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By P. A. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The recovery of cyanide from a gold mill solution containing high levels of copper (400 mg/L to 900 mg/L) using the AVR process was evaluated. It was determined that acidification to pH 2 to 3 provides a suitable balance between HCN generation, copper precipitation and acid consumption. A short pilot plant campaign showed that ~75% of the feed WAD cyanide was recovered while the remainder precipitated along with copper upon acidification. The acid consumption averaged 3.5 g H2SO4 per litre of solution. The copper precipitate, consisting mostly of CuCN and CuSCN, was readily separated from the solution by gravity. The volatilization of HCN in countercurrent packed columns averaged 98.7% efficiency. Reabsorption of HCN was practically 100% in NaOH solutions and slightly lower in a lime slurry. Basic volatilizer design parameters applicable to a large-scale operation were determined, including the Henry’s Law constant and the mass transfer coefficient of HCN gas.

Jan 1, 1998

By P. Choquet, F. Miller

"The development and testing of a simple low-cost gauge for measurement of tension in a cable bolt grouted in a borehole are presented. Its principle is based on a resistance wire which is wound on a 70 cm length into the spiral grooves of the wire strand cable bolt. Readings are then taken by a robust automatic data logger with a several day autonomy or by a portable readout. In order to have a complete profile of tension along the cable bolt, a number of tension gauges can be installed along its length.This paper provides a description of the development and laboratory calibration of the tension gauge and addresses the two modes of loading for a cable bolt in a rock mass, namely pure tension and shearing at a joint location.In the second part of the paper, four field tests in underground and open pit mines are reported. The first test was used to substantially modify both the gauge and the readout unit principles while the other tests which are still on-going show a very satisfactory behaviour of the modified version of the tension gauge. IntroductionCable-bolting is often used as ground support in Canadian mines for a variety of applications. In underground mines, cable bolts can be installed vertically at the back of cut and fill stopes or in an inclined fashion in the walls of large open stopes. Alternatively, cable bolts at Mines Gaspe (Noranda Inc.) are used in a fan-shaped pattern from a drill drift to stabilize the inclined roof in 25 m wide open stapes. This new application oriented our research efforts toward the design of a novel instrumentation to monitor the efficiency of most commonly used 5/8-inch cable bolts."

Jan 1, 1988

By A. Demirci, A. Keçeciler, Y. S. Durutürk

"This paper deals with the results of the variation of thermal conductivity of rocks with pressure on a laboratory scale. For this purpose, the authors have added a pressure-supplying unit to the apparatus developed by Mousset-Jones and McPherson (1986), Önder (1995), Ashworth and Ashworth (1979), and Innaurato and Occella (1989) in order to measure the thermal conductivity under pressure. The values obtained from the tests performed by this new apparatus have been stated using a regression analysis and the related graphs have been drawn. Results have shown that the thermal conductivity of rock varies digressively with pressure. The same results have been obtained in different rocks types. IntroductionOne of the most important tasks of mining engineers is that of establishing, maintaining and sustaining safe and healthy working conditions in underground mines.Heat can have a profound effect on safe and healthy working conditions and is one of the main problems in deep underground mines. In this regard, the temperature of the air passing through the mine openings increases steadily and causes a decrease in the efficiency of workers due to the unwanted physical effects to human bodies in the working area. At the same time, the hot and humid environment resulting from heat and temperature rise causes some important occupational diseases and increases the accident risks in the related openings."

Jan 1, 2002

By Gordan Marrs, O. Matwijenko

"The Kidd Creek metallurgical site has been highly integrated to maximize revenues from its base metals mines. The site's operations include a Concentrator processing 4.3 million tonnes per year of copper-zinc ore, a Copper complex producing 100,000 tonnes per year copper cathode and a Zinc Plant producing 130,000 tonnes per year of zinc metal. To improve operating efficiency with increasing emphasis on productivity, process control, process automation and process optimization have been augmented and expanded during the last decade.New microprocessor based control systems provided the opportunity for the capturing of an expanded number of process related measurements. As supervisory computers were already in place, databases could be generated with only increased disc space and database management programs required. Once the data had been accumulated and stored, a method was then required for handling, screening and sorting large volumes of information in relatively quick and easy terms in order that the stored information could be used. By 1984, a decision to use personal computers for accounting, engineering and management reporting provided the vehicle necessary to handle this data. Using commercially available software, large volumes of stored process data can be downloaded from existing databases, filtered, sorted, analyzed, graphed, displayed, projected, reported and distributed. All this can be performed in very little time."

Jan 1, 1989

By Eric Konigsmann

"Omai Gold Mines is a large scale open pit gold mining operation located in central Guyana, South America with a 12,000 tonne per day milling facility. Mill operations were initiated in December 1992 with commercial production beginning in January 1993. The entire operation employs approximately 120 expatriates and some 800 Guyanese nationals and is expected to produce in excess of 250,000 ounces of gold per year. The total mineable reserves contain 2.5 million ounces of gold with a projected mine life of twelve years.The milling circuits feature an SABC grinding circuit, gravity concentration and a conventional CIP gold recovery circuit. This paper will review the mill start up and ""run-in"" phase during the first year of operation. Emphasis will be placed on descriptions of start up problems and circuit modifications, mill performance trends in 1993, and personnel training and development. An outlook for 1994 is also given.IntroductionOmai Gold Mines is a large scale, open pit gold mining operation located in the Potaro district of Guyana, South America, some 160 kilometers south of the capital city Georgetown. Although there are numerous small scale gold mining ventures in Guyana, particularly with the dredging operations on the rivers, Omai is the first hard rock, open pit mine to be developed in the country. At present, this mining operation is one of the largest gold mines in South America.The Omai gold deposit has been exploited for over one hundred years. In the late 1800's, a German syndicate used hydraulicing with subsequent gravimetric separators such as sluice boxes and trommel screens to recover gold from saprolite, a soft, oxidized, claylike mineral which covers much of the claim area. Through the early 1900's and up until the 1950's, numerous mining companies including Anaconda Mining Co. Ltd. explored and drilled the Omai deposit but the technology and low gold price of the day made the reserve uneconomic to develop."

Jan 1, 1994

By Ilpo O. Auranen

Background: Mines of today are moving ever increasing tonnages of rock. The new ore bodies tend be of lower grade and located deeper in the earth?s crust. The industry?s focus to overcome this ?deeper but poorer? ore problem has traditionally been to lower the costs by increasing the scale of mining. This has resulted in an ever increasing size of mining equipment like drills, loading shovels, dump trucks. The main focus has been in reducing the cost per ton of mining. This cost focus has often resulted in increased waste rock dilution and more ore losses. From costs to value: Waste rock dilution means waste rock in the concentrator feed. It?s value in open pit mining is equal to the value of ore it replaces. In underground mining, waste rock dilution?s value is equal to the value of ore it replaces added to the costs of mining it. It is commonly accepted that waste rock dilution in open pit mining ranges between 5 and 20% and in underground mining between 5 and 40 % . In a typical large open pit mine ore value is from 20 to 60 USD per ton and mining costs are 1 to 3 USD per ton. One percentage point reduction in waste rock dilution represents savings corresponding to about 20% of total mining operation costs. The difficulty of reducing waste rock dilution comes from the complicated nature of the ores. Accurate ore waste-border detection has not been possible due to excessive costs. Core drilling combined with geochemical lab analysis is the most accurate method for locating ore waste borders. However, it is also expensive and time consuming, which is why it is often combined with somewhat lower cost methods like sampling drill cuttings from blasting drill holes or from reverse circulation drills and analyzing them in a laboratory. The main drawback with these methods, in addition high costs, lies in the sampling accuracy and in the quality control of the whole process when a large number of samples have to be handled manually. In every mine it is possible to halve waste rock dilution by using new on-line analysis technology .

Oct 1, 2009

By S. Yalcin, S. Chang, M. Oliazadeh

"Present day ferrochrome demand is on the rise, as more steel products require this material as an alloying element. It is projected that the stainless steel demands will grow by about 6% per year to 2020; as such, the supply and demand for ferrochrome appears promising. Chromite is the only economical source of chromium, which is commonly upgraded by gravity techniques and used to produce ferrochrome. The gravity separation methods are not able to treat particles finer than 0.1 mm efficiently. Therefore, in processing chromite ore, a large quantity of fine tailings; some 25% of the mineral values have been reported as lost in slimes during processing. The chromite content of these tailings is typically 10-20% Cr2O3 and accumulates into a large stockpile/pond. A chromite concentrator project in Canada, considers a cut-off grade of 20% Cr2O3. This indicates further processing might be required to recover chromite from low-grade stockpile when the high-grade deposits are depleted. Low-grade ores normally indicates disseminated chromite ores with low liberation and consequently fine comminution. This paper reviews the techniques for treating chromite from fine material and provides some examples of successful operations in fine chromite recovery. Beneficiation techniques for fine particles include gravity separation, magnetic separation, and flotation. Several case studies are presented here that used one of the aforementioned methods or a combination of them.INTRODUCTIONChromium is one of the essential element and important material for production of ferrochrome alloys and special steel. Chromium occurs as chromium spinel, a complex mineral with chemical composition of (Fe, Mg) O (Cr, Al, Fe)2 . Chromite ore is exclusively found in ultramafic igneous rocks. Major associated gangue minerals are talc, quartz, serpentine and iron oxides.Chromite is a heavy mineral, with a specific gravity in the range of 4-5, relative to associated gangue minerals in a chromite ore, which makes gravity concentration a suitable process. This is generally true for coarse particles, ranging from 1 mm to 100 mm. Typically, the ore is prepared by crushing (and grinding if necessary) to a suitable size and the material is sized for the appropriate beneficiation techniques. It is common to use heavy medium separation (e.g. dense media drums, dense media cyclones, or Dyna Whirlpool) to treat coarse size and intermediate size particles (1 – 100 mm). Intermediate and fine particles (20 – 0.1 mm) could be treated by jigs. Spirals, shaking table, sluices, and Reichert cones can upgrade fine particles. Figure 1 shows a typical chromite beneficiation process flowsheet. As can be seen, it consists of three major sections: feed preparation (crushing, screening), de-sliming, and concentration. Beneficiation recoveries range from 80 to 85%, although the ratio of upgrading is only 2 to 3."

Jan 1, 2013

By L. van Hijfte, A. Piché

"Drilling and blasting are fundamental operations in the mining cycle and constitute an important component of the mining costs. Problems associated with improper drilling and blasting practices can create losses of several millions of dollars per year. For this reason, a Blasting Technology program was initiated in 1984 at the Noranda Technology Centre (NTC). In this paper, advances made at NTC in drill and blast technology are reviewed. Impacts of drilling and basting for Noranda are assessed in terms of dilution and ore losses. Future challenges are addressed. IntroductionUp to 1997, Noranda was a diversified natural resources company that operated in three sectors: mining and metallurgy, forest products, and oil and gas. The company employs more than 33 000 people in operations and sales offices around the world. Today, Noranda has returned to its roots in mining and metallurgy. The new vision of Noranda is to be dedicated to the responsible and profitable development of mineral resources around the world for the benefit of its shareholders. In so doing, Noranda will continue to be deeply committed to the environment, health, workplace safety, cost competitiveness and return on capital. Technology is an integral part of Noranda’s success strategies. For this reason, the Noranda Technology Centre, formerly known as Noranda Research Centre, was founded in 1963. Since then, it has undergone four expansion phases to keep up with the increasing needs of the businesses. Today, NTC employs more than 220 specialists who work in partnership with different Noranda companies to identify, develop, and transfer technology to the operations, as well as to explore new sectors of activity."

Jan 1, 2000

By M. E. Coleman, G. Money

Pneumatic Conveying and Process Injection Technologies have been implemented in the metals markets for the last 40 years and have considerably improved the productivity and the performance of many processes. There have been many steps forward in handling technology and this paper seeks to consider those now offered by Clyde Materials Handling who as an established customer-driven solutions provider has turned its attention to supporting the Metals Market. Clyde seeks to utilise its knowledge, expertise and technologies to transform the production processes of its customers, who operate in the ferrous and non-ferrous metals industries.

Jan 1, 2008

By G. H. Babcock, D. A. Knight, V. G. Medina

"Production commenced at the Golden Sunlight Mine in 1983 and at Kidston Gold Mine in 1985. These projects were both constructed under the management of the Placer Dome Inc. (Technical Services) group of Vancouver, B.C.Golden Sunlight uses a conventional rod mill/ball mill grinding circuit while Kidston uses a SAG /ball mill, and later on, SABC circuit. Since the hardness of the ore and the fineness of the primary grind in both mines are about the same, a meaningful cost comparison can be made. The comparison is made on the basis of capital and operating costs.The result of this study indicates that a significant capital cost savings can be achieved in favour of the SAG /ball mill circuit when the ore is amenable to semi-autogenous grinding. With a good maintenance program, the operating cost for the SAG /ball mill circuit could also be lower that the conventional rod mill/ball mill circuit.HISTORYGolden Sunlight MineGolden Sunlight is a 5 530 t/d gold mine located near Whitehall, a small town 60 km east of Butte, Montana. Originally optioned by PDI U.S. in 1958, the development of the property waited until 1981 when economic conditions became favorable for the project to proceed.Semiautogenous grinding tests were conducted during the final stages of the feasibility study. The hard near surface ore was not quite amenable to semi-autogenous grinding. The best result produced from a series of tests using a 1.83 m diameter mill was a semiautogenous work index of 39. This is substantially higher than the 22 Bond work index of the sample used in the testwork. A conventional SAG/ball mill circuit for this ore will be extremely inefficient, and for this reason, this circuit was rejected in favour of a conventional rod mill/ball mill circuit."

Jan 1, 1991

By Khosrow Ebrahimi

We document the occurrence, mineralogy and firing properties of magnesite from hydrothermal deposits in the upper Cretaceous ophiolites of Eastern Iran. These deposits occur as thin veins of nearly pure cryptocrystalline magnesite with only trace amounts of quartz, calcite, and dolomite. Ratios of CaO/SiO2 in the bulk ore are variable. The composition of dead-burned magnesite from these deposits, calcined at different temperatures and durations, is predictable from phase equilibria. Textures of the calcined magnesite were studied by SEM; results show that the principal impurites produced during calcination are forsterite, monticellite, merwinite, dicalcium and tricalcium silicates, and that these are located principally at triple junctions of the periclase crystals. The size of periclase crystals increased with temperature and duration of calcination and the amount of periclase-periclase grain contacts was reduced by increasing the concentration of impurities in the starting products. EPMA show: 1) that CaO and FeO contents in periclase increase steadily with an increase in the CaO/SiO2 ratio and the FeO content of the bulk ore, respectively, and 2) that limited solid solution exists between impurites. This study demonstrates that high quality dead-burned magnesia refractories can be produced from the Iranian magnesite with low CaO, SiO2 and FeO contents.

May 1, 2004

By Robert J. Kuhne

The Iron Ore Company of Canada has successfully employed advanced process control (APC) to optimize the operation of their induration machines. A significant increase in machine throughput and a reduction in fired pellet quality giveaway were observed following the APC implementation on all six machines. This paper discusses the opportunity for process control optimization in induration, reviews the property estimation and multivariable control technologies, and describes how the IOCC control strategy captured this opportunity. APC performance data is presented. The dependence of APC performance on control room operator acceptance, process equipment and instrumentation is highlighted.

May 1, 2007

By R. J. MacLeod

"INTRODUCTIONThe removal of water or liquid from slurries and solutions is a procedure generally present in many process industries. This has prompted the development of many mechanical and thermal devices with which, I have no doubt you are al1 familiar.In the mining industry, beneficiation of ores necessitates ' the removal of water or other 1iquid from the concentrate material. The most common method of accomplishing this is by means of thickeners, vacuum filters and rotary dryers, generally all three and in that order;The use of spray drying techniques to obtain the same end has many advantages and these will be outlined here.THE PRINCIPLE OF SPRAY DRYINGA Spray Dryer consists of a cyclone shaped chamber where hot air and atomized concentrate are introduced in the upper section. (Sec figure No. 1). Efficient mixing of these two streams produce dry concentrate and moist spent air, both of which are removed from the base of the chamber.Thermal dewatering involves the product ion of heat and spray drying has no special requirements in this area. Generally a direct fired air heater is used and the products of combustion whether they stem from the use of gas, oil or coal fuel go into the spray dryer along with quench or dilution air which is used to reduce the combustion gases to the desired temperature. This generally lies in the range of 1,000 to 1,600° F. In spite of these relatively high inlet temperatures, the spray drying process eliminates the need for refractory lining or indeed any special heat resistant metals except on the air inlet ducting. Waste heat may also be used even if a significant amount of contamination is present."

Jan 1, 1972

By Craig M. Sams

"Variable speed mill popularity has grown during the last 10 years with almost every SAG mill fitted with a variable speed drive. In addition, many of today’s larger ball mills are running a variable speed drive for various reasons. In the past, motor suppliers, especially gearless drive suppliers, have considered mills as being an overpriced rotor. This has lead to mills demanding more torque than what a motor can generate. This paper identifies the reasoning of what has happened and how to mitigate the mismatch in the future. Technical and economical issues are discussed, allowing mill operators to make an informed decision of which path to take in deciding what motor to put on a mill.INTRODUCTIONIt has been generally accepted in the past that motor suppliers and specialists in engineering companies understand the workings of a SAG mill or a ball mill and although there is a fair knowledge within the industry, in regards to mill torque requirements, the advent of variable speed drives in ball mills has shown the writer that a complete understanding of the mill torque requirements are not fully understood.This paper will discuss two aspects of mill torque requirements, (operating torque at various charge levels and start up torque), and how it relates to specifying the proper motor torque requirements.MILL OPERATING TORQUEMill operating torque at a given charge level and density in a mill is essentially constant throughout the entire speed range. For the purpose of this paper, we will take a 38’x 22.5’, 20’ EGL, SAG mill and provide the power draw at variable speeds but fixed loading conditions.The power draw and mill torque of this mill at 8% ball charge and 28% total loading (Highlighted) is shown below as Figure 1, at variable speeds."

Jan 1, 2007

By Glenn Kosick, Roger Amelunxen, Glenn Dobby

"The variability in flotation response within an orebody is often a significant problem to address during the design phase of a flotation circuit. In addition, for existing operating plants, the reasons for such a variability need to be clearly understood and accounted for if plant performance is to be optimized. MinnovEX Technologies, in collaboration with major mining companies, is developing methodologies and tools to address the issue of variability in ore characteristics (such as ore hardness and flotation response). The tool is used for design and scale-up of flotation circuits from lab flotation data, and for prediction of recovery and final concentrate grades throughout the mine block model for any given circuit design.INTRODUCTIOTNH: EI SSUEB EINGA DDRESSEDThis paper describes the current development of a methodology and software tool for improved flotation plant design and enhanced prediction of froth flotation performance in an operating plant. The need for this tool is attributed to two primary factors: variability of flotation response properties throughout an orebody and related difficulties with scaleup from laboratory tests. Consider these in more detail.It is well recognized that separation performance via froth flotation will vary significantly within a single mineral deposit. This has been enhanced through the wide application of SAG milling. Throughput with SAG mills is more susceptible to ore hardness changes than is the case with crushing-rod-ball circuits; it is not uncommon to see SAG mill throughput to vary by up to 100% on a regular basis, e.g. 1000 tph to 2000 tph.The implication of this on laboratory testing for prediction of metallurgical performance is as follows: it is unlikely that either the plant grind (size distribution) feeding froth flotation or the flotation residence time will be known at the time of laboratory testing for a given block of ore. Hence, the grind used for the laboratory test is not likely to be that which actually occurs once the ore is processed, and the laboratory retention time may not represent the plant conditions."

Jan 1, 2002

By J. Keith Haddock

"Introduction The Luscar company, Forestburg Collieries Ltd., operates the Diplomat Mine located 14 km south of Forestburg, Alberta. Production is now at a declining rate from the 1 million tonnes achieved in 1978 as the reserves are being depleted. Three pits are operated at this prairie strip mine utilizing draglines and stripping shovels to uncover the coal. The coal is hauled to a tipple on site for shipment by rail or highway vehicles or is hauled directly to the adjacent Battle River Generating Station. Geology The mine is currently extracting the Battle River seam on the north side of the Battle River. This is the lower-most seam in the Horseshoe Canyon Formation and is the only one present in the area, the upper seams having been eroded by glaciation. The seam lies generally flat and varies from 2.0 to 5.0 metres thick. It lies under glacial till overburden varying in depth from 5.0 to 12.0 metres. The mineable coal extends from the side of the Battle River valley where it outcrops, to approximately 2.5 kilometres to the north. The mine is spread out over a distance of 8.0 kilometres in an east-west direction. Reserves and Coal Quality After over 30 years of mining at Diplomat, there are now less than 1 million tonnes of mineable reserves remaining on the property. With the commencement of coal production from the Paintearth Mine in 1981, supply to the Battle River Generating Station, formerly Diplomat's biggest customer, is being transferred to Paintearth. Rail shipments and domestic supply will continue until reserves are depleted. The coal has the following specifications:"

Jan 1, 1985

By Steve Wilkinson

"""Techniques for coarse-particle beneficiation of some gold ores and methods for determining potential for sorting any gold ore deposit.""With the advent of high speed computers, laser technology end different types of electronic sensing devices, ore sorting machinery has been developed, capable of handling significant tonnage rates while maintaining high level efficiency. Gold ores may be amenable to coarse-particle beneficiation where there exist measurable criteria upon which there can be recognition of auriferous versus barren lumps in the run of mine. Three types of criteria are suitable for sorting and are:i) Photometric - optical variance between ore and waste such as vein ores hosted by barren country rock;ii) Conductivity/Magnetic - based upon the metallic mineral content of ore end waste, and its association with Au, such as found in sulphide/arsenide Au ores,iii) Radtometric - detection of natural gamma activity occurring with uranium-bearirig gold ores.The method for determining the sortability of an ore depositconsists of, at least, three stages:i) Initial stage identification of ore and waste types,mineralogical/petrographical associations,amount of dilution in P.O.M.establishment of any sorting criteria]"

Jan 1, 1985

By Murray Wood, Michael Schaffer, Makat Katom

"An expert system applied to the control of mineral process unit operations is, by its nature, the site best operating practice, having been designed by the local experts in conjunction with consulting metallurgists. The “common sense” layer in a MET (MinnovEX Expert Technology) solution determines an appropriate action for the current operating conditions through a developed heuristic model of the process (expert system). The magnitude of the setpoint change that is made is proportional to the confidence that the system has in its interpretation of the current conditions (fuzzy logic). The solution is always striving to take the process to a constraint and thereby optimise the operation. An accepted limitation of the solution is that the only way the system can determine if a constraint has been reached is to exceed it and then withdraw – essentially “experimenting” with the process. By leveraging a model, which can accurately ""simulate"" the process, this restriction can be circumvented by pre-testing the set point change through a ""what if"" analysis and then modifying the solution as appropriate.At Ok Tedi, the introduction in 1999 of a MET expert system for SAG milling resulted in significant improvement in circuit throughput. Yet, with the additional inclusion of an accurate model of the process there was still more that could be achieved. Hence, in 2002 a MET Neural Network model was developed and deployed to enhance the existing expert system solution. The principal objective of this model was predicting the effect that changes in SAG tonnage and density would have on the power draw of the mill - essentially a power predictor. The results have seen a decrease in process variance with an associated increase in average circuit performance.This paper describes the methodology by which the Neural Network model was implemented, the considerations and limitations when applying this technology and ultimately the results that were achieved."

Jan 1, 2003

By James Pirie

"The major Archean gold deposits in the Red Lake greenstone belt, which have produced over 374 million grams of gold since 1930, occur near the top of the lower komatiitic to tholeiitic mafic to ultramafic metavolcanic sequence. The upper calc-alkalic mafic to felsic rocks form three discrete and separate ediftces overlymg this lower sequence.The gold deposits are classified according to their stratigraphic or lithologic associations into:1) mafic-volcanic-hosted deposits;2) felsic-intrusive-hosted deposits; and3) stratabound deposits.Group 1 and to a lesser extent Group 2 deposits occur within zones of alteration several square kilometres in extent. The nature of this pervasive alteration can be characterized by comparison of petrochemical data from the altered rocks and their fresher equivalents some distance away. The altered rocks have substantial addition of SiO2> CO2, K2O, As and Sb and subtraction of Na20, CaO, MgO and total Fe. Cr, Ni, Co and Zr appear to have been relatively immobile. Hydrothermal alteration and gold deposition probably accompanied early fumarolic activity and continued during subsequent deformation the metavolcanic sequence, with gold eventually being mobtltzed and concentrated into major vein structures to form the present orebodies. The smaller Group 2 deposits formed by emplacement of felsic intrusions into already altered, anomalously gold-bearing mafic metavolcanics, with the heat from the intrusions setting up parasitic hydrothermal systems which mobilized the gold and deposited it along with minor sulphides in fractures in the cooling intrusions."

Jan 1, 1982

By B. Hart, J. Marois

"Scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM–EDX), and Time of flight secondary ion mass spectroscopy (TOF-SIMS)were used to analyze pyrochlore grains from Niobec froth flotation plant. Samples from the mill feed, pyrochlore rougher feed, pyrochlore rougher concentrate, and tail were analyzed in order to identify a potential relationship between pyrochlore matrix composition and selective separation. SEM-EDX analyses indicate that pyrochlore grains with high Fe content appear to be less recoverable than those with a lower Fe content and that the flotation response is related to matrix Fe rather than Fe occurring as inclusions. TOF-SIMS was used to analyse the surface of high Fe and low Fe pyrochlore, in order to identify a potential relationship between pyrochlore matrix composition and the related effect on cationic collector adsorption (tallow diamine). Surface analyses of pyrochlore from a conditioning test show that species indicative of the collector favour the surface of Fe poor pyrochlore relative to the Fe rich variety. The results from the conditioning test illustrate a negative relationship between collector loading and the presence of Fe and related oxidation species. This study identifies the link between pyrochlore matrix Fe content and, the presence of surface oxidation products, to collector loading. Poor Fe rich pyrochlore recovery noted in the Niobec froth flotation plant may be partially explained by this mechanism.INTRODUCTIONPyrochlore, the most abundant niobium containing mineral (Perrault and Manker, 1981) is economically recovered in Brazil, China, and Canada (Niobec) (Kouptsidis et al., 2008). Since 1974 Niobec has been extracting niobium from the St-Honorécarbonatite deposit. Niobec is the only operating Nb extraction facility in North American and one of the three major world producers of ferroniobium (Dufresne and Goyette, 2004; Belzile, 2009).Flotation is the preferred and most cost-effective method for pyrochlore recovery (Burks, 1958; Shapolov and Polkin, 1958; Zakharov et al., 1967; Razvozzhaev and Nikiforov, 1972; Bogdanov et al., 1973; Abeidu, 1974; Raby and Desrochers, 1975; Wilson, 1979; Biss and Nadeau, 1982; Biss, 1985). With the aim of optimising the flotation process for the Niobec ore, numerous experiments were performed on the influence of surfactants and type of water to optimise pyrochlore recovery and grade during flotation (Gomez et al., 1987; Rao et al., 1988; Dufresne and Goyette, 2004; Belzile, 2009)."

Jan 1, 2013