Search Documents

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

By Laxman M. Amaratunga

"The fine fraction of tailings is usually excluded from the backfill process and generally disposed on the surface in tailings ponds. Because of the ever increasing demand for fine grinding in the extraction process for improved liberation of valuables in the ore, increased production of fines in the tailings has resulted. The negative impact of surface impoundment of tailings on the environment is well known. Amaratunga and Annor (1989) first presented a concept of fine tailings agglomeration for backfill.This paper presents the development of the novel cold-bond tailings agglomeration (CBTA) technology for non-reactive fine gold mill tailings. For cold-bond agglomeration regular portland cement was used as a binder. In order to cut costs, alternate binders such as lime, and blast furnace slag cement were examined. The effects of binder dosage, curing time, and agglomerate size on the fracture load strength of the agglomerate were studied.Fine tailings agglomerates are mixed with coarse tailings or non-agglomerated fine tailings to make high density fill compositions to be used as underground backfill. Alternatively, the agglomerates can be used as aggregates for surface applications. The paper discusses the environmental and operational benefits of this total tailings utilization and disposal technology.IntroductionIn Canadian mines, mill tailings are probably the most commonly used material for backfill. However, only the coarse fraction of tailings is desirable for use as hydraulic fill or high density fills. The fines are disposed on the surface in tailings ponds since they are unsuitable for underground backfilling owing to the following factors:i) slow settling ratesii) longer percolation timeiii) excessive consumption of binder due to drainageiv) poor compactionFor improved value liberation more milling operations have resolved to fine grinding in their comminution circuits. Gold milling operations driven by down stream leaching processes grind their ores excessively fine. In general, gold mines use hardly any tailings for backfilling. This can result in periodic short falls and the need to search for alternate backfill material from other sources. Apparently, the gold producers are the most identifiable sector which suffer from a shortage of backfill materials ( Amaratunga and Annor, 1989)."

Jan 1, 1994

By Kristie D. Tarr

Ideally, in situ monitoring would supply the input data for numerical modeling of backfill material property requirements. However, clue to production requirements and costs of conducting field tests, input data are often based on small-scale laboratory tests. The size of test samples is known to play an important role in the laboratory assessment of the behaviour of geotechnical materials, including backfill. There are observed differences between the mechanical properties of laboratory-scale samples and those of in situ materials, and these are generally attributed to the differences in scale. Various scaling factors have been proposed for converting laboratory observations to anticipated in situ conditions for soil and rock materials. With regard to mine backfill, very limited studies exist which have involved the effects of sample size on material properties. The literature indicates that reported backfill strength data are based on a variety of test sample sizes and in some cases, specimen geometries. Carefully determined laboratory scale effects could play an important role in estimating the potential backfill behaviour in the field, especially when developing new backfill systems. Laboratory studies were conducted with sample diameters ranging from 50 to 300 mm. Scale factors relating specimen size to strength were developed wherever possible, and are presented in this paper

May 1, 2008

By BARRY BANNATYNE

About 90 per cent of Manitoba's industrial minerals production is for structural materials. Most of these come from the Paleozoic rocks west of the Precarnbrian Shield, or from glacial deposits that are extensive throughout Manitoba. The major raw materials are sand and gravel, and carbonate rocks for crushed stone (and also dolomite for high-magnesia lime, high-calcium limestone for lime and Portland cement, and dolomitic limestone for Tyndall stone). Glacial lake clays are used both in cement and in lightweight aggregate. The Jurassic and Cretaceous strata exposed along or near the Manitoba Escarpment include siliceous, carbonaceous, kaolinitic and illitic shales, all of which are quarried by Red River Brick and Tile in the Pembina Mountain and Ste. Rose areas for use in a brick plant at Lockport. Non-swelling bentonite near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation is of value as an absorbent clay, and is the only commercial source in production in Canada. It has been quarried by Pembina Mountain Clays Limited since 1940. Gypsum occurs in the Jurassic Amaranth Formation and supplies much of the market for wallboard and Portland cement additive in the Prairie Provinces. Quarries are operated at Gypsumville by Domtar Construction Materials Limited, and north of Amaranth by Westroc Industries Limited. Silica sand from the Ordovician Winnipeg Formation is of glass-grade quality, and about 100,000 tonnes are produced annually by Steel Brothers Canada Limited on Black Island . It is used as a glass sand, as foundry sand, for sand blasting, and as a filter-bed sand .

Jan 1, 1984

By Z. D. Hora

Commercial production of barite commenced in British Columbia in 1940; shipments have been recorded from ten deposits, of which four are particularly significant: The Brisco, Silver Giant, Parson, and Mineral King mines. Parr of the barite production is a by-product of base metal deposits in which barite is a major gangue mineral. About one hundred occurrences are known. COMMERCIAL production of barite in British Columbia dates back to 1940. Production volumes rose and fell and reached 39,900 tonnes in 1972. The main producer is Mountain Minerals Limited . There are two principal areas of barite deposits in British Columbia: ( I) The southeast part of the province along the Rocky Mountain Trench , which is the source of all production to date. (2) Stratabound occurrences in northeast British Columbia in the Gataga-Ketchika rivers and Muncho Lake areas which are not yet developed. Of the approximately one hundred reported barite occurrences, only ten have recorded commercial shipments, some of insignificant amount. So far, four deposits have proved to be important producers: Brisco, Silver Giant, Parson and Mineral King. The Mineral King property is situated near the confluence of Toby and Jumbo Creeks, 35 km southwest of lnvermere. The lead-zinc-copper-iron-barite deposits, as described by Fyles (1959, 1962), replace Proterozoic Mount Nelson dolomites of the Purcell system on the limb in the trough of a complex, tight syncline. The mine operated from 1954 to 1967 and 2,097,900 tonnes of baritic ore that was processed for base metal concentrates and also produced 22,680 tonnes of by-product barite. Since 1970, some 136,000 tonnes of barite have been recovered from the old tailings pond. The deposit is now considered depleted. The Silver Giant mine is located 10 km northwest of Spillimacheen. Barite and lead-zinc sulphides replace Cambrian Jubilee limestone near their contact with the overlying Ordovician McKay slate. Mineralization is located in the nose of an overturned plunging anticline. Between 1951 and 1957 800,000 tonnes of baritic ore were processed for lead and zinc concentrate. After 1959 barite was also produced , first from open pit, and later from reworked tailings. Up to 1979 production of barite totalled approximately 180,000 tonnes. Two other producing mines in the area are descri bed by G.R. Manson (this volume). Large, bedded stratabound barite deposits are reported from northeastern British Columbia. Six major shale-hosted Industrial Minerals in Canada lead-zinc-barite occurrences are known in the Devonian Gunsteel Formation. These are: Driftpi le Creek, Mount Alcock, Cirque, Pie, Fluke and Elf. In addition, numerous occurrences of strati form blebby or nodular barite and locally massive white crystalline barite are known from the Driftpi le Creek and Ak ie River districts in Gunsteel shale and from the Kechika, Road River and Ware map areas from Silurian siltstone . The size of these deposits is impressive; the baritic horizon at Mount Alcock is reported to be 25 to 30 m thick , and dri ll ing results from the Cirque deposit indicate reserves of 30 mi llion tonnes of baritic lead-zi nc-si lver ore. Similar bedded barite deposits are also reported from Midway area, near the Yukon border.

Jan 1, 1984

By J. E. Moran

A groupd of French capitalists, La Compagnie Française des Mines d'Or du Canada, has undertaken the considerable task of developing Otter creek, in the Atlin district, B.C., by hydraulic mining methods. It has long been known that the gravels of this stream carry sufficiently high values in gold to make it attractive as a mining venture, but it was impossible to ignore the existence of formidable natural obstacles to hydraulicing them, and these needed to be taken into serious account before embarking upon any costly programme of development. The tide to the Otter Creek leases was originally held by Mr. H. Maluin, a French engineer well known throughout the north, to whom was to fall the task of financing whatever programme might be decided upon. It was he, too, who would have to assume the responsibility of finally passing judgment upon the practicability of the various devises for overcoming the adverse natural conditions. With an infinite attention to detail, which I believe to be a characteristic of the French people generally, he studied his problem and was finally able to submit to his financial backers a programme which left the very minimum possible to the hazard of accident or chance. Dr. Mandy, on his visit to Otter creek this season, expressed the opinion that our method of opening this difficult creek presented certain features which might be successfully applied in placer operations elsewhere in British Columbia, and it is largely for this reason that the present paper has been prepared. I shall set forth, as well as I can, the practices which have enabled us to overcome rather easily some of the obstacles which nature had unkindly placed in the path which we must take. The natural flow of water in Otter creek is far too little to deal success-fully with the rather excessive amount of glacial drift overburden which lies directly over the gold-bearing gravels. For this natural defect, the only remedy was to procure more water. This we have clone through a system of flumes and ditches, totalling between ten and eleven miles in length, which bring to the mine a supply of water adequate for our needs.

Jan 1, 1932

"No questions.F Energy Consumption in Industrial Minerals : E.Joe No questions.g Automatic Dewaterinq at Mattagami : M. CaronE. Marcotte Is the control valve on the thickener underflow reducedFalconbridge as the pulp density reduces?Reply As the slurry density reduces the valve will constrict to reduce the flow and the density will re-establish itself.E. Marcotte Is there a stopper on the valve to prevent its closing too far?Reply We never shut it off completely because of the danger of sanding. It is just brought down to a normal level. It works very well within a given range and the operator is on hand to prevent any sanding out in the line."

Jan 1, 1984

By Arne Renström

A fleet management system such as Minestar with CAES and Aquila could basically be defined as a tool for production control and distribution of drill and load maps, but should also be considered as continuous improvements and a never ending production study. The objective of production studies is to establish facts to be used for production improvements. In a mine operation there are many issues to improve and they spread from achieving productions plans, drilling precision, improved spotting while loading to equipment utilisation. This gives that there is not one single key value to present; we need to manage information presented on maps, as trends, graphs, tables and pre-calculated data for ?free-use? normally in spread-sheets to be able to turn data into useful information.

May 1, 2003

By G. Tozsin

A six-stage sequential leaching procedure was used to assess the leachability of heavy metals from waste rock in Antamina Mine. Sequential extractions procedure is well established for fine and small (? 1g) samples. However procedures for coarse and large test samples are lacking. This study presents results of the sequential leaches tests conducted on relatively coarse and large representative samples in terms of the availability and mobility of metals. Selective chemical reagents were used to extract metals from six different fractions where metals released with each subsequent extraction are believed to be bound tighter than those released in prior steps and therefore less likely to be leached.

Aug 1, 2013

By H. Dundar

The first application of High Pressure Grinding Rolls was in 1985 at a cement plant, for the purpose of capacity improvement. Then various circuit configurations were derived to achieve a reduction in overall specific energy consumption, by transferring more of the grinding required to the HPGR. In most circuit configurations, the recycle of fines is required for effective breakage between the rollers. By increasing the fines amount in the feed material to a specific level within the recycling load, a uniform material bed is created and a higher pressure gradient along the roller width is obtained, resulting in compact flakes, including more fines. The fines recycle results in enhancement of the interparticle breakage. This paper will discuss the effect of the feed size distribution on HPGR performance.

Jan 1, 2012

By Andreea Catalina Gluhoi

Oxidation and reduction reactions of N-containing molecules have been studied over different types of gold-based catalysts, Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 (M, MI, MII=Li, Rb, Mg, Ce, Zr, Mn, Cu) prepared by deposition precipitation with urea. In general, all the catalysts were already active at low temperatures. NH3 oxidation was effectively catalyzed by Au/CuO/Al2O3, a catalyst which also gives the highest yield in N2. NO reduction by H2 performed over gold-based catalysts produced N2O, N2 and NH3 and N2O reduction resulted in the formation of dinitrogen. For all the reactions, large synergistic effects have been obtained by addition of different kind of additives.

Oct 1, 2003

By Paul D. Young, Michael J. Allan

"The Con Mine has been producing gold continuously since 1938. In 1990 laboratory and pilot plant investigations began into the use of pressure oxidation for treatment of an arsenic trioxide waste product from two previous roaster operations on the property. This led to the construction in 1992 of a 96 ton/day plant to treat a mixture of arsenic waste and flotation concentrate from the existing mill. The plant was commissioned in the fall of 1992.This paper describes experience gained in the commissioning and initial operation of the plant. The unique aspects of treating a hazardous waste product are described including special operating procedures to satisfy environmental and employee safety concerns. The paper further describes modifications made to the process flowsheet, to operating procedures and to materials of construction in the early months of operation."

Jan 1, 1994

By Geoffrey C. Streeton

A continual objective of mine operations is to reduce ground control costs without compromising the overall safety or performance of the installed ground support. Any change in the ground support regime must not result in a less secure or safe workplace. The due diligence required to implement a change in rockbolting practice is extensive, particularly when the new bolting system has not been used at any other mining operation. Factors such as yield, shear strength and embedment strength must all be investigated to gain an understanding of how the rockbolt can be expected to perform. This paper also discusses the substantial cost reductions and efficiency gains which can be achieved through the introduction of the Jumbolt rockbolt.

May 1, 2001

By R. S. Rogers

Abstract - Forensic geology in a mineral exploration context is concerned with geology and related technical matters as they pertain to legal cases involving exploration and evaluation of mineral properties. Such cases involve the possibility of outright scams that include falsification of data and information, as well as inappropriate application of various technical procedures. Experience in forensic geology in such cases emphasizes the need for systematic quality control procedures during routine exploration/appraisal and indicates the need for more attention to ‘target hardening’ (improving security in the chain of custody of samples and assay results). A number of ‘early warning signs’ that might suggest some form of tampering or falsification of information are listed. These measures will support the work of the "Qualified Persons" (geologists and engineers) entrusted with the scientific and technical aspects of mineral exploration, and facilitate the increased attention to regulatory oversight and enforcement of securities laws recommended in the report "Setting New Standards."

Jan 1, 1998

By Jucheng Wang

Unplanned open stope dilution is a major cost factor for many mining operations, even though significant advances in empirical and analytical approaches for estimating stope dilution have been made. Many factors that influence hanging wall dilution are still either ignored or assessed in purely subjective terms. Undercutting the stope hanging wall on both the overcut and undercut development are well recognized factors which contribute to hanging wall instability and dilution. In many mines, undercutting the hanging wall breaks the integrity of the rock mass that may form along continuous foliation or bedding planes parallel to the stope hanging wall contact, reducing stability. This undercutting also increases the zone of destressed or relaxed rock that may potentially fall into the open stope as dilution. An approach is introduced for quantifying the effect of undercutting on potential stope dilution. An extensive database of stope case histories has been collected to look at dilution from Hudson Bay Mining and Smelting operations (HBMS) in Flin Flon.

May 1, 2002

By G. Langlands

"R. Tenbergen Is this flotation machine suitable in the flotation ofInco ball mill discharges where we have a coarse feed at 60% solids?Reply Experience has shown that there is not a significant increase in the wear life of these machines when handling coarse material (8 mesh) at 60% solids. A common practice in Europe is shut down on the week-ends.The material is allowed to settle and on start-up an injectic of air for 15 seconds is sufficient prior to start-up. At,mining we put our unit in the middle of a bank of 44 cells and in order to ensure severe sanding we shut the aker cell down while the remaining cells kept running. After 20-25 seconds of air the cell started without trouble.P. Mahant Is there a build-up inside the impellor shaft housing? Falconbrige Ltd.Reply There is no sand build-up but rather a scale build-up which due to a flexing action frees itself periodically. Part of the design of the machine permits a water injection into the shaft housing to free any build-up. This is done in Europe during the week-end shut down."

Jan 1, 1984

By W. Dan Hausel

"Abstract-Hundreds of diamonds have been found in the United States. The majority of the discoveries occurred during the 19th century as a by-product of placer gold mining. Most of these early diamond finds have no known source, and in many cases are situated in areas unfavorable for diamond exploration based on current models that require kimberlite or lamproite to be emplaced in a stable Archean craton or Proterozoic craton margin.Diamonds have also been recovered in situ from lamproite at Murfreesburo, Arkansas, from kimberlite in the Lake Ellen region of Michigan, and in several kimberlites in the Colorado-Wyoming State Line district. Unverified reports also suggest that diamonds may have been recovered from other related intrusions at a number of localities in the United States."

Jan 1, 1995

By Masatake Haruta

Gold can be deposited as nanoparticles on a variety of support materials by coprecipitation or deposition-precipitation of Au(OH)3, grafting of organo-gold complexes such as dimethyl-Au(III)-acetylacetonate, mixing of colloidal Au particles, and vacuum deposition. Owing to the moderate adsorption of at least one of reactants (for example, CO) on the edges and corners of Au nanoparticles and to the activation of the counter reactant (for example, O2) at the perimeter interface with the supports, supported Au nanoparticle catalysts exhibit unique and practically useful catalytic properties at relatively low temperature below 473K. They have already been commercially used for deodorizers in rest rooms in Japan and will find growing applications in indoor air quality control, pollutant emission control, production of hydrogen energy carrier, and innovations in chemical processes. Cluster science of Au may also open an exciting area of research showing some magic numbers for dramatic changes in reactivity.

Oct 1, 2003

By Y. Konishi

This paper reviews the mechanism and kinetics of bioleaching of chalcopyrite by the thermophilic archae Acidianus brierleyi in batch and continuous-flow reactors. Rate data for the batch bioleaching of chalcopyrite concentrate were collected to clarify mechanism of the chalcopyrite bioleaching with A. brierleyi. The chalcopyrite leaching was markedly accelerated in the presence of A. brierleyi, and greater than 90% copper leaching was achieved within 10 days. Chalcopyrite leaching took place predominantly as a result of direct attack by adsorbed bacteria on the sulfide surface, the chemical leaching with ferric iron being insignificant. Batch rate data collected under a variety of operating variables were analyzed with our batch bioleaching model, in order to estimate microbial kinetic and stoichiometric parameters for the microbial growth on chalcopyrite. The batch model and the estimated parameter values were used to find optimum operating conditions. Moreover, the batch model was extended to describe the bioleaching in continuous-flow stirred tank reactors. Simulations based on the continuous reactor model and the estimated parameter values were used to predict the leaching fraction as a function of the number of reactors connected in series.

Jan 1, 2007

By Christopher H. Clement

The International Commission on Radiological Protection (ICRP) is an independent, international organization that advances for the public benefit the science of radiological protection, in particular by providing recommendations and guidance on all aspects of protection against ionizing radiation. This presentation touches on aspects of The 2007 Recommendations of the ICRP, a fundamental document that lays out the system of radiological protection for all exposure situations and types, and focuses on other recent publications relevant to the uranium industry. Of particular relevance are the 2009 ICRP Statement on Radon and the accompanying report on lung cancer risk from radon.

Aug 1, 2010