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By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019

By R. P. Viljoen, A. L. Sokolov

"The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonicmagmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonicallycontrolled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian platform, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu mineralization. It does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By A. Navarra, Norman Toro, T. Marín, Fernando Ayala

The quantitative techniques to evaluate the enhancement of a particular unit operation should consider the corresponding changes to the adjacent unit operations. For example, the expansion of off gas handling capacity should consider the corresponding changes in converter cycle times, matte grade, and other operational parameters, that can provide the optimal system-wide benefit. In general, the upgrading of smelter equipment is risky due to the size of capital investment, as well as any unforeseen impacts on rest of the operations. However, this risk can be mitigated by applying the principles of Front End Loading (FEL) in the formulation of multiphase re-engineering projects. The initial phases of engineering are relatively inexpensive, and determine whether or not to pursue the subsequent phases that are comparatively more expensive. Each phase of engineering depends on increasingly detailed descriptions regarding the critical phenomena that can effect design decisions; the increasing levels of detail may result from numerical simulations, as well as laboratory and plant trials. The quantitative framework should be sufficiently flexible to accommodate these increasing levels of detail, regardless of the particular phenomena, so that it may evolve throughout the project. The current article describes the combined usage of mass balancing, thermochemistry and multiphysics, in the development of discrete event simulation (DES) and finite differences (FD). The incorporation of finite differences into a DES framework depends on adaptive time-stepping, to determine threshold-crossing times, e.g. when the matte temperature surpasses a critical level that necessitates the addition of cold charge. The hybridization of DES and FD is appropriate for multiphase smelter development projects, as it supports semi-continuous material flows, operational policies and scheduling, as well as unexpected events and trends, in increasing levels of detail. This type of framework will support the installation and tuning of modern control systems, including state-of-the art sensors and machine learning algorithms.

Jan 1, 2019

By G. W. H. Norman

The surficial Archæan rocks of the southern gold belt of western Quebec are constricted near Kewagama lake by granite masses to the north and south. This divides the belt into natural eastern and western parts. This paper deals with the eastern part, extending from Malanie to Haig township. In this section the Keewatin-Timiskaming rocks have a length of about 70 miles and end abruptly against garnetiferous gneisses of the Grenville terrain. In the western half of the section where exploration has been under way since the early twenties, there are sixteen mines that are or have been in operation, and eleven prospective mines. In the eastern half where exploration has been carried on since the early thirties, six prospective gold mines are under development, one· of which, Louvicourt Goldfields, is at the initial production stage. Of the sixteen properties in the western half that are operating or have operated, all, except the Golden Manitou, which is a base metal mine, and the old Green Stabell from which there was a small production of copper, produce gold. Of the eleven prospective mines in the western half nine have gold. New Bidlamaque has gold and copper and one, East Sullivan, has copper-zinc ore. Since production began in 1927 gold, silver, zinc, copper, and lead having a total value of about $10,000,000 have been produced from the mines of the eastern section of the southern gold belt of western Quebec.

Jan 1, 1954

By Fathi Habashi

New technology first introduced by Nippon Steel Corporation at Kitakyushu in Japan in 1976 now used at a number of plants in other countries, known as dry quenching of coke, uses nitrogen in a closed circuit to avoid environmental emissions. In addition, heat is recovered in the form of steam, from the red-hot coke. In steel plants oxygen is used extensively and therefore by-product nitrogen from air liquefaction can be effectively utilized in this way.

Jan 1, 2014

By Alessandro Navarra

Discrete event simulation provides a computational framework in which the use of smelting equipment can be analyzed and optimized, leading to the development of alternative modes of operation. Much of the complexity of copper and nickel smelters is centered on the converter aisle. These converters operate in parallel, produce batches, and set the tempo for the downstream operations. In practice, smelter staff schedule daily operations to coordinate the smelting furnaces and converters with downstream operations. Thus, a realistic simulation of smelter operations, over hundreds of days, should incorporate converter scheduling algorithms as presented in this paper.

Jan 1, 2014

By STEPHEN V. FORGERON

The Loch Lamond celestite properties in central Cape Breton Island were mined by Kaiser Celestite Mining Limited from 1970 until 1976. Poor market conditions in J976forced operations to cease. Kaiser holdings included the Lake Enon, MacRae and A mac prospects. A total of about 272,000 tonnes of raw celestite have been mined. Celestite deposits are situated in the Loch Lamond Basin, specifically in Lower Windsor sedimentary rocks. Of the five formations in the Lower Windsor Group, celestite is found in the upper four. Celestite in the Enon Formation occasionally replaces shale that separates stromatolitic dolomite columns; elsewhere in the formation it occurs in association with siltstone and gypsum. Jn the B2 Limestone Formation celestite fills pores or grades between limestone and gypsum. It replaces both limestone and silty limestone conglomerate in the Loch Lamond Formation; this limestone is of unusually high grade (60 to 70% SrSO,J for the area. Evidence indicates that the Uist Formation may hold important celestite reserves. Original celestite mineralization probably resulted from evaporation of seawater on mudflats or 'sabkhas'. Secondary mineralization also may have occurred. Strontium ions could have been leached from pre-existing concentrations and overlying gypsum, moved downdip in groundwater and combined with sulphate rich waters to deposit as celestite in porous B2 limestones.

Jan 1, 1984

By Z. D’Amico

"IntroductionWE HAVE HEARD quite a lot recently on newer methods -of supporting roof, such as roof bolting or the use of metal props and •booms, but, with the exception of roof bolting, these methods are confined mostly to comparatively low, regular seams and even .bolting cannot be used to hold soft sides. Thus, where a seam of coal has great variations in thickness, or where it is faulty, or where the coal sides must be supported, nothing can wholly take the place of timbering with wood. This paper will deal mainly with the method of timbering such a seam, namely, the No. 3 seam mined by Brazeau Collieries, Limited, at Nordegg, Alberta, where the full height of a thick seam is mined in development. However, a few words on one or two other systems practised in Alberta when, in development work, a thick seam is only partially mined, should be of interest.Examples of Timbering in High SeamsThere .are several methods in use today for dealing with high seams of coal. The most popular is to develop the seam by driving road-ways in the coal by some conventional method, usually recovering the full thickness of the seam on the retreat. The following examples illustrate two variations of this method.In Figure I we have a thick •seam of friable coal, with a good roof, pitching about 30 degrees, which is being mined by taking the upper part of the seam in the development work, leaving the •bench coal in place. Figure 1A shows a section through a room."

Jan 1, 1954

By John Eggert, Paul Benford

"Since 1982, Placer Dome Inc. -Dome Mine has steadily increased mill throughput. Tonnage has increased from a nominal design capacity of 3000 short tons per day, attained in 1985, to 4130 stpd by the end of 1992. Many minor and major circuit adjustments were tried to maximize tonnage.Having utilized most conventional means of increasing tonnage, further increases required a newer approach. This paper discusses the Dome experience in the development and implementation of an expert system.The Comdale/C system was chosen for a controlled trial. The criteria for acceptance were: increased tonnage had to be sufficient to pay for the system; the increase had to be visibly sustainable and the mill operators had to be willing to accept the system.The criteria for purchase were met during the trial and the system was purchased. The system continues to perform well. The tonnage throughput increase has been sustained while operator acceptance remains high.IntroductionPlacer Dome Inc. -Dome Mine is Canada's oldest operating gold mine. The mine was among the first established in the Porcupine camp in what is now Timmins, Ontario. The City of Timmins is located approximately 500 miles or 800 kilometres north of Toronto. Figure 1 shows a map of the province of Ontario and the mine location.In 1912, milling began at a rate of 350 short tons per day. With two minor exceptions, milling has been continuous since this time. The first of these shut downs was in 1918 during the first world war. The war created labour shortages which forced the mine to stop production for more than a year. The second was in 1930 when fire destroyed the mill."

Jan 1, 1994

By John F. Vynne

This paper will discuss several of the systems and processes that have been developed over the past few years, and are now being utilized by major mining companies on draglines in North America, Australia and South Africa. These technologies include production monitors and reporting systems, GPS navigation systems, structural integrity monitoring systems, structural analysis studies to increase the dragline RSLs, and inspection and response strategies. The use of these technologies provides significant increases in dragline production, and reduces maintenance costs and downtime. The question that needs to be asked is what value is there in monitoring? Increasing dragline productivity is dependent upon to two items with the overall goal being to maximize the number of bank cubic meters moved and to uncover more coal: 1) maximizing payload and 2) maximizing the number of cycles. If you do not measure and try to optimize the parameters that impact payload and number of cycles, there is very little chance that you can improve overall dragline productivity. These parameters are: Maximizing payload is dependent upon the following: ? Geology ? Blasting ? Monitor weighing accuracy ? Engage location ? Disengage Location ? Rigging ? Suspended load ? Bucket characteristics ? Operator skills ? Minimizing rehandle Maximizing the number of cycles depends upon maximizing digging time, and minimizing cycle and delay/down times by: ? Minimizing Operational Delays ? Minimizing Mechanical Delays ? Minimizing Idle time ? Minimizing Walking time ? Minimizing Fill Time ? Minimizing Swing Angle ? Maximizing Swing & Return Rates ? Minimizing Spot Time A third reason to monitor, conduct structural analysis studies, and have inspection strategies is to prevent catastrophic failures such as shown in the following photographs (figures 1 & 2).

May 1, 2008

By John C. Loretto

"Answers to some of the problems ofRecovery and Metallurgical AccountingIn Gold and Silver Hydrometallurgical PlantsThe start-up over the last few years of new hydrometallurgical plants for the recovery of gold and silver has brought to the surface again a number of problems. Most of the problems have existed for some time and they manifest themselves mainly in two ways. Firstly, the plant results do not agree with the Metallurgical Test work figures and secondly, the Metallurgical Accounting figures do not balance.The plant results not agreeing with testwork figures are mainly due to:a) The testwork samples were not representative of the eventual plantfeed;b) Misinterpretation or misunderstanding of testwork;c) Plant losses;d) Plant design not allowing testwork results to be achieved;e) Operating deficiencies.a} The testwork samples being dissimilar to the plant feed occurs on a very high proportion of projects. The effects of this can beccr.ie exaggerated because the upper levels of the mining company often regard the original testwork figures as sacred and therefore base their judgement of current plant performance on these figures.Frequently the test work samples represent only a minor part of the orebody or alternatively a single composite of the whole ore body is used for the testwork long before it has been determined that all of the potentially different ore zones behave in the same manner. These errors can be compensated for by repeating the ""testwork tests 11 on current plant feed on a routine basis and using these tests to determine whether or not the plant is operating satisfactorily."

Jan 1, 1982

By J. A. Meech

"The technology known as Expert Systems is being used within the minerals industry in a wide variety of problem areas. Applications include diagnosis, prediction, training, monitoring and control. Expert Systems provide a way to program computers to imitate human thinking. The construction of such systems is a straight-forward task that can be quickly learned by novices but can require a lifetime to master.To assist in the understanding and utility of this technology, a special manual bas been prepared which operates on a microcomputer under the MS-Windows environment. The manual covers all aspects of Artificial Intelligence of relevance to Expert Systems. A hypertext system allows users to probe as d•~ply as needed to achieve understanding or to simply skim the surface of the knowledge to obtain a quick overview of subjects. The manual was developed under the sponsorship of the Mineral Sciences Laboratory of CANMET and is available from the Mining and Mineral Process Engineering Department at the University of British Columbia. Annual updates are planned to keep abreast of new developments in this rapidly changing technology. RESUMELa technologie: des Systèmes Experts est utilisée par l'industrie minière pour résoudre une grande variété de problèmes. Les domaines d'application comprennent le diagnostic, la prédiction, la formation, la surveillance et le contrôle des procèdes. Les Systèmes Experts permettent d'écrire des programmes d'ordinateur qui imitent le processus de la pensée humaine. La construction de tels systèmes e:st une tâche qui peut être apprise rapidement mais qui peut prendre des années à maitriser.Pour aider à mieux comprendre et utiliser cette technologie, un manuel spécial opérant sur microordinateur dans l'environnement Windows a été développe. Le manuel couvre tous les aspects de l'intelligence artificielle qui concement les Systèmes Experts. Un système ""hypertexte"" permet à l'utilisateur d'étudier un sujet en profondeur ou de simplement couvrir une grande variété de sujet en surface. Le manuel a été développe avec l'aide financière du Laboratoire des Sciences Minérales de CANMET et est disponible au Département de Génie Minier et Minéralurgique de l'Université de la Colombie Britannique. Des mises à jour annuelles sont prévues de manière à couvrir les changements et nouveautés de cette technologie en évolution."

Jan 1, 1993

By G. Heinrich

Size by size recoveries and pentlandite liberation data from image analysis were used to evaluate plant tests of pentlandite flotation and pentlandite/pyrrhotite middlings flotation from pyrrhotite in a circuit treating low grade magnetic intermediates at the Strathcona Mill. Raising the pH with lime gave improved selectivity for liberated pentlandite but there were major losses of middlings unless the circuit was pulled hard indicating the need for finer regrinding. However, size by size recoveries at the normal regrind showed that, while the pentlandite recovery improved in the finer ranges, the pyrrhotite recovery also increased leading to little selectivity in any size range. A much finer regrind gave greatly improved selectivity in all size classes suggesting that 'surface polishing' as well as liberation effects were being seen. Using liberation data from image analysis of the products, surface polishing accounted for over 99 % of the improvement in selectivity. Unreasonable recoveries of more highly liberated particles were observed for liberation analysis by volume fraction but showed the expected trend in recovery when the analysis was based on surface liberation. The surface liberation data showed that the improved pentlandite recoveries after finer regrinding were to more than 90 % caused by improved liberation with the remainder contributed by surface polishing effects. The practical implications of this work are that i) the comparison of particle grades with product grades allows to estimate the effect of regrinding on co-flotation/entrainment, ii) surface liberation models should be used for evaluating recoverabilities by flotation and iii) regrind circuits may be set up to ensure that all particles go through the mill or that only the coarse fraction is reground depending on the surface scrubbing found to be required.

Jan 1, 1993

By Adrian White

Agenda Overview of pastefill at Kidd Mine Pipeline wear and the need to monitor Steel Loop monitoring Steel Borehole monitoring Monitoring pipe linings

May 1, 2013

By C. T. Wiliams, John B. Bush, John Lamb

"THE TOWN OF HEDLEY is in the valley of the Similkameen River, about 200 miles east of Vancouver and 25 miles north of the International Boundary between British Columbia and the State of Washington. The main ore deposits are located on Nickel Plate Mountain, northeast of the town.The outcrop of the Nickel Plate system of orebodies is at an elevation of 5,900 feet. It was discovered in 1898 by prospectors and sold in the following year to the Marcus Daly interests of Butte, Montana. Production commenced in 1904 under the name of Daly Reduction Company. In 1909 control passed into the hands of the Hedley Gold Mining Company. Operation of the mine continued until 1930, when exhaustion of known ore reserves forced it to close. Upon the recommendation of Paul Billingsley (3) the mine was optioned by the 1. W. Mercer Exploration Company in 1932. Production began once more in 1934 under the name of Kelowna Exploration Company Limited, and was practically continuous until August 1955, when the mine was again shut down. The name of the latter company was changed in 1951 to Kelowna Mines Hedley Limited.The Mascot Fraction, a small wedge-shaped claim lying astride the Nickel Plate orebodies, was mined by Hedley Mascot Gold Mines Limited between 1935 and 1949. The geological setting and structural control of ore are essentially the same as in the adjoining Nickel Plate Mine.Total production from all operations on Nickel Plate Mountain to the end of 1954 was approximately 3,800,000 tons of gold ore, with a gross value in excess of $48,000,000.General GeologyNickel Plate Mountain occupies the gentle westerly dipping limb of an asymmetrical anticline, the axis of which trends northeasterly. The rocks are composed of a thick pile of Triassic limestone, limy argillite, and quartzite, -resting on a flattish floor of granodiorite near the base of the mountain. Associated with these sediments is a host of porphyritic sills and dykes of gabbro-diorite composition. In the mine area east-west brown soda-rhyolite dykes and north-south black andesite dykes crosscut all the other formations and the ore, probably following steep later fractures."

Jan 1, 1949

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

By David W. Smith

"This paper is devoted mainly to a discussion of the hydrocarbon potential of the offshore, with a few brief remarks concerning the inorganic mineral potential.OFFSHORE OIL AND GAS POTENTIALIN ORDER TO HAVE HYDROCARBON ACCUMULATIONS, we must satisfy three basic requirements. First, we re-quire a sufficient thickness of sedimentary rocks which contain some porous and permeable formations to act as reservoirs. Second, we require some type of trapping mechanism, such as faulting, folding or stratigraphie trapping. Finally, we require that large quantities of hydrocarbons have been generated within the sedimentary rocks and have migrated to the traps."

Jan 1, 1969

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By Tom Shumka

All mineral processing facilities that use girth gear driven mills need to inspect the gear teeth on a routine basis, whether it is every six months or every three years. The inspection frequency depends upon gear tooth condition, and the objective is to ensure operational integrity of the gear teeth. Conventional methods such as magnetic particle testing, visual inspection, or dye penetrant examinations rely heavily on interpretation. At best, these techniques can determine whether a defect exists, but are unable to provide information on defect severity. This paper describes the use of combined Eddy Current Array (ECA) and Alternating Current Field Measurement (ACFM) to provide a complete survey of all surface breaking indications on the whole gear tooth depth. This method accurately determines the size, length and depth of any cracks found on the surface.

Jan 1, 2012

Some Statistics ? Feasibilitystudiescostbetween2% & 3% of capital andrequire8% to15% of total engineering effort ? Feasibilitystudiesusuallytakebetween8 and16 months ? Historically more than80% of projects fail to achieve all their objectives, usually blame the feasibility study ? What is bankable? Means that your promises will long be remembered. ? Poorly executed feasibility studies ? Driven by inexperience, unrealistic expectations, time constraints, financial constraints, lack of objectivity, front end loading activities incomplete or poorly done ? lack of minimum standard to provide a consistent approach Trend to improve???

May 1, 2010