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By E. Alldén Öberg

In 2004, LKAB decided to start a basic engineering study in expanding its existing production lines at the Malmberget mine site. It was expected that some of the production lines would become bottlenecks with reference to capacity. In this study, the sorting plant is examined and the results show that several unit operations will be limiting under current operating conditions. An additional purpose with the study was to investigate how replacement of some machines would influence performance and if production plans for the coming years might be achieved. Steady-state simulations using the software Modsim? were extensively used to study process performance for different operating conditions, such as iron content and size distribution in run-of-mine ore. Model parameters were derived from pilot plant data and when possible from ex-isting circuits. A complication for the simulations was the lack of relevant data and therefore some of the initial results were only indicative. The result shows that installation of new screens would give a much better operation, but also new crushers would be an improvement. This, since they can be run with full crusher chamber and tighter CSS. During 2007, most of the proposed remedies were implemented and the result is that the bottle-necks are gone, and the grades and material balances are even better than what was envisioned from the simulations.

Jan 1, 2014

By A. M. Ozbayoglu

Gross calorific value (GCV) of coals was estimated using artificial neural networks, linear and non-linear regression techniques. Proximate and ultimate analysis results were collected for 187 different coal samples. Different input data sets were compared, such as both proximate and ultimate analysis data, and only proximate analysis data and only ultimate analysis data. It was observed that the best results were obtained when both proximate analysis and ultimate analysis results were used for estimating the gross calorific value. When the performance of artificial neural networks and regression analysis techniques were compared, it was observed that both artificial neural networks and regression techniques were promisingly accurate in estimating gross calorific values. In general, most of the models estimated the gross calorific value within ±3% of the expected value.

Sep 1, 2012

By R. K. Dwari

The electrostatic beneficiation of coal is based on tribocharging characteristics of ash forming minerals and coal particles. The tribocharging of quartz, pyrite and coal particles contacted with various metals and polymeric materials have been measured and the charge acquisition is assessed through surface energy calculations from liquid contact angle data. The contact angles, before and after tribocharging of solids, are measured using Krüss tensiometer and Washburn?s method where the sample holders in tensiometer are specially constructed with tribocharger materials. The charge polarity and amount of charge acquired by quartz, pyrite and carbon with metal tribochargers were found in good agreement with the reported work functions of the contacting surfaces. The charge results with polymer materials differed from the work function values, presumably caused by surface contamination. The surface energy of quartz calculated by all the theoretical approaches in the literature showed that the tribocharging increases the surface energy. Both polar and non-polar components computed from Fowkes and Owens-Wendt-Rabel-Kaelble approaches dis-play that both these components increased after triboelectrification. However, the polar component divided into acid and base components, as in van Oss approach, manifest decreasing acid part and increasing base part. Since quartz charged negatively during tribocharging with metal surfaces and therefore accepted electrons, the determined acid and base surface energy components are consistent with charge transfer process. The results also elucidate an explicit correlation between the charges generated by powders and the surface acceptor (acid) and donor (base) electronic states and thereby the work functions. A novel fluidized bed tribocharger was designed and developed with internal baffle system for efficient contact electrification of mineral and maceral to produce high differential charging for efficient separation. The results achieved on coal with 45% ash content are presented and discussed.

Jan 1, 2014

By M. R. Hosseini

Among all gravity concentration methods, Shaking-table is the most effective one from the metallurgical point of view. In this study, Shaking-table was used for concentrating a manganese ore sample from Ghasem Abad area in Kerman, Iran. Experiments were designed by using L8Taguchi design with five variables and each variable in two levels. The influence of each variable and their interactions on the operation of the device was studied. The variables under investigation were: table slope, table frequency, water flowrate, feed rate, and particle size. The manganese concentrate grade and recovery were used as response variables. It was shown that water flowrate, table slope, feed rate, and particle size are the significant variable on concentrate grade; while, all the variables influence manganese recovery.

Jan 1, 2014

By A. R. Hasankhoei

Water recycling is of prime importance in mineral processing due to consumption of large amount of water. This issue is vital in areas with a low rainfall such as Shahre-Babak (Kerman, Iran). Deep cone thickeners, unlike conventional thickeners, have a low diameter to height ratio where large amounts of flocculants are used to increase particles settling rates. The high bed heights (over 10 m) produce enough pressure to create a paste type underflow indicating maximum water recovery. Flocculent preparation, conditioning, and distribution along with the bed height are among the important factors affecting the performance. Four deep cones are used to recover water from the tailings of the plant. Plant data indicated that the thickener never reached the target underflow percent solids (63%) and the average underflow concentrations were between 49 and 57%. By modification and optimization of flocculent preparation and distribution methods the underflow percent solids increased by 3-4%. This translated to an increase of water recovery from 67 to 73%. This was equivalent of 53000 m3 saving in monthly water consumption. Keywords: deep cone thickener, water recovery, flocculant, copper tailings

Sep 1, 2012

By A. Pankewitz

The well-established on-line particle size analyzer OPUS manufactured by Sympatec GmbH, has been successfully implemented in several mining and industrial minerals project. OPUS monitors the particle size distribution in 31 fractions as well as the solid concentration in opaque and highly concentrated ore and mineral slurries on-line in real time e.g. behind mills or cyclones applying 31 ultrasonic frequencies for highest resolution. Ultrasonic extinction overcomes all limitations known from optical and mechanical systems like contamination, blockage and wear. OPUS measures slurries in their original state without any dilution, hence no extensive sampling procedure or sample conditioning is required thus no dilution errors occur. Due to the OPUS design and suitable algorithms entrained air bubbles do not affect the quality of analysis at all. The sensor covers particle size distributions from 0,01 to 3.000,00 µm and solid concentrations up to 70 % by volume and can be easily adapted to a number of production lines simultaneously. Jiangxi Copper?s Dexing Mine is one of the biggest copper mines in Asia and among the first users for OPUS on-line particle size and concentration analysis in mining industry. OPUS is connected to 2 process lines. Jiangxi Copper has implemented OPUS for into their central control system for the grinding & classifying circuit of one SAG mill and one ball mill. Analysis data and process control as well as optimization based on OPUS particle size and concentration measurements will be discussed Keywords: particle size analysis, ultrasonic extinction, concentration analysis, grinding control

Sep 1, 2012

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki

"Hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in various applications. It has also been reported to reduce the recovery of sulfide minerals. Moreover, the previous work applied H2O2 aqueous solution in selective flotation of chalcopyrite and molybdenite. However, the oxidation method suffered in pilot scale test due to too long conditioning time. Furthermore, the excessive reagent consumption increased the reagent cost, causing the method not economically feasible. Consequently, further improvement is required to reduce the conditioning time and the reagent consumption. The oxidation performance of H2O2 can be improved by using ferrous iron as catalyst, producing a Fenton’s reagent which is more powerful oxidizer than the H2O2 itself. Therefore, the effect of Fenton’s reagent on the floatability of chalcopyrite and molybdenite was investigated in this study. The flotation test results show that selective flotation of chalcopyrite and molybdenite might be possible at low concentration of H2O2 aqueous solution by adding ferrous iron. Moreover, the conditioning time could be shortened by this improvement. To understand the phenomenon, surface characterization using atomic force microscopy (AFM) along with x-ray photoelectron spectroscopy (XPS) analysis were carried out. The AFM images show that the surface of chalcopyrite was readily covered with mountainous features which alters its hydrophobicity after the oxidation treatment. Meanwhile, the molybdenite surface remained clean and relatively hydrophobic. The XPS results indicate that the mountainous features are various oxidation products (i.e., FeOOH, Fe2(SO4)3, CuO, Cu(OH)2). Possible mechanisms of this phenomenon were proposed in this work.INTRODUCTIONConventionally, copper and molybdenum ores are separated in selective flotation circuits by using copper depressants (i.e., sodium hydrosulfide (NaHS), sodium sulfide (Na2S), and Nokes reagent (P2S5+NaOH)). However, these depressants are usually toxic or hazardous. Therefore, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, ozone, and plasma pre-treatment (Arbiter and Young 1951; Barzyk et al. 1981; Curtis 1941; Hirajima et al. 2014, 2017). Recent study by Chimonyo et al. (2016) reported the effect of H2O2 on reducing the recoveries of sulfide minerals. Moreover, Hirajima et al. (2017) demonstrated that H2O2 depressed the floatability of chalcopyrite and could deliver a selective separation on copper and molybdenum (Cu-Mo) bulk concentrate in flotation process. However, they reported that this method required a higher concentration of H2O2 and a longer treatment time (4.5 h) to get a comparable result to that of using NaHS as copper depressant. Therefore, further improvements are necessary to reduce the conditioning time and reagent consumption."

Jan 1, 2018

By E. Barsky

Physical principles of two-phase flows with a polyfractional solid phase have not received a sufficient theoretical interpretation as yet. Two-phase flows in the separation mode with a counter-flow of particles are even more complicated. Only statistical methods give an insight into general regularities of such processes. These processes can be interpreted best by analogy with the statistical model of an ideal gas developed by L. Boltzmann, although here a number of difficulties arise. The notion of a statistical system for such flows is substantiated. A mathematical estimation of a statistical system is presented. New notions are introduced, namely, potential extraction of a system and lifting factor. A relationship having the physical meaning of entropy is derived for a two-phase flow in the separation modes. The connection of this new entropy with flow parameters, such as the number of particles, separation factor and chaotizing factor, is established. Properties of this entropy are analyzed, as well as the analogy and difference between this entropy and Boltzmann?s entropy. The notion is formulated and the definition of the chaotizing factor of a process is suggested. In the framework of a statistical approach to two-phase flows in the separation mode, the notion of flow mobility has been formulated. Principal regularities of mass transfer in zone/apparatus sys-tem are analyzed. Principal ideas of a cellular model of the process are formulated, and main relationships for its description are derived. Proceeding from the cellular model, a dependence describing the degree of fractional separation of a narrow size grade is found. The analysis of this dependence makes it possible to reveal the crucial role of the Froude criterion for gravitational separation processes. It is found empirically that this parameter is a basis for the affinization of separation curves (Barsky E, Barsky M, 2006; Barsky, 1980).

Jan 1, 2014

By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Automatic identification and characterisation of mineral raw materials and beneficiated products are of major importance in mineral processing. However, minerals show great variety in their composition and physical and chemical properties. Industrial minerals may contain the same elements in about the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. By means of EBSD, diagnostic mineral information can be achieved if indexible patterns are provided.Until now EBSD has not been used frequently on geological samples for mineral and micro structure discrimination.The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques."

Jan 1, 2003

By V. Panayotov, M. Panayotova

"The combined use of semiconductor properties and specific flotation characteristics of minerals under different conditions with external influences ensures a possibility for process control and management. This work presents the relations between the volumetric and surface characteristics of minerals and the minerals' flotation ability (flotability), as well as the possibility for the flotability purposeful change. Results from proprietary laboratory and industrial research are presented showing how controlled impacts on minerals and flotation pulp improve flotation technology. Such an approach reveals prospects for the creation of new technologies for the minerals' beneficiation.INTRODUCTIONThe decrease of the useful components content in the ores, the increasingly complex nature of the raw materials, the increasing energy consumption per the unit of production, and the need to solve the problems related to the environment pollution require solutions different than the existing classical ones. One of the ways to find such solutions is the detailed consideration of the fundamental properties of minerals and, in particular, of minerals having semiconductor properties. The studies of Plaksin et al. (1968), Chanturia and Shafeev (1977), Chanturia and Vigdergauz (2008), Carta et al. (1973), Hoberg and Shneider (1975), Rao et al. (1992) have given an idea of the energy state of the minerals, their flotation ability, and the ways in which this ability can be changed in one or the other direction. The main line in these works is the study and use of the relationship between bulk and flotation properties of minerals. To improve the efficiency of the process, it is also necessary to consider the relationship between the surface properties of the minerals, especially minerals-semiconductors, and their flotation ability.THEORETICAL BACKGROUND IN BRIEFA quantitative estimation of energy changes in a solid phase in the process of flotation may be made by taking in account the changes in the Fermi level. Its position in the forbidden band is an indicator about the direction and the intensity of electron exchange between solid and liquid phases. The Fermi level energy EF enables the estimation of flotability, intensity of needed external impact before flotation, as well as efficiency of the process going on. Quantitative estimation of these processes can be made by means of the flotability coefficient Kf."

Jan 1, 2018

By Christopher Tucker, Marcello Veiga

Social issues are increasingly recognized as significant inhibitors to mineral development projects. Increasingly social risk is being recognized as a key factor determining the success of a mineral investment. Groups opposed to a mine for social or political reasons often use environmental impacts, real or perceived, to prevent mine development. These risk factors depend largely on cultural perceptions of mining activities and must be understood as such in order to be appropriately managed. A first step to addressing social issues is inclusive, transparent and meaningful engagement of stakeholders. This process allows stakeholders to understand what the other parties value in order to collectively establish a common currency for development and the creation of mutual value. Expanding the scope of benefits and values a mine can bring is of increasing importance to mining companies who typically consult outside specialists remote from the mine site and late in the development timeline for this purpose. Training technical staff, engineers and geologists, who make initial and ongoing contact with local interests, in a holistic approach to mine development is crucial to successful and economic mineral development projects. Further extending this conversation to the general public, media governments and non-governmental organizations is a necessary step in developing a meaningful discourse on the benefit of mining activities.

Jan 1, 2014

By E. Scheepers

The process under investigation is the large-scale production of phosphorus. Gravity delivers the feed, consisting of pelletised apatite, coke and silica (in the form of gravel), to a submerged arc furnace through ten, evenly distributed feed chutes ensuring constant packed bed volume. Within this packed bed, solid-gas reactions are dominant in generating the gaseous product. These reactions, as well as the packed bed itself, were the main focus in the development of a fully three-dimensional CFD model in which fluid flow and energy distribution are represented as functions of chemical reactions, heating and melting of material and heat losses. The associated complex process interactions necessitated the creation of two process-specific, user-developed models that integrates accurate, thermodynamical data with computational fluid dynamics calculations, as well as reaction kinetics. The boundary conditions are provided by industrial measurements, and the key model parameters of reaction kinetics were obtained by laboratory experiments for different feed mixtures. Thirteen temperature probes installed inside the refractory lining of the furnace especially for this project allowed parameter fitting and validation to be guided within the constraints of real measurements. Simulation results reveal a thin, dome-shaped, reductive zone where conditions are optimum for maximum phosphorus recovery, as well as evidence of a thermal reserve zone similar to an ironmaking blast furnace located above this reduction zone. When compared to actual operating data, the CFD model can successfully predict the specific power consumption, the phosphorus in the slag and gaseous product flowrate under given operating conditions. This CFD model forms part of a larger project that aims to create a Dynamic-CFD hybrid control model.

Jan 1, 2014

By Z. He

Based on full investigation of the characteristic of sphalerite in the residue obtained from cyanidation leaching process and the study of the mechanism of the interaction between flotation reagents and sphalerite with the aid of electrochemical analysis, the reagent named YO was developed for eliminating the depression effect of CN- on sphalerite and reducing the dosage of CuSO4. The achievements have been used in commercial production for the treatment of the cyanidation residue to recover the zinc minerals, obtaining a zinc concentrate with grade of 56.49% Zn and recovery of 86.63% Zn.

Jan 1, 2014

By T. Bhambhani

Research at Cytec over the past two decades has shown that the traditional approach for ore metallurgical characterization (typically conducted via laboratory-scale batch flotation tests), which involves changing reagents and conditions one-factor-at-a-time, leads to several pitfalls. The chemical solution thus selected has a narrow un-optimized window of performance and will likely fail in the plant. A holistic approach, called the Flotation Matrix 100? process for ore metallurgical characterization, was developed at Cytec about a decade ago and has been successfully used to develop robust reagent solutions for several operations around the world. The premise for the approach is that flotation outcome from ores is variable and is determined by complex interactions between various physical, chemical and operational factors. A key component of the process is the use of efficient multivariate designs focused on the chemistry aspects (reagents and pulp chemistry), which helps identify the best processing conditions for each ore type, as well as the conditions resulting in poor performance. It also includes advanced statistical methods for dealing with the complexity and variability of experimental data. The holistic approach is illustrated in this paper with a case study on Pb/Zn ores. Using just 18 carefully designed batch tests, it is possible to partially simulate the behavior of each ore type in the plant. The best conditions for each ore type, along with the conditions to avoid, are identified. Along with this, insights are obtained into the reasons for high reagent dosages for certain ore types, and interactions between variables. Keywords: flotation, holistic approach, metallurgical characterization, multivariate experimental designs, base and precious metals recovery, sulfide collectors and modifiers, Pb/Zn sequential flotation

Sep 1, 2012

By X. S. Yuan

With a demand for increasing energy efficiency and a need for improving bitumen recovery, a highly integrated solution for sustainable lease development of Aurora North of Syncrude has been proposed and implementation plans are underway. Flocculation and thickening technology as an important component of the integrated solution provides Syncrude an opportunity of rapid heat recovery from tailings and more flexible tailings closure and reclamation options. Flocculation of fine-particle suspensions by polymers is a non-equilibrium process whose performance is strongly influenced by physical and chemical variables. While polymeric flocculants are frequently used to establish the chemical conditions favorable for flocculation, the actual performance of a flocculation process generally depends more on the physical variables, such as the hydrodynamic conditions in mixing the flocculants and slurry. In order to study the effect of hydrodynamic conditions on flocculation of Syncrude fine tailings, a standardized laboratory test procedure called power flocculation has been developed in comparison with the conventional manual mixing methods. It is shown that the agitation speed and time in conditioning the flocculant solution and the slurry have a profound effect on the flocculation performances measured by initial settling rates, supernatant clarity and sediment density. It was found that the optimum bench test conditions for power flocculation of Aurora fine tailings with a sand-to-fine ratio (SFR) of about 1:1 are conditioning of the flocculant solution and the tailings slurry at 250 rev/min to 300 rev/min in 20 s to 40 s. The test results are inter-preted with a flocculant adsorption/redistribution kinetic model that helps understanding of the effect of hydrodynamic conditions on flocculant adsorption, floc formation and floc growth.

Jan 1, 2014

By Bo Feng

The development of surface charge of serpentine mineral and implications for sulphide ?otation have been studied through flotation tests, sedimentation tests, zeta potential measurements and optical microscope photos. The results show that the serpentine mineral was positively charged at an extensive pH range, with an isoelectric point (IEP) of 11.9. The magnitude and sign of the pyrite particles were pH dependent and were negative for pH values above 2. At pH value 9, where ?otation of nickel sul?de ores is routinely performed, serpentine and pyrite particles attract through an electrostatic mechanism. Slime coatings of serpentine adhere to the surface of pyrite, reducing pyrite flotation recovery. The removal of magnesium ions from the serpentine surface by acid leaching results in a decrease of serpentine IEP and eliminates the adverse effect of serpentine on pyrite flotation. Therefore, it has been clearly established that the surface charge value developed in the serpentine/aqueous electrical interface is a function of the serpentine surface incongruently dissolution. As a result of hydroxyl dissolution, the magnesium ions are left in serpentine surface, which is responsible for serpentine surface charge. The methods, which can remove magnesium ions from serpentine surface, can be used to eliminate the adverse effect of serpentine on pyrite flotation.

Sep 1, 2012

By Swati Mohanty

Spiral concentrator, which works on the principle of gravity separation, is widely used in the mineral industries for separation of solid particles based on the size and density. In the present study, CFD simulation of the flow profile on a laboratory scale spiral concentrator of height 2.29 m, pitch 0.435 m and width 0.17m was carried out. A single computational domain covering the entire spiral was considered. Volume-of-Fluid algorithm was used to track the interface and predict the flow profile. In the present study the Donor-Acceptor method was used for the calculation of volume fraction in the cell. Simulation results show that the velocity increases as the water flows down due to the convective force and gravitational force, but the viscous force acting in the opposite direction retards the flow. Thus the maximum velocity is attained at turn three at which the viscous force overpowers the other forces and further down the velocity decreases. Measured water depths along the radius of the spiral at various heights were compared with simulated depths, which were in good agreement. The simulated liquid phase velocity profile was used to carry out preliminary studies on the flow profile of solid particles of size 500 micron and densities 2600kg/m3 and 5100kg/m3, based on the Lagrangian model taking into consideration fluid-particle interaction.

Sep 1, 2012

By Sanjay Chaudhuri, V. K. Kalyani, Pradeep Kumar Singh, T. Gouri Charan

"Indian coal industry is the world's third largest in terms of production and fourth largest in terms of proven coal resources. Indian coal deposits are generally of high ash content varying from 24 to 50%. The coking coal reserves of India constitute about 12% of the total coal inventory, and the coals are washed in washeries, before being used for metallurgical purposes. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells. Extensive studies were carried out for understanding the performance of an operating conventional flotation plant. The performance studies revealed that appreciable quantity of clean coal is being lost in the tailings due to varied reasons and the required quantity and quality was not achieved. In this study, laboratory Flotation experiments were carried out to examine the cleaning characteristics of the said tailing and to determine the effective process parameters for recovery of clean coal at desired ash level ( 16-17%). Response Surface Methodology was applied to investigate the operating conditions of the Froth Flotation for modeling and optimization. Primary study reflects that there is a possibility to recover clean coal at 16-17% ash level with a yield of about 60-70% from that Flotation tailing of feed ash about 28%.INTRODUCTIONMost of the Indian coking coals are difficult in cleaning characteristics and high ash content due to its drift origin and its age of formation for more than 225 million years. Indian coking coal reserve is limited about 12% of total coal reserve. The minerals are homogeneously mixed with the coal macerals. The open cast mining practice and mechanized mining methods are being adopted to meet the increasing demands of coals resulting in generation of more coal fines and subsequently the quality is deteriorated. Indian good quality coking coal reserves of higher seams are fast depleting and hence coking coals of difficult cleaning characteristics of lower seams (LVC) are being now explored. Due to increased mechanization of coal mines to cope up the increased demand and followed by size reduction of lower seam coals in search of better liberation , the coal fines are increasing by leaps and bounds. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells."

Jan 1, 2018

By E. T. Tuzcu

In this manuscript, a new approach for modeling the rate of grinding process is explained. A review about grinding rate definitions so far is given and the possible ultimate way for grinding modeling is given as modeling the rate based on energy spectra. The traditional/phenomenological approaches for modeling size distribution of grinding mills give their place to a new generation modeling technique. Developments in the computational methods and necessity to model product size distribution of large mills, larger than ball mill size, paved the way for this novel technique. The traditional grinding rate models are mostly based on the back calculated breakage parameters from the experimental data. However, direct modeling of breakage parameters and hence the prediction of size distribution of the grinding mills may become possible with this approach. The material breakage data and discrete element method (DEM) energy spectra are the main components of this approach. Albeit the focus in this study is on modeling of breakage rate under impact mode of breakage, the abrasion mode of breakage was also tested by carrying out abrasion tests. Impact mode of breakage was analyzed using ultra-fast load cell device (UFLC) and drop weight tester. Dry tumbling test was carried out for abrasion experiments. Obtained material breakage versus energy data are combined with the collision energy spectra to obtain the breakage rate function. In addition, the material breakage versus energy information from the tests is converted into breakage distribution function. The model was verified in a lab scale mill (90 cm diameter-15 cm length). 10 to 15 kg of limestone was ground using 50 mm steel ball at varying conditions, i.e., rpm, volume loading. It is shown that the proposed model predicts all (1, 2, 4 min.) grinding intervals for all experiments highly accurate.

Sep 1, 2012

By C. Abbruzzese, F. Vegliò, S. Ubaldini, R. Massidda

"Gold solubilised during cyanidation can be recovered by precipitation (Merrill-Crow process) or by adsorption onto activated carbon, these being the techniques applied in industrial plants.Precious metals (Au, Ag) adsorbed onto activated carbon are extracted during a subsequent stage in aqueous phase, by various technologies, such as hot elution (70-80°C) or under pression desorption (100-130°), with hydro-alcoholic solutions.This stage is of great interest from an economic point of view, due to the high energy costs. Temperature represents the critical kinetic factor.The aim of this paper was to study the influence of different water/organic solvent mixtures (isopropyl alcohol, ethanol and ethylene glycol) on the desorption process.The experimental work was carried out on laboratory scale, using activated coconut carbon with different temperatures and extraction times, without adding cyanide.Best results have been obtained in this order: isopropyl alcohol > ethylene glycol > ethanol. Starting from gold concentration of about 5 g Au per kg of carbon, best kinetics resulted in 97-100% of gold extraction, after 8 hours of desorption, at a temperature of 80ºC."

Jan 1, 2003