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By Karsten Hagenah, Tor Jensen, Jens Laugesen, Øyvind Fjukmoen, Lucy Brooks

"The methods and technologies to be used for environmental monitoring of seabed mining activities are a key issue. Due to the large water depths, there are special challenges with respect to the monitoring equipment that is suitable. DNV GL has built up substantial experience of environmental monitoring from oil & gas projects in deep waters in the Norwegian Sea.Monitoring equipment and experiences from the oil & gas sector can to a large extent be applied to seabed mining.BackgroundThe International Seabed Authority is currently developing an environmental management strategy for the Area (ISA, 2017) as a part of the work on the regulations for exploitation for mineral resources in the Area.The draft environment strategy contains provisions related to monitoring and reporting of the activities. An Annex (Annex III) of the draft document describes the format and content of the environmental management and monitoring plan.The monitoring plan should contain, inter alia: ?Technology to be deployed.?Monitoring frequency of respective elements/components of the Marine Environment.?Monitoring procedures required to implement the Monitoring programme.?Details of the environmental monitoring stations across the Environmental Impact Area.?Monitoring specifics e.g. water quality; sedimentation rates; sound; plume extent; etc., as well as relevant Environmental Targets.?Monitoring of Mining Discharges.?Processes for Monitoring reviews and Environmental audits."

Jan 1, 2017

By Michael J. Cruickshank

A workshop to examine recovery systems for selected strategic and critical materials in the U.S. National Seabeds for the National Defense Stockpile in the 21st Century was held in Hawaii September 26-28, 1991, sponsored by the National Science Foundation and the Marine Mineral s Technology Center. The National Defense Stockpile of critical and strategic mineral commodities is presently in a deficit position of more than 7.5 billion dollars. Current domestic reserves of some commodities are limited or nonexistent. As defined by the U.S. Bureau of Mines, "Reserves are select resources . . . which at the time of classification, can be mined at a profit." Occurrences of these minerals have been discovered offshore within U.S. jurisdiction. If the technology could be developed to convert these resources into usable ore reserves, our dependence on foreign ores could be greatly reduced. Preliminary estimates indicate that a ten-year program of ore reserves definition, with appropriate technical developments to demonstrate a recovery system, could cost less than half the amount authorized for stockpile acquisition in FY 1989 alone.

Jan 1, 1991

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamaji, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamajim, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By Sup Hong

A pilot mining robot, named MineRo-II, has been developed by KIOST during 2011-2012. The pilot scale was defined as 1/5 of the commercial mining capacity, 1.5 million dry-tons of nodules per year. The development purpose of MineRo-II is to use for the pilot mining test planned in 2015. MineRo-II was designed to be self-propelled by electric-hydraulic power and remotely operated in real-time from aboard. The main operational functions are crawling on seafloor, pick-up and crushing of nodules, discharging nodules out to buffer. Prior to MineRo-II, a test miner (MineRo-I) was developed in scale of 1/20th in 2007, and performed two times sea trials in 2009 and 2010. The results of performance tests were evaluated and utilized for the concept of MineRo-II. The design concept aimed at the expandability of the mining capacity based on modularity of configuration, maintenance simplicity and multiplicity of backup solution. The pilot-scale mining capacity is achieved by four pick-up modules of each 1m wide, which are moving forward with robot vehicle and sweep the nodules entering below the pick-up heads. Principally, by adding the pickup modules in lateral dimension the mining capacity may increase linearly. MineRo-II was designed and constructed in unit-module wise. The robot consists of two unit-modules having an identical mechanical and hydraulic configuration. Each unitmodule has two tracks, two pick-up devices with attitude control devices, two crushers, one discharge pump, and one hydraulic system. Two unit-modules are connected by one loading frame and integrated by electric-electronic system. Two thrusters for control of the

Sep 14, 2011

By V. V. Ivanov, A. I. Khanchuk, E. V. Mikhailik, M. G. Blokhin, P. E. Mikhailik

At present, marine ferromanganese crusts of seamounts are of great interest as a source of high-tech metals. The metals most enriched in these deposits are essential for a wide variety of green-tech, emerging-tech, and energy applications (Hein et al., 2013). There is a grate number data on the content of major and minor metals (thousands analyses). However, information on the content of such elements as platinum, gold and silver in the world literature is limited. The concentrations (N – number of analyses) of platinum, gold and silver in the Pacific are 418 ppb (N = 105), 35 ppb (N = 72), 1.02 ppm (N = 26), respectively, and in the North Pacific Prime Zone - 477 ppb (N = 66), 55 ppb (N = 13), 0.1 ppm (N = 4); in the Atlantic Ocean is 567 ppb (N = 2), 6 ppb (N = 2), 0.20 ppm (N = 18), in the Indian Ocean, 211 ppb (N = 6), 21 ppb (N = 2), 0.37 ppm (N = 9) respectively; (Hein et al., 2013). The northern part of the Pacific is poorly studied in this question. The samples of ferromanganese deposits (FMD) was recovered from the Govorov Guyot (Magellan seamounts), MZh-33 Guyot (Marshall Islands), as well as the Detroit Guyot (Imperor Ridge) and Yomei Guyot (Fe-Mn placer Holes 431 and 431A DSDP, Imperor Ridge).

Jan 1, 2018

By P. E. Halbach

On June 26, 1988, the Jade Hydrothermal Field was discovered in the Okinawa Trough by the German RV Sonne. This research cruise has taken place within the scope of a German-Japanese cooperative project. The Okinawa Trough, located between the Ryukyu Island Chain and the east coast of China, is an active backarc-basin formed by extension within the continental lithosphere. The Ryukyu arc consists of a nonvolcanic outer arc, forming the main island chain and representing compressive highs of the Asian continental margin, and an inner arc with present-day volcanism in its northern part (Sibuet et al. 1988). The valleys and ridges of the trough are cut across by transverse faults, giving rise to younger volcanic intrusions. The Jade Hydrothermal Field was detected in a caldera-like structure. It is. located at about 27°15,0'N and 127°04,5'E with a maxi- mum water depth of about 1650 m. Data of heat flow measurements show a high anomaly in the cauldron basin with values ranging from around 100 to 800 mw/m2 (Halbach et al. 1989). The hydrothermal vent area was discovered in the northern part of the inside northeast slope of the cauldron in a water depth between about 1300 and 1500 m. We identified different varieties of hydrothermal

Jan 1, 1989

Welina mai to the 40th Underwater Mining Institute, UMI 2011 - Marine Minerals: Recent Innovations in Technology. Since the first conference in Milwaukee, Wisconsin in 1970, the UMI Founder Professor Robby Moore always insisted on actively seeking the participation of industry, academia, and government. History has proven the wisdom of this approach, which is probably the key to its survival for so many years. The UMI is very much influenced by the cyclical pressures of the minerals commodity markets. When minerals demand and prices are rising rapidly, industrial participation in the Institute dominates the agenda, and participants share optimistic and aggressive views of the commercial prospects of the day. When metals prices are falling and world economies lethargic, academic experts continue to provide guidance and breakthroughs in the concepts and practices of exploration, technology, and environmental protection. Throughout the ups and downs, government participants provide a stabilizing force with conservative and environmentally sensitive policy statements, patient development efforts with long-term objectives, authoritative resource assessments and, sometimes, much needed regulatory clarity.

Jan 1, 2011

By James R. Hein

Rodriguez Seamount, located 150 km off the central California coast at the base of the continental slope, was studied using the ROV Tiburon aboard MBARI?s R/V Western Flyer, October 13-16, 2003. Fe-Mn crust and rock samples were collected along the SW flank of the seamount at water depths from 700 to 2100 m; bottom-water dissolved oxygen content (O2) and temperature were determined at each sample site. Fifty-three samples of bulk crusts, crust layers, and surface scrapes (~0.5 mm) were analyzed for 59 elements. Data allow for the correlation of crust compositions with precisely known water depths and seawater O2 measured at the actual site of sample collection. This is the first detailed study of Fe-Mn crust compositions in a region of strong continental-margin upwelling. Compared to open-ocean seamount Fe-Mn crusts, Rodriguez crusts have significantly higher (2-6 fold) mean concentrations of Fe (26.9%), Al (1.65%), Si (13.0%), Cr (82 ppm), Th (64 ppm), and Ag (1.7 ppm); and significantly lower (2-8 fold) mean concentrations of Ca, P, Bi, Co, Cu, Ni, Tl, and especially Te (8.2 times lower). All but one Fe/Mn ratio are >1 compared to <1 ratios for open-ocean crusts. O2 contents (0.35-2.03 ml/L) are nearly perfectly corrected with water depth and elements correlated with one are correlated with the other. The Fe-Mn surface scrapes represent 60-450 ka (mean 150 ka) of growth, whereas the dissolved oxygen contents of seawater represent an instant in time. Assuming that the entire sample set was affected uniformly by oceanographic changes, we suggest that correlation of elements with O2 may reflect oceanographic processes. O2 has a negative correlation with P, V, As, Fe, U, Be, Pb, Cr, Mg, Y, Bi, Te, and REEs (except Ce) and a positive correlation with aluminosilicate-hosted elements (Al, K, Rb, Cs). This later relationship is related solely to water depth, indicating that detritus shed down the seamount slopes accumulates in greater abundances in deeper-water crusts. Si/Al ratios indicate that the detritus includes a large component of biosilica produced by upwelling-mediated high productivity. These observations are supported by positive correlations of aluminosilicate-hosted elements with crust growth rates (range 1.2-13.0 mm/Myr). In contrast, other elements (Sr, Co, Mn, Mg, Te, As, Mo, V, W, U, Ti, Ni, REEs, etc.) are negatively correlated with growth rates. Growth rate has a weak positive correlation with O2. These compositional characteristics indicate that even though low-O2 seawater acts as a reservoir for Mn and associated elements and produces slow growth rates, which would allow for the concentration of elements and surface oxidation processes to occur, the high rate of input of detritus and high bioproductivity ameliorate the strong concentration of most metals. This dilution is significantly enhanced by the doubling of FeOOH in the crusts--the main cause of the generally high growth rates compared to open-ocean crusts. The high growth rates limit the oxidation of Co, Tl, and especially Te on the crust surface, which is reflected by their relatively low concentrations. Within the range of oxygen contents measured, O2 has less of an influence on crust chemistry than does the availability and incorporation of FeOOH and detritus.

Jan 1, 2004

By The DY125-33(Leg 2) Science Parties, Chuanshun Li, Xuefa Shi, Bing Li

"The slow-spreading Mid-Atlantic Ridge (MAR), with a length of ~1.26*104km (Bird, 2003), is the longest mid-ocean ridge on this plant. Separated by the large, left-stepping Equatorial fracture zones, it then be divided into two approximately equal-length parts: Northern Mid-Atlantic Ridge (NMAR, ~6292km) with an average spreading rate of 24mm/yr, and Southern Mid-Atlantic Ridge (SMAR, ~6332km) of 33mm/yr (calculated from PB2002 model, Bird, 2003). Previous works (e.g. Fouquet 1997, Hannington et al., 2011) suggest that slow-spreading ridge could support hydrothermal activities and further favorable for the development of extensive seafloor massive sulfide deposits (SMS). Unlike the NMAR for which large part has been explored for SMS (Hannington et al., 2011; Beaulieu et al., 2015), the SMAR is amongst the least hydrothermal explored spreading ridges until now (Haase et al., 2005, Beaulieu et al., 2015), though both of them show significant similarities in terms of spreading rate, ridge morphology, segmentation, etc. (Macdonald et al., 2001, Sandwell et al., 2014, Tucholke et al., 2008).Before this work, several hydrothermal cruises had been to SMAR since British and German programs starting in 2002, some hydrothermal fields, along with systematic geophysical data, were newly investigated, and types of geologic setting that can host hydrothermal activity were firstly identified (e.g. German et al., 2008; Haase et al.,2005; Haase et al.,2009; Devey et al.,2010; Schmidt et al.,2011).."

Jan 1, 2017

By Sang Joon Pak

Deep-sea mineral resources explored by Korea are categorized into mainly three types; manganese nodules, manganese crusts and seafloor massive sulfides. Manganese nodules have high Pt enrichment factors (EF=400, ore/crust ratios). Rare earth oxides (REO) contents from manganese nodules show from 0.037 to 0.302 REO% with mean value of 0.12%. Te and Pt are highly enriched in manganese crusts, displaying EFs of 10800 and 150, respectively. REO contents of manganese crusts are slightly richer than manganese nodules (0.013~0.387 REO%, average = 0.18 REO%). Seafloor massive sulfides deposits are featured by outstanding values of Se (EF=1300) well as In (EF=110). Au (0.8~26.3 g/t) and Ag (0.9~348.0 g/t) are another enrichment metals in SMS, although they belong to precious metals. Rare earth elements of SMS are meaningless as resources but REE are increasing in sediments overlying SMS. Heavy rare earth elements (HREE) from both manganese nodules and manganese crusts are typically higher than ones from land-based REE deposits. HREO grade and their portions of manganese nodules as well as manganese crusts are greatly similar to ion-absorbed type REE deposits in China, implying REE of subsea mineral resources are absorbed in nodules and crusts. Rare metals including REE could be exploited as by-production of commodities such like Ni, Co, Cu and so on. Rare metal resources from manganese nodules and manganese crusts are featured by low-grade and large scale deposits. Therefore rare metals in subsea mineral resources will add its economic values.

Jan 1, 2011

By Peter A. Rona

The recent discovery of the first black smoker-type hydrothermal venting and massive sulfide mineral deposits at a site in the rift valley of the slow-spreading Mid-Atlantic Ridge near latitude 26°N, longitude 45°W (Rona et al., 1986, Nature, 321: 33-37), demonstrates that a complete series of hydrothermal mineral deposit types exists at slow-spreading oceanic ridges (half-rate = 2 cm/y), similar to the series previously known at faster-spreading oceanic ridges (half-rate > 2 cm/y). The largest hydrothermal mineral deposit known at a seafloor spreading center is a stratiform massive sulfide body with bulk dry weight of about 100 x 106 metric tons in the Atlantis II Deep at the slow-spreading axis of the Red Sea. This observation invalidates the concept that size of a hydrothermal deposit is directly proportional to rate of seafloor spreading. Instead, the occurrence, grade and size of a hydrothermal deposit formed at a seafloor spreading center is controlled by anomalous chemical and physical conditions which may occur at extremely localized sites at the full range of spreading rates. The basic hydrothermal process involving subseafloor hydrothermal convection driven by magmatic heat sources appears to be similar at slow- and faster-spreading centers. However, differences exist in the periodicity of magmatic cycles that energize hydrothermal circulation (104 y at slow-spreading centers; 103 y at faster-spreading centers); in the distribution of hydrothermal sites along a spreading axis (estimated 100 km along slow-spreading centers; 10 km along faster-spreading centers); and in residence time

Jan 1, 1986

By Dwight D. Trueblood

The Benthic Impact Experiment (BIE) is designed to address the effects of sediment redeposition prior to the commencement of commercial mining. The experiment is being conducted in collaboration with Russian scientists from the Yuzhmorgeologiya Association aboard the R/V YUZHMORGEOLOGIYA. Sediment resuspension and subsequent redeposition during manganese-nodule mining is predicted to be one of the primary impacts on benthic communities living on the abyssal seafloor. The redeposition thicknesses that will cause significant faunal mortality in the deep sea are unknown. Sediment redeposition could adversely affect abyssal benthic communities through entombment, or through starvation caused by food dilution and obstructed feeding. This spring NOAA conducted the main portion of the BIE experiment, blanketing the experimental area with varying thicknesses of sediment using the Deep Sea Sediment Resuspension System (DSSRS). The DSSRS was conceived by NOAA scientists, designed and built by Williamson and Associates, and is the critical piece of equipment used to generate the controlled sediment redeposition environment on the 4800-m deep abyssal plane. The DSSRS consists of an 1800-kg sled, 4.8 m long, 2.4 m wide, and 2.2 m high. The sled was towed and powered using an 8,000-m, 26-mm single conductor cable having a 3,000 VAC capacity. As the sled was towed across the bottom, mud was ingested through two rear-facing, 45-cm wide intakes using two 7.6-horsepower pumps, and discharged 10 to 20 m above the bottom through two 20-cm diameter riser hoses. Each pump was instrumented with optical backscatter sensors providing real-time information about the discharge concentration.

Jan 1, 1992

By J. Bruce Gemmell

ODP Leg 158 drilled seventeen holes into the active TAG hydrothermal mound and underlying stockwork, 26°N, Mid-Atlantic Ridge. Drilling in five different areas, including a high-temperature black smoker complex and a lower-temperature white smoker vent field, revealed the multi-stage depositional history and character of sub-seafloor mineralization and alteration. The upper portion of the mound consist of massive pyrite and pyrite breccias which are underlain by pyrite-anhydrite breccias and then by quartz-pyrite breccias. Quartz-pyrite breccias grade down into silicified wallrock breccias. Chloritised basalt breccias occur at depths greater than 100 m. Several stages of quartz-pyrite±chalcopyrite veins occur in the stockwork zone and lower portions of the mound, whereas anhydrite±pyrite±chalcopyrite veins occur within the upper parts of the mound. Recovery of unaltered basalt near the edges of the mound has constrained the extent of the stockwork zone to a pipe-like feature 80 meters in diameter. A detailed sulfur isotope investigation of sulfides and sulfates within mound and the underlying stockwork zone has revealed the overall range of sulfide d34S analyses to be 0.35% to 10.27%. Anhydrite has a tight range of d34S values 20.55% to 21.56%. There are distinct differences in d34S values between the different textural types of pyrite (massive sulfide, breccia clasts, disseminations associated with alteration, and veins). The massive sulfide and breccia clasts have a similar distribution of d34S values (6%-8%), however the d34S values of the disseminated pyrite associated with the alteration are distinctly heavier (8%-10%). Vein sulfides have the lightest d34S values (5%-7%). Sulphur-isotope values at TAG are, in general, the heaviest reported for unsedimented mid-ocean ridge deposits.

Jan 1, 1998

By Fernando JAS Barriga

The world-class Neves-Corvo deposits were intersected by drilling in 1977. They occur in the (Carboniferous) Iberian Pyrite Belt (IPB), Western Europe&apos;s largest stock of base metals (see Bamga, 1990, in Dallmeyer RD, & Martinez E, eds, Pre-Mesozoic Geology of Iberia, Springer-Verlag). Massive and stringer sulfides in the area sum up to about 200 Mt (109 kg), in five main orebodies (Neves, Corvo, Graca, Zambujal and Lombador). They include unique, extremely high grade copper and tin ores ( - 33 Mt Cu ores, -7.5% Cu, and -4 Mt Sn ores, -2.6% Sn, - 12.5% Cu). Also present are -50 Mt polimetallic ores (-6% Zn, 1.2% Pb, 64 ppm Ag). The remaining are relatively low grade pyritic massive and stringer sulfides (Cu < 2%. Sn < 1%, Zn equivalent < 4%). The geological setting is one of bymodal submarine volcanism, with predominant felsic, explosive volcanism and associated sedimentation (detrital and chemical), which took place on a shelf-facies, quartzite-phyllite basement (of Upper Devonian age). The plate tectonic setting has been the object of much debate. Current interpretations favour that the IPB volcanism took place in a tensional fore-arc region, associated with oblique subduction and collision (Silva et al., 1990, same volume as above). At Neves-Corvo there are many different ores, that may be grouped in four main types: fissural (at the base), breccia, massive (intermediate) and "ruban6 " (at the top). Fissural ores seem to correspond to stockworks in contrasting types of host rocks (gray to black shale, sericitic, chloritic and graphitic, and light gray volcanic rock). Massive ore may contain significant shaly gangue, at the base of individual orebodies, and silica-rich (cherty) varieties towards the top. The more sulfide-rich varieties predominate, and are usually well banded.

Jan 1, 1993

By Jelena Milinovic, Sofia Martins, Anna Lichtschlag, Sven Petersen, Fernando J. A. S. Barriga, Bramley Murton, Adeline Dutrieux

"The active TAG hydrothermal mound is one of the largest and better studied. Due to its size (one of the largest, known so far, in the Atlantic Ocean) and concentration of specific economic valuable elements, it might be considered for future exploitation due the increasing demand for raw materials. However, the discovery of several large inactive sulfide mounds, some partially buried under sediments may relieve this pressure. Exploration for such occurrences can, together with geophysical exploration tools, be accomplished by mineralogical and geochemical studies of those sediments.INTRODUCTION AND GEOLOGICAL SETTINGThis study reports the results from sediment samples collected during the Meteor M127 cruise on the TAG hydrothermal area in 2016. The Trans-Atlantic Geotraverse (TAG) hydrothermal field (Mid-Atlantic Ridge, 26°08’N) is located 2.4 km east of the main rift valley at depths of about 3650 m. The TAG hydrothermal field stands as an example of a massive sulfide deposit on a low-spreading ridge associated with an active detachment fault (Humphris et al., 2015).Associated with the TAG hydrothermal field are metalliferous sediments/deposits that can reach several meters in thickness (Metz et al., 1988). These sediments/deposits can be formed by hydrothermal plume fall out (buoyant and nonbuoyant), massive wasting of hydrothermal edifices (sulfide mounds and chimneys) and authigenic mineralization (Gurvich, 2006). By studying the grain size, mineralogy and geochemistry of the sediments it is possible to identify each type of sediments and find their proximal or distal distribution. The location of the gravity cores studied here is distributed along sediment ponds near inactive hydrothermal mounds [Three mounds area (B)], actively venting low-temperature mound [Shimmering mound (A) and Mir zone (D)] and an area of sediment accumulation [Central area (C)] (Rona et al., 1993) (see Figure 1)."

Jan 1, 2017

By Peter A. Rona

The Mid-Atlantic Ridge in the central North Atlantic and the Gorda Ridge within the U.S. Exclusive Economic Zone off northern California and southern Oregon are yielding new discoveries of seafloor hydrothermal mineralization. The TAG hydrothermal field in the rift valley of the Mid-Atlantic Ridge near 26 degree N, 45 degree W has been a site of international collaborative research since the discovery there of extensive manganese deposits associated with low temperature hydrothermal activity in 1973 as part of the TAG (Trans-Atlantic Geotraverse Project). The first high-temperature hydrothermal activity, massive sulfide deposits and vent biota discovered in the Atlantic were found at the TAG hydrothermal field in 1985. Collaborative dive series with DSV ALVIN in 1990 and in 1991 with the two Russian MIR submersibles in the TAG field have found and sampled large inactive sulfide mounds in addition to the previously known active sulfide mound. The active sulfide mound on the floor of the rift valley is about 250 m in diameter and 40 m high with a concentric zonation of mineral types and flow regimes decreasing in temperature from 365 degree C black smokers at the center to white smokers and diffuse flow toward the margins. The recent dive series in coordination deep-towed instrument surveys have delineated a zone extending about 5 km along the lower east wall of the rift valley of inactive sulfide mounds up to a kilometer in diameter. MIR Mound in this zone consists of a central sulfide zone about 400 m in diameter and 50 m high surrounded by a halo of low-temperature deposits to 200 m wide. Inactive sulfide chimneys contain the first primary, free gold grains found at a hydrothermal site on a mid-ocean ridge (P.A. Rona, Y.A. Bogdanov, E.G. Gurvich, N.A. Rimski-Korsakov, A.M. Sagalevitch and M. D. Hannington, 199 1 EOS, Transactions, American Geophysical Union, 72:470-471 and Journal of Geophysical Research, submitted).

Jan 1, 1992

By Roger Amato

The 1982 United Nations Convention on the Low of the Sea includes provisions under Article 76 for extending a coastal State&apos;s jurisdiction beyond the 200-nautical-mile (nm) Exclusive Economic Zone (EEZ) and for establishing the seaward limits of sovereign rights over natural resources. Article 76 prescribes a set of methodologies for determining these outer limits based on physiography and sediment thickness. The methodologies were applied to each of the five continental* margin areas of the United States - Atlantic, Pacific, Gulf of Mexico, Alaska, and Pacific Islands-using existing digital hydrographic and geologic data. Figures 1 and 2 show the results of applying the methodologies to the Atlantic, Pacific, Alaskan, and Gulf of Mexico continental shelves. Figure 1 depicts the preliminary limits of each of the Article 76 determinations for the Atlantic and Gulf of Mexico continental shelves. The Atlantic limits were described by Carpenter, Thormahlen, and Amato (1995) at the 26th Underwater Mining Institute.1 The limits for the Alaskan continental shelves are shown in Figure 2. Additional areas beyond the 200 nm EEZ are highlighted. These include a small area north of the U.S. - Canada boundary, containing 7,000 km2, a large area north of Point barrow (395,000 km2), and a third area north of the Aleutian Islands (178,000 km2). The shelf between the first two areas appears to have sediments thick enough to qualify for the 1 percent method (Irish Formula); however, year-round ice cover has prevented acquisition of seismic or drill data. The entire northern Alaska shelf is prospective for petroleum The Gulf of Mexico (Figure 1) has two small areas beyond the EEZ known as "doughnut holes." One is south of Louisiana and includes part of the Sigsbee Escarpment, an area believed to have potential for oil and gas. Oil was found on Sigsbee Knoll in cores from Deep Sea Drilling Project&apos;s Leg 1 cruise in 1968. The Sigsbee areas contains about 6,000 km2. The second area is south of the Florida panhandle and contains about 12,000 km2.

Jan 1, 1996

By Natalia Konstantinova, Kira Mizell, James R. Hein, Georgy Cherkashov, Amy Gartman, Pavel Mikhailik

INTRODUCTION Ferromanganese (FeMn) crusts from Mendeleev Ridge, Chukchi Borderland, and Alpha Ridge, in the Amerasia Basin, Arctic Ocean, are similar based on morphology and chemical composition. The crusts are characterized by two- to four-layered stratigraphy. The chemical composition of the Arctic crusts differs significantly from hydrogenetic crusts from the North Pacific Prime Zone (PCZ; Hein et al., 2013), such as a high mean Fe/Mn ratio (2.6 versus 1.3) and low Si/Al ratio (1.8 versus 4.0), with lower Mn, Ca, Ti, P, Ba, Co, Cu, Ni, Pb, Sr, and Zn and higher Si, Al, Mg, As, Li, V, Sc, and Th. Based on Arctic FeMn crust mineralogy, chemical composition, and growth rates, crust formation was dominated by three processes: Precipitation of Fe-Mn (oxyhydr)oxides from ambient ocean water, sorption of metals by the Fe and Mn phases, and fluctuating but large inputs of terrigenous debris (Konstantinova et al., 2017; Hein et al., 2017). The Mn and Fe phases are hydrogenous and reflect bottom ocean-water chemistry and the aluminosilicate phase contains stable detrital minerals such as quartz, feldspars, zircon, monazite, and clay minerals. A precise method of studying the distribution of elements in FeMn crust phases is sequential leaching that dissolves four mineral phases of different stability step-by-step, in the following order: easily leachable phase, mostly bio-calcite; manganese oxides; iron oxyhydroxides; and residual aluminosilicate minerals (Koschinsky and Halbach, 1995). Twelve bulk crusts and crust layer samples obtained from six hydrogenous FeMn crusts were studied. Those crusts were collected during Russian (Arktika 2012) and USA (HLY0805, HLY0905, and HLY1202) research cruises from different parts of the Amerasia Basin (Mendeleev and Alpha Ridges, Chukchi Borderland). Samples were chosen for the sequential leaching experiments based on their morphology, location, and water depth. Hydrogenetic crust (D07-33) from the Tuvalu EEZ, central-west Pacific Ocean, was included in the experiment for comparison. Recovery during the four-step sequential leaching, with respect to the bulk analyses, was between 80% and 120%.

Jan 1, 2018

By Sofia Martins, Anna Lichtschlag, Sven Petersen, Fernando Barriga, Bramley Murton, Adeline Dutrieux

"Sediments in the vicinity of the hydrothermal seafloor massive sulphide (SMS) mounds are characterized by high concentration of metallic particles. They result from a long process of weathering of the primary mineral deposits and have been accumulated in depressions by mass wasting and hydrothermal plume fall-out. We present here the first results obtained on pore waters analyses of such sediments in distinct geological seafloor environments (in low-temperature hydrothermally active zones, on extinct hydrothermal mounds and in a remote depositional channel). Vertical concentration profiles suggest that the pore fluid composition is affected more by seawater circulation compared with hydrothermal fluid flow in all environments. The composition of pore fluids is affected by diagenesis and redox processes in the distal depositional channel where Mn2+ is released at depth with Cu2+.IntroductionMarine hydrothermal fields, hosting seafloor massive sulphides, are potential resources for future deep-sea mining and might become economic reserves for the industries. They are widespread at mid-oceanic ridges, arcs and back-arc spreading centers (Hannington et al., 2011; German et al., 2016). Sediments in the vicinity of these fields can contain unusually high concentration of Fe, Mn, Zn and Cu among other metal elements (Shearme et al., 1983). These hydrothermal, or metalliferous, sediments result from a combination of processes such as collapsing and weathering of chimney material, filling of the channels by turbidite-like mass wasting, in situ authigenic mineralization and hydrothermal plume fall-out (Goulding et al., 1998; German et al., 1990). The sediments contain important indicators reflecting the development of the hydrothermal systems. Because of their widespread distribution and metal content, they themselves can be considered potential mineral resources. Circulation of seawater through these deposits, however, often modifies the sediment composition by oxidizing the sulphides into oxyhydroxides and clays causing mobilization of the metals. To address the importance of alteration and diagenesis of these hydrothermal sediments, including the result of seawater circulation, we investigated the post-depositional processes occurring in the hydrothermal sediments at the TAG Hydrothermal Field (Mid-Atlantic Ridge, 26°N), focusing on the mobility of metallic cations in a number of different seafloor environments."

Jan 1, 2017