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By Charles S. Allbright

To develop a method for predicting the stability of a fuel during long-term storage from rapid aging tests at 200° F, the Bureau of Mines determined the stabilities of three gasoline base stocks and an alkylate blending stock in both sealed storage and aerated storage at 110° F for periods extending to 32 weeks. Stabilities of samples containing gasoline-additive compounds were compared by aging, using two methods--rapid aging in a bomb at 200° F for intervals up to 16 hours and storage at 110° F. The additives used were an uninhibited tetraethyllead motor mix, N,N'-di-sec-buty1-p-phenylenediamine and 2,6-di-tert-butyl-4-methylpheno1. Results were related by graphs that enable predictions of gum and sediment formation during storage from data obtained in bomb tests. A premium-gasoline base stock and the alkylate proved to be stable, but the two regular-grade gasoline base stocks were found to be unstable. Addition of the diamine antioxidant improved the stability of both of the regular gasoline base stocks, while the phenol antioxidant improved only one of them. The presence of the tetraethyllead decreased the storage stability of all four fuels, both with respect to formation of gum and precipitation of inorganic sediment. The rapid test at 200° F appears to offer promise as a basis for a method of predicting gasoline stability in long-term 110° F storage.

Jan 1, 1968

By M. B. Bransford

A calculation procedure was evolved by the Bureau of Mines for determining the heat-transfer characteristics of dilute gas-solid mixtures in an externally heated tube. The procedure accounts for differences in gas and particle velocities and covers a range of particle sizes. Heat transfer coefficients obtained by the calculation procedure are compared with values reported in the literature.

Jan 1, 1970

By A. Oyler

The U.S. Bureau of Mines has compiled data on the major causes of fatal and nonfatal electrical accidents related to mining, and their associated costs, for the 1980-85 period. Specific electrical problem areas were identified, allowing future research to be focused on reducing the frequency of these occurrences. Recommendations for reducing the number of electrical accidents and injuries are provided. The four mining sectors for which data were gathered and compiled are (1) underground coal mines, (2) surface at underground coal mines, (3) underground metal-nonmetal mines, and (4) surface at underground metal-nonmetal mines. Nine categories of information pertaining to specific aspects of the accident are used in this report: activity engaged in when the accident occurred, source of injury, job title, mining method, location, machine, nature of injury, accident type, and part of body affected. The number of years of experience at the specific job the employee was performing when the accident occurred, time of accident, and in the case of nonfatal accidents, the total days lost per year, are also summarized.

Jan 1, 1990

By A. L. Engel

In recent investigations of chloride Volatilization of gold at the Reno Station, it was found that the addition of small amounts of copper and NaCl to the charge brought about improved volatilization of the gold. The investigations described in this report were concerned with the recovery, in an aqueous medium, of fumes from chloride volatilization of gold. It was attempted to discover a suitable aqueous medium that would permit absorption, solution, or precipitation of all the volatilized gold immediately upon contact with the medium. A simple laboratory apparatus was employed to produce fumes by volatilization. To this furnace was attached an absorption train consisting of a series of chambers containing the aqueous medium, through which the fumes were drawn by suction. A satisfactory synthetic ore that contained metallic, gold in a quartz-matrix was made and utilized, enough. gold being present in a' small amount of material to permit an accurate, metallurgical balance of the volatized values' to be obtained in all the experiments.

Jan 1, 1949

By Mayo D. Hercey, Edward W. Butzler

"Purpose and Origin of Investigation.For many investigations of mineral products such as metallic and ceramic materials, especially refractories, a knowledge of thermal conductivity and specific heat at high temperature is required. Such data have been needed by the Bureau of Mines for checking heat balances in kilns, and computing heat loss through furnace walls.Design of apparatus for thermal conductivity tests was undertaken by the Bureau early in 1922, an industry at that time indicated that no equipment intended for extreme high-temperature observations was elsewhere available or likely to be in the immediate future.The Bureau's investigation was begun by C. R. Greenslade, assisted by F. A. Hartgen, and temporarily discontinued owing to their resignations in the summer of 1922. The work was later turned over to the writers of this report, and has been carried forward at intervals, along with other problems."

Jan 1, 1924

By T. L. Hebble

The Bureau of Mines investigated a hydrometallurgical procedure to recover Co, Ni, and Cu from an electrolytic zinc industrial copper filter cake. The copper filter cake is presently unmarketable or of low value because economic and environmentally acceptable processing technology is lacking. Research by the Bureau of Mines has developed a multistage process for recovering or recycling over 93 pct of the Zn, Cd, Cu, Co, and Ni from this material. The stages involved are (1) wet sizing, (2) H2S04 leaching of undersized material, (3) H2S04-Mn02 leaching of H2S04 leach residue, (4) selective precipitation of As, Cu, and Co-Ni products, and (5) precipitation of manganese for recycling to the leach circuit. The final process residue is only 1.6 wt-pct of the initial cake and consists of lead sulfate.

Jan 1, 1981

By T. H. Ueng, S. D. Thompson, Y. J. Wang

"INTRODUCTION There is considerable interest among mining companies and government agencies in finding new ways to better control the generation and dispersion of respirable coal dust. Mine face ventilation generally has been considered the most effective tool for lowering the concentrations of respirable dust. Unfortunately, only a limited amount of research has been undertaken to determine the relationships between the various face ventilation parameters and the dust dispersion patterns. If these relationships are better understood, more efficient ways of controlling dust generation and dispersion may be evident. A practical and economical way to gain more in-depth understanding of these relationships is through scale model studies. Past research (1, 2, 3) has substantiated that scale models can be successfully used in studying ventilation parameters provided that geometric, kinematic, and dynamic similitues are maintained.To better understand face ventilation and dust dispersion, a 1/5 scale model of a room and pillar mine face was constructed. This model was then used to conduct experimental investigation on two ventilation parameters. The parameters which were examined included the line brattice distance from the face and the air quantity. The values of these parameters were varied in numerous experiments so that their effects on dust dispersion could be measured.The experiments of this study were unique in two ways. First, two different substances were used to simulate the respirable coal dust. Experiments were conducted with a tracer gas (methane) serving as the dust simulation substance. They were then repeated with an actual dust (Arizona Road Dust) replacing methane as the dust simulating substance. In previous scale model studies, the dust simulation substance has been limited to a tracer gas such as methane. The validity of using a tracer gas to simulate dust is not clearly known yet. The other unique thing about these experiments was the number of points measured for methane (or dust) concentration. Twenty five points in a grid arrangement were measured during each experiment of this study. The number of points measured for concentration in other studies has generally been very small (often 2 to 4). It is difficult to obtain an accurate assessment of how the ventilation parameters are effecting dust dispersion when only 2 to 4 points are measured."

Mar 1, 1989

The results of a Feasibility and Design Study of Surface Impregnation Equipment to be used for Chemical Stabilization of Coal Mine Structures are described in this report. The study was sponsored by the United States Department of the Interior, Bureau of Mines, under Contract H0210055. This program was undertaken as an essential part of the Bureau of Mines Chemical Ground Stabilization Program. The responsible prime contractor was The Eimco Tunneling and Mining Machinery Division of the Envirotech Corporation. The Rocketdyne Division of the North American Rockwell Corporation performed part of the feasibility study and design and testing of the metering and feed system as a subcontractor to Eimco.

Jan 1, 1972

By N. S. Dalal, B. Jafari, X. Shi, M. M. Suryan

"It is well known that prevalence and severity of coal worker's pneumoconiosis (CWP) differ markedly in different regions and mines despite comparable exposures. These variations in the pathogenicity of different coal mine dusts can only partially be explained by the mineral composition of the coal mine dust and the rank of coal. Laboratory studies also do not correlate with the human experience. One major difference between human exposure and laboratory studies is that the coal miner breathes dust from freshly broken coal, while the animals or cells are exposed to stale dust. In an effort to find biochemical clues for resolving this apparent paradox, we have carried experiments to detect differences in chemical reactivities of fresh versus stale coal dust from several U.S. coal mines. Electron spin resonance (ESR) was used as a technique for the direct detection of the concentration and reactivity of free radicals. ESR measurements of freshly ground coal dusts of different ranks and composition showed significant differences in the amount and reactivities of the organic free radicals produced. The half-lives and reactivity patterns of these newly formed species of free radicals seem to correlate with the expected toxicity and pathogenicity of the dust, thereby, providing new clues to the biochemical mechanisms and pathogenesis of CWP. Similar detection of free radicals in freshly crushed quartz suggest that free radicals might play a significant role in the pathogenicity of quartz in causing fibrosis and eventually silicosis.IntroductionThe pathogenesis of coal workers' pneumoconiosis (CWP) has been an important topic of concern for decades, but the mechanism of CWP is still not understood. It is well known, for example, that the prevalence and severity of CWP differ markedly in different regions and mines despite com¬parable exposure'(1,2) but these observations can only par¬tially be explained by differences in mineral composition and rank of coal (3-5) Specifically, while epidemiological studies of coal miners indicate (1,2) that the effectiveness of coal in producing CWP correlates roughly with the rank (i.e. %,carbon content) of coal, such correlation has not been established via biological studies.(4-6)"

Mar 1, 1989

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clarion County, Pa. Of the 15 samples collected, 1 was of metallurgical quality as received, 4 could be sufficiently upgraded to provide acceptable products, and the remaining 10 samples could not be upgraded to metallurgical quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, 1 sample was of low sulfur content as received, 1 sample could be upgraded to low sulfur content, and 10 samples could be upgraded to medium sulfur content. The original sulfur content of the remaining three samples can be appreciably reduced by removal of the sink 1.58 specific gravity material; however, these coals would be classified as medium sulfur coals both before and after removal of the sink material.

Jan 1, 1968

By M. E. Tyrrell

Despits its high melting point (2,135° C.), resistance to attack by molten metals, and its hardness (8), spinel (MgO?Al203) synthesized by the fusion of alumina (Al 2 0.) and magnesia (MgO) is not used on a large scale as a commercial furnace lining, mainly because of the prohibitive cost. This investigation by the Federal Bureau of Mines was prompted by the possibility of producing synthetic spinel from inexpensive raw materials by methods outlined in U.S. Patent 2,029,773, "Process for Obtaining Products Containing Spinets," dated February 4, 1936. In this patent Ture B. Haglund described a process for recovering crystalline spinels from melts in the system Mg0?Al203-2CaO-SiO2, a system well suited to the use of starting materials such as dolomite CaMg(C03)2, olivine [2(Mg?Fe)0.Si02], and bauxite (Al203?2H20) which are abundant in the southeastern United States. Compositions, ranging from a low content in the eutectic mixture of 35 percent spinal and 65 percent dicalcium silicate (2 CaO?SiO2) to a high of 75 percent spinel and 25 percent dicalcium silicate, were fused in electric furnaces of the arc-resistance and internal-resistance types. So long as members of the system were in proper chemical balance, "dusting" slags could be produced over the entire range of spinel concentration.

Jan 1, 1961

By H. E. Perlee

Mathematical expressions are derived for the histories of the pressure, flame radius, mass fraction burned, and burned and unburned gas temperatures associated with a spherical flame propagating concentrically in a spherical vessel. The equations are solved numerically for a 9.5 pct CH4/air mixture using the best available information for the burning velocity, expansion ratio, and specific heat ratio. Calculated histories are in complete accord with experimental measurements. The accuracy of calculated histories is determined relative to errors in the system parameters, and it is found that 10 pct errors in either the burning velocity or the expansion ratio results in a 40-pct error in the pressure history. A 10-pct error in either burned or unburned specific heat ratio results in a 22-pct error &apos;in the pressure history. It was further established that the usual assumption of constant specific heat ratio is unacceptable, but equating the burned and unburned specific heat ratios result in no apparent error in the histories. The cubic law (P = Kt3 + Po) is derived and discussed, and it is found that the law is valid only during the early period (P<2 atm) of flame growth.

Jan 1, 1974

By R. Hogg, Y. Lee, D. E. Rannels

"Lee, Yu-Chen, Richard Hogg, and D. Eugene Rannels. Extracellular matrix synthesis by coal dust-exposed type II epithelial cells. Am. J. Physiol. 267 (Lung Cell. Mol. Physiol. 11): L365–L374, 1994.—Although integrity of the alveolar basement membrane may influence progression of lung injury induced by inhaled particulates, little is known about direct effects of coal dusts on the alveolar epithelium or its extracellu¬lar matrix (ECM). Effects of dust on synthesis of cell and ECM proteins by type II cells (T2P) was thus investigated. Three coal dusts (anthracite no. 867; bituminous no. 1451 and no. 1361) and mine dust MIT-3, of respirable size, were studied as a function of dose and time over 3 days of primary T2P culture. On day 1, 750 µg/ml of 867 were required to increase relative synthesis of ECM proteins (ECM/cell). MIT-3, 1451, and 1361 were without effect. By day 3, 867 or MIT-3 increased ECM/ cell 60-100% at 300 µg/ml; 1451 produced modest, dose-dependent stimulation, whereas 1361 remained without effect. None of the dusts caused significant cytotoxicity. The results show dose- and time-dependent effects of well-characterized coal and mine dusts to modify partitioning of newly synthesized proteins into the ECM and suggest that coal dust exposure may modulate structure or function of the subepithelial basement membrane.basement membrane; cell culture; inorganic dust; lung injury; extracellular matrix deposition; pulmonary epitheliumCHRONIC EXPOSURE to coal dust may be associated with development of pulmonary fibrosis and consequent loss of normal lung function (see Ref. 26 for review). Al¬though the pathways of inorganic dust-induced lung injury are recognized to involve an inflammatory re¬sponse, the underlying pathogenic mechanisms are not understood in detail. Acute and chronic responses to dust exposure involve a variety of interacting cells of the immune system, including macrophages, T cells, and B cells, along with pulmonary fibroblasts. These responses reflect direct effects of the dust particles, as well as indirect effects mediated by soluble factors, including cytokines and eicosanoids (see Ref. 41 for review).Studies of pulmonary macrophages and fibroblasts following silica exposure suggest that dust-induced damage at the airway surface may involve cellular injury through oxidant-mediated pathways. Coal dusts and related inorganic particulates can activate the alveolar macrophage (42) to produce fibronectin (15) and cytokines, such as interleukin-1 or tumor necrosis factor (4) and/or other soluble products which act locally (29) to cause acute cellular injury and to initiate the progression of fibrotic lung damage (16). Type I epithelial cells are typically more susceptible than type II cells to oxidant injury. Type I cell damage and subsequent death leads to denudation of the subepithelial basement membrane (2, 21) and can be associated with leakage of plasma constituents from the pulmonary vasculature into the alveolar compartment (13)."

Dec 1, 1995

By J. J. Drost

The feasibility of basic oxygen furnace (BOF) offgas heat recuperation by preheating scrap was investigated on a pilot plant scale by the Bureau of Mines. In this study, offgases generated during the oxygen blowing of a molten pig iron and scrap charge were passed through a static bed of shredded auto scrap. Scrap quantities varying from 100 to 180 pounds and representing from 22 to 40 percent of the 450-pound BOF metallic charge were preheated in this manner. Average scrap bed temperatures of 1,650° F for 100 pounds of scrap and 1,150° F for 180 pounds of scrap have been achieved during the blows. As compared to cold scrap used in the normal BOF practice, it was found that by preheating scrap, usage could be increased by 43 percent. The thermal energy recovered by this preheating method can account for up to 44 percent of the energy necessary to melt the scrap.

Jan 1, 1974

By M. D. Schlesinger

As part of the development of processes for producing synthetic fuels from coal, the Bureau of Mines prepared a special jet fuel in a pilot plant for evaluation by the Air Force. This jet fuel had all the required physical properties, including the important specifications of high heating value and high density. However, the finished fuel did not pass the stability test specified by the Air Force and conducted by the Southwest Research Institute in a high-temperature research coker. The cause for this instability is being investigated because pure compounds of the type identified in this fuel are known to be stable. The tar acid oil used was a 230° to 300° C. fraction of low-temperature tar obtained by carbonization of a West Virginia bituminous coal in the pilot plant of the Consolidation Coal Co. Both the desulfurization at 400° C. and saturation at 300" C. were done in the vapor phase at 2,500 p.s.i.g. After catalytic treatment and distillation the final jet fuel had a boiling range of 194° to 247° C., a net heating value of 18,420 B.t.u./lb. and a specific gravity of 0.8463 60° F./60° F. It also had u pour point below -62° C., and at 0° C. its viscosity was 4.5 cs. The oil was virtually all bicyclic, 41 pct. noncondensed and 56 pct. condensed.

Jan 1, 1961

By H. W. Kilau

The U.S. Bureau of Mines examined the wettability of bituminous and subbituminous coals before and after exposure to ambient air atmosphere, as part of an ongoing project investigating the coal-wetting abilities of surfactant solutions intended for the suppression of dust during coal mining operations. Exposure periods were generally 7 days or less, and the changes in wetting response were measured with a capillary penetration apparatus. Wetting solutions tested included a nonionic surfactant, two anionic surfactants, and pure distilled water. After exposure, higher ranked bituminous coals treated with nonionic surfactant solution and pure water showed increased wettability, but lower ranked subbituminous coals showed decreased wettability. With the anionic surfactants, the coals demonstrated opposite responses. The wettability changes appeared to be related to the coal moisture content. These changes may be amplified by specific, but incompletely understood, interactions between surfactant polar groups, absorbed water, and the coal surface.

Jan 1, 1989

By E. P. Youngman

At the time of the preparation of the monograph upon the mining legisla- tion of Newfoundland, by the Imperial Institute of London, the existing local statutory law (as distinct from case laws and the applicable English acts) con- sisted of the following legislation: 1. Chapter 129 of the consolidated statutes, entitled "Of Crown Lands, Timber, Mines and Minerals," as amended by the Crown lands act, 1928. 2. Chapters 131 and 132 of the consolidated statutes (acts relating to mines regulation and rewards for discovery of minerals, respectively). 3. Crown lands act, 1918, as amended by the crown lands (amendment) act, 1921. 4. The Labrador Act, 1927. 5. The Crown royalties act, 1927. 6. Crown lands act, 1928, together with rules and regulations issued thereunder.

Oct 1, 1932

By Susan M. Moore

Many challenges are faced by workers in lower-seam (42 inches or less) mines. The lower-seam heights confine mine workers to their knees as they perform their daily tasks such as installing roof bolts, delivering supplies, repairing belt, or cutting coal. Miners working in these lower seams often consider kneepads to be their only line of defense against knee injuries. However, healthy knees do not start and stop with kneepads. Other interventions such as changing postures, proper hygiene, and work station design may also be used to reduce mine workers? risks for developing knee injuries. Incorporating these and many other interventions into a mine worker?s ?way of life? is an important step to ensuring a long, healthy career and retirement. Keeping knees healthy is also a key aspect to reducing costs in low-seam mines as the industry battles rising health care costs, and training/recruitment of replacement workers is time-consuming and costly. Educating the workforce about the possible interventions to reduce knee injury risk is a primary objective for the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Laboratory (PRL). Therefore, NIOSH researchers, along with industry and academia, developed a training package to educate the mining com­munity about some possible interventions beyond kneepads that may be used to help decrease knee injury rates. Increased awareness and simple changes are the first steps to reducing knee injuries.

Jan 1, 2008

By d&apos, Kathleen J. Amico

THIS SUMMARY appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operatons at or near mines.

Jan 1, 1963

By Ronald H. Church, Walter E. Pittman, J. T. McLendon

In its role of providing technical assistance to the mining industry, the Bureau of Mines&apos; Tuscaloosa Research Center has conducted research to develop trapped miner location systems which would aid in locating miners trapped by underground mining disasters. Efforts to produce electromagnetic systems for the location of trapped miners underground and to communicate with them were surveyed, from the 1920&apos;s to 1981. Theoretical studies of through-the-earth electromagnetic transmissions are described as well as studies of the electrical characteristics of various rocks, minerals, and soil. Several trapped miner location systems are reviewed including the Westinghouse systems, the DEVELCO system, and an automated three-dimensional location system, and the phase difference of arrival technique. Tangential research, relevant to trapped miner location systems is described. A comprehensive bibliography covering all aspects of trapped miner, through-the-earth electromagnetic location and communications systems is appended.