Search Documents

By M. J. Kahn

A new Scramble has hit the African continent. This Scramble has many drivers: the 1978 Deng Xiao Ping liberalizations in China; the 1989 collapse of the Soviet empire; the ICT revolution; the ease of global communications. The underlying dynamic is the end of the bipolar world of the Cold War and its replacement with multipolarity. According to HSBC (2011), in 2050 China will be the world?s largest economy, with India number 3 and Brazil number 7. Russia will be 15th (below its old rival, Turkey). South Africa maybe ranked 30th, yet has been invited to join the exclusive (BRIC) club. One has to ask, why? It is sad to note how low South Africa is assessed to be?currently it is around number 24 in the world; the reason for the fall is that the HSBC model includes population growth, and it is in this domain that South Africa is a loser, being constrained by the impact of HIV/AIDS on its life expectancy. The original four BRIC nations include the factory of the world (China), the garden of the world (Brazil), the gas station of the world (Russia), and the back office of the world (India). South Africa comes to the club both as jeweller of the world and as gatekeeper. China, Brazil, and Russia all have considerable expertise in mining exploration, extraction, and processing.

Jan 1, 2011

By M. S. Janssen, J. L. Taylor, M. A. Ford, E. B. Viljoen, H. A. Simonsen

The Stilfontein and Buffelsfontein Gold Mines, near Klerksdorp in the Transvaal, had accumulated a large amount of uranium-containing residue and, when the price of uranium rose in the 1970s, consideration was given to the possible recovery of this uranium. Preliminary tests showed that concentration of the uranium prior to leaching would not be economic. However, the pyrite in the residue could be concentrated by flotation, and the flotation concentrate could be roasted to pro¬vide both enough acid for leaching the uranium and a calcine from which the gold could be recovered. The feasibility study showed that a uranium operation of 270 kt per month would be most economically attrac¬tive, and a plant of that size was accordingly designed and built. In the first six years of its existence, the plant treated over 20 Mt of residue and produced about 3,5 kt of uranium oxide. During that time, the plant was con¬tinually being improved to make it more reliable and cost-efficient. This paper analyses the operation of the plant during its first six years from the viewpoints of its mechanical, process, and economic performance. The criteria on which the selection of the process was based are reviewed and compared with the actual performance of the plant, emphasis being placed on the leaching, solid-liquid separation, recovery, and purification stages.

Jan 1, 1987

By J. W. Wilson, J. G. Taylor

The mechanization of haulage drilling in the gold mines of Anglo American Corporation by J. w. WILSON, Ph. D., C.Eng., M.AIME, F.!.Min.E., F.I.M.M. (Fellow), and J. G. TAYLOR, A.C.S.M., C.Eng., M.!.M.M. (Visitor) Some one-thousand kilometres of tunnels are mined annually in the gold mines of South Africa. Until two years ago, mechanized drilling on South African gold mines was not an economic proposition because of the availability of inexpensive labour and the fact that mechanized equipment developed for other mining markets could not perform satisfactorily in the tough, abrasive quartzites of theWitwatersrand System. A project team from the Technical Development Services Organisation of the Anglo American Corporation, in collaboration with various manufac turers of drill rigs and drill steel, has been concerned with the development of suitable equipment for mechanized main-haulage drilling. After two-and-a-half years of extensive testing and development of drifters, drill steels, and bits, many of the problems encountered have been sotved, and gradually jumbos mounting pneumatically and hydraulically powered drifters are being phased into production on various gold mines of the Group. A description of the development work is given, and actual operating results are recorded, together with details of the drilling and blasting techniques used.

Jan 1, 1975

By H. Rosenberg

Haldor Topsoe A/S has developed its WSA technology to meet the demand in the market for a simple and reliable process that converts sulphurous emissions from off-gasses into high-grade sulphuric acid. With more than 50 references in 25 countries, the WSA technology has proven its ability to generate acid at 98% concentration, efficiently and economically. The wet gas sulphuric acid (WSA) technology treats the furnace off-gas directly from upstream gas cleaning plants. No further drying is required, since the humidity present in the off-gas is used to hydrate the SO3generated in the converter and produce sulphuric acid. The heat generated during the oxidation, hydration and condensation processes is principally reused in the process to preheat the off-gas to the required temperature level, and also to generate high pressure superheated steam for process use. This advantage of steam production, coupled with lower water and power consumption requirements, is particularly important in the African production environment. Having fewer process components than conventional acid plants, the WSA technology is a simple and compact operation, which makes it easier to retrofit into an existing smelter plant. Further, the WSA technology simultaneously offers the possibility to treat multiple gas streams arising within the production facility due to superior flexibility in terms of SO2concentration and turndown ratio.

Jan 1, 2006

Branch Minutes of the General Meeting held at President Steyn Gold Mine canteen on Wednesday, 10th May, 1978, at 4.00 p.m. Erratum We apologize to Mr J. G. Taylor for the error in one of his qualifications. Bio-engineering monograph The selection of papers presented at the International Bio-engineering Conference at the University of Cape Town organized by the South African Institution of Mechanical Engineers and held in April 1977, and which are appearing in The South African Mechanic al Engineer during April to June this year, will shortly be available in book form. Mathematics The Institute of Mathematics and Its Applications is planning the following conferences and symposia: The Nand F Proposals in Relation to Mathematics, 1st July, 1978: London School of Pharmacy. NIM reports Report no. 1917 The instrumental neutron-activation analysis of granites from the Bushveld Complex. (31st Mar., 1978.) Report no. 1951 Potentialities and limitations of four-parameter equations for the correlation of formation constants of metal-ion complexes in aqueous solution.(15th May, 1978.) Report no. 1963 An evaluation of the methods used at the National Institute for Metallurgy for the analysis of base-metal concentrates. (28th Apr., 1978.) Report no. 1964 The separation, by anion exchange, of noble metals on substituted cellulose. (28th Apr., 1978.) Guide To The Preparation Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal.

Jan 1, 1978

By R. G. B. Pickering, B. Ebner

The hard rock gold and platinum mines in South Africa have seen little development in the technology of mining. Holes are still drilled in the rock—though the latest water hydraulic rockdrills will complete that task in two minutes compared with the eight hours for hand drilling. Charging up is with far safer explosives and with available initiation systems it is no longer necessary to run up the face lighting each fuse. Movement of rock in the stope is predominantly by means of scraper buckets and scraper winches — these were first introduced in the 1920s.Support is still mainly rock, either in sit pillars or backfill, or alternatively wood. Just as themining process has changed very little it is hardly surprising that the productivity of mining is also relatively unchanged. Major efforts have been made to mechanize the mining process. However, most of the narrow reef mines where ‘trackless mechanized mining’ was introduced in the early 1980s have reverted to conventional mining. In the wider reefs mechanized mining is the option of choice, unfortunately most of the gold and platinum mines have very narrow reefs that are not suitable to’ off the shelf’ equipment. The move to introduce room-and-pillar mining into the narrow UG2reefs is at the expense of mining more waste with the reef, fortunately it appears that appropriate waste and reef separation processes are available. Room-and-pillar mining followed by long holedrilling and blasting of a narrow slot of reef out of the pillars currently appears to offer the best of both worlds—maximum reef recovery with minimum waste dilution. All these mining methods are still dependent on blasting to break the rock. The cyclic nature of mining by blasting places severe constraints on the rate of face advance that can be achieved and consequently the utilization of the invested capital. For narrow reef hard rock mining to break out of these constraints and to really make progress in the 21st century it is necessary to follow the lead of the soft rock mining industry and change the technology of mining. In the underground coal mining industry, coal cutting has been proved to be the most cost-effective solution. In narrow reef hard rock mining the future must be based on the development of non-explosive methods of rock breaking that in turn are integrated into continuous mining systems. Non-explosive so that the mining operation can be conducted on a continuous basis, with nodelays for the removal of blasting fumes. Continuous mining also maximizes the return on the capital invested in developing the mine. Rock cutting will define the stope width and that in turn will be designed to minimize waste dilution; it will also minimize damage to the hanging and create a safer environment. Mechanization makes it possible to automate the mining process and further improve safety by positioning the operators in a safer environment. This paper defines the work to evaluate cutting processes carried out by Sandvik TamrockVoest Alpine. The evaluation was in the UG2 and the pyroxenite and norite typical of the Merensky Platinum Reefs. A novel form of mining machine is proposed that will utilize existing technology. Finally the paper describes the interaction between Sandvik Tamrock Voest Alpineand Lonmin Platinum and the initiation of an agreement to develop and trial a prototype hard rock narrow reef mining machine.

Sep 1, 2001

By D. G. Millenbruch

An account is given of a four-phase system for the appraisal of a mineral project while it is still in the exploration stage, and for continual consideration of a favourable appraisal until the production stage is reached. There are ten stages from the idea of a likely project to the production stage, and all the staff that are eventually to be concerned with the development of the project are involved at an early stage.

Jan 1, 1979

By D. G. Wymer, A. G. du Plessis, N. C. Joughin

The use of a dense hangingwal-support configuration extending right up to the face would enable greater levels of safety and productivity to be achieved in stopes, and becomes a practical proposition if water jets are used for stope cleaning. Such an arrangement opens the way for extending the use of water hydraulic power to the whole stoping operation. This, in turn, can provide further productivity benefits and significant savings in working costs. With al the necessary equipment being available, such a system could be introduced immediately, although the designs of props and rockdrills are not yet ideal.

Jan 1, 1989

This paper describes the extraction of gold, as the anionic aurocyanide complex, from solution by strong- and weakbase anion-exchange resins. The effects, on the rate of extraction and the loading capacity for gold, of parameters such as pH, temperature, ionic strength, agitation, and the presence of competing anions are reported. The elution and regeneration of strong- and weak-base resins will be examined in a second paper. A third paper in this series will present the results of several smallscale pilot-plant investigations carried out with strong- and weakbase resins In cyanide pulps from various South African gold mines, and will compare the metallurgical performance of resin-In-pulp with that of the carbon-in-pulp process.

Jan 1, 1984

By I. Wigden

This paper discusses system integration and installation of High-Tec systems in underground mines. ABB has the capability to be a System Integrator and co-operates with partners in different areas of technology. Today it is difficult to find one Company that is responsible for the complete Automation System. The design of the system is also dependent on the caving procedure that is currently being used in mines. Most of the engineering must be done during the feasibility study and the design phase. Any mistakes made during these phases will be costly to rectify in the commissioning phase. The paper will also include a presentation of the benefit of using Automation in an Underground Mine, and the importance of integration with the people component. Most of the experience and discussions in this paper are from different technologies that have been developed in Scandinavia and adopted from LKAB in Kiruna. The author of this paper was responsible for the Automation projects in Kiruna Mine during1994 - 1999. These projects include: • Broadband communication of data, audio and compressed video in one data stream. • Control System for Haulage -1045m • Automation of Load Haulage and Dumping machines (LHD) • Control of Production Drilling Rigs from a Central Control Room.

Sep 1, 2001

By D. Gregurek

The complexity of metallurgical processes in the non-ferrous metals industry. especially changes in the process conditions in combination with a diversity of metal processing furnaces, requires a precise knowledge of the system for the selection of refractory products. However, particular importance is still focused on the specific refractory consumption being as low as possible. The addition of recycling material with a high amount of impurities and the increase of low-grade ore concentrates used in the base-metals industry also entails a significant change of slag chemistries, process temperatures, etc., which influence the performance of already approved linings. This acknowledgement of process changes with decreased brick lifetimes provided the motivation for RHI AG to develop high-performance refractory bricks especially for non-ferrous metals applications. The internal laboratory tests with fayalitic slag showed very promising results compared with our approved magnesia-chromite bricks for this application. In order to identify suitable refractory products and to improve the life of the refractory lining, innovative product development has to be undertaken. In addition, the practical corrosion testing methods and facilities available within the RHI Technology Center, such as the induction furnace and the rotary kiln test equipment, allows the best possible understanding of brick wear at a laboratory scale. Based on the results of the test work, the optimal refractory solution can be recommended for a field trial at the customer?s site.

Jan 1, 2012

By D. Hanekom

Over the past couple of years, Anglo Platinum has made extensive use of technology within the core disciplines (geology, evaluation, survey, and planning) that collectively form part of mineral resource management (MRM). While these technologies were primarily developed to enable geology, evaluation, survey, and planning to carry out their daily tasks, with the main objective of supporting the mine?s production effort, they have also enhanced the disciplines? ability to produce the required outputs within the annual business planning cycle. Anglo Platinum has developed a very comprehensive business planning process, and these technologies play a vital role in enabling both the quality and quantity of inputs into the process, and also the value-add of the final product. This prompted a question regarding the practical application of the CADSMine software. If we changed our thinking in how we applied the software, would it be possible to further improve on the time taken to deliver a business plan? In changing the current planning approach, would we be able to further simplify the process? Is there a way to reduce the data generated in order to enhance the time taken to do reporting, as the CADSMine software is totally network dependent? Less data should equal faster reporting. This paper focuses on the practical application of the CADSMine software, and demonstrates the value-add to the business planning process that can be gained if the mine design methodology is changed from individual panels to bigger blocks representing a raise line.

Jan 1, 2012

By S. Curry

The Objana Cement Plant is located in central Nigeria, approximately 200km south of capital city Abuja (figure 1). It is the second largest cement plant in Africa, and the fifth largest in the world [1]. The selected mining location is unique as it has all the major raw materials (except gypsum) in close proximity. This includes limestone, clay, marl, laterite soil, and laterite iron. [ ] The plant has a capacity of 5 million metric tones per year (~15,000 tones per day). A 135 megawatt gas-fired power plant, with 90 km of natural gas pipeline, was constructed to power the plant. The total project cost is approximately 1.2 billion US dollars. The lifeline of the plant is two overland conveys totalling 7.7km in length. The first 800m conveyor is relatively mundane. The second conveyor however, is unlike any other troughed belt conveyor in the world. It 6.9km length transports 2,400 T/H and operates at 5.0 m/s. Its ?snake? profile consists of 11 vertical cuvees, and four horizontal curves. The last of which is 2,000m in radius, has a length of 2.2km, and is located at the high tension head end of the conveyor. Although these specifications are noteworthy, the unique feature of this system is that it is entirely elevated from head to tail using a triangulated truss gantry structure (figure 2).

Jan 1, 2008

By S. M. Bradshaw

In order to assess the requirements for online matching when using a transverse electric field (E-field) applicator to treat mineral ores continuously, the effect of varying load properties on matching has been investigated by simulation. The effective permittivity of the ore to be treated is expected to show variation on both short (< 1 s ) and long (minutes) time scales. By modelling the ore as a series of slices with alternating effective permittivity values, it was shown that permittivity variations on the scale of the expected particle size are attenuated significantly and matching is not required. For variations in permittivity on the length scale of the free-space wavelength, variations in reflected power are at most within ±10% of the mean. This is not considered operationally significant, as extreme permittivity variation over this length scale is unlikely, given the expected distribution of ore particle sizes to be treated. At typical ore transport speeds through the applicator, these variations occur on a time scale an order of magnitude shorter than the response time of typical industrial online matching equipment. This implies that online matching is neither required nor possible for short time scale variation. Long-term variations in dielectric properties can be adequately compensated for by current matching technologies. It is concluded that the transverse E-field applicator is robust to changes in the dielectric properties of crushed ores within the expected range of their variation.

Jan 1, 2012

To the members of The South African Institute of Mining and Metallurgy I have audited the annual financial statements of The South African Institute of Mining and Metallurgy set out on pages 641 to 644 for the year ended 30 June 2006. These annual financial statements are the responsibility of the Institute?s Council members. My responsibility is to express an opinion on these annual financial statements based on my audit. Scope I conducted my audit in accordance with International Standards on Auditing. Those standards require that I plan and perform the audit to obtain reasonable assurance about whether the annual financial statements are free of material misstatement. An audit includes: ?examining, on a test basis, evidence supporting the amounts and disclosures in the annual financial statements, ?assessing the accounting policies used and significant estimates made by management, and ?evaluating the overall financial statement presentation. I believe that my audit provides a reasonable basis for my opinion. Audit opinion In my opinion, the annual financial statements present fairly, in all material respects, the financial position of the Institute at 30 June 2006 and the results of its operations and cash flows for the year then ended in accordance with generally accepted accounting practice appropriate to the Institute. Supplementary information The supplementary schedule does not form part of the annual financial statements and is presented as additional information. I have not audited this schedule and accordingly do not express an opinion on it.

Jan 1, 2006

Actual observations of rockburst damage, together with some theoretical considerations, strongly suggest that conventional approaches to the design of tunnel support are inappropriate where there is a significant seismic risk. The present widely used support systems, which are based on stiff, fully grouted re-bars, are inadequate where rock displacement velocities exceed 1 m/s. It is shown by means of a simple conceptual model that yielding of the support elements is essential to ensure their survival when they are subject to the high strain rates typical of severe rockbursts. The model proposes that the total load in the element is an impulsive tensile force imposed and sustained by a single &apos;tributary&apos; block ejected from the tunnel wall. The stability of the system is determined from a comparison of the kinetic energy developed by the block with the energy of deformation absorbed by a grouted steel tendon. A novel test procedure was developed for the validation of this approach, and for an examination of the energy-absorbing capacity of stiff and yielding tendons. The results of an initial series of tests showed that the recently developed cone-bolt is an effective yielding device. It absorbs twenty times more impulsive-load energy than is consumed by the complete fracture of grouted re-bar of equivalent strength, and it remains totally unscathed. Importantly, the results demonstrate that the ejection model is not merely an explanatory concept, but can be used as a representative and valid design method.

Jan 1, 1994

The following comment has been received from Mr A. D. Osche* on the above paper, which was published in the Journal in October 1977 (vol. 78, no. 3, pp. 51-62). Obituary: T. K. Prentice The Institute records with deep regret the death on 30th January of its senior surviving Past President, Mr Thomas Kennedy Prentice, at the age of 83. Book reviews R. A. Rich, H. D. Holland, and U. Petersen. Hydrothermal uranium deposits. (Developments in Economic Geology, vol. 6). Amsterdam, Elsevier Scientific Publishing Co., 264 pp. with 77 illustrations and diagrams, 30 tables. U.S. $34,75. M. David. Geostatistical ore reserve estimation. Amsterdam, Elsevier Publishing Company, 1977. 364 pp. World mineral industry The Australasian Institute of Mining and Metallurgy is celebrating its sesquicentenary in 1979. A conference will be held in Perth from 13th to 18th August, 1979, as part of the celebrations, the theme being &apos;Australia&apos;s Role in the World Mineral Industry&apos;. Engineering teaching staff UNESCO has extended its technical assistance to the Venezuelan government in the training of engineers to suit the rapidly developing economy of the country. UNESCO vacancy Vacancy for a post of expert under the UNDP. (1) Title of post: Expert in metallurgical engineering. (2) Duty station: Instituto Universitario Politecnico of Ciudad Guyana (Venezuela). Shell Design Awards The annual Shell Design Awards, organized by the Design Institute and sponsored by Shell South Africa (Pty) Ltd, focus attention on achievements in South African design.

Jan 1, 1978

Council and Standing Committees, 1977-1978 President: P. A. von Wielligh. Vice-Presidents: Dr M. G. Atmore and D. A. Viljoen. Honorary Treasurer: J. K. E. Douglas. Immediate Past President, Dr M. D. G. Salamon. Members of Council: J. D. Austin, A. N. Brown, A. A. Hazell, Dr P. R. Jochens, Prof. R. P. King, Dr D. G. Krige, Prof. F. Q. P. Leiding, D. G. Malan, J. C. Mostert, H. G. M. Rose, W. T. Ruhmer, A. A. Sealey, R. A. von Maltitz. Chairman, Witbank-Middelburg Branch: T. S. Wilmot. Chairman, Orange Free State-Klerksdorp Branch: A. N. Shand. Past Presidents Serving on Council: R. J. Adamson, H. Britten, J. K. E. Douglas, Prof. D. D. Howat, Dr J. P. Hugo, D. G. Maxwell, Prof. R. P. Plowman, Dr R. E. Robinson, P. W. J. van Rensburg. Standing Committee Chairmen: Membership, D. A. Vil¬joen; Technical Programme - Metallurgy, Dr P. R. Jochens ; Technical Programme - Mining, Dr D. K. Krige ; Vacation School - Metallurgy, Prof. R. P. King ; Vacation School - Mining, Dr M. D. G. Salamon; Awards, Dr M. D. G. Salamon; Excursions, Dr M. G. Atmore; Adjudication, Dr M. D. G. Salamon; Consti¬tution, Rules, and Policy, Dr M. D. G. Salamon; Mines and Works, P. A. von Wielligh ; Education, Dr M. D. G. Salamon; Monograph Series, Dr R. E. Robinson; Phoenix National Committee, Dr R. E. Robinson ; Pyrometallurgical Discussion Group Convenor, Dr J. B. See/Dr D. I. Ossin.

Jan 1, 1979

By A. M. Starfield

Discussion J. de V. Lambrechts (Fellow): The author&apos;s paper is a brilliant follow-up of an earlier paper by Starfield and Dickson.1 I have no quarrel with Dr Starfield&apos;s computerization of a complex problem, but I do not believe that he is getting quite the right answers from his programme. My impression is that his predictions about wet bulb temperature increases in very deep mines are over optimistic; in other words, that it will be hotter than Dr Starfield predicts. This is putting my views in a nutshell. This is not the occasion on which to indulge in lengthy argument about the original paper by Starfield and Dickson, but the present paper is, after all, based directly on that earlier paper and if the one fails, the other cannot succeed. I did level certain criticisms at the first paper and cannot say that the authors&apos; replies were very convincing. I do not think it is a sin to admit that I belong to the old school which believes in thorough field experimentation and practical trials and no amount of mathematical manipulation or physical theorizing, no matter how excellent, can make up for inadequate practical confirmation. This, as I see it, is still the crux of the matter. The original paper by Starfield and Dickson still rests on somewhat scanty practical evidence and I would be much happier if Dr Starfield&apos;s computer programme, based on the Starfield-Dickson model, had been checked against a large mass of observations in the practical mining situation. This is what both Wiles2 and myself3 had tried to do previously. What we lacked in mathematics and/or computer aids, I think the present paper by Dr Starfield lacks in practical substantiation. This is no condemnation of the author&apos;s paper which, taken by itself, is excellent but I think the final stage is still lacking, namely the bringing together of theory and empiricism in a manner acceptable to all. This may be wishful thinking on my part but I hope, within the next year or so, to come up with a modified Starfield-Dickson model in such a way that the computer answers will agree in the majority of cases with the few hundred field observations which are already on record. It might be a case of applying the proverbial &apos;Cook&apos;s Law&apos; to the Starfield-Dickson model! REFERENCES 1. STARFIELD, A. M., and DICKSON,A. J. &apos;A study of heat transfer and moisture pick-up in mine airways.&apos; J. S. Air. Inst. Min. Metall., 68, (5), 1967. 2. WILES, G. G. &apos;Wet bulb temperature gradients in horizontal airways.&apos; J. S. Air. Inst. Min. Metall., 59, (7), 1959, p. 339. 3. LAMBRECHTS, J. DE V. &apos;Prediction of wet bulb temperature gradients in mine airways.&apos; J. S. Air. Inst. Min. Metall., 67, (11), 1967, p. 595. R. Hemp (Visitor): Dr Starfield&apos;s paper has very effectively rounded off one particular aspect of the general problem of heat flow in mines. The ease with which this computer programme can be used to calculate temperature increases in horizontal airways must lead to its wider use in ventilation planning and, in developing this rapid method, Dr Starfield has indeed rendered a valuable service to the mining industry. One could consider further instances of heat flow in airways in which the availability of a rapid computer method would be desirable, e.g. the flow of air down a shaft, where there is an increase in temperature due to adiabatic compression, as well as an increase in virgin rock temperature as the depth increases. However, this particular case would not present any new problems and would merely require an extension of the exisitng work. I should like in this contribution to talk about an aspect of environmental control in mines which, I think, will become more important in the future. It is well known that wet bulb temperatures are subject to fluctuations underground. In some instances, particularly in stopes, the fluctuations, both with time and position, can be considerable. The theoretical work which has been carried out on temperature increases has been aimed at the prediction of mean temperatures, and no account has been taken of fluctuations around this mean. It is questionable whether this approach will, on its own, be sufficient, particularly when temperature increases in stopes are considered. The fluctuations in air temperatures underground arise from two causes. The first of these would be the fluctuations in surface conditions, and here one could list random, diurnal and seasonal fluctuations. The second cause is the multitude of things which vary in a mine and here one could list variations in air flow quantity, sources of evaporation, heat transfer from pump and compressed air columns and, particularly in the stope, variations in air flow patterns. Fluctuations arising from surface temperature variations should be amenable to calculation, and here one envisages figures relating the decay of temperature variation with distance to factors such as air flow quantity. Fluctuations resulting from changes in the mine are perhaps more difficult to tackle theoretically and the best approach could well be to analyse underground observations. In this connection, there is a good case to be made for the increased use of statistical methods in the analysis of underground temperature measurements, and it might be of value to look at current air-conditioning practice. When carrying out cooling load calculations for a particular location it is customary to use design wet bulb

Jan 11, 1969

By N. Mulaudzi

The use of SO2/air gas mixtures as an oxidant to precipitate Mn from Co(II) leach liquors was investigated. The effects of SO2/air ratio, pH and temperature on Mn precipitation were evaluated. It was found that the use of SO2/air gas mixtures resulted in significantly higher Mn precipitation kinetics compared to using air or pure O2 alone. The SO2/air ratio was varied from 0% to 6% SO2(v/v) in air and similar Mn removals were achieved at 0.75% to 3% SO2 at pH 3. The solution pH was varied from pH 2 to pH 4; Mn precipitation did not increase considerably from pH 2 to pH 3, but increased significantly at pH values higher than pH 3. Cobalt co-precipitation also increased as pH increased, with 1% Co co-precipitation at pH 3. An increase in temperature from 30°C to 60°C also increased Mn precipitation and 100% Mn precipitated at 50°C. Cobalt co-precipitation also increased significantly with an increase in temperature. An activation energy of 25 kJ/mol was calculated from the Arrhenius plot, which is an indication that the precipitation reactions were both chemically and diffusion controlled. XRD analysis showed that Mn precipitated in the form of Mn2O3 instead of MnO2 that was predicted from thermodynamic data. SEM and XRD analysis also revealed that the precipitate consisted mainly of gypsum or bassanite (99%), with the Mn containing phase (< 1%) distributed within the gypsum phase. The co-precipitated Co reported to the Mn phase. Keywords: manganese precipitation; SO2/O2 gas mixtures; cobalt solutions.

Jan 1, 2009