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By Ashley Tews

In 2005, we automated a forklift-based Hot Metal Carrier to be capable of typical metal transfer operations around a smelter. The project was highly successful and the vehicle has demonstrated hundreds of hours of live autonomous operations to thousands of people from industry and the public. As a result of the exposure and success of the project, we have expanded its focus to demonstrate how various technology components can be utilised to gain benefits in other areas of industrial operations. These include asset tracking, vehicle usage analysis, pedestrian detection and infrastructure profiling. Each of these components was derived from the core autonomous vehicle technology suite and has shown a high potential for improving safety and efficiency of vehicle-related operations, and improved diagnostic processes for measuring deformations of bakes and furnaces. The autonomous vehicle project and its extended technologies are described in this paper.

Aug 1, 2013

By R. O. Grieve

"IntroductionCALEY (1945) and Evans (1950) pointed out that certain instances of convergence between Devonian and Silurian horizons, frequently evident in wells drilled for oil and gas in Ontario, appear to be related to local thinning of salt beds in the Salina formation and they suggested that leaching of the salt beds may have occurred. Exploratory drilling by Imperial Oil Limited since 1945 has brought to light several examples of structures similar to those discussed by Caley and Evans. The writer has had the opportunity to examine cuttings and data from wells which penetrated these structures and the attempt to interpret them in the light of the theory of leaching and subsidence proposed by Landes ( 1945a) to explain the marked brecciation and deformation of Upper Silurian and Middle Devonian sediments which crop out in the Mackinac Straits region of northern Michigan has led to the observations presented in this paper."

Jan 1, 1955

By Trent Hamilton

Cameco ? McArthur River Operation is a high-grade uranium mine in northern Saskatchewan. Average grades mined are nearly 20%, more than 20 times higher than other operating uranium mines in the world. The significant risks involved with mining this grade has been effectively mitigated using innovative and unique controls, implemented from development and production mining through to ore processing. The types and sources of radiation are presented and protection measures are discussed. McArthur River?s strong radiation culture is evidenced by continually low radiation exposures while transitioning to new mining zones.

Aug 1, 2010

By M. Sakata, H. Hata, K. Haiki

"Most of the secondary ZnO contains fluorine (F) in large quantities. Serious troubles at the zinc electrowinning are occurred by the cathode corrosion caused by F, therefore we developed iron compounds as F-adsorbents used in zinc sulfate solution. The iron compounds can be reused repeatedly as F-adsorbents because they can adsorb/desorb F alternatively depending on the pH. Moreover, if the adsorptive capacity decreases, we can dissolve and re-synthesize them easily. In this paper, results of the experimental process which consists of five steps (leaching, F removal, Cl removal, purification and electrowinning) to produce high purity electrolytic zinc from the secondary ZnO are reported. INTRODUCTIONThe recycle material for zinc, secondary ZnO, contains large amounts of fluorine (F) and chlorine (Cl) which are halogen elements, compared with calcine obtained by roasting of zinc sulfide concentrate. The halogen elements cause adverse effects in the zinc electrowinning process and particularly F causes corrosion of aluminum cathode plates and eventually sticking of electrodeposited zinc and therefore, F concentration in the electrolyte is controlled to less than approximately 20 mg/L. There are several methods to remove F from secondary ZnO, such as leaching with Na2CO3 or NaOH solution [1-2], vaporizing in a rotary kiln by roasting at 1000 to 1200 degrees C [3-4]. However, up to the moment, there has been no effective method for the removal of F from zinc electrolyte and it has been a big obstacle in treatment of secondary ZnO in electrowining of zinc.The authors, therefore, developed an iron compound used as an adsorbent of F in the zinc sulfate solution [5-8]. This iron compound is Akaganeite that has a crystalline structure of ß-FeOOH. Akaganeite is synthesized by neutralization of FeCl3 solution containing a small amount of SO4 2- with Na2CO3. When this iron compound is immersed into weak acidified zinc sulfate solution, F in the solution is adsorbed. F adsorbed in the iron compound is removed by immersing in weak alkaline solution and the iron compound can be reused as F adsorbent."

Jan 1, 2012

By F. Bélanger, P. Fournier

"The Detour Lake Mine is located in northeastern, Ontario, approximately 300 kilometres northeast of Timmins and 185 kilometres by road northeast of Cochrane. The mill processes a free milling gold ore using both gravity circuit and leaching with a state-of-the-art carbon-in-pulp circuit. The grinding circuit is a conventional SABC circuit with a tonnage of 60,000 mtpd at 95 microns with the addition of pre-crushing upstream of the SAG mill. This paper will highlight the impact of a pre-detox thickener on the cyanide consumption in a gold leach/CIP circuit. While the pre-detox thickener was built with the intention to reduce the cyanide consumption, the opposite effect was observed when the thickener was put temporarily offline. It will show how the re-circulation of a dilute stream of cyanide into the grinding circuit, increases the overall slurry temperature and by the same effect, increases the dissolved copper concentration in the leaching circuit which subsequently increases the cyanide consumption.INTRODUCTION The processing plant is using a conventional gravity, cyanidation and carbon-in-pulp processing facility currently operating at approximately 60,000 mtpd. The comminution process is based on two parallel SABC lines, each fed from an individual reclaim tunnel. Cyclone overflow from the two ball mill circuits is directed to the pre-leach thickener. The thickener underflow is distributed to two (4) parallel leach trains of 5 tanks each, each leach train providing 29 hours of leaching retention time. After leaching, the gold in solution is recovered in a carrousel CIP circuit consisting of two (2) parallel leach trains. Tails from each CIP circuit are combined and sent to a pre-detox thickener to recover as much cyanide solution as is economically practical before being diluted and fed to a cyanide destruction system. The detoxified tailings are sent to the Tailing Management Area (TMA) for settling and retention. The excess water from the TMA is reclaimed and recycled back to the processing plant. The pre-detox thickener is designed to thicken the leach tails slurry to 64% solids with the overflow being recycled to the grinding circuit. It is estimated that the pre-detox thickener will recover 60% of the cyanide in the CIP discharge solution. It is also designed to reduce the SO2 consumption by diluting the thickener U/F to 50% solid using the tailing pond reclaim water which has very little cyanide content."

Jan 1, 2019

By Lawrence Devon Smith

"The Management and Economics Society has undertaken a survey of industry practice in the evaluation of mineral projects. The survey addresses a number of issues relating to evaluation techniques, discounted cash flow methodology, and risk. Completed during the spring and summer of2005, the results provide a record of opinion at an active and vital time in our industry.The 2005 survey questionnaire was distributed by e-mail to groups and organizations around the world. There were 22 respondents out of several hundred questionnaires distributed (we gather this small proportion of respondents is typical for such surveys). The responses, although a small number, show a consistency that suggests that the survey has captured the views of the industry. The results of the survey are summarized below in series of tables and graphs.The reader is cautioned that the results are a snapshot of industry practice at a point in time as represented by a small sampling of the industry's practitioners. These results should be viewed as indicative values."

Jan 1, 2003

By John Loop, W. A. Gibbins, Donald D. Hogarth

"Introduction Background The Frobisher voyages of 1577 and 1578 were organized by the Cathay Company for the express purpose of finding and mining gold ore. Since publication of the Baffm expedition of Charles Francis Hallill, the location of Kodlunarn or Countess of Warwick Island, the headquarters of Frobisher's third (1578) voyage, and focal point of the largest Arctic voyage of all time, has been known to the world. Through Hall we also know the location of the Countess of Warwick Mine on Kodlunarn Island. However, the exact locations of the other mines are not known. Of the ""ore"" we know little. Pieces of the original ""black stone"", once as large as ""a half-penny loaf' have now disappeared altogether. Specimens collected at random from the repository of shipments in England and from loose rock on Kodlunarn Island were termed, respectively, ""hornblende pyroxenite"" and ""amphibolite"" and from a locale about 200 yards from Kodlunarn as (hornblende) ""pyroxenite""121. However, it is uncertain whether these specimens are representative of Kodlunarn or of the other mines, although Blackadar131 notes that, in the northern trench of Kodlunarn, biotite gneiss contains lenses and bands of amphibolite. The ""gold"" itself is even less well defined. It has long been accepted that gold was virtually absent in Frobisher's ore. The ""gold"" has been termed pyrite, biotite and both biotite and pyrite together. Even t h e word "" marquesset"" , which appears and reappears in contemporary descriptions, is nebulous and is defined as ""a stone participating in the nature of some metal, yet in so small quantity, that the metal cannot be melted from it"" (0.E.D., definition of 1616)."

Jan 1, 1999

By R. Chen, K. Xia

In deep mining activities, blasting induced compressive stress wave would be reflected as tensile wave at a free surface around the openings, which would facilitate the tensile failure of the deep rock since it is much weaker in tension than in compression. It is thus critical to understand the dynamic tensile failure of rocks subjected to static tension for deep rock engineering applications. A modified split Hopkinson pressure bar (SHPB) system is adopted to load Brazilian disc (BD) samples statically, and then exert dynamic load to the sample through stress wave generated by impact. The pulse shaper technique is used to generate a slowly rising stress wave and thus to facilitate the stress equilibrium of samples during each test. Five groups of Laurentian granite (with tensile strength of 12.8 MPa) BD samples under the pretension stress of 0 MPa, 2 MPa, 4 MPa, 8 MPa, and 10 MPa are tested under different loading rates. The result shows that the dynamic tensile strength of the rock decreases with the increase of pre-tension stress, which is easy to understand because pre-tension stress weakens the rock sample. It is also observed that under the same pre-tension stress, the dynamic tensile strength increases with the loading rate, revealing the so-called rate dependency that is common for engineering materials. Furthermore, it is found that the loading rate sensitivity of the rock increases with the increase of pre-tension stress. A qualitative explanation for this phenomenon is that more microcracks are generated and activated under higher pretension stress, resulting in a more viscous material. Based on the results, an empirical equation is proposed to fit the data and explain the dynamic tensile behaviour of rock under pre-tension stress. A physical model is used to simulate the dependency of the dynamic tensile strength of rock on the pre-tension stress and the loading rate, which is shown to be in good agreement with the experimental results.

Jan 1, 2015

By Dan Nower

Machinery Health Monitoring of Shovels MINExpo 2012: Caterpillar announced the largest Electric Rope Shovel, capable of 120 short tons The next day, JoyGlobal (P&H Mining) ?one-upped? CAT, introduced a shovel capable of 135 short tons Large Concern: breakdown (unplanned outages) of one machine will be more disruptive to production

May 1, 2013

By K. W. Fritzsche

The prosperity of any nation depends, to a large extent, on its natural resources such as oil, coal, 'metal, timber, waterpower, and fertile soil. Each one of these resources forms the basis of a huge industry. The mining and smelting industry ranks among the first since it paves the way for a number of other industries. The mines and smelters provide a market for electric power, coal, timber, and agricultural products: other industries in turn provide a market for metals and non-metals. The real pioneering, however, is done by the prospector who goes into the wilderness to search for the ores from which the metals are to be extracted for the use of men. Prospecting is an interesting and fascinating occupation. There are many difficulties and hardships in the way but the lure of gold and the vision of finding an outcrop that may develop into a large bank account, within a reasonably short time, will urge the prospector forward. Thus, on the outskirts of this northern hemisphere hundreds of prospectors are searching and toiling and of whom nothing is known or heard until they reach civilization and announce a new discovery. Then a mad rush takes place and everybody who can afford to go will take a gamblers chance and plant stakes in the neighbourhood of the new discovery, or wherever an outcrop of mineralized rock can be found, with the hope of winning a fortune.

Jan 1, 1925

By V. Schwinn, P. Fluess, N. Cauderlier, J. Bauer

From a strategic and economic point of view, the development of fine grain high strength steels for long distance pipelines is intensified world wide to satisfy the demand for natural gas in the future.The project related property profiles based on strength, toughness, crack arrest and sometimes resistance against HIC at defined design temperatures require an effective structural refinement using advanced steelmaking and processing in the rolling mill. The microstructure of modern line pipe steels ranges from ferritic pearlitic to ferritic-bainitic and structures where bainite is the dominant component, possibly upgraded by secondary phases. This paper illustrates microstructures and properties of recent orders on line pipe steels both for onshore and offshore application using different processing routes in the plate mill. Examples will be given for SAWL 485 offshore grades, X65 HIC and X70 HIC onshore grades, respectively. Finally, production results of a recent X80 order will be presented.

Jan 1, 2005

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By F. Habashi

"While bioleaching of pyrite concentrates has been successfully used in industry to liberate gold from the sulphide matrix for subsequent cyanidation, the same technology cannot be recommended for leaching chalcopyrite concentrates for copper recovery. It will be shown to be uneconomical and cannot compete with pressure leaching technology. Data on the pilot plants that were constructed for this purpose and were shut down will be given.INTRODUCTIONBacterial leaching has been successfully applied for heap leaching of low-grade copper ores (Habashi, 1978, 1999). One of the major operations is that at Bingham in Utah (Figure 1). The leach solution collected at the bottom of the heap is extracted by organic solvents and the strip solution is electrolyzed to get high purity copper. The process was extended to treat auriferous pyrite concentrates to liberate gold and render it amenable to cyanidation by a process known as BIOX (Marsden & House, 2006; Lunt & Briggs, 2005).BIOX plants currently or recently in operation are the following:??Ashanti Goldfields Company, Ghana. Designed with an initial capacity of treating 720 tonnes of concentrate per day, the Sansu plant has since been expanded and currently has four modules processing 960 tonnes per day in all. It is by far the largest biooxidation plant in the world. The capital cost of the plant totalled US $25 million (1994 terms) and the operating cost is currently US $17/tonne milled.??Fairview, South Africa. The plant at the Fairview mine in Barberton, which was the initial pilot plant, has been fully operational since 1986. It was originally designed to treat 10 tonnes/day of concentrate but with the success of the project this has been increased to 55 tonnes per day. With the purchase of Fairview by Avgold’s Eastern Transvaal Consolidated, Avgold concluded a licensing agreement with Gold Fields, formerly known as Gencor, entitling it to use the BIOX technology to treat itsconcentrate.??Saõ Bento, Brazil. A BIOX plant was recently in operation in Brazil at the Saõ Bento Mine where a pressure oxidation circuit is used to treat the refractory flotation concentrate. This plant has confirmed the viability of combining bio-oxidation with pressure oxidation as a cost-effective method ofincreasing capacity at an existing oxidation plant.??Wiluna, Australia. The plant at Wiluna Gold Mine, Western Australia, was commissioned in 1993. Although originally designed to treat 115 tonnes per day of concentrate this has subsequently been increased to 158.??Other plants at Tamboraque in Peru, Harbour Lights and at Youanami in Australia have been commissioned recently."

Jan 1, 2012

By Ltd Changsha Research Institute of Mining and Metallurgy Co., Shi Yunliang, Luo Yunbo, Chen Jun, Liu Miaohua, Xiao Jinxiong, Long Yan

"A refractory lead-zinc oxide ore located in Yunnan has hundreds of tons of metal reserves, which is hard to be recovered effectively by conventional oxide ore beneficiation methods. In this study, by sulfidation roasting of raw-ore, sulfide deposit is formed on the surface of the lead-zinc oxide ore, and then the roasted ore is processed with bulk flotation. The test results indicate that a bulk concentrate with grade of 7.85% lead and 34.24% zinc, recovery of 79.13% lead and 79.04% zinc, respectively, can be obtained by using conventional sulfide ore flotation method.The sulfidation process shows that pyrite in the raw ore releases S firstly, then S reacts with PbO and ZnO to transform into PbS and ZnS. When the mole ratio of sulphur:zinc is 0.59, the surface of smithsonite is covered with a layer of zinc sulfide. When the mole ratio of sulfu:zinc rate is 1.47, entire simthsonite particle is transformed into zinc sulphide. Thus the transformed particles can be recovered by flotation without complete sulfidation.INTRODUCTIONWith the increasing demand for zinc and decreasing of zinc resources, people pay more attention on development and utilization of zinc oxide ore. However, zinc oxide ore has wide range mineral kinds, complex mineral composition, disseminated fine-grained particle size, and high content soluble salt, so current study results about the zinc oxide ore with conventional flotation are not satisfactory. So far, process dealing with zinc oxide ore includes: sulfuration (Na2S)-flotation, direct flotation with fatty acids collectors, metallurgical methods, in which sulfuration flotation is the most widely used method. The basic principle of sulfuration flotation method is firstly roasting oxide ore with vulcanizing agent, and then recovering the sulfurated oxide ore with flotation, which is similar with recovering nature sulfide ore by using conventional collectors such as amines and xanthate."

Jan 1, 2016

By J. -P. Tshibangu, M. Ramos da Silva, F. Descamps, C. Schroeder, J. -C. Verbrugge

"The mechanical behaviour of rock materials is largely influenced by the stress state and pore pressure; this needs to be considered in many applications, such as petroleum engineering, tunnelling or stability of underground excavations.Conventional triaxial tests (d2 = d 3) are generally used to assess the influence of confining and pore pressure. In this work, those tests are performed on a porous rock named Sorcy limestone, along with more advanced stress paths like triaxial extension (d 2 = d 1) and purely deviatoric tests with independent pore pressure control. Those tests are combined to a true triaxial study on the dry rock in order to investigate the effect of true triaxial stresses and, hence, build three-dimensional limiting envelopes accounting for the influence of pore pressure.Three-dimensional limiting envelopes of dry Sorcy limestone are built in meridian and octahedral planes. The shape of the octahedral sections changes with the mean stress from triangular to hexagonal and then quasi circular. At even higher mean stresses, the evolution continues towards a triangle with apexes oriented in the direction of triaxial extension stress states. In meridian sections, the deviatoric stress first increases with the mean stress. The transition between this deviatoric mechanism and the cap surface occurs at different mean pressures depending on the Lode angle.Terzaghi’s effective stress is found to govern the yield and plastic behaviour of saturated Sorcy limestone. Triaxial tests show that the limiting envelope does not depend on the loading path (conventional compression and purely deviatoric stress paths). In triaxial extension, the brittle-ductile transition is observed for a higher mean pressure than in triaxial compression, as previously found for true triaxial tests on the dry rock.Finally, it is shown that upon appropriate normalisation, the dry and saturated yield envelopes come very close one to each other. This suggests that only the size of the yield envelope changes between dry and saturated state (pore pressure = 5 MPa); its shape does not seem to evolve."

Jan 1, 2015

By W. J. Kempson

In recent years, substantial progress has been made with respect to the definition and control of the primary energy requirements in underground mines. Little has, however been done to develop a more detailed understanding of how to limit the various pressure losses which are intrinsic to shaft systems. This is in spite of the fact that more than half of the pressures generated by the ventilation fans in deep level mines are dissipated as pressure losses within the shaft system. This paper presents research which has been completed to optimise the pressure losses which occur in shaft systems as a result of the ventilation air flowing through them. In this regard, the response of various shafts to the ventilation air flowing through them was measured. These results were evaluated against the current theory for the calculation of shaft pressure losses. Finally the results of the measurements and calculations were used to calibrate a Computational Fluid Dynamics model of the shaft systems. This model was then iterated to allow meaningful conclusions as to the specific make up of the shaft equipment which contributes the most to pressure losses in shaft The results of the above analysis demonstrated that the current theory used for the evaluation of these pressure losses is deficient. The paper discusses these conclusions and the specific ramifications of the analysis. Finally, the understandings gained with regards to the above research are applied to the design and layout of equipment in mine shafts. In this regard, the shape and orientation of the shaft steelwork is evaluated and it specific interaction with the piping and conveyance is evaluated. Coming out of this evaluation are specific recommendations for the design of future shaft systems. These recommendations are based on the above models and offer specific savings on the lifetime operating costs of shaft systems.

Aug 1, 2013

By A. Ashrafi

The electrochemical deposition of polypyrrole coating on different pretreated aluminum-alloy 7075 substrates was carried out using cyclic voltammetry, The pretreatment of specimens consisted of mechanical polishing and/or electrochemical etching, In the latter case, an aqueous solution of phosphoric acid and ethanol was used, The electrodeposition solution was 0,25 M pyrrole and 0,1 M oxalic acid in double-distilled water, The cyclic voltammetry scan rate used was 700mv/s, Morphology of the coatings was examined using scanning electron microscope (SEM), Using the Tafel experiment, corrosion resistance of the coated substrates was investigated in 0.1 M NaC1 solutions, Results obtained revealed that electropolymerization of polypyrrole on 7075 aluminum alloy would increase the resistance against corrosion in 0,1M NaC1 solution, Also it was observed that, compared with mechanical polishing, electroetching pretreatment would be more effective.

Jan 1, 2005

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By Oberlando Gonzalez, Claudia Serna, Andrea Alzate, Esperanza López, Maria Holuszko

This paper presents a systematic approach on gold recovery from electronic waste (e-waste) using ammonium persulfate. This process was developed as a response to the lack of hydrometallurgical systems capable of separating gold from its metallic substrate without material grinding, with minimum formation of pollutants, and achieving a lower reaction time. Computer memory boards, electronic processors and electronic pins and contacts were analyzed to determinate base metals (Ni, Fe, Cu) and gold (Au) using microwave plasma atomic emission spectroscopy (MP-AES). An aqueous commercial grade ammonium persulfate with oxygen and pressure was used to produce the persulfate anion (S2O82-) and the oxidative sulfate ion (SO42-), which partially oxidized and leached the base metals breaking the Au-Ni-Fe-Cu bonds and allowing gold to be recovered in its original non-leaching state. The influence of the oxidative parameters was evaluated using full factorial (FF) and central composite designs (CCD) with response surface methodology (RSM) and first and second order models were developed. Using RSM allowed to obtain a faster recovery of gold, minimizing the agent consumption. The findings presented suggest that optimized quantities of ammonium persulfate, oxygen, pressure, temperature and liquid solid ratio could be used for selective oxidization of the base metals and to extract more than 96% of gold from e-waste.

Jan 1, 2017