peculiarity of retorted shale materials to be investigated and a discussion of the various laboratory and field tests which would need to be conducted to define their physical and chemical properties. The proposed research and development program was divided into eight work phases as follows: I - Program Development II - Exploratory Laboratory tests on old U.S.B.M., retored shale III - Laboratory tests on Pilot Plant retorted shale IV - Laboratory tests on retorted shale from Semi-Works Plant, and field and test plots and ponds. V - Field compaction tests

Jan 1, 1975

This report, 27th in a continuing series1, describes Bureau of Mines research and technologic work on coal and related investigations during 1962. While the brief discussion in each section of the report presents only the highlights of Bureau work during the year, details of many investigations can be found in publications cited in this text. Other work, reported here for the first time, will be covered in greater detail in later publications. Recent trends in coal research and technology both at home and abroad were reviewed in several publications2. Bureau research, as in the past3, continued to stress improved methods of mining, preparing, processing, and using coal. The program included a wide variety of applied and basic studies for developing information useful to the coal mining industry and the coal consumer while promoting wise conservation and utilization of our coal resources.

Jan 1, 1963

This: symposium was sponsored by the Bureau of Mines, U.S. Department of the lnterior, in order to critically examine the state-of-the-art of sulfide flotation chemistry and to define current and emerging problems that should be emphasized in future fundamental research. The topics covered through invited papers include both reviews and recent research results in the areas of thermodynamics of reagent-mineral interactions; collector adsorption processes; the effects of solid-state point defects on flotation; activation and deactivation phenomena; the electrochemical role of oxygen in sulfide flotation; environmental problems in flotation; and selective flocculation of fines. Papers riving perspectives on flotation research in relationship to our national mineral requirements and the relationships between industrial flotation research and academics are also presented. An edited summary of the symposium follows the papers.

Jan 1, 1980

By G. W. Jones

The operation of combustion engines of various types at high altitudes and other combustion processes at reduced pressures have made it desirable to determine limits of flammabilities -under these conditions. Experiments carried out by the Bureau of Mines have shown that although natural gas-air mixtures become more difficult to ignite as the pressure is reduced below atmospheric, with a suitable source of ignition the limits of flammability are as wide at 175 mm mercury absolute as they are at atmospheric pressure.

Jan 1, 1949

By George A. Burrell, Frank M. Seibert

The Bureau of Mines, as part of its designated duty of investigating the causes of mine accidents, is conducting at its experiment station in Pittsburgh, Pa., a study of mine gases. Some of the work already done in connection with this study is outlined below. A large number of mine-gas samples have been collected under normal conditions in returns and in splits, and at other points in the ventilating current, also at the face, in the goave or gob, in unventilated places, and wherever the air was still. Samples have also been obtained under abnormal conditions, as after explosions and while mine fires were in progress, or from sealed areas behind stoppings and darns where the air had been stagnant for some time. Chemical changes in the composition of mine atmospheres during mine fires have been studied," and conditions peculiar to certain mines have been investigated. The question of the effect of a change in atmospheric pressure on the escape of gas (methane) in coal mines has been studied. Explosives have been fired in both coal and metal mines, and samples of resulting gases have been collected to ascertain the degree to which these gases vitiate the air. A series of samples in mines where gasoline locomotives were being used have been examined in order to ascertain the degree to which the exhaust gases from such locomotives foul the mine air. Experiments have also been performed in regard to the relative effect of carbon monoxide b upon men and small animals. A preliminary report relating to the inflammable gases in mine air has been published. Full reports of the results of the investigations outlined above will be published as soon as all the necessary data have been gathered. The first part of this report deals with the methods used by the bureau in the collection and examination of the various mine gases; the latter part discusses the bureau's methods of sampling and examining natural gas.

Jan 1, 1913

By Wilson Blake

This report presents the results of a 7-year Bureau of Mines program to review, revise, and make an effective engineering tool of the microseismic method of determining the stability of rock structures. The program consisted of developing new microseismic equipment and data analysis techniques and extensive field investigations to demonstrate the effectiveness and potential of the broad-band microseismic method. The guidelines for choosing the components of a microseismic system are presented along with approximate cost figures. Different microseismic systems are discussed, including completely automated systems. Procedures for conducting microseismic investigations and analyzing microseismic data are discussed in detail. Field situations which show the full value of the microseismic technique as an engineering tool are described.

Jan 1, 1974

By A. J. Kraemer, H. M. Thorne

The following account of oil-shale operations in Australia is based upon infor- mation obtained by the authors while visiting Australia from September 15 to October 7, 1947, supplemented by published data, and augmented by analyses of samples of oil shale and its products at the Oil-shale Research and Development Laboratories of the Bureau of Mines at Laramie, Wyo. The primary objective of the authors' trip to Australia was to obtain, first hand, information regarding the equipment and methods used by National Oil Proprie- tary, Ltd., at Glen Davis, New South Wales, in mining oil shale, extracting oil from it, and refining the shale oil. This company was operating the only oil-shale plant that had been active in Australia since 1945. The plant comprised an oil-shale mine, 104 modified Pumpherston (Fell) retorts in 2 batteries, a hele refinery, and a 3-inch gusoline pipeline to the railroad loniing terminal t Sun Junction, 30 miles away. There were, also, the usual and necessary any uralities, such as a power house, mechanical shops, offices, and laboratories One Information regarding the company's operations was wance because of its bear- Ing upon the synthetic liquid fuels program of the Bureau of Mines, pursuant to the Synthetic Liquid Fuels Act of April 5, 1944 (30 U.S.C., 321-325, as amended). objective of the Bureau's program. In accordance with the maniate of the Act, is to furnish American industry cost and engineering data necessary for the development of synthetic-liquid fuel industry, and an obvious means of obtaining some of these data is to learn how oil shale is being mined and retorted and how shale oil is re- rined in countries where these operations have been conducted on a plant scale for many years. The authors spent 2 weeks at the plant of National Oil Proprietary, Lt., at Glen Davis, and were afforded every opportunity to obtain letailed and specific information regarding all aspects of the company'a operations.

Jul 1, 1951

By W. K. Tolley

The Bureau of Mines is testing super critical fluids as solvents to selectively extract valuable components from complex matrices. Materials recovered during supercritical fluid extraction are often highly purified. Using laboratory apparatus designed specifically for supercritical fluid research, Bureau re-searchers have measured the solubility of titanium tetrachloride (TiCI4) in supercritical, liquid, and gaseous carbon dioxide (C02), CO2, a commonly used supercritical fluid, is inert, inexpensive, and nontoxic. Supercritical CO2 formed a single phase with TiCl4 at 45° C and 1,500 psig. When the solution was heated at constant pressure beyond 55° C, TiCl4 precipitated from the fluid. Results showed that TiCl4 solubility in supercritical CO2 is not controlled by the vapor pressure of the solute.

Jan 1, 1989

By Erie C. Donaldson

Gas-displacement tests were made in Berea Sandstone and Arbuckle Lime-stone cores to determine the relative permeabilities to gas, oil, and water for two-and three-phase dynamic systems. Three-phase relative permeabilities were obtained by displacing oil and water from the core with gas and measuring the flow rates of the three fluids simultaneously. It was found that relative permeabilities to fluids in a porous medium are affected by the saturation distributions of other fluids in the medium as well as by their own saturation distributions.

Jan 1, 1966

By A. A. Cochran

The objective of the research was to determine the final distribution of cerium additions to steel, their effect on sulfide inclusions, and the usefulness of radiotracer methods in investigating steel problems. Fifty-gram heats of steel were prepared that contained either cerium 141 and nonradioactive sulfur, or sulfur 35 and nonradioactive cerium. These steels were studied by autoradiography, measurements of their surface radioactivities, optical microscopy, and chemical analysis. Samples of the crucibles were analyzed quantitatively for cerium or sulfur by radioactivity counting methods. The addition of cerium to steel melts reduced the size and number of iron sulfide inclusions in the resulting steel. A significant fraction of the sulfur and most of the cerium penetrated into the MgO crucible during the melting operation, The cerium inclusions in steel were identified as cerium sulfide. Radiotracer methods were found to be versatile and highly sensitive.

Jan 1, 1963

By A. Landsberg

Kaolinitic clays are potentially a vast domestic resource for aluminum. Utilization of this resource could decrease or eliminate the nearly complete dependence of the United States on foreign raw materials for this important metal. Furthermore, processing of clay to aluminum through anhydrous chloride metallurgy could reduce the high electrical energy requirements of the conventional Hall-Heroult aluminum reduction process. Several anhydrous chloride processes have been proposed; however, unresolved technical problems have prevented their commercialization. In particular, an acceptable chemical means has not been found to extract aluminum from clay as a highly pure anhydrous aluminum chloride. This Bureau of Mines report identifies and discusses the important chemical problems involved in achieving an acceptably rapid, self-heating, selective chlorination reaction and the subsequent separation of iron chloride byproduct from the anhydrous aluminum chloride.

Jan 1, 1983

By Ronald P. Hollenbeck

Samples of clays, shales, and slates from 29 locations in the Appalachian Region of Alabama and Georgia were tested and evaluated to determine their suitability as raw material for the manufacture of lightweight aggregate by the rotary-kiln method. Samples from 11 locations in Alabama (one each in Etowah, Lawrence, and Morgan Counties and two each in Colbert, Cullman, Tuscaloosa, and Walker Counties) and one location in Walker County; Ga., produced satisfactory lightweight aggregate.

Jan 1, 1969

By Arthur B. Campbell

This Bureau of Mines report describes a method that utilizes a computer program to evaluate integral Gaussian profiles of atomic concentration versus depth in a solid. The specific use illustrated involves profiling ion- implanted metals using proton-induced X-ray emission (PIXE) analysis and ion sputtering (IS) for sectioning

Jan 1, 1979

By C. F. Winquist

The Bureau of Mines is engaged in research to evaluate the effects of cutter bit wear at coal mine faces. This paper addresses one element of conical bit wear, bit rotation. A discussion on mounting configura-tion and bit forces and their effects on rotation is presented. The effects on rotation and bit forces of bit attack angle, cutting depth, and skew are determined for two types of conical bits during linear cutting of sandstone-inclusive rock. The results indicate that a 10° negative skew angle and 35° attack angle produce the maximum rotation of 17.5° for each foot of cutting. Data on bit rotation and bit forces are presented in an appendix.

Jan 1, 1985

By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By J. E. Chilton

The Bureau of Mines has examined the operation of an oxygen sensor manufactured by the City University, London, England. The sensor produces a current proportional to the oxygen concentration by reacting oxygen at a nonconsumable cathode. The sensor design is unique in that the primary mode of oxygen transport to the cathode is by diffusion through a capillary, The sensor using this design has a stability of 0- to 0.02-pct reading change per day over a 4.7-month test, small temperature coefficient of 0.29-pct reading change per °C, and small pressure coefficient of 0.34-pct reading change per 1,000-ft altitude change, If this sensor were incorporated into an oxygen detector or monitor, this would be a distinct improvement in electrochemical-type oxygen analyzers and would be useful to the mining industry.

Jan 1, 1983

By Rena I. Geroyan

This U.S. Bureau of Mines report presents an evaluation of the coal mining industry's impact on the economy of Pike County, KY. A software package called IMPLAN was used to perform the analysis. The results of this study show that coal mining was the primary income producing industry in Pike County in 1990, accounting for about 46% of the county's Total Industry Output, and 21% of the total employment.. Coal production in that year amounted to 29.6 M mt (32.6 M st). Two alternate economic scenarios were developed to study the potential effects of changing coal market conditions on the county. Scenario A assumes market changes result in a coal production increase of 4.5 M mt/yr (5.0 M st/yr), and scenario B assumes a decrease of 4.5 M mt/yr (5.0 M st/yr). Scenario A would result in a 15.3% rise in the value of Pike County's Total Industry Output, adding a total of 1,663 jobs (+6.1%) in all sectors in the county. Scenario B would have the opposite effect, decreasing the Total Industry Output and employment by identical amounts. Such knowledge would allow local and regional officials to anticipate the economic and social impacts of shifts in coal production, and plan accordingly to mitigate impending changes.

Jan 1, 1994

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements on solutions and isolated powders provide direct evidence for the involvement of Cr(V) species in the reduction of Cr(VI) by NAD(P)H. ESR analysis of an isolated Cr(V)NAD( P)H solid yields 6 11 = 1.9831 and 6.i. = 1.9772, indicating that the unpaired electron occupies the d22 orbital of the Cr(V) ion, with square-pyramidal geometry. Addition of hydrogen peroxide (H2 0 2 ) to the N AD(P)HCr( VI) reaction mixtures suppresses the Cr(V) species and generates hydroxyl (""OH) radicals. The ""OH radicals were detected via ESR spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide and a-(4-pyridyl-1- oxide)-N-tert-butylnitrone as spin traps. The dependence of Cr(V) and ""OH radical formation on the H20 2 and Cr(VI) concentrations indicates that the Cr(V) species react with H20 2 to generate the ""OH radicals. Similar results were obtained by using various diols (arabinose, cellobiose, FAD, fructose, glyceraldehyde, ribose, and tartaric acid), a-hydroxycarboxylic acids, and glutathione. Investigations with superoxide dismutase showed no significant participation of 02 in the generation of OH radicals. These results thus indicate that the Cr(V) complexes, produced in the reduction of Cr(VI) by cellular reductants, react with H20 2 to generate ""OH radicals, which might be the initiators of the primary events in the Cr(VI) cytotoxicity.In this paper we report an electron spin resonance (ESR)3 spectroscopic detection of Cr(V) species in the reduction of potassium dichromate, henceforth called Cr(VI), by NAD(P)H and other diols. Also reported here is the detection of the hydroxyl (""OH) radical in the reaction between hydrogen peroxide (H2O 2) and a variety of Cr(V) complexes. This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step m the mechanism of Cr(VI) toxicity, mutagenicity, and DNA alteration, the details are not yet clear (1-5).Earlier studies on the mechanism of Cr(VI) reduction in cellular systems include those on the reduction of chromate by microsomes (6-8), rat liver DT-diaphorase (9), and aldehyde oxidase (10). All these studies imply that Cr(VI) can be reduced to Cr(Ill) by cellular constituents. Regarding the mechanism of Cr(Vl) carcinogenicity, Jennette postulated that Cr(V) is the ultimate carcinogenic form of chromium compounds (8). This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions (11-33). More recently, however, Kawanishi and co-workers (34) have investigated the mechanism of DNA cleavage induced by Cr(VI) in the presence of H20 2 and have argued that it is not Cr(V) itself that is carcinogenic, but it is the reactive oxygenated species (02, 10 2 , ""OH) (produced by the decomposition of the Crv(02) ¾ - ion) that cause the DNA alteration."

Jan 1, 1990