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By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

The objectives of this study were to propose a viable alternative method for recovery of precious metals such as gold (Au), silver (Ag) and palladium (Pd) from waste printed circuit boards (WPCBs) and to regenerate the spent lixiviant solution for reuse. The proposed method generally consists of several steps as follows: 1). iodine-iodide leaching for metals extraction; 2). separation and recovery of precious metals and metal impurities from a pregnant leach solution; 3). regeneration of the spent iodine-iodide solution/lixiviant. In this method, more than 99% of Au leaching was achieved in the iodine-iodide solution from the solid residue of WPCBs that was obtained via sequential processes including incineration at 800 ?C and high pressure oxidative leaching with a diluted sulfuric acid at 120 ?C, while the leaching of Ag and Pd was less than 1%, respectively. Besides Ca, Cu, Ni, Co and Zn as main metal impurities, leaching efficiency of other metals did not exceed 1%. The precious metals and base metals as metal impurities present in the pregnant leach solution were separated and recovered by precipitation using L-AA and NaOH solutions. About 99.8% Au, 81.7% Ag and 72.8% Pd were recovered from the pregnant solution at pH of 2 with the addition of 0.1 M L-AA as precipitating agent. The remained small amounts of precious metals and metal impurities were precipitated at pH 13 using 1 M NaOH. The spent lixiviant after sequential precipitation was regenerated in the presence of hydrogen peroxide, hydrochloric acid and potassium iodide. It was revealed that over 90% of gold could be extracted from the residue of WPCBs with the regenerated lixiviant solution.

Jan 1, 2018

By Dietmar Freyhammer

Grinding is the last stage of the comminution process. In the grinding process the particles size are reduced by impact and attrition stresses. The fine grinding of ores is nowadays finding increased application due to depletion of coarse grained, easily processed ore bodies and the increased need to process distributed fine grained deposits, such fine ground iron ore powder is the basis for the pelletisation process. Depending on the ore type and the project environment different approaches to comminution are requested to provide an adequate ground iron ore for the pelletisation process. Currently the ball mill is the most used equipment in grinding iron ore for pellet feed. Based on the various examination and investigation of minerals on grind ability related to the throughput, to the resulting sieve characteristics and necessary energy consumption, the mill circuit can be: Open dry circuit. Closed dry circuit Open wet circuit Closed wet circuit. CEMTEC GmbH is a renowned name worldwide and offers tailor made solutions to cope these issues.

Sep 1, 2012

By S. V. Petrov

Oxidised ores possess a significant share among raw materials which are treated by traditional plant technology. As usual, the chemical composition of these ores is rather simple. They can be treated by standard cyanidation. In this case, the resulting wastes have an alkaline reaction. Their toxicity (in case of ROM ores treatment) is mainly due to the presence cyanides and thicyanades. The tails are dexotified before disposal. However, chemical reagents used cannot provide a complete removal of toxic matters. In this case, this disposal poses a real problem because these tails contain a significant amount of CN and SCN and their behavior during a long disposal should be studied. A sample with a simple composition taken from cyanidation tails was studied. The sample presents itself the quartz low-grade sulfide gold-bearing ore. Sulfide sulfur content is 0.15 per cent,and heavy metals content is 0.023 per cent. Method of testing is described further. The samples were tested under moderate and subarctic climates based on the difference in temperature, moisture and the degree of oxygen saturation of air. The pH of water extract, which was prepared using distilled water, was also determined besides measuring the concentration of cyanides and thiocyanates. This demonstrates the stability of sulfide-bearing minerals in the disposed tails. The tests time was 820 days. It was found that the alkalinity of the samples tends to lower under oxygen-containing conditions in proportion to temperature increasing. Under conditions without oxygen, the pH lowering is minimal. Mineralogical and chemical properties of the ore material give positive alkaline balance during testing. The solid sample contains enough alkaline agents to compensate dangerous to the environment reactions of sulfides oxidation.pH value maintaining under alkaline conditions witnesses to the possibility of a safe disposal of this tails type. The largest amount of cyanide is removed under acid-containing conditions at positive temperatures. The higher the temperature is, the more intensive destruction is. At the moment, of finishing the tests at 20ºC temperature, the residual concentration of CN- was 0.06-0.10 mg/L, at 4ºC, the residual concentration of CN- was 0.2-0.3 mg/L and at -18ºC was 0.4-0.6 mg/L. Under conditions with the lack of oxygen, cyanides can be removed within the first 200 days. Then, this process fully stops. A stabilized cyanides concentration is 3.0-4.0 mg/L. The presence of sulfides increases the content of cyanides at the initial stage of testing. Then, the concentration of SCN at the temperatures above 0ºC decreases rapidly under oxygen-containing conditions. At the rise of temperature, a narrowing of peak at the curve and an increase of the destruction process are observed. At the end of testing, the concentration of thiocyanates in the moisture of wastes was 0.2-0.3 mg/L at the temperature of 20ºC and 0.5-0.6 mg/L at the temperature of 4ºC, respectively. The concentration of thiocyanates contained in a frozen sample and media which have the lack of oxygen stabilizes at a certain level owing to sulfides and does not practically change further. It was found that detoxification of oxidized cyanidation tailings with a simple composition which were disposed as filtration cakes can be possible. In this case, the concentration of cyanide in the moisture of disposed wastes can have a close value or equal to actual concentration during cyanidation. In order to meet the requirements of high ecological safety standards and successful detoxification process of toxic compounds in the tails under the action of natural factors, the conditions of air aeration with oxygen for the whole volume of tails are required. Keywords: cyanides, thiocyanates, storage, detoxification, flotation cakes

Sep 1, 2012

By H. Mengbing, A. Potokin, A. Usov

"Revealed and analyzed in the study are the ways of significant perfection of specific characteristics of the equipment, such as use of high-frequency voltage transformation to create a charger; use of pulse transformers, with core made of materials with high magnetic permeability, in pulse generating circuits; as well as use of special ways to produce voltage pulses with a short front. The experiments have proved the possibility to adapt these technological solutions for electric-pulse installations, and suggested on this base is a strategy of further development and application of electric-pulse technologies. The different applications joint work schemes of voltage sources with two levels voltage and energy in electric pulse technologies are investigated. The possibility of increasing energy efficiency of destruction is shown."

Jan 1, 2014

By Ray Everson, Henry Kasaini

"We carried out adsorption experiments in chloride media to study the adsorption characteristics of Pd (II) anions on the surface of activated carbon. Throughout the experiments, we used commercial activated carbon pellets (0.8 Norit). The adsorption process was interpreted by using the ionisation and adsorption model. This implies that palladium anions were adsorbed physically on a protonated surface of activated carbon either as anionic complex species (PdCl4 -2) or aqua chloro-complex species [PdCl3(H2O)-] in acidic media. Furthermore, we established that adsorption of Pd (II) species was reversible at high chloride [Cl-1] concentration. The maximum adsorption capacity (Qsat) of Pd (II) anions averaged 27 mg/g. The Toth adsorption isotherms fairly predicted the equilibrium adsorption of Pd (II) species and the associated surface coverage.The effect of temperature and acid strength of the feed solution on the adsorption of Pd (II) ions were quantified. The adsorption kinetics was limited by external mass transfer since the effect of pore diffusion on the overall rate constant was negligibly small. A pseudo first-order kinetics model was used to describe the adsorption kinetics."

Jan 1, 2003

By Henrique Kahn, Daniel Uliana, Carina Ulsen, Guilherme Nery

"Gold has been a material in high demand since the dawn of humanity. After hundreds of years of exploitation, the increasingly search for gold occurs in lower grade deposits with greater extraction difficulty. Therefore, for maximum efficiency, deep knowledge of the characteristics of these minerals and their associations is crucial, which is acquired through an accurate and rigorous routine of process mineralogy and batch extraction tests. The industrial gold process extraction occurs by gravity concentration, sulphides flotation and cyanidation. For gravity concentration, it is fundamental to establish the proportion of free or coarse gold grains and its association to heavy minerals; regarding flotation, the most relevant data are the proportion of gold associated to sulphides and their liberation by the surface area; for cyanidation, it is crucial to evaluate gold accessibility and the kinetics of leaching. Thus, the characterization of gold associations and liberation is vital to establish the plant design, to optimize operating plants and to reduce gold losses. Our aim is the characterization of gold occurrence in low-grade Brazilian deposits with complex mineralogical assemblages to support processing flowchart definition and to predict metallurgical recoveries. Gold distribution in light and heavy minerals was evaluated by heavy liquid separation and the occurrence of gold in free or locked particles was carried out on heavy products by SEM-based automated image analysis using the MLA system. All the products of heavy liquid separation were cyanidated in head samples with different milling conditions to evaluate the reaction kinetics and maximum recovery."

Jan 1, 2014

By Rod Hocking, Nenad Djordjevic, Randolph A. Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures from standard operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill. Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulate the assemblage of a physical mill.By modelling the assemblage of steel balls in a 1 m pilot mill and duplicating the experimental arrangement exactly with the PFC3D model, it was possible to replicate the pattern of falling balls in the experimental mill. Furthermore, the key features of the acoustic emission spectrum that was calculated compared favourably to the measured spectrum at low frequencies. The experimental spectrum is shown in Figure 1."

Jan 1, 2003

By Johannes Käppeler, Alexander Weh, Harald Giese, Klaas van der Wielen

"High voltage breakage is a novel comminution technology that shows considerable potential for various applications in mineral processing and recycling. It relies on highly energetic electrical pulses to induce electrical explosions in rocks, causing the formation of plasma channels and powerful shockwaves that result in fracturing and fragmentation of particles. There has been considerable interest in this technology for its ability to weaken rocks and preferentially liberate target minerals, as previously demonstrated by other authors. Weakening has the potential to significantly reduce energy consumption during comminution, or alternatively, increase throughput of a circuit. Better liberation may yield an improved concentrate grade and/or recovery, reduce fines losses to tailings or increase the grind size required for liberation, thereby also reducing energy requirements. This review aims to increase general awareness of this technology, and promote further research into it by providing a general summary of the theory underlying high voltage breakage, as well as the envisaged applications of this novel technology. A brief history of the technology is presented before progressing onto the physics underlying the electrical and geomechanical aspects of high voltage breakage. Key results regarding weakening and liberation are discussed, and some mention is made of current challenges and planned developments to increase the throughput of high voltage breakage units to the level where it can be integrated into new and existing processing circuits."

Jan 1, 2014

By S. F. Kaplan, A. S. Dolotov, V. N. Kovalev

"The proportion of refractory sulphide ores and concentrates in world gold mining industry is growing every year. Pressure oxidation of these materials (in autoclave) allows to oxidize gold hosting minerals. Traces of halides and pseudohalides present in the slurry liquids contribute to formation of complex gold compounds. Sorption-active carbon present in ores leads to irreversible adsorption of complex gold compounds and their loss. The objective of the research is to study gold extraction dependence on the concentration of chloride-, cyanide- and thiocyanate-ions in the slurry liquids during pressure oxidation. Double refractory flotation concentrate of the Bakyrchik deposit was used for the testwork. The research was planned on the basis of a full factorial experimental design with additional refining experiments. Ligand concentrations (0 – 1000 mg/l Cl-, 0 – 600 mg/l CN-, 0 – 1200 mg/l of SCN-), temperature (200 – 240 °?) and retention time (1 – 6 h) were used as variables of pressure oxidation process. It was determined that sulfide minerals oxidize much faster than ""organic"" carbon. Under the conditions of T = 240 ?C, t = 2 h, sulphide sulfur oxidation was 95.6%, while ""organic"" carbon oxidation was 46.1 %. Each of the examined ligands has a significant adverse impact on gold extraction. Analysis of the experimental data demonstrated that with a high degree of confidence (R2 = 0.883) gold extraction does not depend on the ligand type, but only on its concentration and the ""organic"" carbon oxidation degree. In case of complete oxidation of ""organic"" carbon, the presence of the ligand (L = Cl-, CNS-, CN-) in the liquids at a concentration of up to 20 millimole/L does not significantly affect gold extraction. The assumption that the main factor of preg-robbing in ???-CIL treatment of double refractory concentrates is the natural ""organic"" carbon sorption-active to gold has been confirmed. INTRODUCTION In recent decades, placer gold mining has been gradually declining and hardrock gold mining, including ""refractory"" gold mining, has been growing all over the world, as well as in the Russian Federation (http://www.miningworld.ru, 2015). One of the main reasons why gold ores are refractory is gold adsorption on natural carbonaceous materials (""organic carbon""). Only a few technologies are suitable for processing such ore concentrates (a significant amount of gold is contained in refractory hardrock ore both in Russia and worldwide) (Vorob'yev-Desyatovskiy N.V., Yepifanov A.V., 2014)."

Jan 1, 2018

By A. V. Abshilawa, D. G. Talakhadze, R. I. Sturua

"Processing of the tailings accumulated over the lifetime of Madneuli Copper Concentrator is an opportunity to extract additional salable copper and gold products. This paper presents a pre-concentration process for the valuable components (copper and gold) of the accumulated tailings. The developed process makes it possible to obtain a copper pyrite concentrate with a yield of 14.05%, copper grade of 1.36%, and recovery of 83.22% containing 3.78 g/ton of gold at a recovery of 84.31%. The bulk concentrate is produced by a combined process bringing together selective flotation to produce salable copper concentrate and hydrometallurgical processing of the selective flotation tailings to recover gold. KEYWORDS: FLOTATION, ALBION PROCESS, LEACHING, COPPER CONCENTRATE, SELECTION Madneuli Copper Concentrator, Georgia, was put into operation in 1975. Over its lifetime, 40 mn tons of tailings have been accumulated at the tailings storage facility (TSF). Sampling of the TSF has indicated that the average copper and gold grade is 0.23% and 0.56-0.65 g/ton, respectively. Accordingly, the TSF can be classified as a technogenic reserve. This paper discusses pre-concentration of valuable components using flotation, followed by processing of the bulk concentrate in the Albion process. Mineralogical analysis of the accumulated tailings showed that the main ore mineral is pyrite (11.71%). Copper minerals are mainly represented by chalcopyrite (0.7%). The main nonmetallic mineral is quartz (67.3%); sericite, chlorites, etc. also occur. Pyrite is present both as liberated grains and intergrowth. The absolute majority of copper minerals are found as intergrowth with pyrite, less often with quartz. Ore minerals are slightly oxidized. Chemical analysis results are shown in Table 1. Particle size distribution shows that the size class -0.2 mm - 0.045 mm has the highest grade of 0.85 to 0.97 g/ton of gold. Size class +1.25 mm has the lowest grade. Based on the chemical and mineralogical studies and particle size distribution, an optimized process was developed for pre-concentration of the valuable components prior to hydrometallurgical processing. Several gravitation, direct selective, bulk, and bulk selective flotation processes were trialed. (1,2)"

Jan 1, 2018

By Y. Y. Emelianov

The results of the test work of four treatment options of three refractory gold-pyrite and gold-arsenic flotation concentrates are presented. These concentrates were obtained during the concentration of primary ores of large gold deposits. It was found that ultrafine grinding of refractory flotation concentrates did not increase the recovery of gold during subsequent cyanidation. The elimination of sulfur and arsenic during oxidative roasting is 99 per cent. 88-93 per cent of gold is recovered by cyanidation from calcines. After biooxidation of the flotation concentrates with a mixture of strains Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans 88-91 per cent of gold is recoverable by direct cyanidation. The recovery of gold from flotation concentrates by pressure oxidation is 88-99 per cent. These results suggest that gold recovery is important but the following strategies would have an impact on a plant performance and would be considered when developing an option to treat refractory ores: capital and operating costs, ore reserves, mine location, infrastructure and qualified staff. Keywords: gold, flotation concentrates, recovery, cyanidation, roasting, biooxidation, pressure oxidation

Sep 1, 2012

By A. Koizhanova

Kumistinskoye gold- and silver bearing ores (Republic of Kazakhstan) as well as standardized test solutions containing gold, silver, copper, zinc and iron were studied. The best results in silver and gold recovery from Kumistinskoye gold- and silver bearing ores were achieved through use of complex cyanide-thiosulfate solutions as compared to individual cyanide solutions and thiosulfate solutions. It was found that such complex solutions substantially step up leaching process herewith increasing precious metals recovery rates. Thermodynamics of studied chemical processes was calculated. Reaction order, kinetic constant and activation energy of gold leaching process through use of cyanide-thiosulfate solutions were identified. We managed to prove that the sorption rates and holding capacity in process of gold anions recovery with anionite AM-2B are comparable to sorption characteristics for cyanide solutions. Keywords: gold, silver, copper, zinc, iron, cyanide-thiosulfate solutions, anionite AM-2B

Sep 1, 2012

By Stephen Simukanga, Jewette Masinja

"Mining has been going on commercially in Zambia for over 100 years. The backbone of the mining industry has been copper production and its by-products of cobalt and gold. Over these years, the mining industry ownership structure has swung from private ownership to state ownership in 1972, and back to private ownership in 1995. Environmental management was first introduced into the body of Zambian legislation in 1991 through the promulgation of the Environmental Protection and Pollution Control Act (EPPCA). The Act’s main functions included the protection of the environment and control of pollution, and in particular to provide for the health and welfare of the people, animals, plants and the environment in general. This Act, was replaced in 2011 by the Environmental Management Act (EMA). The new Act has a number of new elements including: mainstreaming environment in national planning, it provides for the domestication of multilateral environmental agreements, enhances public participation issue, creates a central environmental information depositary, elaborates access to information principles, establishes an environment fund, creates enforcement orders, provides for both Zambia Environmental Management Authority and members of the public to sue for damages following environmental pollution, and provides for the appointment of honorary Inspectors. In addition to this, the Mines and Minerals Act of 1995 provided, for the first time, a section on environmental management in the mining sector. This section also created the Environmental Protection Fund (for mining), and made it obligatory to undertake environmental impact assessment before mining permits could be issued. The Environmental Protection Fund has now been established, as provided for by the law, and currently has more than USD9.0 million in the account. Secondly, environmental auditing is now being carried out annually on mines around the country, the effect of this has been a significant improvement in the environmental management of mining in Zambia. This paper looks at the response of the Zambian mining sector to these pieces of environmental management legislation, and the direction that the mining sector is expected to take on environmental management going forward."

Jan 1, 2014

By Andrey V. Yevdokimov

The results of the test work on gold leaching using high strength of cyanide solution in the presence of activators are presented. The major physical and chemical relationships of gold leaching were determined. Intensive cyanidation results of gravity concentrates with various material compositions using an activator are given. Process design criteria for intensive cyanidation unit were developed on the base of pilot plant test results. Keywords: gold, activators, intensive cyanidation, gravity concentrates

Sep 1, 2012

Results of the study of chloride ion concentration effect to osmium-187 sorption from wastewater of copper smelter with use of foreign anionites of different basicity and structure are presented in the work. It was found that the increase of chloride ion concentration in the wastewater helps to increase recovery of osmium using anionites regardless of their nature. The ways to intensify the process are proposed. The method for osmium elution from the anionites with potassium iodate solution was developed. It was shown that the method lets to recover up to 99% of osmium from the anionites. Recommendations for selection of eluents for better recovery of osmium from the anionites were elaborated. Keywords: wastewater, osmium, anionite, sorption, chloride ions, eluent, recovery

Sep 1, 2012

By Robert Snow, Shibo Zheng, Wenyi Song, Xiaoqing Ma, Patrick Zhang

Numerous phosphate mineral depressants have been reported in the literature for use during anionic flotation of dolomite from carbonate fluorapatite in slightly acid circuits. In one part of this research, laboratory flotation experiments were conducted to compare the effectiveness of phosphate depressants to process ground, deslimed high-MgO Florida phosphate pebbles. Ten potential phosphate depressants were evaluated during laboratory anionic flotation of dolomite from phosphate in a slightly acid circuit using a sulfonated oleic acid soap plus oil as the dolomite collector. Eight of the depressants have been used by various investigators with foreign and domestic carbonate-phosphate ores. Four of the depressants were found to be reasonably effective during the current flotation study, namely: sodium tripolyphosphate (STPP), sodium hexametaphosphate (SHMP), tetrasodium pyrophosphate (TSPP) and diphosphonic acid (DPA). Without depressants, the sulfonate collector required to produce cell underflow phosphate products containing <0.80% MgO and MgO/ P2O5 ratio <.033 was 1.13 kg/ton of flotation feed at a flotation pH range = 5.5-6.0. Using this collector level with 0.91 - 1.36 kg/ton of feed of STPP, SHMP or TSPP yielded phosphate products analyzing 0.73-0.92% MgO and MgO/ P2O5 ratios = .027-.034 at 90.0-96.8% P2O5 recovery. Similar grade phosphate products were obtained using DPA as the phosphate depressant at 84.1-87.5% P2O5 recovery. When no depressant was used, a similar grade phosphate product was obtained at only 65.9% P2O5 recovery. Another part of the research aimed at reducing MgO content in the final concentrate from Florida phosphate plants by conducting dolomite flotation on the final concentrate. Numerous phosphate depressants were tested for this purpose, including acidic, neutral and alkaline reagents. The most effective phosphate depressant was found to be phosphoric acid, giving both high grade and recovery.

Jan 1, 2014

By B. A. Kutlin

29% of the total ore mined in the Russian Federation for copper production is finely disseminated copper-zinc-pyrite ores of the Ural Region. Physical and chemical characteristics of pyrite copper-zinc ores make for difficulties in obtaining high indices during processing. At present, the authors have elaborated the technology to improve the quality of copper concentrates up to 20.0% for the ones obtained during pyrite copper-zinc ore processing (based on the example of the ore mining and processing enterprise ?Uchalinsky GOK?, Russian Federation). There are examples of use of fair-sized pneumo-mechanical flotation machines by modernization of processing plants. Keywords: copper-zinc-pyrite ores, Ural region Russian, selective flotation, pneumo- mechanical flotation machines

Sep 1, 2012

By Y. Foucaud, I. Filippova, L. Filippov

Flotation is the most common beneficiation route for tungsten ores, but the predominance of minerals with similar surface properties poses a real challenge. This study investigates the use of Falcon centrifugal separators for gangue minerals removal and desliming prior to flotation. A typical tungsten-bearing skarn ore (Tabuaço, Portugal) is used, containing scheelite (CaWO4) associated with dense calcium-bearing silicates (vesuvianite), fluorite, apatite and light silicates (feldspars) as gangue minerals. Two types of Falcon bowls (Falcon UF and Falcon SB) were used, prior to flotation tests with fatty acids as collectors and a combination of sodium carbonate and sodium silicate as gangue minerals depressants. This flowsheet was compared with a reverse configuration, using flotation prior to Falcon concentrator, and with a classical flowsheet, using hydrocyclone and flotation. Gravity pre-concentration and desliming with the Falcon concentrator were optimized through the design of experiments (DoE) methodology. The influences of pulp density, rotational speed, feed flowrate and fluidisation pressure (for the Falcon SB) were studied for both bowls. Results showed that the Falcon can be used as a desliming and pre-concentrating apparatus. Separation performances depend mainly on rotary speed and pulp density for the Falcon UF, whereas rotary speed and fluidisation pressure are the main parameters for the Falcon SB. With only one stage of Falcon SB, an enrichment ratio of 7.9 is obtained with a 65% WO3 recovery while 89% of apatite and fluorite are rejected, which constitutes a very good selectivity. In comparison, Falcon UF shows lower enrichment ratios, around 2.7. In terms of desliming, Falcon UF is as efficient as the hydrocyclone, while the Falcon SB is significantly more efficient. Hence, the use of Falcon SB prior to flotation improves the overall performance of the tungsten flotation route by desliming the flotation feed while pre-concentrating the scheelite. It impacts very advantageously the flotation, as most of the calcium-bearing minerals are eliminated. A Falcon SB stage prior to flotation yields a final concentrate grade of 29.7% WO3 with a recovery of only 36.8 % that should be optimized as the reagents dosages were not adapted to the pre-concentrated feed.

Jan 1, 2018

By Kevin Davey, Liza Forbes, Leanne Smith

Given the global scarcity and value of potable water, interest in the use of water of lower quality in mineral processing has grown significantly in recent years. Previous laboratory batch flotation tests conducted at CSIRO have shown that chalcopyrite floats strongly without collector in distilled water and that the collectorless flotability of chalcopyrite is unaffected by the use of brackish water, sea water or hypersaline water. In contrast, bornite is moderately flotable without collector in distilled water but all three lower-quality waters have a detrimental effect on the recovery of bornite. The depressant effect is so strong that the little recovery achieved in these waters was only slightly above what might have been expected from entrainment alone. This work has now been extended to another important copper sulfide mineral, chalcocite. In contrast to chalcopyrite and bornite, chalcocite does not exhibit collectorless flotability so the chalcocite tests in this study were performed in the presence of a standard collector (potassium ethyl xanthate). The results reveal that chalcocite is flotable with xanthate in distilled water but the lower-quality waters have a detrimental effect on the recovery of chalcocite. This effect is partly reversed by increase collector additions. Further tests were completed in order to investigate the effect of the different ions present in the saline waters on chalcocite flotation. Possible reasons for the observed differences are discussed in terms of the pulp chemistry of the system.

Jan 1, 2014

"The research aimed at solving the problem of measuring instantaneous local physical quantities for multiphase flows in mineral processing, which are common in minerals industry and with significant challenges. Due to the lack of proper measurement tools currently in minerals industry, multiphase flows (such as in flotation cell) are treated as in a “black-box”. It is crucial to develop measurement technique by which the acquired processing data can be used for process optimization and control. By measuring the conductivity distribution across a measurement area, Electrical Resistance Tomography (ERT) has been adopted by many researchers to monitor and investigate many processes involving multiphase flows in other industry sectors. A compact ERT probe was built and then used to measure the conductivity distribution within a few flotation machines. In a flowing foam flotation column, the results showed that ERT can accurately measure the change of liquid content (high conductivity fluid distribution). In another part of work, based on the Green-Kubo relations, ERT can measure turbulence via the fluctuation of conductivity caused by bubbles moving through the measurement area, changing the density of the fluid. The tests with the Metso 3 m3 RCS flotation cell were also carried out for turbulence measurement under different air rates and impeller speeds. The results of flotation cell from ERT measurement showed that varying impeller speed had more pronounced influence than changing air rate. When impeller speed is increased, the size of the high turbulent zone increases. ERT is a powerful technique that has the potential to be used for a wider range of applications. The future work will be carried out with more case studies and expanded to more processes such as leaching process, high temperature flows in further downstream production chain (steel making process and alloy manufacturing process).INTRODUCTIONMultiphase flows constitute a majority of the naturally-occurring and industrially-relevant flows, especially in mineral processing. Some of the measurement techniques have been used for the study of fluid characteristics. Optical techniques such as Laser Doppler Anemometry (Kyselaa et al., 2013) and Particle Image Velocimetry (Nobach and Bodenschatz, 2009) can produce accurate measurement results with high spatial and temporal resolution, but their applications are limited to transparent flows. Hot wire probes (Amini et al., 2013) have high spatial and temporal resolution in turbulence quantification, but they are susceptible to environmental factors."

Jan 1, 2018