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By A Cox

It has been demonstrated that all the cadmium from spent batteries, typically 4 g per battery, can be recovered by burning polyvinyl chloride waste to yield hydrogen chloride; this reacts to produce volatile calcium chloride, which can then be condensed and collected in a separate reactor. Alternatively, chlorine may be used to chlorinate the cadmium with equal efficiency. There is also a prospect of using very low concentrations of these gases, less than 1%, to effect the separation. The Cd was recovered more quickly when exposed to sustained, controlled flow rates of chlorinating gases, whereas when PVC was burnt most of the gas was produced in a very short time, not allowing complete reaction. This problem can be overcome by recirculation of the gas into the reactor. The technology is efficient and clean and the equipment used is simple, enhancing the prospects for a pilot-scale version of the process

Jun 21, 1905

By M. T. Styles, E. Condliffe, R. C. Leake, R. J. Chapman, D. J. Bland

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Quantitative point analysis and microchemical mapping identified 52 different types of mineral in inclusions, usually ranging in size from 5 to less than 1 micrometre, inherited from source bedrock. A combination of grain chemistry, heterogeneity and inclusions provides a grain signature reflecting the type and history of source mineralisation. Several grains from an alluvial site are needed, to allow for bedrock variation and the presence of inclusions in only 10-20% of grains. A total of 1 530 grains obtained from 30 localities in Scotland were of ten types, two of them minor variants. Two types in the Highlands may be related to centres of Caledonian igneous activity, but the most widespread is likely to have been of deep-seated origin and structurally controlled. Gold in the Ochil Hills is probably from a source associated with Devonian andesitic activity. In the Southern Uplands, grain types reflect two separate episodes of mesothermal lode gold mineralisation and relationships with Permian red beds/mafic volcanics and with Tertiary dykes

Jun 19, 1905

A production drill rig at a site in Sweden was equipped with a monitoring system to estimate production statistics. Drill running times, drill hole depths, penetration rate, rotation speed, thrust, air percussive pressure and torque pressure were recorded for every 10 mm of hole length for a period of 5 months. Operational activities (rock penetration, tube handling, moving and set-up time) accounted for almost 62% of the time consumed, the remaining 38% being different types of stoppage. Drilling itself, as opposed to handling, took less than 24% of the total time. The results give an indication of how the overall drilling capacity can be increased and which activity should be emphasised. The impacts of automation, new developments and reorganisation on production can also be predicted. Average production was found to be around 100 m/day, but varied between 50 and 160 m/d. The company's specification for the drill rig, before purchase, was that an average production rate of 130 m/d be attained over two consecutive months of drilling - a rate which monitoring shows will not be achieved

Jun 19, 1905

By K. D. Russ, A. J. Beer

Non-contact systems for measuring underground voids have used theodolites, reflective or non-reflective laser methods and sonar techniques. An effective but cheaper alternative is based on use of a Wild T1000 electronic theodolite coupled to a Leica Data DISTO and a Wild GRE3 data logger. The software used to process the theodolite data is a spreadsheet and macro combination, while Surpac, Datamine and AutoCAD modelling packages have been investigated for viewing the tunnel profiles. The main limitations were found to be blinding, when irregularities in the stope obstructed the line of sight, and the 30 m range of the Data DISTO model used in the study, although more powerful models are available. All three modelling packages proved suitable, with Surpac providing the best-quality printed images of the voids surveyed and AutoCad by far the cheapest alternative

Jun 21, 1905

By T. Serradj

A study has been carried out to: develop a method for routine characterisation of rock strength and drillability through the particle-size distribution of crushed or drilled rock products, defined by the Protodyakonov index; establish correlations between the Protodyakonov index, uniformity coefficient and the constant grading equations; and propose an alternative rock characterisation index to classify rock strength and drillability for the northeast region of Algeria

Dec 1, 1996

By G. D. Schena, C Chiaruttini

The feasibility is demonstrated of reconstructing the volumetric distribution of liberated particles and middlings by use of a damped, weighted least-square regularisation method. This allows a precise mass balance to be obtained around a separation/concentration unit, permitting evaluation of the partition curve (Tromp curve) of the separator. Areal grade measurements are made on polished sections of feed, concentrate and tailings and a kernel-based inversion technique is then used to obtain the volumetric grade distribution of the three assemblages. A plain kernel (number of occurrences) and a weighted kernel (each occurrence counted with its area) are used for the solution. Testing of the method on computer-generated synthetic areal grade measurements indicates that it offers a valid alternative to the tedious conventional procedure of conducting experiments with heavy liquids

Jun 21, 1905

By D. C. Kaliampakos, A. K. Moutsatsou, J. K. Skotaras

The wastes from marble extraction in the Thasos- Kavalla-Drama region of northeastern Greece could be utilised as a new source of high-quality white carbonate fillers for the European market. Large deposits, satisfactory properties, acceptable processing costs and environmental benefits are among the factors that would have a positive bearing on a proposal for their use in this way. DTH, the waste arising from dolomitic marble quarrying operations on the island of Thasos, appears to be the more suitable material than DA waste from Nikissiani on the mainland because of the lower cost of primary grinding and the higher production rate of ultrafines with a mean particle size of 5 micrometres (the optimum size for filler properties in the case of both DTH and DA), its superior whiteness, the benefits that such use would bring to a very severe and complex environmental problem and the lower transport cost

Jun 18, 1905

By D. M. Evans, D. L. Buchanan

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. The Zinca area was chosen as a suitable location for an investigation of the weathering and secondary dispersion of platinum group metals from the Zone. It was concluded that platinum is immobile while within weathered rock, its mineral phases tending to alter from primary sulphides and tellurides to secondary Pt-Fe alloys. Palladium is variably mobile in weathered rock. In stream sediments Pt occurs mainly as small, dense, discrete particles, giving rise to a nugget effect, whereas Pd probably occurs as much finer particles or chemically adsorbed on to a suitable substrate. Pt shows a rapid decrease in sediments downstream from mineralisation, whereas Pd has a much slower downstream decay

Apr 1, 1994

By E. O. Afreh, R. J. Bowell, E. Hanssen, D. Pohl, S. Abe, R. K. Yao, N. d'A. Laffoley

In the largely preserved laterite profiles at Syama mine, in the savanna region of southern Mali, element geochemistry in the mottled-clay horizon and below can be related directly back to the protolith, but above this, in the ferricrete and cuirasse horizons, the hypogene signature is much modified by pedogenic processes. In tropical rainforest terrains extensive remobilisation can result in wide but weak geochemical targets for gold and pathfinder elements. At the Hire concession in central Ivory Coast, intense recent alteration of the largely intact laterite sequences has modified soil-geochemical dispersion patterns extensively, producing Fe-rich nodular stone lines and obliterating previous patterns and features. Where the upper horizons of the laterite profile have been removed or reworked, as at the Senoufo concession in northern Ivory Coast (savanna) or the Kubi prospect in Ghana (rainforest), all soil horizons can be related directly to hypogene geochemistry. In these truncated profiles, gold and base metal anomalies are essentially those of the lower weathering profile and form narrow but strong dispersion haloes. A good understanding of the geochemical processes active in deeply weathered profiles is required if targets are to be recognised effectively

Apr 1, 1996

By S. Al-Hassan

The deposit has been exploited for Mn oxide and carbonate since 1916. Known reserves of MnO, however, are almost depleted and the survival of the mine will depend on the exploitation of the carbonate. Kriging, inverse distance weighting (IDW) and cross-sectional methods have been applied to the evaluation of the carbonate resources and reconciliation of the estimates obtained shows that kriging and IDW give almost identical block values. A comparison using conditional probability indicates that there is virtually no difference between the global reserve estimates derived from the cross-sectional and kriging methods. The physical causes of these similarities are highlighted and the problems of dealing with multimodal distributions are discussed together with the difficulties of semi-variogram modelling

Jun 19, 1905

By F. Tailoka, G. Zhao

Pb is an unwanted impurity in Al for which there is no established method of removal. As it interacts strongly with alkali metals, separation was achieved by adding Na or K to molten Al at 953-1 003 K. Direct Na addition led to considerable evaporative loss but in-situ addition by electrochemical titration from a eutectic NaCl-KCl or KCl-BaCl2 mixture was found far more effective, in some cases reducing Pb content below detection levels within 2 h of titration. K appeared more effective than Na at low Pb concentrations but the use of Na was preferred as it is less toxic and explosive. Na removal from Al-Na and Na-Pb alloys was also carried out electrochemically, the use of these two alloys rather than the eutectic salt as a source of Na avoiding liberation of Cl2 at the anode

Apr 1, 1995

By G. W. Harris, J. J. K. Daemen

Slightly shorter, modified version also published in CIM Bull., vol.94, no.1047, Feb. 2001, p.52-55. To minimise ore dilution induced by blast movement in surface mines it is necessary to quantify such movement. This will allow more accurate location of the grade boundaries on the surface of a blasted rock pile before excavation. A method has been developed and tested for measuring accurately the direction and magnitude of subsurface blast movement, using a caesium vapour gradiometer and a real-time, differentially corrected global positioning system to locate the pre- and post-blast positions of magnetically enhanced target objects placed in blastholes inside a bench. The procedure does not necessitate disturbance of the blasted rock and the movement information is available sufficiently quickly to allow for modification of the selective mining boundaries for each surveyed blast. It was found that the maximum depth of target detection was 18 m and the overall accuracy was plus or minus 1 m horizontally and 1.2 m vertically

Jun 21, 1905

By J. Crummy, I. K. Anderson, A. J. Hall, R. S. Haszeldine

Bedrock gold mineralisation has been located in association with an extensive float train 25 km west of known alluvial gold. It is in the form of open, matrix-supported breccias comprising pyritic quartz/sericite clasts in a vuggy, cherty chalcedonic and crystalline quartz matrix. Fluid inclusions in pyritic clasts indicate trapping temperatures for gold mineralising hydrothermal fluid of 170-240 degrees C. This mineralisation could represent the upper part of a feeder zone to an exhalative hydrothermal system. It is possible that other high-level feeder zones could be preserved elsewhere in the area. Deep weathering of such a system could provide a source for the alluvial gold localities near Helmsdale. It is suggested that east and central Sutherland presents good prospects for exhalative epithermal gold mineralisation and the associated feeder zones

Jun 19, 1905

By S. L. Gay

The conventional mass-balance equations used as constraints can lead to flow estimate values of zero even though the flow estimates should be some positive number. This is because many of the constraint equations are satisfied if the flow rates are zero. The way to overcome the problem is to use a slightly different form of the equations. For example, rather than use the conservation of flow of solids as a constraint it is better to use the constraint that the percentage of solids going into a unit equals the percentage of solids coming out of the unit. Examples are given using mineral processing data sets from Mount Isa, Queensland, and Red Dog, Alaska

Jun 21, 1905

By B. J. Breen, C. S. Mogg

Considerable borehole investigation work has been completed at a proposed site at Sellafield in Cumbria, supplemented by seismic surveys, other geophysical sensing and geological mapping. The focussing of investigation on the rock mass itself will be achieved by means of the planned underground rock characterisation facility, giving access to depths of about 800 m in the strong, low-permeability basement rocks of the Borrowdale Volcanic Group. Characterisation work undertaken during the sinking phase and interaction with continuing surface-based exploration and monitoring should permit a firmer assessment of the long-term safety of a repository. Key considerations in the choice of a design for the repository include the waste handling method, underground inlet cell, underground vaults, vault environment and environmental effects

Aug 1, 1994

By J. Konnerup-Madsen, T. Unlu, H. Stendal

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The region includes the Deveci siderite/goethite deposit and the Hasancelebi, Karakuz and Kuluncak magnetite/goethite deposits; Deveci is the only mine in operation. The area consists of a serpentine-gabbro complex overlain by a volcano-sedimentary sequence hosting the iron ores. At least three generations of hydrothermal alteration have affected all rock types except the latest trachytic dykes. The Deveci deposits occur in a pyroclastic volcano-sedimentary sequence with shales and carbonates equivalent to the main mafic sequence, whereas the other three deposits formed contemporaneously with the intrusion of trachytic dykes. The deposits are of the volcanic-exhalative type, with syngenetic siderite in pillow lavas or stratiform layers the primary and main Fe-bearing mineral. In the west hydrothermal alteration has replaced siderite in pillow lavas with magnetite or has remobilised sideritic iron into magnetite veins

Apr 1, 1995

By R. O. Suominen, P. A. Taskinen, K. R. Lilius, A. T. Jokilaakso

Chalcopyrite concentrate was flash-oxidised in a laminar-flow furnace in oxygen-nitrogen atmospheres that ranged in composition from N2 to N2 + 50 vol% O2. Gas pre-heating temperatures were 500-1100 degrees C and four particle-size fractions were studied: 28-38, 38-44, 44-62 and 62-74 micrometres. The effect of the residence time of the particles on sulphur removal was studied in the range 0.1-0.35 s. Scanning-electron microscopy combined with energy-dispersive analysis and back-scattered electron analysis was used to determine the morphology and mineralogy of the reacted particles. Total desulphurisation was achieved under the most oxidising conditions. Particles were observed to undergo fragmentation during oxidation, the violence of this depending on the iron and sulphur contents and the original particle-size fraction. The melting and/or reaction stages of the particles under different conditions were studied in powder samples. Polished sections were examined to follow the development of porosity and the mineralogy of the particles. A model for the fragmentation process is described

Jul 1, 1991

By V. Krupa, E. Lazarova

A method is proposed for the continuous calulation of a rock mass in real time while tunnelling with a TBM. Rock properties are investigated through models of the fracture stress under the disc cutters, the quasi-shear stress between the disc cutters and the specific energy of cutting under the disc cutters. Comparison of theoretical and monitored data of cutting specific energy can be used to determine theoretically the prevailing shape and size of the bulk debris. The shape and size of the chips from a given rock vary with the boring parameters. Introducing shape and volume corrections into the models of the evaluated stresses suppresses the influence of the boring regime and allows the rock properties to become dominant

Dec 1, 1996

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By L. J. Barnes

The process for bio-remediation of sulphidic slag (BROSS) operates at 45 degrees C in a neutral (pH 7), aerobic aqueous environment in which sulphide in the slag is converted to sulphate. A two-stage version has been developed that involves quantitative chemical pre-oxidation of total sulphide to thiosulphate, followed by complete biooxidation of thiosulphate to sulphate. Ferric hydroxide, also produced, acts as a flocculant in the bioreactor effluent, concentrating heavy metal precipitates in the thickener as a sludge which can be returned to the smelter. The process has a high sulphate production rate and low acid and nutrient consumptions. Microorganism growth is the rate-limiting stage, requiring a minimum liquid residence time in the bioreactor of about 7 h. Although large quantities of oxygen are needed, sufficient gas mass transfer can be attained in an air-lift reactor. Products are an aqueous stream containing sodium sulphate with only trace levels of toxic heavy metals and a benign, toxic metal-containing sludge

Jun 18, 1905