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By S. D. Hudock, C. M. Keran

A review of all upper extremity cumulative trauma disorder (UECTD) injuries was conducted by the U.S. Bureau of Mines for 1985 through 1989. This review was performed by analyzing each injury, as reported by law and maintained on the U.S. Mine Safety and Health Administration's accident data base. This analysis found that incidence rates in mining were lower than in private sector industry, although the number of reported UECTD injuries increased sevenfold and their percentage of all mining injuries increased fivefold from 1985 through 1989. Metal-nonmetal mines accounted for 80 pct of UECTD injuries, while coal mines accounted for 20 pct. Nearly 63 pct of UECTD injuries were accounted for by only four occupations-mechanics, laborers, boney (crusher) operators, and miners not elsewhere classified (NEC)-with an incidence rate well above the private sector industry rate.

Jan 1, 1992

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements provide evidence for the formation of Cr(V) intermediates in the enzymatic reduction of Cr(VI) by glutathione reductase (GSSG-R) in the presence of NADPH, indicating an initial single-electron transfer step in the reduction mechanism. Depending on the pH, at least two different Cr(V) species are generated which are relatively long-lived. In addition, we have detected the hydroxyl (·OH) radical formation during the GSSG-R catalyzed reduction of Cr(VI) by spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and a-(4-pyridyl-1-oxide)-N-tert-butylnitrone (4-POBN) as spin traps. Superoxide dismutase (SOD) causes only a minor effect on the ·OH radical and Cr(V) formation, indicating that the ~ - is not significantly involved in the reaction mechanism. Catalase enhances the Cr(V) formation and substantially inhibits the ·OH radical formation, indicating the involvement of hydrogen peroxide (H20 2) in the reaction mechanism. Addition of H20i suppresses Cr(V) and enhances the ·OH radical fonnation. Measurements involving N-ethylmaleimide show that the Cr(V) species, produced enzymatically by the reduction of Cr(VI) by GSSG-R, react with H2O2 to generate ·OH radicals, which might participate in the initiation of Cr(VI) carcinogenicity.INTRODUCTIONC(VI) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals [1-4) and to cause mutations in bacteria and transformation of mammalian cells [5-8). In contrast, most Cr(lll) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic [9, 10]. Cr(VI) and Cr(lll) oxidation states are different in their metabolic pathways: Cr(VI) ions are rapidly transported across cellular membranes [2, 11-13), while Cr(lll) moieties do not easily penetrate cells and are not oxidized by cellular constituents [3]. Since it is known that the reduction of Cr(Vl) is required for its reaction with DNA [2], the molecular mechanisms for the intracellular Cr(VI) reduction have been the focus of studies during the past decade but the details are still not understood."

Jan 1, 1990

By Spencee L. Willett

In 1984, at the request of the Bureau of Land Management, the U.S. Bureau of Mines conducted mineral surveys of the 20,508-acre Blue Lakes (NV-020-600) and 5,142-acre Alder Creek (NV-020-600D) Wilderness Study Areas (WSAs) in northwestern Humboldt County, Nevada. The WSAs are part of an upthrown, north-south trending fault block associated with the Basin and Range province. Both areas are predominantly underlain by the Cretaceous Duffer Peak pluton which intrudes Triassic metasediments and Jurassic plutonic rocks to the east and Permian Happy Creek volcanics to the south. In the Alder Creek WSA and in the southwest portion of the Blue Lakes WSA, Duffer Peak granodiorite and Happy Creek volcanics are overlain by Tertiary basalt. No active mines exist within the Blue Lakes WSA; but, several prospects, claims, and mineralized outcrops are in the south and northeast portions. No mineral resources were identified but samples from discontinuous, vein-type deposits contained anomalous amounts of gold, silver, copper, lead, zinc, molybdenum, antimony, and uranium. Very fine, residual gold was detected in nine alluvial samples collected from a small deposit in the southwest corner of the WSA; average gold value was $3.58 per cubic yard (at $350/ounce). Two mines, several prospects, and mineralized outcrops adjacent to the Blue Lakes WSA contain mineralized, irregular structures which do not appear to extend into the Blue Lakes study area.

Jan 1, 1986

By L. B. Pankratz

High-temperature heat-content values of pure lutetium sesquioxide and dysprosium sesquioxide were measured over the temperature range from 298° to 1,800° K. Similar data for cerium sesquioxide were calculated from measurements of a mixture of cerium sesquioxide and dioxide and known values for cerium dioxide. The results for lutetium sesquioxide are regular. Dysprosium sesquioxide has a minor thermal anomaly near 1,590° K, the extra heat absorption being 220 cal/mole, Hexagonal cerium sesquioxide undergoes a transformation around 1,050° K, which is only slowly reversible; consequently results were obtained for both the low- and high-temperature varieties. The original heat-content data are reported, and smooth values of heat content and the corresponding entropy increments are tabulated. Equations were derived to represent the heat-content values.

Jan 1, 1963

By M. M. Wong

Electrolysis of titanium carbide and a material consisting of titanium, carbon, nitrogen, and oxygen as soluble anodes in Used electrolytes was investigated by the Bureau of Mines for the preparation of crude titanium metal. Tests made in all-chloride electrolytes showed only a low recovery of titanium as well as a substantial volatilization of titanium trichloride (TiC13) when present in the electrolyte. Electrolysis at 750° to 850° C in a mixture containing 85 percent NaC1-15 percent potassium floutitanate (K2TiF6) yielded as high as 91 percent recovery of titanium from titanium carbide and 62 percent recovery of titanium from the titanium-carbon-nitrogen-oxygen material. Problems associated with the preparation of crude metal by fused-salt electrolysis are discussed. The crude metals produced from both anode materials were electrorefined in a sodium chloride-titanium chloride (NaCl-TiC12) electrolyte, and ductile titanium metal was obtained.

Jan 1, 1963

By K. J. Miller

A two-stage froth flotation technique was developed in the laboratory to separate fine-size pyrite from coal. The process consists of the initial flotation of a 15-percent solids coal slurry with a minimum of frother; the coarse, free pyrite and other refuse are removed in the tailings. The froth product from this first stage is then repulped and treated with a coal depressant, a pyrite promoter, and a frother to float the remaining fine-size pyrite or pyrite attached to coal particles. With the two-stage process, the pyritic sulfur content of a Lower Freeport bed coal sample was reduced from 1.78 percent to 0.75 percent in the first stage, and from 0.75 percent to 0.27 percent in the second stage with good clean coal recovery.

Jan 1, 1972

By Michael S. Miller

In 1986 and 1987, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 550-acre Carson-Iceberg Wilderness Study Area (NV-030-532), in order to evaluate its identified mineral resources. The Wilderness Study Area is located in Alpine County, CA, 11 mi southeast of Markleeville, CA. Tertiary volcanic and granitic rocks, as well as alluvium, underlie the area. Hydrothermal alteration and faulting have affected some rocks; argillic, silicic, and limonitic alteration are found, particularly near faults. No mineral resources were identified in the Wilderness Study Area. The area has one small pit and no mines or claims. Samples from the Wilderness Study Area and vicinity contained uneconomic amounts of gold, silver, copper, lead, zinc, mercury, arsenic, and molybdenum. Mineral occurrences are too small and low grade to be of interest within the foreseeable future.

Jan 1, 1988

By Raja V. Rarnani, Robert L. Frantz

"Scientific, engineering, and biomedical research teams synergystically developed major topical research areas in the Respirable Dust Center. Descriptions of their interactions and resulting accomplishments demonstrate how cooperative research within and among these study groups benefits the overall respirable dust research and practical application needs of the mineral industries.The development of a state-of-the-art small animal inhalation exposure facility suitable for studies of fresh and aged coal mine dust, a major goal of this research group, will contribute toward the GTCRD goal of advancing the understanding of causative mechanisms for the occupation-related lung impairments and the airway diseases of mine and mill workers. Such understanding includes improved definition of the role of various aspects of the lung environment (e.g., surfactant and the mucociliary system) in the disposition and toxicity of respirable dust, comprehensive characterization of the role of the pulmonary alveolar macrophage (PAM) and its secretory products on the development of dust-related lung disorders, and an expanded search for methods to reduce the toxicity of respirable dust both before and after it enters the lung. The National Academy of Sciences has recommended, in Measurement and Control of Respirable Dust in Mines, that respirable dust research should include study of the behavioral and constitutional factors affecting individual susceptibility to workers' pneumoconiosis occupational disease and the development of methods for detecting the potential onset of pneumoconiosis earlier and more conclusively than can be done using X-ray methods. These recommendations have guided the research group in its goals of establishing and disseminating a scientific protocol for standardizing the inhalation testing for all research objectives within the Generic Center which involve small animal exposures and implementing the infrastructure necessary to make lung tissues obtained during inhalation studies available to all researchers within the Generic Center."

Jan 1, 1995

By Richard A. Winters

In 1987, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 6,022-acre Spring Basin Wilderness Study Area (OR-005-009) in order to evaluate its mineral resources. The study area is in Wheeler County about 13 miles southwest of Fossil, Oregon. No mineral resources were identified. The area is underlain by volcanic flows, domes and sediments ranging in composition from olivine basalt to rhyolite of the Clarno and John Day Formations. There are three mining claims in the study area, all apparently located for lapidary material. Samples of agate were of poor quality. Four of 13 alluvial samples, two inside and two adjacent to the area, contained gold; content ranged from 0.0000097 to 0.00416 troy ounce per cubic yard. About 23 percent of the Wilderness Study Area is covered by oil and gas lease applications.

Jan 1, 1988

By Robert A. Bruce

A motion transducer based on coherent mixing of laser light backscattered from rough surfaces is evaluated in terms of sensitivity, bandwidth and range. Tests made with a prototype composed of a 4-mw HeNe laser, a silicon avalanche photodiode, and a 15-cm aperture telescope demonstrate that remote measurements with reasonable bandwidth and accuracy are feasible at distances up to 100 meters.

Jan 1, 1977

By R. V. Lundquist

Lime-soda sinters, made and processed for recovering alumina and soda, consisted of several types of compound structures differing from the ideal dicalcium silicate and sodium aluminate. Many or these compound structures were causes for low alumina recovery and contributed to the relation or leach slurries. Presence or free lime, whether in the sinter or released by hydrolysis of sinter compounds, contributed to relation of leach slurries. Free lime tends to establish the initial viscosity assumed by a leach slurry. Previous investigations by the Bureau of Mines (1, 4)4/ and by other laboratories (5) have demonstrated the technical applicability of the lime-soda sinter process to the recovery of alumina from aluminum silicate materials. The basic concept of the process is sintering aluminum silicate materials with limestone and soda ash for the production of dicalcium silicate and sodium aluminate and then extracting the sodium aluminate by leaching the sinter in causticized liquors. Alumina is precipitated from the pregnant liquors by carbonating with carbon dioxide. Reaction in the sintering operation may be represented by the following simplified equation: A1203?SiO + 2CaCO3 + Na2C03 = 2Ca0?SiO + Na20?Al203 + 3C02

Jan 1, 1960

By Robert K. Koch

The reactions of alumina and alumina monohydrate with wet hydrogen fluoride gas were studied by the Federal Bureau of Mines to determine the feasibility of producing commercial-grade aluminum fluoride from offgases generated by pyrohydrolysis of siliceous fluorspars. The test results showed than an aluminum fluoride reactor operating at maximum efficiency could retain 96 percent of the fluorine contained in off-gases generated by pyrohydrolysis of siliceous fluorspar. The requirements are a reactor temperature of 200° C. and a reactor entrance gas containing 5 mole-percent hydrogen fluoride. Partial pressure equilibrium constants were determined for the reaction of alumina monohydrate and wet hydrogen fluoride gas from 200° to 350° C. and for the reaction of alumina and wet hydrogen fluoride gas from 350° to 700° C. Both reactions are reversible, and they proceed in directions that are dependent upon the temperature and the relative HF:H2O concentration. Logarithms of the equilibrium constants were used to plot the reaction isobars; these can be used to calculate the theoretical maximum efficiency of a reactor processing wet hydrogen fluoride gas between 200° and 700° C. The theoretical maximum efficiency decreases with increasing temperature.

Jan 1, 1961

By C. B. Manula, R. L. Sanford, R. A. Rivell

The large amount of computer code required for this simulation model dictates that reasonable limitations be placed on some of the input variables. The program permits the following maximum sizes: 1. Ten mine car stations 2. Twenty track intersections 3. Three hundred mine cars 4. Eight motors 5. One hundred profiles 6. Twelve intersections between stations 7. Forty-five profile changes between stations 8. Thirty station pairs (routes) These may be changed by the user providing the particular computer in use has available core storage. Major Array Descriptions This section is a detailed description of four of the major arrays used in the rail haulage simulator for data storage and logical control. Other arrays are used; however, they may be considered sub¬servative to the major ones. These major variables are explained on the following pages. Motor Control Array (XXXDEF). The first 99 locations in this array are arranged according to and are developed by data input. Unit conversions are made at input time which include: 1. Tons to pounds. 2. Rolling resistance in pounds/ton to percent/100. 3. Miles per hour per second (mphps) to feet per min. per minute. 4. Miles per hour to feet per minute. The following information is stored for each motor at the array

Jan 1, 1974

By J. E. Tiffany

Some of the gases produced by permissible explosives on detonation are poisonous, and the probable hazard involved by the inhalation of carbon monoxide in the past has been evaluated from results of tests in the Bichel Gage. Tests have now been made in the Experimental Coal Mine of the Bureau of Mines at Bruceton, Pa., to determine the composition of the gases obtained under actual mining conditions for the purpose of comparing these, results with those found by the Bichel gage tests. Two permissible explosives were procured for these tests, one that produces a relatively low quantity of poisonous gases in the Bichel gage (24.8 liters per 1-1/2 pounds of explosive) and another that produces a relatively high quantity of poisonous gases (94.6 liters per 1-1/2 pounds). The first of these is designated by the Bureau of Mines as a class A4/ explosive and the other is designated a class B explosive. In comparison with Bichel-gage tests, the shooting of permissible explosives in a coal shot hole resulted in a large reduction in the quantity of carbon monoxide, the principal poisonous gas, which; in the mine tests, was only 22 percent of that found in Bichel-gage tests: The quantity of carbon monoxide from the class B explosive in Bichel-gage tests was 3.8 times larger than that from the class A explosive; in the coalmine tests the ratio was 4:1. The concentrations of carbon monoxide in the mine tests, as determined by analysis of the atmosphere in an enclosed space resulting from shooting 1-1/2-pound and 3-pound charges of the class A explosive, were 0.03 and 0.06 percent, respectively, and the concentrations from 1-1/2-pound and 3-pound charges of the class B explosive were 0.10 and 0.24 percent.

Jan 1, 1950

By A. L. Murray, D. Harrington

From 1870 to the end of 1929 the coal production of Utah has been some- what less than 110,000,000 tons. During this period at least three major disasters have occurred with fatalities totaling about 380, establishing a decidedly bad record of approximately 3.5 persons killed by major mine explo- sions per million tons of coal produced. Even during the period when there have been no disasters, such as the years 1914 to 1920, inclusive, the fatalities in ordinary working were about 5.4 per million tons produced, against 3.7 per million tons for the whole United States for the same years. The 5-year period following the World War, 1918 to 1922, inclusive, had 4.7 fatalities per million tons; hence, the fatality record in the coal mines of Utah has uniformly been in excess of the average of the coal mines of the entire country. Notwithstanding this poor record, Utah has given to the coal-mining world many excellent safety methods and practices, and Utah coal mines in general take greater measures toward safe mining than do the coal mines of any other State; if practices and methods allowed and pursued in coal mines of other States were tried in Utah coal mines, there would be a succession of disasters.

Nov 1, 1931

By N. Greninger

The Bureau of Mines examined the possibility of a seasonal variation of respirable dust concentration in U.S. coal mines. The first step was to review company and MSHA-inspector dust samples that had been collected during the past several years in 14 selected mines for compliance purposes. Results indicated severe scatter in data; most standard deviations of the dust concentrations measured in winter and summer months were comparable in magnitude with the mean values of dust concentrations for the seasons. Therefore, a detailed statistical analysis was conducted. At the 90% confidence level, the company samples of three mines had winter means 0.15 to 0.54 mg/m3 higher than the summer means; six mines had negligible seasonal variations; and five mines had winter means that ranged from higher to lower than the summer means. Inspector data, however, were too sparse for analysis. In view of both the low frequency of occurrence of a seasonal effect and its wide scatter in several of the mines, the study was ended with the conclusion that seasonal varia-tion in respirable dust levels, in general, is an insignificant factor.

Jan 1, 1986

By A. B. Needham

This report describes the exploration work done in 1941 in connection with the search for strategic minerals as authorized by the Strategic Materials Act approved by the President on June 7, 1939. It deals with the various manganese deposits and showings in the Tombstone mining district of Cochise County, Ariz. The exploration project comprised a study of the geology, mapping of the areas, and exploration of various mines and deposits by sampling old drifts, crosscuts, and scopes, supplemented by diamond drilling from underground stations. The Federal Government's manganese-purchasing programs have revived interest in occurrences such as the scattered deposits near Tombstone. Because of this, the Bureau of Mines project report on the Tombstone district, prepared originally in 1941 but not published, has been revised and now is being made public.

Jan 1, 1956

By J. P. Bennett

The Bureau of Mines is investigating the acid resistance of ceramic materials to identify construction materials for emerging technology in chemical and metallurgical processes. Eight commercial ceramic materials, including two red shale, two fireclay, a silica, a silicon carbide, a carbon, and a high-alumina brick, were evaluated. Samples were exposed to 40 wt pct HN03 at 70° and 90° C and 60 wt pct HN03 at 50°, 70°, and 90° C for time periods of 110 days. Statistically significant changes in cold crushing strength were generally small or not detected, except for a strength drop in the high-alumina brick, which decreased in strength when exposed to the chosen acid concentrations at 90° C. Vol-ume and weight changes were also measured. The leach rates of Al, Ca, Fe, K, Mg, Na, Si, and Ti were monitored. Increasing temperature or a decrease in the acid concentration resulted in an increased ion leach rate. Of the conditions tested, the most severe corrosion occurred at 90° C for a 40-wt-pct-HN03 solution. The silica brick had the best overall acid-resistant properties, followed by a red shale and a fire-clay brick. The carbon and silicon carbide bricks are not recommended for service.

Jan 1, 1984

By L. B. Berger, S. J. Pearce

One phase of Bureau of Mines' work in health and safety is promotion of the use of safe, satisfactory, and reliable respiratory protective. devices. To insure that such devices will be available, the Bureau has established schedules of minimum requirements for self-contained breathing apparatus, gas masks, supplied-air respirators. (hose masks, air-line respirators, and abrasive blasting helmets, hoods, or masks), dispersoid (dust, fume, and mist) respirators, and nonemergency gas respirators (chemical cartridge respirators). Approval tests of self-contained breathing apparatus are conducted by the Safety Branch; approval tests of other types of respiratory protective equipment are conducted by the Health Branch. Both branches are in the Health and Safety Division.

Jun 1, 1950

Develop computer software that can aid in improving the visibility and illumination in underground mines by providing quick analysis of existing equipment and conditions and the effects of potential modifications. Background Poor visibility and illumination are common problems in underground mining. Mining equipment often restricts operators' fields of vision. Also, fighting systems are often positioned where they cause excessive glare, which restricts the visibility around the machines even further. To help address these problems, the U.S. Bureau of Mines (USBM) has developed a PC-based software package to analyze certain human engineering aspects (ergonomics) of mining equipment design. The software is available for use by equipment manufacturers and mining companies for design work on new machines, as well as for evaluating proposed modifications to existing machines. Approach The Crewstation Analysis Programs (CAP) package includes assessments of visibility, illumination, and glare in the surrounding work area. The advantage of using computers for these types of analyses is that numerous design iterations can be tested quickly and efficiently to determine the effects of changes on visibility. This cuts down the need for expensive testing using physical mockups. Another advantage is that design ideas can be tested in situations where testing would not normally be possible. For instance, the effects of modifications to a lighting system or canopy design could be tested while the machine remained in service.

Jan 1, 1993