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By G. L. Neumann

"INTRODUCTION Mining in this area is inactive. The entire region is now comprised of small farms. Because approximately 1,500,000 tons of magnetite ore had been shipped from this area between 1855 and 1915, it was deemed probable that geophysical surveying and core drilling might indicate other ore bodies or sizable extensions of the previously mined ore bodies.ACKNOWLEDGEMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has, as its primary objective, the most effective utilization of our mineral resources, thus fortifying our national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiatien tests.The chemical analyses and beneficiation tests included in this report were performed at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and the immediate direction of Dr. Alton Gabriel, head of the laboratory service unit.The Mineral exploration Was under the general supervision successively of G. D. Jermain, district engineer, C. B. White, district engineer, and McHenry Mosier, chief, College Park Division, Mining Branch.The geophysical section of the exploration was performed by G. B. Botsford, engineer of the Bureau of Mines. Assistance was given by the Division of Geophysical Exploration of the Bureau of Mines, Dr. F. W. Leo, chief."

Dec 1, 1947

By J. A. Kosek

Work has been carried out under Bureau of Mines Contract HO 395132 to develop improved sensor cells for use in direct-reading detectors and diffusion exposure meters. A pumped CO sensor cell was developed which has a shorter response time, improved temperature cycle characteristics, and improved linearity and stability at high CO concentrations. Diffusion CO sensor cells have shown good response level stability and linearity up to 1000 ppm. In addition, a new sensor cell catalyst has been developed for NO2 sensor cells which has a much shorter response time and improved response stability characteristics.

Jan 1, 1982

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By H. William Zeller

The Bureau of Mines is conducting research to determine whether the use of chemical surfactants improves respirable coal dust control and is evaluating laboratory test criteria for selecting effective surfactants. This publication presents the results from wetting effectiveness tests with emphasis on the capillary rise test. The test variables investigated included coal particle size, type of surfactant, surfactant concentration, test duration, and mineral con-tent of the water. In addition to the rise test, measurements of con-tact angle, zeta potential, and sink time for various coal and surfactant combinations were conducted. No significant correlations among the four wetting tests were observed, a surprising result which implies that each test type measures specific aspects of the wetting phenomenon and also that each test type should only be used to select surfactants for specific applications. For example, the rise test shows solution penetration into porous materials, and the sink test discriminates among surfactants for dispersing finely ground materials into suspension. Another important conclusion is that combinations of agents retain their individual wetting properties, allowing mixtures to be for-mulated to perform well in both rise and sink tests.

Jan 1, 1983

By R. D. Leitch

[The accepted theory of acid formation in coal mines with the subsequent appearance of the acid in coal-mine drainage, is oxidation of iron pyrite and subsequent solution and hydrolysis of the iron sulphate formed. It has also been found that 5 gobbed sections and worked-out areas, where there is usually an abundance of iron pyrite-bearing, materials in contact with air, are the sections that make the most important contribution to the quantity of acid drainage. It would thus seem obvious that if oxygen can be kept out of contact with tae acid-forming materials in tie- sections mentioned the amount of acid in coal-mine drainage could be reduced markedly and corrosion problems with mine pumping equipment and general stream pollution mitigated thereby. Although the efficiency of the suggested remedy as been borne out by laboratory experiments6, it has appeared desirable to substantiate the laboratory work by field observations in so far as pertinent data are available. It has been difficult to learn of mines or sections of mines about to be sealed, whereby an actual comparison of the drainage before and after sealing can be made. In view of that difficulty it has been necessary to devote attention to a comparison of the character of the water from areas already sealed with that from open but otherwise comparable sections of the sane mine. Previous cork has shown that the acidity of drainage in different parts of the same mine may vary, but if it can be shown also that the water from sealed areas is with but fen exceptions less acid than the otherwise similar open sections of tae same mine, the laboratory finding will be supported in a practical gray. This report presents some of the evidence that has been obtained.]

Jan 1, 1930

By Walter G. Dupree

When the original version of this study was published in 1972 it was evident that a problem was developing on the energy scene. The ability of the United States to find the energy supplies it needed within its own boundaries--at least in the forms desired--was declining. Production of crude oil in the United States had peaked in 1970 and was declining slowly; environmental restrictions had begun to hamper the production and consumption of high sulfur coal; natural gas reserves were beginning to dwindle; and the development of nuclear power was proceeding more slowly than originally planned. Shortfalls in energy supply were being met through the importation of increasingly larger quantities of petroleum, but supplies were adequate and the price of the imports was below that of domestic production. The energy problem was more prospective than current. In October of 1973 the prospective problem became the "Energy Crisis' when the Arab petroleum exporting countries reduced crude oil production, imposed an embargo on the shipment of crude oil to the United States, and then raised the price of crude oil in a series of large steps. This crisis was a clear demonstration of the dangers of the dependence of the United States on imported petroleum, and of the Nation's vulnerability to the actions of the oil exporting countries. After the embargo was lifted, attention shifted to the immediate hardships resulting from the higher prices for gasoline, fuel, and electricity,

Jan 1, 1975

By N. Dixon

This report summarizes all work performed under U.S. Bureau of Mines Contract J0377014, "Development and Evaluation of Noise Control Techniques for Taconite Processing Equipment." Three areas of taconite processing equipment, grinding mills, fine screens, and crusher screens have been investigated. Extensive noise and vibration measurements have been made on grinding mills in which the process parameters that affect mill noise have been identified, and the level of shell impact noise around the mill defined. A multiplexing telemetry system was used to obtain shell vibration measurements from a rotating mill. Mill noise control methods were investigated and a partial mill barrier was built and tested on a semi-autogeneous mill. A noise reduction of approximately 3 to 6 dBA was achieved on the falling side of the mill. The use of rubber mill liners on autogenous mills has been evaluated. The noise sources on fine screens have been quantified, and noise control treatments developed. Noise reductions of 11 to 13 dBA were achieved at positions around the fine screen and some in-service testing has been done. Noise measurents of crusher screens were obtained and noise control through resilient screen decks appears to hold the most promise. Additional benefits might be lower life-cycle cost, since the service life of resilient decks is claimed to be longer than steel.

Jan 1, 1983

By R. L. King, J. Cervik, A. A. Campoli

The Bureau of Mines performed laboratory experiments to evaluate the triboelectric effect of particulate-laden gas streams on polyethylene pipe at various velocity, humidity, dust-size, and dust-load conditions. Charges in excess of 10 kV were produced on the outside and inside surfaces of laboratory pipe samples, when exposed to 40 pct relative humidity (RH) gas stream containing coal dust. However, no charges were produced in laboratory tests that duplicated the over 75 pct RH and dust-free gas streams found in working underground pipelines. Bare cop- per wire, which is wound around the polyethylene pipe in a 1-ft (31-cm) spacing and grounded, eliminated the charge on the outside surface of the pipe, but not on the inside of the pipe surface,

Jan 1, 1986

By Willard L. Hunter

The Bureau of Mines studied the effect of temperature upon the reduction of chromite by carbon and the relative reducibility of chromites as a function of their composition. Ferric oxide was also studied to provide comparative data. Pellets weighing approximately 1 gram and containing 70 percent ferric oxide, chromic oxide, or chromite and 30 percent graphite were subjected to closely controlled temperatures under a flow of argon for 15 minutes. The amount of CO and CO2 evolved was measured, and the reduced sample was analyzed by X-ray diffraction techniques. The reduction of Fe2O3 was studied over a temperature range of 600° to 1,400° C, while the reduction of Cr2O5 and chromite was conducted from 9000 to 1,621° C. The temperature above which appreciable reduction of Cr203 by graphite took place was 1,125° C. The temperature at which significant reduction started for three of the four chromite samples was approximately the same, indicating that there was concurrent reduction of iron and chromium oxides in the chromite mineral rather than selective reduction of iron oxides followed by reduction of chromic oxide. Rhodesian chromite appeared to dissociate at a lower temperature with concurrent reduction of iron. Based on the temperature at Which chromite was 50 percent reduced in 15 minutes, Transvaal chromite reduced most easily, followed by Mouat, then by Kampersian, and finally by Rhodesian DFC material. Statistical analysis of test results indicated that the ferric iron content of chromites affects their reduction behavior more than any other constituent.

Jan 1, 1966

By G. D. Coe

Float-and-sink tests indicate what results are obtainable by gravity separation and rare therefore an invaluable adjunct to most coal-cleaning processes. However, it is difficult to make a direct interpretation of float-and-sink data on coal, and several systems for interpreting them have been proposed. Of these, that developed and used extensively by Bird3/, Yancey4/, and Gandrud5/ is considered by the author to be the most satisfactory. It makes use of four interrelated curves (hereafter referred to as be "washability curves"). These curves were explained by Bird in a paper6/ published in 1923, but his explanation has been regarded by some as not sufficiently

Jan 1, 1938

By E. S. Leaver

Experiments dealing with the dissolution of silver by cyanide from various silver minerals were reported several yews ago.4/ This work showed that the silver in some silver minerals is completely and readily soluble in cyanide solution, whereas other silver minerals must be given special treatment before or during cyanidation to obtain much dissolution of the silver by cyanide. Flotation as a method for treating silver ores has not been studied much, except in the case of base-metal ores carrying silver, particularly lead-silver ores. However, many mills now are concentrating gold ores by flotation, and when such ores also contain silver the recovery of the silver by flotation is of considerable importance. Moreover, many mines contain ore in which silver is the principal valuable constituent. Some of these ores are amenable to cyanidation, but the cost of a cyanide plant may be prohibitive because of limited ore bodies or other factors. In such instances the successful application of flotation would mean that the property could be operated.

Jan 1, 1939

By R. M. Ray

The Bureau of Mines evaluated five commercial badge-type carbon monoxide dosimeters. Color changes in the badge reagent indicated the presence of carbon, monoxide. Possible effects of ambient conditions on dosimeter response to CO during or after coal mine fires or explosions were studied. Temperature and humidity changes did not change dosimeter sensitivity to CO. Contaminant gases such as CO2, N02, S02, and H2S had effects that varied with brands of dosimeters ranging from no effect to increased sensitivity to CO. Dosimeters tested after 6 months of storage showed an increase in failure rate as high as 25 percent. Tests were conducted to determine the effects on dosimeter time-for-color change caused by observer's sight (colorblind); lighting, and coal dust on dosimeters. No significant effects were observed. Observer variance was the most pronounced factor observed in all tests.

Jan 1, 1975

By Manuel Gomez

A general prediction model for the Hardgrove grindability index was constructed from 735 coal samples using the proximate analysis, heating value, and sulfur content. The coals used to develop the general model ranged in volatile matter from 12.8 to 49.2 percent, dry basis, and had grindability indexes ranging from 35 to 121. A restricted model applicable to bituminous coals having grindabilities in the 40 to 110 range was developed from the proximate analysis and the petrographic composition of the coal. The prediction of coal grindability within a single seam was also investigated. The results reported support the belief that mechanical properties of the coal are related to both chemical and petrographic factors of the coal. The mechanical properties of coal may be forecast in advance of mining because the variables used as input to the prediction models can be measured from drill core samples collected during exploration.

Jan 1, 1970

By J. A. Ruppert, P. M. Sullivan

A study was made of filtration techniques for recovering the major part of the tin contained in iron - tin alloys known as hardhead . Special smallscale filtering apparatus and a three - stage cyclic process were developed . Eighty- seven percent of the tin contained in an alloy of 82 percent tin and 17 percent iron was recovered as pure metal by pressing at 975° C followed by a second pressing at 800 ° C and a final filtering at 250 ° C. Small amounts of Sb , Cu , and Fe impurities were removed by adding Al to the molten product and performing another filtration at 250 ° C.

Jan 1, 1964

By R. P. Vinson

The Bureau of Mines examined the effects of high humidity and water droplets on the GCA Corp. real-time aerosol monitor (RAM--l). which uses a lO4mm cyclone preseparator. Tests were conducted both in a laboratory and in a full-scale model mine entry. The laboratory tests were conducted in a test chamber saturated with moisture and water droplets. Under these extreme conditions. the RAM-I responded by indicating dust concentrations of 1-1/2 to 2 mg/m3? although the air was dust free. Within the first 2 h of each test. water accumulated in the cyclone and affected the cyclone particle separation characteristics. resulting in readings of 3 to 4 mg/m3. In addition. condensation formed inside the RAM-I case and affected the liquid crystal display (LCD). However. the full-scale mine entry tests revealed that the RAM-I can function ac-ceptably in an atmosphere of water vapor and water droplets similar to the most severe conditions found in an underground mine.

Jan 1, 1984

By H. D. Hess

This report presents the results of laboratory mineral evaluations conducted by the federal Bureau of Mines under the joint sponsorship of the U.S. Atomic Energy Commission (AEC) and the Bureau a! Ships, U. S. Department of the Navy. The major purpose of this investigation was to examine and evaluate zirconium minerals representing sizeable deposits in an effort to locate com¬mercial sources of high-hafnium ores. Although determination of the hafnium content was the principal objective, each of the zirconium minerals also was analyzed for combined zirconium-hafnium oxide, silica, uranium, thorium, yttrium, and cerium. The general laboratory procedure involved microscopic examination of the test samples, concentration of the hafnium-bearing zirconium mineral by standard laboratory techniques, and analysis of the derived concentrate by quantitative microscopic, chemical, and X-ray spectrographic methods. Of the several hundred samples tested under this program, 147 are discussed in this report, including 94 from domestic occurrences and 53 from widespread foreign sources.

Jan 1, 1962

By Robert J. Hundhausen

During the early part of World War II , it appeared likely that supplies of chromite for United States industry might become critically short . As a part of the ensuing search for new sources of domestic chromite supply , the chromite - bearing black sands along the coast of southern Oregon were hurriedly investigated by State and federal agencies and by private interests , These investigations led to a decision to begin exploitation of the deposits immediately . A government stock- piling program was put into effect , a concentrator was financed by the Defense Plant Corporation , two privately controlled companies were encouraged to start mining operations , and the Bureau of Mines and the Geological Survey were authorized to search. for additional reserves of minable ore .

Feb 1, 1947

By A. R. Taylor

This report describes the design, construction, and operation of a low temperature adiabatic calorimeter for measuring heat capacities of solids or liquids from 60° to 300° K. A brief discussion of the basic theory involved in chemical thermodynamics and the problems involved in obtaining accurate experimental data is presented. The operation of the calorimeter was tested by measuring the heat capacity of a sample of benzoic acid obtained from the National Bureau of Standards over a temperature range of 60° to 300° K. The measured heat capacity values of the benzoic acid compared favorably with similar values obtained by the Bureau of Standards, the maximum deviation being 0.5 percent. THEORY A brief discussion of the basic theory involved in chemical thermodynamics will illustrate the applications of heat capacity data and the problems involved in obtaining accurate experimental data.

Jan 1, 1962

By William A. Beck

This paper is one of a series, describing current practice in diamond drilling for production at various mines throughout the United States. It describes the drilling and blasting methods, used at the Tennessee Copper Co., which started using deep-hole drilling for blasting in 1927, employing inde- pendent, rotation percussion drills with sectional drill steel. Since 1942 the company has employed diamond drills for deep-hole drilling. This method has now passed the experimental stage and promises to become permanent. The elimination of rock dust and safer working conditions for the drill crews are listed as the main advantages. The higher initial cost of equip- ment is the principal disadvantage.

May 1, 1948

By B. W. Madsen

A modified transpiration apparatus was devised by the Bureau of Mines to permit rapid and accurate measure of the vapor transport and vapor diffusion coefficients of antimony sulfide (Sb2S3) and other compounds at temperatures to 1,045 K. The apparatus was equipped with dual condensers and valves to switch the flow of vapor in a fraction of a second from one condenser to the other, thus allowing short-interval sampling under equilibrium conditions. Reliability of the technique was established by measuring the vapor pressure of ZnC12 as a function of temperature and comparing the results with published data. As part of an investigation of the vapor concentrations and species of accessory element sulfides associated with copper and zinc smelting, the apparatus was used to measure the rate of vapor transport and diffusion coefficients of vapor over liquid Sb2S3 as a function of temperature between 870 and 1,045 K. The calculated vapor density was combined with published direct measurements of vapor pressure to calculate the average molecular weight of the gaseous species. Average molecular weight of the vapor in equilibrium with Sb2S3 ranged from 286 to 112 g/mol over the temperature range studied.

Jan 1, 1983