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By J. A. Finch

Solvent-coated air bubbles in the Air-Assisted Solvent Extraction (AASX) process achieve the dual role of high solvent specific surface area and ease of phase separation. The thickness of the solvent film is of fundamental interest but difficult to measure directly in the process itself. As an approach interferometry (in the UV-vis region) was used to measure the time dependent thickness of a film formed by blowing an air bubble in kerosene-based solvents. The film was stabilized by the presence of 1.5 ppm silicone oil, as employed in AASX. The film appears to comprise two layers; an outer "free" layer of almost constant thickness and an inner "bound" layer which decreased in thickness with time. The bound layer is considered relevant to AASX. For a 20 mm diameter bubble blown in LIX/kerosene solvent the initial thickness was ~ 3 um which decreased over 10 minutes to a final rupture thickness of 500 nm. The bound layer thickness and time to rupture decreased with decreasing bubble size. Correspondence to prior indirect estimates of solvent layer thickness is examined.

Jan 1, 2006

By I. Ciabatti

Inorganic salts of hexavalent iron (ferrate (VI)) are versatile reagents for water and industrial effluent treatment because of the strong oxidising effect of the ferrate ion (FeO42-) and the well-known coagulation properties of the resulting ferric ion. Among other applications, ferrate can effectively remove arsenic, cyanide and phenols from industrial effluents. Furthermore, ferrate salts can be prepared from ferrous sulphate, a common byproduct of the steel and titanium industries, and possibly from other iron wastes. Notwithstanding their many potential advantages, the industrial-scale application of ferrate salts, such as potassium ferrate (K2FeO4), for effluent treatment has been hindered by the difficulties inherent in their synthesis and stabilisation. Within a project co-funded by the European Commission, the large-scale synthesis of stabilised potassium ferrate was realised through a new synthesis process, and different applications of the resulting ferrate to effluent and wastewater treatment are under investigation. This paper reports the results of the application of stabilised potassium ferrate for the purification of textile effluents. Laboratory and pilot-scale tests were carried out and the performance of the ferrate was compared to that of chemicals currently used in wastewater treatment. According to these experiments, potassium ferrate is a promising reagent for an effective treatment of textile and other industrial effluents.

Jan 1, 2006

By Eldridge Haynes

IF you ask the average American to define 'total war' he is apt to fumble for an answer. But in Britain everyone knows the answer, because Britain has mobilized its total labour force, including women. If we were to match, proportionately to our population, Britain's mobilization of labour, we should have 60,000,000 people working full time in the armed services, civilian defence, and war industries. Actually we have fewer than 35,000,000 so employed. In Britain two out of every three persons between the ages of fourteen and sixty-five are so engaged. For the first time in the history of any democracy Britain conscripts women for service in the army, navy, and air force. Two hundred thousand British women have been conscripted for the army, known as ATS, meaning Auxiliary Territorial Service. There are more women in the air force than the total personnel of the RAF at the outbreak of the war and almost all of the land base jobs of the British navy are now handled by women. In addition to cooking and office work, Britain's women soldiers and sailors are driving trucks and motorcycles, repairing motor vehicles, packing and repacking parachutes, installing, inspecting, and maintaining gun equipment and ammunition of combat planes after each raid, raising and lowering barrage balloons, forecasting weather, manning harbour craft, sending and receiving radio messages. A normal ack-ack unit is composed of 229 women and 189 men. The women man the gun height finders and predictors, give bearings, and signal to fire.

Jan 1, 1942

"Discrete Fracture Network (DFN) modelling has increasingly being used in many geotechnical and mining engineering problems, the authors believe there is an ever greater demand to provide updated guidelines that address the collection of discontinuity data in the specific context of DFN models. In general terms, the generation of a DFN model requires collecting information on i) fracture orientation, ii) fracture intensity, iii) fracture length and iv) fracture terminations. The International Society of Rock Mechanics (ISRM) suggested methods for the quantitative description of discontinuities in rock masses directly include most of these parameters. However, there are important differences engineers should be aware. To what extent discontinuities can be sampled and which limitations are inherently introduced in the analysis by the sampling methods being adopted represent important aspects that should drive the collection of discontinuity data for DFN analysis; this will require the introduction of a more appropriate set of guidelines bridging the gap between the current, very practical, ISRM methods and the data requirements imposed by the use of new DFN technologies.INTRODUCTIONThe last decade has seen a major increase in use of the Discrete Fracture Network (DFN) approach, both as a stand-alone tool or integrated within more complex geomechanical simulations (Rogers et al., 2014 and Elmo et al., 2014). In particular, the DFN approach offers the opportunity to maximise the use of fracture data collected from mapping of rock exposures and to construct synthetic rock mass (SRM) models. However, the potential of DFN based modelling is limited if there is insufficient care in collecting the necessary structural data at the required engineering scale. DFN models are also subject to the process of data calibration and validation (Hadjigeorgiou, 2012). With DFN modelling becoming an almost integral part of many geotechnical and mining engineering problems, the authors believe there is an ever greater demand to review the process of collecting fracture data in the specific context of DFN modelling.The value of the DFN model depends directly on the quality and quantity of available field data. For example, fracture length (persistence) is an important parameter in DFN modelling; however, this parameter is either seldom available at the pre-feasibility stage due to a lack of exposures (man-made or natural), or engineers have access to limited length data collected along exploratory drifts. Characterisation of rock exposures should also take into account limits of window/scanline mapping techniques with respect to both trace length bias and the effect of cut-off assumptions inherent in the mapping methodology."

Jan 1, 2015

By Karen M. Moffitt

Developments in mining methods and rates have led to an increase in the frequency and size of waste dump failures that have not been adequately predicted or explained in terms of conventional slope stability analysis. Monitoring data and visual observations suggest a unique mode of failure responsible for large runout events. A numerical model has been developed to capture commonly observed patterns of deformation, and investigate the formation of the ensuing failure mechanism. The analyses have yielded a good correlation with observed field behaviour and have provided significant insight into the coincident stresses and deformations within the dump. Results indicate that while creep effects in the waste dump could have a significant effect on the magnitudes of displacement, the overall dump stability is governed by the strength of the foundation soils underlying the toe region. Consideration of both the stress and velocity fields leads to factors of safety for various dump heights and foundation slopes that are considerably less than predicted from limit equilibrium analysis. The results suggest that conventional limit equilibrium analysis techniques may not be adequate when assessing the stability and design of waste dumps on steeply sloping terrain.

May 1, 2001

By K. V. Konigsmann

"The mill at Mattagami Lake Mines treats 3,850 tons per day. The mill feed is a heavy sulphide ore. It is composed ofPyrite & Pyrrhotite - 40%Marmatite - 17%Chalcopyrite - 2%Magnetite - 10%Talc and other Silicates - 31%The sulphides are intimately associated with each other and often finely disseminated throughout the siliceous gangue. An abundance of middling particles exist in the circuit and a delicate balance has to be maintained between concentrate grades and metal recoveries.The metal content of the mill feed fluctuates between 0.4 to 0.7% for copper and 6 to 13% for zinc.The flow sheet of the concentrator is shown in Figure 1.Eight sample streams have been selected for on-stream analysis, namely1. Copper Concentrate 2. Copper Cln Tailings 3. Copper Tailings 4. Zinc Concentrate5. Zinc Rgh Concentrate6. Zinc Cln Tailings7. Zinc Rgh Tailings8. Flotation TailingsThe mill feed is not being analysed. Only a very coarse sample could be obtained which would be difficult to pump, and the fluctuations in the copper content are too small in absolute terms to have much of a bearing on circuit operations."

Jan 1, 1969

By H. J. Meyer

"A hydrostatic elevation difference meter has been developed for use in measuring elevations along gravity traverses. Elevations of stations 100 feet apart can be obtained at a rate of 1/2 mile per hour and to an accuracy better than 1/3 foot. This can be done along traverses which have not been cut and chained. The instrument is durable, lightweight and constructed of materials which will withstand any temperature encountered in field work.It is believed that this device will more than double the rate at which gravity surveys over mining prospects can be carried out."

Jan 1, 1972

By William C. Boggis

EKATI? Diamond mine is located 300km northwest of Yellowknife and 200 km south of the Arctic Circle in the Northwest Territories of Canada. The site is a remote tundra area with continuous permafrost and is in the Canadian Shield. EKATI? is the first diamond mine in Canada and is operated by BHP Diamonds Inc., which is a part of BHP Minerals. BHP Diamonds Inc. is an incorporated company based in Vancouver, BC. The mine is a joint venture of BHP Diamonds Inc. (51%), Dia Met Minerals Ltd. (29%), Charles E. Fipke (10%) and Dr. Stewart L. Blusson (10%). The mining area lies within the 10,960 ha land leases held by the joint venture. The total claim block covers 344,000 ha. To date over 136 kimberlite structures have been identified within the claim. Five of these provide the basis for the present mine plan with three others identified for future inclusion. At full capacity the mine will produce 4.5 million carats per year, approximately 4 % of world production and employ approximately 600 people, with over 33% being Aboriginal from the Northwest Territories.

May 1, 2001

By R. N. W. DiLabio

"In a continuing program of mapping glacial dispersal trains, near-surface till samples were collected down-ice from a copper-silver-gold prospect at Onaman River, Ontario, and down-ice from the past-producing gold district at Oldham, Nova Scotia. The program is designed to aid exploration by illustrating glacial dispersal from various types of known occurrences and by identifying postglacial processes that control drift composition at a detailed scale.Native gold was mined at Oldham from arsenopyrite-bearing saddle reef quartz veins in a dome in Early Paleozoic slates of the Meguma Group. Gold abundances greater than 10 ppb in till form a dispersal train at least 1900 m long. Gold abundances between 40 and 100 ppb occur in clusters up to 600 m down-ice from gold-bearing bedrock. Anomalous arsenic abundances in till form a broad train 1100 m long that is significantly different in shape from the gold train.At Onaman River, subeconomic amounts of Cu-Ag-Au occur in quartz lenses in Archean mafic volcanic rocks. A dispersal train defined by the distribution of mineralized boulders and increased abundances of Cu, Ag and Zn in till extends 600 m down-ice from mineralized bedrock. Gold abundances between 10 and 70 ppb do not define this dispersal train, but occur instead in clusters 300 to 600 m down-ice from mineralized bedrock. In vertical sections in the upper 2 m of copper-rich till, Au abundances vary sympathetically with Ag and Cu levels; however, there seems to be no preferential site of Au enrichment in the mineral portion of the soil profile.Several of the mineralized boulders at Onaman River are richer in Au and Ag than the mineralized bedrock from which they were derived. Although some of the high Au and Ag assays were caused by biased sampling of sulphide-rich portions of the boulders, many were caused by leaching of sulphide minerals from 'the boulders, which left a limonitic boxwork that is enriched in Au and Ag. A few of the Au-rich boulders may have been derived from an unknown bedrock source."

Jan 1, 1982

By G. Kallfa P. Geo

Exploration at both Greenfields and Brownfields stages entails business risks of different nature and success rates. Greenfields exploration is exceedingly assumptive and the success rate of exploration or return on investment is low because exploration is an inherently risky business. Brownfields exploration on the other hand is less risky, as the geology is better understood, but generally speaking since the larger ore bodies close to surface have already been found the return is lower. In addition, most exploration at the Brownfields stage is generally more expensive due to extensive use of drilling. Surface geology mapping and expensive drilling have been key technical contributors to most exploration programs over the last two decades. However, as client expectations, logistics, target depths and complexity of exploration programs increase, there has been a growing emphasis on using geophysical techniques to complement other methods. Integration and optimization of various geoscientific disciplines is becoming more important in successful exploration programs of the future to reduce exploration risks, successful integrated exploration requires putting reliable geophysical parameters and correspondent petrophysical property contrasts into an assumed or conceptual geological model. This paper discusses a new multi-parameter geophysical methodology finalized in a unique conceptual geologic model which can be used either as a root model in grassroots exploration or as an efficient tool in Brownfields exploration to successfully find satellite orebodies of almost any size. The application of a new multi-parametric geophysical approach to Brownfields exploration is illustrated with examples from Manitoba, including a past producing nickel sulphide deposit in Lynn Lake and the Reed Copper deposit, currently in development.

May 1, 2013

By B. Crane, S. Schwartz

"IntroductionThe Cape Breton Development Corporation (CBDC) located in Cape Breton, Nova Scotia, in eastern Canada, was established in 1967. Its mandate at that time was to facilitate a phased downsizing of the coal industry and developing viable replacement industries. The oil crisis in the early 1970s changed CBDC’s mandate and focus was modified to increase coal production to support Nova Scotia Power Commission’s “off oil” policy for their power generators. In the late 1980s the mandate to develop viable replacement industries was eliminated and CBDC became primarily a coal mining company. CBDC presently operates two underground coal mines, Phalen Colliery and Prince Colliery, using a retreat longwall method of mining. Both mines operate beneath the Atlantic Ocean. CBDC also operates associated infrastructure — central workshops, a railroad, coal preparation plant, and international pier. The Need For Substantial ChangeOver the last few years, CBDC has been facing some challenging issues, including improving labour management relations and achieving financial self-sufficiency and profitability. Recent achievements with regard to human resource issues, especially in the areas of collective bargaining, absenteeism, and attendance, show noticeable improvements. All participants should be commended for successfully concluding the collective bargaining process with all four CBDC unions, CUPE; CAW; IAM&AW; and UMWA. However, although these changes are encouraging, even critical in the short term, they are not sufficient to ensure the long-term viability of the company. Market ForcesShort- and long-term financial realities are drawing the need for further substantive changes. The corporation has a mandate to achieve financial self-sufficiency by the year 1999. This goal can only be achieved through a combination of cost reductions and productivity gains, specifically, a reduction in the workforce of 658 and an increase in production of 800 000 tonnes annually. This increase in productivity requires CBDC to re-think the way it does things.In the longer term, CBDC faces even greater challenges. The energy market is becoming more competitive. The electrical utilities across Canada are anticipating deregulation and are positioning themselves for the resultant competition. As primary fuel supplier to Nova Scotia Power Inc. (NSPI), the corporation will have to become ever more competitive to stay in business."

Jan 1, 1997

By R. C. Wallace

Since the time when Canada's East and West were joined by the railway, and communication was established into the interior, settlements grew on the southern fringe of the great Precambrian area that formed the northern protaxis of the continent during its vicissitudes of growth. They clung precariously to the fringe of that ancient land, for the Precambrian is not generous to those who wish to live by the fruits of the soil, except in those limited areas where the Pleistocene ice-sheet has been profuse in its gifts of clay to cover the hard surface of the Precambrian rock. Later settlements spread westwards over the expanse of Cretacean plains that now form the wheatfields of the Canadian West; but there still remained in northern and western Ontario, in eastern and northern Manitoba, a pioneer race, to whom agriculture had attractions only in so far that it provided the wherewithal to lay siege to the riches of the Precambrian. And they had a vision beyond their time. More than they knew, they had seized the fact that for the complete rounding out of Canadian national life, a8 well as for the establishing of the necessary contributions towards the economic stability of Canada and its provinces, an industry in mining sh01.dd be well and truly built in the hinterland of the central provinces. Failing the winning of mineral from the rocks, and timber from the forests, there would remain between the East and the West an enormous barrier of unproductive country which would not only be an incubus to the agricultural people in their struggle for economic liberty, but would effectively, and for all time, remain an un-populated void across which the aspirations of East and West would be unable to unite.

Jan 1, 1924

By Robin Phinney

Certain statements in this presentation may constitute "forward-looking" statements which involve known and unknown risks, uncertainties and other factors which may cause the actual results, pe1formance or achievements of the Corporation, or industry results, to be materially different from any future results, performance or achievements expressed or implied by such forward-looking statements. When used in this presentation, such statements use such words as "may", "would", "could", "will", "intend", "expect", "believe", "plan", "anticipate", "estimate" and other similar terminology. These statements reflect the Corporation's current expectations regarding future events and operating performance and speak only as of the date of this presentation. Forward-looking statements involve significant risks and uncertainties, should not be read as guarantees of future performance or results, and will not necessa1ily be accurate indications of whether or not such results will be achieved. A number of factors could cause actual results to differ materially from the results discussed in the forward looking statements including, but not limited to, the factors discussed in the Corporation's annual information form filed on March 9, 2011. Actual results could differ materially from those currently anticipated due to a number of factors and risks. These include, but are not limited to, the failure to obtain necessary regulatory approvals, including environmental approval, the failure to secure full project financing, the failure to implement the recommendations set out in the Technical Report, the failure to raise financing to implement the recommendations in the Technical Report, risks associated with the mining industry in general (e.g., operational risks in development, exploration and production; delays or changes in plans with respect to exploration or development projects or capital expenditures; the uncertainty of estimates and projections relating to production, reserves and resources, costs and expenses; and health, safety and environmental risks), decrease in potash prices and exchange rate fluctuations. Although the forward-looking statements contained in this presentation are based upon what management of the Corporation believes are reasonable assumptions, the Corporation cannot assure shareholders that actual results will be consistent with these fonvard-looking statements. These fon\?ard-looking statements are made as of the date of this presentation and are expressly qualified in their entirety by this cautionary statement. Subject to applicable securities laws, the Corporation assumes no obligation to update or revise them to reflect new events or circumstances. This presentation is a market update based on the Corporation's public disclosure and does not form a part of any offer of securities, or constitute a solicitation of any offer to purchase or subscribe for securities. Any purchase of securities in the company should be made solely on the basis of information contained in the Corporation's public record which is available on www.sedar.com .

May 1, 2013

By Douglas A. Karvonen

"Competition in the world potash market has increased significantly since the late 1970s. The failure of consumption to grow at expected levels has led to industry over-capacity, a situation which is likely to persist at least until 1990. Individual Saskatchewan producers and their offshore marketing company, Canpotex, have responded to this challenge by increasing mining efficiency, developing more cost-effective and reliable transportation systems and establishing innovative financing and market development programs tailored to customers' special needs. Investment in warehouse facilities to serve U.S. customers and exploration of opportunities for intermodal distribution through the Great Lakes and the Mississippi River system have maintained individual producers' position in the highly competitive domestic market.Export sales through Canpotex have been bolstered by utilization of CIDA funds, Exp ort Development Corporation financing guarantees and other innovative payment plans which enable heavily indebted developing countries to maintain the import levels which are necessary for their agricultural development.IntroductionPotash is the general term applied to various potassium salts both natural occurring and commercially derived. The most common of the commercial product s are potassium chloride, potassium sulphate and potassium magnesium sulphate. The potassium content of potash is measured in units of K20 equivalent. The common grades of potassium chloride produced for agriculture average at least 60 0/0 K20 compared with approximately 50% Kp for potassium sulphate and 22% for potassium magnesium sulphate."

Jan 1, 1985

By K. M. Sarkar

"In many plant trial s(1,2) it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described.For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. lt is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery.Recovery by Ion ExchangeMine water, in this study, is defined as the water coming from the underground mine, or mine pits, and the run-off water from stockpiles, mine shops, crushing plant , washdown areas, etc.In nature, uranium mainly occurs in two stages; reduced (tetravalent) and oxidized (hexavalent) . The oxidation of sulphides present in the orebody often causes the presence of S04- and acidity in mine water, and this acidic water readily dissolves U+6 part of the depo sit. The react ion between hexavalent uranium, which is dissolved in water as U02+ 2 cation and S04 producing uranyl sulph ate as,"

Jan 1, 1984

By E. Y. Carlson

"IN A SHORT PAPER it is impossible to do much more than to list the industrial minerals found in Saskatchewan and to give a brief description of the activity associated with each. I will not attempt to discuss the geology. It is sufficient to say that the settled part of the Province is covered by glacial drift which varies in thickness from a few feet to several hundreds of feet, and that this has hindered the search over much of the Province.CLAYA notable exception to this is the Cypress Hills area in the southwest corner which did not suffer any glacial action and where we find some of the large exposures of Cretaceous clays. In this area, the majority of the deposits are of stone-ware clays which are •an excellent raw material for such products as face brick and sewer pipe. Although the clay cannot be transported over any great distance it is used extensively in Alberta and Saskatchewan in the production of these products."

Jan 1, 1959

By L. Voisin, G. Damm

"In order to develop a new pyrometallurgical process for eliminating detrimental arsenic and antimony from the impurity-rich matte produced from copper concentrate, and for treating the occasionally generated speiss in nonferrous smelting processes, the phase relations in the Fe-Cu-S-As-Sb system saturated with carbon at 1473 K were investigated. The distribution of elements between the condensed phases at the miscibility gap, where three equilibrated phases of iron-rich alloy, copper-rich alloy, and matte coexist, were also studied. The investigation was carried out by performing a series of laboratory scale experiments in an electrical furnace at 1473 K, followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Inductively Couple Plasma (ICP), Atomic Absorption Spectroscopy (AAS) and Carbon Infrared Spectrometry (CIS) techniques.The results were compared with previous investigations for the Fe-Cu-S-As-C and Fe-Cu-S-Sb-C systems and discussed on the basis of the molar fraction distribution for both arsenic and antimony in the matte phase at five different matte grades. It is expected that by using this phase separation technique it might be feasible both, the cleaning of a complex copper matte and the elimination of arsenic and iron together with an acceptable amount of antimony into the iron-rich alloy phase, which can be discarded as a harmless and smaller deposit."

Jan 1, 2014

By F. R. Archibald

IN a recent paper on Roasting of Beattie Concentrate (1), the importance of controlling the temperature, and the sulphur dioxide concentration was pointed out. It is the purpose of the present paper to present further information by which the most satisfactory conditions for roasting are more specifically defined. Incidentally, a method of illustration is developed for representing roasting curves on a three-dimensional diagram. The primary purpose of this investigation, as in the case of the earlier work, was the search for information that would be of practical value in improving plant operation and gold recovery. For this reason, emphasis is laid on the regulation of essential variables and on definition of their optimum values and limits for maximum gold recovery in the subsequent cyanidation process. Good roasting is considered at least as much an art as it is a science, and, in this light, theoretical consideration of the nature and sequence of the chemical reactions involved is of secondary importance. The presentation which follows includes a series of graphical illustrations, an interpretation of the graphs, some theoretical considerations, and a description of laboratory technique.

Jan 1, 1940

By D. J. W. Piper, T. Hundert, G. Pe-Piper

"Abstract - Potentially commercial deposits of kaolin are found in the fluvial Lower Cretaceous Chaswood Formation, the sedimentologically proximal equivalent of deltaic sediments of the offshore Scotian basin. The geological setting of the kaolin deposits has been interpreted from high-resolution seismic-reflection profiles and boreholes, and mineralogical studies on one reference borehole. The kaolin is a product of early diagenesis involving meteoric water below the water table. The distribution of kaolin is controlled by the presence of intraformational unconformities that were sites of ground water recharge, and are marked by the development of oxisols above the water table. Such diagenesis was facilitated by interbedded, loosely consolidated, permeable sandstone. The highest-grade kaolin deposits are found in areas close to river belts, where overbank muds were not sufficiently drained to develop paleosols, but where later uplift created intraformational unconformities. In the sandstone, meteoric water flow altered feldspars to kaolin, thus yielding commercial silica sand deposits. It also altered ilmenite to rutile, which is concentrated as secondary placers in modern rivers that have eroded the Chaswood Formation and tills derived therefrom. Sommaire - Des dépôts de kaolin potentiellement économiques ont été notés dans la Formation de Chaswood d'’âge Crétacé Inférieur, laquelle constitue un équivalent latéral en milieu fluviatile aux sédiments deltaïques du bassin de Scotian. Le contexte géologique de ces dépôts de kaolin a été interprété a partir de profils de seismique-réflection à haute résolution, de sondages, et d’études minéralogiques sur un sondage de référence. Ce kaolin est un produit diagénétique précoce formé par de l’eau météorique sous le niveau de la nappe phréatique. La distribution du kaolin est contrôlée par la présence de zones de recharge associées à des discordances intraformationelles marquées par le développement d’oxisols au-dessus du niveau de la nappe phréatique. La présence d’interlits de grès perméables faiblement consolidés a contribué à l’efficacité de ce processus diagénétique. Les dépôts de kaolin les plus riches se trouvent en périphérie des rivières, là ou les boues de la plaine d’inondation n’étaient pas suffisamment bien drainées pour permettre le développement de paléosols, mais où des mouvements verticaux subséquents ont crée des discordances intraformationelles. La circulation d’eau météorique dans les grès a entraîné l’altération des feldspaths en kaolin, générant ainsi des dépôts économiques de sable de silice. Elle a aussi causé l’altération de l’ilménite en rutile, que l’on trouve dans des placers secondaires situés dans des rivières contemporaines qui ont érodé la Formation de Chaswood et les tills qui en sont dérivés."

Jan 1, 2006

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014