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By R. C. Buehl

[Improvements in refractories for high-temperature service have made possible the use of higher temperature in many processes. Consequently, it sometimes is desirable to use gases heated above 1,600° F., and for moderate rates of gas flow, there gases can be heaters best with pebble heaters. Pebble heaters of the stationary-bed type in which the chanber was lined with mullite brick and pebbles of pure alumina served as the heat-exchange medium have been used recently to heat the air blown into an experimental blast furnace4/ These pebble heaters worked well and made it possible to use air temperature up to 2,500° F. at the tuyere of the furnace. Since little has been published on this type of gas heater, a review of the construction on employed and operating data should assist in selecting applications and designing units.]

Jan 1, 1953

By Thomas M. Garland

Reports that set forth the pertinent facts of existing secondary-recovery operations are an integral part of the work of the Bureau of Mines in promoting conservation and efficient utilization of the petroleum resources of the Nation. Knowledge of the success or failure of waterflood projects in an area is very useful to other operators. Although projects will not have identical results, information concerning the flood performance, method of operation, and difficulties encountered on one project will help operators to determine the feasibility of flooding a similar sand and to select the methods of operation most likely to prove successful. The increasing cost of discovering and developing new oil reserves, as well as the unending effort to reduce operating costs and increase ultimate oil recovery from known petroleum reservoirs, has required the petroleum industry to evaluate continuously the performances of various secondary-recovery methods. Waterflooding was recognized early by the petroleum industry as a possible means of increasing oil recovery. From the early accidental floods in Pennsylvania and through many haphazard attempts to inject eater into oil-bearing formations, waterflooding emerged as one of the more important methods of oil recovery. Waterflooding is important not only to the oil industry but also to the economy of the area concerned.

Jan 1, 1962

By William A. Beck

Since bauxite mining began in the Irwinton District, Wilkinson County, Ga., in 1912, it has been on a small scale, as most of the deposits of high-grade ore are small. The bauxite has a high silica content, and its use has been largely limited to the chemical industry. Drilling under this project did not disclose any bauxite deposits of commercial value: However, numerous holes penetrated high-alumina clay deposits, but no attempt was made to delimit them, as the project was solely an exploration for bauxite. Bauxite was first discovered near Irwinton in 1907. The district covers virtually all of Wilkinson County and extends into the adjoining counties of Washington, Baldwin, and Twiggs. Mining was begun in 1912 by the Republic Mining & Manufacturing Co. on the Honeycutt, Parker, and Daniel properties, which are 1.5 miles from Wriley on the old Irwinton to Milledgeville Road.

Jan 1, 1949

By R. E. Campbell

Uranium metal of improved purity was prepared by electrorefining commercial magnesium-reduced uranium in a molten sodium chloride-uranium trichloride electrolyte. The best operating conditions for the preparation of refined metal were established as follows: an electrolyte containing 8.7 to 13.3 weight-percent uranium; initial cathode current densities from 300 to 1,500 amp/sq ft; and a molten salt temperature of 860° C. Ingots produced from electrorefined uranium crystals prepared with these operating conditions were substantially free of metallic impurities. The only impurities in the refined and consolidated metal were present in low or undetectable amounts.

Jan 1, 1965

By Oliver A. Dibble

This paper it one of a series being prepared for and published by the United States Bureau of Mines, describing mining methods and costs at clay pits throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. The open-pit recovery of clay for cement plants is a comparatively simple operation in comparison with underground mining of clays; nevertheless, it represents an appreciable factor in the cost of cement manufacture. The following report deals specifically with the methods employed by the Aetna Portland Cement Co., which operates cement mills at Fenton and Bay City, Mich., in recovering clay from their pit at Corunna, Mich., on the Grand Trunk Western Railway.

Jan 1, 1932

Reduce dust generated during bagging at minerals processing facilities, such as silica sand operations. Approach Installation of a new type of bag nozzle system eliminates the major dust sources during the bag filling process. How It Works The drawing illustrates components of the new bag nozzle system. The system differs in several ways from the conventional nozzle system. An improved bag clamp reduces the amount of blow-back during bag filling, because it has direct contact with approximately 80 per-cent of the nozzle. A two nozzle arrangement includes an inner or "fill" nozzle surrounded by another nozzle, which is designed to exhaust excess pressure from the bag after it has been filled. The exhaust is powered by an eductor, which uses a venturi effect to exhaust the bag at approximately 50 cfm. The exhaust exits into a bucket elevator and is recycled. A pinch valve automatically opens and closes the exhaust system to the bag.

Jan 1, 1984

By Jr. Karr

The Bureau of Mines studied the influence of carbonization method, temperature, and carrier gas on the composition of eight different low-temperature tars produced from a Colorado subbituminous coal. A fluidized bed was compared with an entrained bed, temperature was varied from 500° C to 650° C, and external heating using recycle gas as the carrier gas was compared with internal heating using oxygen-containing gas. The entrained bed yielded significantly more m-cresol and m-ethylphenol, indicating that thermodynamic equilibrium was more nearly approached in the system. Increasing the temperature greatly increased the yield of benzenes and naphthalenes, while paraffins, olefins, and total tar acids were reduced. Using oxygen in the carrier gas decreased the yield of low-boiling phenols and increased that of paraffins and olefins at 650° C.

Jan 1, 1966

By C. A. Pearson, W. D. Dietzman, M. E. Hawkins

Results of chemical analyses and electrical resistivity measurements of 422 samples of oilfield brines from 120 east Texas fields in Railroad Commission of Texas Districts 5 and 6 are presented in tabular form . These samples represent water from all of the major petroleum- productive formations in the area . Water analyses and electrical resistivity data , when fully utilized by proper study techniques , are useful tools in the solution of many engineering problems such as detection of well leaks , identification of water sources , and interpretation of electrical well logs . In the area included in this study , these representative data should facilitate the solution of problems in which water analysis and water resistivity are factors .

Jan 1, 1964

By D. Harrington, M. W. Von Bernewitz

Sections 120 and 121 of Article XI. Fire Control, of a proposed Mine Safety Law in preparation, to be used as desired and when approved by any State, contains these provisions: After the adoption of these regulations, no mine operator shall erect any nonfireproof structure within 50 feet of any mine entrance. or airway. Every operating mine having nonfireproof structures within 50 feet of any mine entrance or airway, except headframes necessary for hoisting, shall have such structures fireproofed or removed and replaced with fireproof structures within six months of the adoption of these regulations. Before reopening, mines idle at the time of the adoption of these regulations shall have all non- fireproof structures fireproofed, removed, or replaced with fire- proof structures as required by the foregoing sentence. Upon receipt of the written statement of a mine operator that the fireproofing of existing structures is impracticable, the chief mining engineer (of the State commission) shall satisfy himself as to the abouracy of the statement. If he concurs that fireproofing is impracticable, and if at the same time he holds the opinion that adequate protection can be provided otherwise by such procedure, he shall have authority to issue a written permit for the substitution of fireproof door at or near portals of mine openings and collars: of shafts. Such doors shall fit as nearly gas-tight as possible. and shall be installed in such a way that the mouths of mine open- ings can be closed readily from outside of structures. The effec- tiveness of such permit may be made contingent upon the operator's continued compliance with any additional precautions which are necessary in the chief mining engineer's opinion to protect the lives of miners.

Mar 1, 1932

Provide the U.S. mining industry with the means to measure and control exhaust emissions of diesel engines used in underground mines. Approach Diesel research is divided into four primary areas: exhaust aerosol measurement, particulate control, gaseous emission control, and chemical and biological characterizition of particulate matter. Diesel research is frequently cosponsored by industry; collaborative research ventures between industry, academia, other government agencies, and the Bureau arc common. Diesel research at the Bureau is conducted in the diesel engine research facility at the Bureau?s Twin Cities Research Center (TCRC). This facility is a state-of-the-art laboratory capable of performing emissions testing, exhaust control evaluations, and safety tests. Background Exposure of mine workers to airborne contaminants from diesel engine exhaust is potentially harmful. The National Institute for Occupational Safety and Health has recommended that whole diesel exhaust be regarded as "a potential occupational carcinogen" and that ?reductions in exposure to diesel exhaust in the workplace would reduce the risk." The U.S. Mine Safely and Health Administration (MSHA) convened an Advisory Committee on Standards and Regulations for Diesel-Powered Equipment and is beginning to implement its recommendations, which cover health, safety, and certification and approval issues surrounding the use of diesels underground. In January 1992, MSHA published an advance notice of proposed rulemaking to regulate diesel particulate matter in underground mines.

Jan 1, 1992

By R. F. Abernethy

A chemical method of determining microgram quantities of arsenic in coal was investigated by the Bureau of Mines to supplement a semiquantitative spectrographic method of determining arsenic in coal ash. In accordance with a method recommended by the International Organization for Standardization, 1-gram samples of coal are decomposed by wet oxidation with boiling sulfuric acid (H2S04) and nitric acid (HN03) to remove the organic matter. After heating to fumes of SO3 to remove HN03, the arsenic is separated as arsine by the action of zinc in H2S04 solution. The arsine is absorbed in dilute iodine solution in which the arsenic is determined colorimetrically by the molybdenum-blue reaction. Two modifications of the method for obtaining the arsenic in solution, in addition to the wet oxidation method, give satisfactory results. The modifications are (1) furnace ashing with MgO added to the coal, followed by treatment with H2S04, and (2) extraction of arsenic from the coal by dilute HNO3 without ashing. Float-and sink-tests show that arsenic is associated mainly with mineral matter in the three coals examined. High-temperature ashing tests show that very little arsenic is volatilized from coal ash below 1,000° C, but it is virtually all removed from the ash at 1,300° C.

Jan 1, 1968

By Thomas J. Peters

The U.S. Bureau of Mines studied the 3,500-acre Winegar Hole study area, Idaho, a legislatively proposed (101st U.s. Congress) addition to the Winegar Hole Wilderness, Wyo.; it adjoins the western boundary of the Wilderness at the Idaho-Wyoming border, about 15 m; east of Ashton, Idaho. The study was part of an Idaho Land Assessment Program to provide minerals information for land-use decisions, and ensure domestic mineral supplies. The study area is an east-west elongated, wooded plateau south of Falls River. Although the area is covered with surficial glacial deposits, it is probably underlain by volcanic flows; light-colored and mafic flow rock were noted in sparse outcrop. No mines, prospects, mineralized areas, or mineral resources were found in the study area during a literature and field search. The only nearby prospects include geothermal and rock aggregate (volcanic cinder) sites, and several placer claims. Although the Winegar Hole study area lies within a region of potential geothermal resources, no evidence of geothermal activity was observed. Rock in the area does not split into flat slabs, which could be useful as dimension stone, and would require crushing to be used 8S aggregate. Alluvium (placer) samples contain less than SO.01 per cubic yard gold (at a $350 per oz price); alluvial deposits are too small to contain gold resources.

Jan 1, 1992

By A. R. Elliott

In the early part of the your 1919 the Bureau of Mines undertook a study of methods of handling oil after it had buon produced, with the view of pointing out the losses due to evaporation and other causes. Observations on present methods show that the oil is subject to largo losses in both quantity and quality from the time it loaves tho well until it is recoivod by the pipe-lina company. During this time it is splashed into four or more tanks of various sizes and with little or no protection over the tops. From the settling tank, where the flow of oil is tamporarily stopped in order to permit sparation of ter and sediments, through the gago tanks and leaso gathering tanks to the largo tank storage where it is hold for many days, rich gasoline vapors roadily escape, especially from tho ghor gravity oil. As no effort is made to measure the oil before it reached the storage tanks, where it is delivered to the pipe-line company, the lossos of the light products of the oil can only be approximated, and, as final results will show, are no doubt usually very much underestimated. In conducting this investigation, the Bureau has endeavored to make tests that would show quantities and values lost, in order to impress better upon those concerned what might be saved through a little more diligence. Eperiments were conducted on both California and Mid-Continent oils. The field operimental work done in California, on which a report is to be published in the near future, is cutlined briefly below: The field work consisted in collecting from operating companies data on storage of oils in large tankage and in performing experiments in the field on storing and piping oil to small lease tanks under practical conditions. Acourate Easurements were takon on the volume, gravity and gasoline content of the oil as it passed through the various stages in its removal from the lease. The work extended over the four seasons of the year in order to obtain better the effect of varying winds and high and low atmospheric temperatures during those periods. Thanks are due to the many oil operators who have taken a personal interest in the work and gave valuable information and assistance. One company furnished the oil and tanks and much of the apparatus and labor. This company also per- mitted the work to be done on its properties in the Coalinga field. This was of material aid, as the results were to be comparative and therefore it was necessary that the same gravity oil be used throughout the experiments.

Oct 1, 1920

By Thomas Varley

"Concentration, ore-dressing, or the dressing of minerals are common terms used in metallurgy and indicate processes of separating valuable minerals from worthless gangue. It is understood, of course, that the products from such processes, being separated from the various minerals and gangue, are ready for commercial sale or for further treatment by smelters and refineries.Gravity concentration takes advantage of the difference in specific gravity of the various constituent minerals and gangue of waste material in the ore. The two most common forms of concentration by this means are jigging and table concentration. Jigs usually are used in the separation of relatively coarse material and the tables for the finer material, the line of division in general being about 20 mesh.There are mar factors to be considered .before a decision can be made as to what method would be best adapted to the successful treatment of an ore and only by careful experiments can this be determined. Among the important factors to be considered are. The nature of the minerals present, their physical and chemical relations to the gangue material, and the gangue material itself. Perhaps the most important is the number of minerals present and their relation to each other.Metals exist in ores in three principal forms -- sulphides, oxides or carbonates, and native. Concentration by gravity methods is in general best suited to sulphide ores, although in some places considerable success has, been obtained in the concentration of oxide ores by gravity methods."

Apr 1, 1920

By James Rowland, Isaac Zlochower, Richard Mainiero, Michael Sapko

The National Institute for Occupational Safety and Health (NIOSH) carried out exploratory laboratoryscale studies to identify factors that may contribute to nitrogen oxides (NOx) production associated with non-ideal detonation of blasting agents. Explosive admixture with drill cuttings, loss of fuel oil in ammonium nitrate and fuel oil (ANFO) from wicking, ammonium nitrate dissolution with water, degree of explosive confinement, ANFO density, and critical diameter were identified as contributing factors to increased NOx production under the laboratory test conditions. Experiments were also conducted to examine the effectiveness of various additives in reducing the NOx production from ANFO, emulsion, and ANFO/emulsion blends. Aluminum powder, coal dust, urea, and excess fuel oil in ANFO formulations were tested and were found to reduce both the nitric oxide (NO) and nitrogen dioxide (NO2) production. Fumes measurements were obtained in the NIOSH underground closed chamber from the detonation of 4.5-kg (10 lbs) charges in schedule 80 seamless steel pipe and from detonations in light weight galvanized steel stove pipe. Some exploratory tests were also conducted with 0.8-kg (1.8 lbs) charges of pulverized ANFO initiated with 0.08-kg (0.18 lbs), 50/50 (Pentolite) boosters (in the NIOSH 12-ft (3.7-m) diameter steel sphere) to measure the degree of fumes production associated with post-detonation oxidation. Ammonium nitrate, emulsion and Pentolite boosters were also detonated in an oxygen-poor environment.

The Government of New South Wales has granted approval for Hunter Valley Aluminium Pty., Ltd" and Alcan Australia Ltd. to proceed with the building of an aluminum smelter at Lochinvar and the expansion of a smelter at Kurri Kurri. Construction of the smelters is expected to start as soon as the consortium is finalized in early 1982. The smelters are part of a plan to increase Australia's aluminum capacity fivefold to 1.5 million tons by the mid-1980's. CHILE Construction of a $61 million lithium carbonate plant in northern Chile will be started in early 1983 by Sociedad Chilena del Litio Ltdao Production is scheduled to begin in 1984 with an initial capacity of 6,350 tons of lithium carbonate produced from a brine deposit. The firm is owned 55% by Foote Mineral Company, of Exton, Pennsylvania, and 45% by Corporacion de Fomento de la Produccion-CORFO.

Jan 1, 1982

By Leonard F. Heising

Domestic production of Metallurgical-grade manganese has contributed such a small percentage of the United States industrial demands that areas known to contain large tonnages of low-grade manganese ore have been investigated by the Bureau of Mines to reduce this country's dependence on foreign ores. A major source of low-grade manganese is the Cuyuna iron range in Minnesota. The entire Cuyuna iron range is covered by an overburden of glacial drift that, in some places, reaches depths of 200 feet or more. Prospecting and exploration must be guided by geophysical methods, drilling results, or projections of exposures found in operating mines because there are no outcrops near the productive parts of the range. Past drilling for the purpose of outlining iron ore generally was confined to the highly oxidized zones. Much of the manganese with which the Bureau of Mines is concerned occurs in thin-bedded unoxidized iron formations, too low in iron content to have been of interest to those seeking commercial iron ore. The primary objective of the core-drilling reported here was to obtain cores of different classes of manganiferous rocks and to determine whether or not the samples were amenable to beneficiation.

Jan 1, 1959

By T. F. Dumm, O. Trass, V. R. Koka, L. G. Austin

"The size distributions of carefully screened 2 size fractions of ground materials were determined using a Microtrac laser dif-fractometer. The size distributions were fitted to the empirical function P(x) = 1/[1 + (x50/x)1] where P(x) is cumulative mass fraction less than Microtrac size, x. The standard deviation of A for a 50 second test time was approximately 0.5, so that seventeen test times give a mean with an estimated error within t 0.25 (95% confidence level). Values of were 5.44, 4.82, 4.40 for a coal ground under different conditions, indicating statistically different shape distributions; the average value for mica was 2.91 owing to the high aspect ratio of the particles. The ratio of x50 to the geometric mean sieve size was 1.2 for the coal and 0.70 for mica.1 IntroductionKoka and Trass have presented evidence [1,2] that materials ground in the Szego mill [3] give different shapes depending on the milling conditions. The variations in shape were deduced qualitatively by viewing SEM photomicrographs of selected 1/2 screen fractions. This paper quantifies their observed differences in shape by using measurements of the size distributions of screen fractions examined in a laser diffractometer [4] (Microtrac, Model 7991). The basic concept is that particles of 'a given ""screen"" size will give a wider distribution of ""Microtrac"" size when the particles are flaky with high aspect ratios, and a narrower distribution when the particles approach the cubical and spherical geometries.2 TheoryAustin and Shah [5] have shown that coal screened within a 1. 1/2 upper-to-lower sieve size range will give rise to a much wider distribution of Microtrac size. They found that the screen interval of irregular fragments of comminuted coals or quartz gave Microtrac size distributions which could be described by the simple function"

Jan 1, 1988

By N. S. Dalal, X. Shi

"SUMMARYElectron spin resonance (ESR) measurements provide direct evidence for the involvement of the glutathionyl radical, as well as an isolable Cr(V)-glutathione intermediate in the Cr(VI) glutathione redox reactions. These results indicate a new mechanism for the reduction of Cr(VI) by glutathione in relationship to cellular environment and suggest that synergistic reactions of Cr(V) and GS· might be responsible for the (unexpected) increase in the Cr(VI)-induced DNA-strand breaks at high glutathione levels.INTRODUCTIONWhile the reduction of Cr(VI) by glutathione (GSH) is thought to be a critical' step in the pathogenesis of the Cr(VI)-exposure related carcinogenesis1- 4, the exact reduction mechanism is not yet understood. The following reaction steps have been suggested :(A) Initial step:Cr04 2- + GSH - GSCrOa - (1)(B) At high GSH levels:GSCroa- + GSH - Cr( IV) + GSSG (2)(C) At low GSH levels: GSC rO a - - Cr ( V ) + GS ·(3)Thus far, however, in these reactions, the GS· radical has eluded spectroscopic detection, while the evidence for the Cr(V) formation has been reported positives as well as negative2·. Her~ we present spin-trap ESR evidence for the formation of the GS· radical, and a definitive ESR detection of an isolable cr(V)-GSH intermediate in Cr(VI)-GSH reactions.MATERIALS. AND METHODSESR spectra were obtained at X-band (-9.7 GHz) using a Bruker ER200D ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR Gaussmeter (Bruker, Model ER035M) and the microwave frequency was measured with a Hewlett-Packard (Model 5340A) frequency counter. The spin probes, a-(4-pyridyl-1-oxide) -N -tert-butylnitrone (4-POBN) and 5,5-dimethyl~1-pyrroline-1-ox1de (DMPO) were purchased from Aldrich, K2Cr201 from Fisher and used without further purification. All experiments were done at room temperature."

Jan 1, 1989

By E. G. King

In continuation of the study of thermodynamic properties of the common interoxidic compounds of ferroalloy elements, this report gives the results of low-termperature heat-capacity measurements and entropy evaluations of the monotungstates of sodium, magnesium, and calcium. Previous reports4 5/ of this laboratory dealt with low-temperature heat capacities, entropies, and heats of formation of the sodium vanadates. Heat-capacity measurements of the monotungstates of sodium, magnesium, and calcium (Na2W04, MgW04, and CaW04) were conducted throughout the temperature range 51° to 298° K. The entropies at 298° K. were evaluated and then combined with entropy data for the elements and oxides to obtain entropies of formation. This information is an essential part of the data needed for thermodynamic appraisals of chemical reactions of these substances. No similar data for any tungstate are to be found in the literature.

Jan 1, 1961