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By D. A. Wilson

A process was developed on a laboratory scale in which a solid waste byproduct from refining of secondary lead was converted into three valuable products. Roasted lead blast furnace matte was leached with water to recover copper. This was followed by brine leaching to recover lead. Residues were finally smelted to yield pig iron. Copper was precipitated as cement copper and the lead product obtained was a mixture of pure 3PbO.PbC12.xH20 and Pb(OH)C1. Copper recovery was 89 percent and lead recovery was 96 percent.

Jan 1, 1967

By E. D. Calvert

As part of its goal to minimize the requirements for critical and strategic minerals, the Bureau of Mines is conducting research to foster the use of domestically abundant materials such as molybdenum. This report describes the development of an investment shell molding technique that can be used to make castings of molybdenum and its alloys. The mold material is cubic Zr02 with a monoclinic Zr02 binder. The shell, formed by standard investment molding techniques described in the text, is prepared for molybdenum casting by firing for 6 hours at 1,550° C (2,822° F) or for 4 hours at 1,650° C (3,002° F). The resulting castings have predictable and reproducible dimensions with good detail. As-cast strength is poorer than the strength of wrought materials below 1,600° F. At and above this temperature, tensile strengths of cast and wrought materials are nearly equal. Aqueous corrosion of the castings in most media is insignificant.

Jan 1, 1982

By T. J. Ballard

The Rickard mine in York County, S. C., named for the original owner, Alexander Rickard, was operated about 50 years as. No records are available of the quantity of corundum shipped. Pratt states, "Many tons were picked up from the surface and shipped." The mine was visited on August 6, 1943, by the author, accompanied by Gilbert W. Withers of Atlanta, Ga. Investigation of the property was begun by the Bureau of Mines after some initial work by the Mi-Cor Corp., a company organized by Gilbert P. Withers of Atlanta to explore the property. In conducting the Bureau program, 754 linear feet of trenches were dug, 110 feet of old drifts cleaned out and examined, and 38 feet of shaft retimbered.

Jan 1, 1948

By M. K. Larson, J. P. Dunford, E. G. Zahl, T. M. Brady

Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, Spokane, WA, have collaborated with three Western longwall coal mines in an on going effort to develop technologies that will aid in providing safe and stable working areas. The goal of the research described here is to develop a stress monitoring system that will provide immediate information to mine managers for making daily safety decisions as areas of poor ground are mined through. Initial work has focused on answering preliminary questions regarding the reliability and use of stress change patterns. Research is concentrated on monitoring horizontal stress because horizontal stress is transmitted over long distances through stiff strata, thus allowing an extended length of entry to be monitored. This paper presents an explanation of the concept, key results from field tests at two mine sites, and a proposed process for implementing a monitoring system. System design layouts, instrument use, data collection and interpretation methods, and processes to present findings to mine staff are described. Additional validation and correlation with actual failure mechanisms are required before this approach can be recommended at ongoing operations. However, initial results indicate that this approach shows promise in mines prone to bumps and roof falls associated with large stress changes. In particular, analyses of measured changes in horizontal stresses appear useful.

By G. S. Scott, G. W. Jones

"INTRODUCTION In the course of the investigation the Bureau of Mines is carrying on to determine the causes, behavior, a. control of mine fires, the detection of incipient heating underground in the mines and above ground in refuse banks has received consideration.Many of the anthracite fires have been active for years and have progressed considerable distances free their original source.Some of the fires are in inaccessible territory, and it is often impossible to determine with any degree of accuracy their exact location or even the veins of coal that are afire, especially when the fire is in the upper strata and when it is impossible to go underground because of flooded conditions or the presence of an irrespirable atmosphere.In such cases, the only means by which the trend of a fire may be ascertained (as a result of any fire-fighting methods that may have been employed) are the sampling, exanination, and interpretation of the gaseous products coming from the fire area. The most important information desired is to know whether the temperature in the heated area is increasing or decreasing and to determine whether a fire that has been sealed is cooling down to normal mine temperatures or is maintaining its heat or is increasing in intensity due to infiltration of outside air.Interpretation of the analyses of gaseous products from refuse banks on the surface also should be of value in combating such fires. Refuse bank fires, with the additional danger of starting an underground fire through ignition of the outcrop, are by no means unknown in the anthracite coal region, and the causes of such fires are not always apparent. In a few cases the causes have been strongly suggestive of spontaneous origin."

Jun 1, 1938

By David C. Oyler, William P. Diamond

Three long horizontal holes were drilled from a directionally drilled sur¬face hole at the Emerald Mine near Waynesburg, Pa. The purpose was to adapt the technique of directional drilling for use in draining methane from coalbeds. A 504-m (1,652-ft) long, 76-mm (3-in) diam¬eter, circular arc pilot hole was drilled, using a downhole mud motor, to enter the Pittsburgh coalbed at a verti¬cal depth of 305 m (1,000 ft). The hole was reamed to 222 mm (8-3/4 in) and was cased to a measured depth of 486 m (1,595 ft). Three 76-mm (3-in) diameter horizontal drainage holes were then drilled, totaling 2,909 m (9,544 ft) of horizontal hole. Improvements in drilling methods increased the average drilling rate from 20.4 m (67 ft) to 64.9 m (213 ft) per day. The cost of drilling the directional and horizontal holes (using a Government-owned drill rig) was $1,169,530, a figure inflated by inexperience and by delays caused by lost-circulation problems and fishing operations. An estimated total drilling cost of $960,000 (including rental of a drill rig) for an improved system, was determined by a detailed cost analysis. Initial gas and water production from November 1979 through May 1980 was low because of caving of the horizontal holes drilled in shale near the bottom of the casing.

Jan 1, 1982

By T. E. Sterner

A laboratory investigation was conducted to determine the applicability of the thermal oil-recovery method as a means of increasing ultimate oil recovery in the Appalachian region. The primary objective was to establish self-sustained combustion in consolidated and unconsolidated sand test assemblies saturated with various amounts of Pennsylvania Grade crude oil and synthetic brine. Tests using blocks of sandstone were unsuccessful because of sealing problems and fracturing of the rock due to thermal stresses. A combustion wave of about 700° F was propagated through the sand-oil-water packs in the linear tube tests. The high air flux used resulted in high oil consumption and rapid movement of the combustion wave through the tubes. Analytical tests on the sand pack showed that sufficient fuel was deposited during the linear tube experiments for a self-sustained combustion wave.

Jan 1, 1967

By James J. Olson

The Bureau of Mines recorded peak particle-velocity levels and vibration frequencies to determine the nature and intensity of ground vibrations for tunnel blast rounds at the NORAD Complex, Colorado Springs, Colo. Previous Bureau of Mines studies in quarries and underground mines had shown that scaling (dividing) the distance from the blast by the square root of the charge weight removed the effect of the various charge weights on vibration amplitudes. The analysis of variance tests performed on the NORAD vibration data, however, indicated that the cube rather than square root scaling exponent grouped the data more effectively. The empirical propagation equation, V = 560 (D/w1/3)-2.04, where V is the maximum peak particle velocity in inches per second, D is the distance from the blast in feet, and W is the zero-delay charge weight in pounds described the attenuation, with distance, of the particle velocities from the tunnel blasts in the Pikes Peak Granite of the NORAD Complex.

Jan 1, 1972

By M. M. Fine

In an experimental study by the Bureau of Mines, in cooperation with National Lead Co., the roast-flotation process was found to be an effective means of upgrading certain cobalt-nickel stockpiles. The research was undertaken to determine whether the process could yield an enriched feed, with a minimum cobalt content of 6.0 percent, for the company refinery. The stockpiles (products of the company Fredericktown, Mo., milling operations) were essentially complex sulfides of cobalt, nickel, copper, lead, and iron, 1 sample of which contained 2.84 percent Co and 3.57 percent Ni. After a controlled oxidizing roast at 400° C., laboratory flotation with conventional sulfhydric reagents yielded an enriched concentrate analyzing 9.22 percent Co and 11.43 percent Ni, with recoveries of 84.9 and 85.8 percent, respectively. These are typical laboratory data; other data indicated higher grades were possible but at reduced recoveries. A brief, continuous campaign verified the applicability of the process to the raw material in question but was not continued long enough to establish optimum conditions. As a consequence, the results of the large-scale tests did not equal those obtained in the laboratory but definitely confirm the beneficiation possible from the roast-flotation process.

Jan 1, 1958

By Raymond F. Helinski, Linda J. McWilliams, Sean Gallagher, Thomas R. Battenhouse, August J. Kwitowski, John R. Bartels, Dean H. Ambrose

This report examines the boom arm vertical speed for roof bolting machines to study a moving boom arm appendage at different speeds during different work scenarios. The goal of this study is to determine the impact of the appendage speed on the likelihood of the operator's hand, arm, head, or leg making contact, such as touching the moving appendage. The overall research goal is to reduce workers' risks to injury from exposure to underground mining machinery. Accident investigation reports from the Mine Safety and Health Administration do not usually contain enough information to aid in studying this problem, and lab experiments with human subjects are not feasible because of safety issues. As an alternative, researchers used a unique computer simulation model that uses a virtual human, vision tracking, and generates random virtual human motions and risky work behaviors. By using specialized software to simulate the computer model, researchers accurately identified potential hazards of tasks where it is not possible to perform experiments with human subjects. Results of a frequency distribution analytic approach show that, regardless of other variables, contact incidents were always greater when the boom was moving up, always greater on the hand, and always greater or the boom arm part of the machine. The reason why the subject experiences more contacts when the boom arm is moving up rather than down is that more risky behaviors occur during drilling and bolting when the boom is ascending. Results of a cross-tabulation analytic approach show that the 25th-percentile operators experienced more contacts than other operator sizes and had most of their contacts during a boom speed of 13 in/sec. The hand-on-boom behavior during drilling and bolting tasks experienced more contacts than other work behaviors, and both tasks had most of their contacts during speed 13 in/sec. The 60-in seam experienced more contacts than other seam heights and had most of the contacts during speed 16 in/sec. For univariate logistic regression models, seam height is the most important predictor of the probability of a contact. However, a multivariate logistic regression model predicted contacts are more likely with the both-knee work posture in the 60-in seam, a 25th-percentile operator compared to a 55th-percentile operator, and speeds 16 and 22 in/sec compared to 7 in/sec. Results of a survival analytic approach suggest that controlling the boom speed is the most important factor in determining the risk of an operator making contact. Based on the data collected, boom speeds greater than13 in/sec result in a substantial increase in risk to the roof bolter operator making contact. Speeds less than or equal to 13 in/sec are associated with a more modest relative risk of making contact, which represents a decrease in potential hazard. Virtual operator's response time has little effect on the number of contacts experienced. The mining industry can use the information in this study to reduce the likelihood that roof bolter operators will experience injury due to contact with a moving roof bolting machine's boom arm.

Jan 5, 2005

By Larry Patts, Michael J. Brnich

Approximately 45% of U.S. coal is produced from underground mining. The use of diesel engines to power under- ground mining equipment has steadily increased over the past four decades in an effort to improve mine safety and productivity. Several advantages realized with the use of diesel-powered mining equipment in underground coal mines are listed in Table I. The primary disadvantage of using diesel equipment in underground coal mines is that diesel exhaust emissions can contaminate mine ventilation air. The major constituents of diesel exhaust are gaseous emissions (which include carbon monoxide, carbon dioxide, oxides of nitrogen, sulfur oxides and unburned hydrocarbons) and diesel particulate matter (DPM). The Mine Safety and Health Administration (MSHA) has incorporated threshold limit values for all gaseous components of diesel exhaust into their regulations. These have been established by the American Conference of Governmental Industrial Hygienists.

By Joseph A. DeCarlo

This publication presents a tabulation of oven-and beehive-coke plants in the United States as well as pertinent statistical data on the number, capacity, kind, and condition of the ovens. Coke is an essential raw material in pig-iron production and the coal-chemical materials produced during the coking process are used to manufacture fertilizers, paints, plastics, synthetic rubber, explosives, detergents, nylon, pharmaceuticals; dyes, and many other products necessary to the high standard of living in this country. In table 1 the oven-coke plants in the United States on December 31, 1959, are listed. This shows the name and address of the company, location of the plant, classification or type of ownership, number and type of ovens, annual coke capacity, and the coal-chemical materials produced. The "furnace" plants I are those owned by iron and steel companies and most of them are integrated with blast furnaces to facilitate transportation of raw materials for steel making. Furnace plants represented 87 percent of the total coking capacity and their average annual capacity was 1. 3 million tons. The "merchant" plants are those associated with chemical companies, gas utilities, as well as those that produce metallurgical, industrial, and residential-heating grades of coke and coal-chemical materials for sale on the open market. These coke plants are smaller than furnace plants and in 1959 their average coke capacity was only 520 thousand tons annually. On December 3l, 1959, there were 54 furnace and 20 merchant oven-coke plants in existence in the United States.

Jan 1, 1960

By Doris M. Hyde

To a greater or lesser extent, the economies of the smaller Caribbean Island countries continued to have common problems. These included unemployment, inflation, foreign exchange shortages, trade deficits, and unstable world prices for their exports. Declining prices for petroleum provided some relief from scarce foreign exchange. Overall, the mineral sector remained stable. The Amerada Hess Corp. crude oil transshipment terminal on St. Lucia was completed during 1981. However, there were no shipments during the year. No official reason was offered for the delay in opening the terminal, but it may have been related to the world surplus of crude oil that occurred in 1981. There has been no further action on the refinery, which was to complete the island's petroleum complex. During the first half of 1981, an announcement was made that a second oil transshipment terminal would be built on St. Lucia. The report indicated that the terminal was to be financed by Saudi Arabia and include underground storage. After the original announcement, no further information was made available. This terminal, like the Hess petroleum complex, may have been temporarily postponed because of the crude oil surplus.

Jan 1, 1983

By A. Gene Collins

The Bureau of Mines conducted a research study of the geochemistry of the Smackover Formation to determine what geochemical relationships are useful in exploration for and production of oil and gas. Samples of oil, gas, brine, and rock were collected and analyzed. The oilfied brines were analyzed by methods recommended by the American Petroleum Institute and by tentative methods of the American Society for Testing and Materials. The crude oils were analyzed by Bureau of Mines methods; the gas, by Bureau of Mines methods; and the rocks, by wet-chemical, atomic absorption, and neutron activation methods. The results were correlated and interpreted, and several geochemical relationships useful in exploration and production were found. These include the type and class of brine, organic constituents in the brine, redox potential, in situ temperature and pressure of brine, degree of sulfate and carbonate saturation of brine, and halide concentrations in the brine.

Jan 1, 1974

By D. S. Colby, E. M. SEELEY

The total production capacity of the natural-gasoline industry increased to 27,212,000 gallons (647,905 barrels) daily on January 1, 1950, from 21,322,000 gallons (507,670 barrels) daily on January 1, 1948. The rate of growth during these 2 years averaged 13 percent per year, compared with 9 percent per year from 1946 to 1948 and 6 percent from 1944 to 1946. The total number of operable plants on January 1, 1950, was 554, 5 more than at the beginning of 1948. The number of absorption plants increased by 12, the number of cycling plants by 7, and the number of combination plants by 4. The number of compression plants and charcoal plants continued to decrease. Absorption plants accounted for 67 percent of the total capacity on January 1, 1950, compared with 62 percent 2 years previous. Eighty-two per- cent of the expansion in these 2 years was in absorption-plant capacity. Cycle plants accounted for 24 percent of the total industry capacity at the beginning of 1950, compared with 27 percent on January 1, 1948. The average daily capacity of absorption plants increased from 38,400 gallons at the beginning of 1948 to 50,600 gallons at the beginning of 1950. During the same period, the average daily capacity of cycle plants decreased from 150,200 gallons to 144,100 gallons. Texas showed the largest gain in number of plants 13 absorption, 4 compression, and 4 cycling plants. The State accounted for 67 percent of the gain in capacity and on January 1, 1950 had 50 percent total national capacity. Louisiana followed with 7 additional plants. Pennsylvania reported 14 and West Virginia reported 13 fewer plants than in 1948. Most of these reductions were in the number of compression plants.

Jul 1, 1950

By D. E. Traut

A fluidized, countercurrent ion-exchange system was developed, operated, and evaluated by the Bureau of Mines in support of its objective to help assure an adequate uranium supply for future national needs. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows are continuous, except for short periods when resin increments are withdrawn. The exchange of uranyl sulfate between a simulated acid-leach-uranium solution and a strong-base, ion-exchange resin was studied, together with subsequent elution using an acidified sodium chloride solution. The effects of the number of compartments, compartment height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. Also examined were the kinetic and equilibrium relationships for the absorption and elution steps. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The columns system was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By Walter W. Fisher

A kinetic investigation of copper cementation in a revolving drum was undertaken by the Bureau of Mines to explore the effects of a porous copper deposit attached to the iron surface and a fluidized slurry of copper particles surrounding the iron precipitant. The rate of cementation was found to be significantly enhanced by the increased cathodic areas provided by a porous copper deposit or the presence of a fluidized bed of copper particles contacting the iron precipitant. The cementation rate was found to be retarded by increased ionic strength, low pH, and the presence of oxygen. The cementation reaction was first order with respect to precipitant surface area. Copper cementation on iron is visualized to occur by two basic mechanisms. Precipitation may occur through a series of shorted electrochemical cells, whereby cupric ion precipitates on a growing cathodic copper deposit, or, deposition may occur via a fluidized cathode of copper particles contacting the ion precipitant.

Jan 1, 1976

By F. D. DeVaney

An examination of the physical properties of manganese ores is being made at the Mississippi. Valley Station of the United States Bureau of Mines in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Missouri. The object of the study is to find out how much these ores can be beneficiated by such processes as jigging, tabling, magnetic separation, and flotation. Some. of the results were given in an earlier report.4 Eighty samples obtained from various prospects and mines throughout the country have been examined; this is a very small part of those that should be examined before the work can be a definite factor in-the appraisal of manganese ores or the guide in beneficiation which the operators seek. The ore deposits are not expected to reach to great depths vertically, after the manner of copper and gold, but in lateral distribution their greater extent is notable. This applies particularly to the residual and replacement deposits of manganese.

Jan 1, 1929

By Bruce D. Sartwell

The Bureau of Mines is using characteristic X-rays produced by proton bombardment of a solid surface to provide quantitative compositional analyses of surface layers of metals. An integral X-ray yield equation has been developed that quantitatively relates the measured X-ray yield to the thickness of thin films ranging from less than a monolayer to several thousand angstroms. The use of the integral yield equation is demonstrated for the growth of a thin film by vacuum evaporation. Results are presented that show haw proton-induced X-ray emission (PIXE) has been used to determine the oxidation kinetics of iron that had been implanted with several different species of heavy ions. The sensitivity of PIXE for the measurement of very-thin-film growth kinetics is demonstrated from studies of the effect of fractional mono-layer coverages of sulfur on the initial oxidation kinetics of iron. Results are also presented in which PIXE has been used to study the redistribution of alloying elements in components of a gas turbine that had fractured due to corrosion fatigue. By combining PIXE with low-energy ion sputtering, quantitative composition depth profiles of surface layers are obtained. Examples are presented for the profiling of iron samples implanted with 25-kev nickel ions and for a platinum coating on an Fe-5Cr substrate.

Jan 1, 1980

By Peter F. Strong, Robert L. Lagace, Alfred G. Exslie

The theoretical study of WF radio communication in coal mines, with particular reference to the rate of loss of signal strength along a tunnel, and from one tunnel to another around a comer is the concern of this paper. Of prime interest are the nature of the propagation mechanism and the prediction of the radio frequency that propagates with the smallest loss. The theoretical results are compared with published measurements. This work was part of an investigation of new ways to reach and extend two-way communications to the key individuals who are highly mobile within the sections and haulageways of coal mines.

Nov 14, 1974