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By Sabine Noelte, Mikko Petteri Rantamäki, Christopher Robben, Anssi Takala, Karl-Erik Rånman

"Sensor-based ore sorting is on its way to establish as a standard option for physical separation. The increasing number of installations in coal, iron ore, industrial minerals and hard-rock metal mining segments underlines the technological and financial potential that is beginning to be untapped. The Ma’aden Phosphate installation with 1.650 t/h sensor-based ore sorter feed sets a new benchmark for the possible capacity of stationary installations. Besides stationary installations, including multiple sorters parallel in different size ranges and multiple stages, containerised semi-mobile plants are applied. These offer two advantages, first being the reduction of transport costs when applied close to the mining face. The second is that semi-mobile systems enable processing of tens of thousands of tonnes of ore in a piloting phase with an approximate duration of 0.5 to six months, verifying the results laboratory mini-bulk tests on 5–10 tonnes of sample. This is especially important for low-grade metal ores because of the inherent Fundamental Sampling Error, as well as the Grouping and Segregation Error. The paper elaborates the results achieved within the I2MINE project, treating polymetallic ore at the Boliden Concentrator in Sweden.INTRODUCTIONSensor-based ore sorting (SBS) is becoming a standard option for physical separation, applied in all segments of mineral production. The Umm Wu’al project sets the bar for stationary SBS installations with 1,650 t/h feed (TOMRA, 2015). TOMRA Sorting Solutions has finalised an agreement in cooperation with Outotec to supply Outotec-branded sorting solutions for the mining and metallurgical industry (TOMRA, 2014). Especially for low-grade hard rock metal ores, an interdisciplinary approach is necessary applying experts for all aspects of mineral production. Due to the impact on the whole process stream, it is important on the end user side to have high level managerial support and involve all disciplines to ensure that all stake holders are involved in the analysis."

Jan 1, 2016

By Louise Corriveau

A Targeted Geoscience Initiative transect in the eastern Grenville Province reveals an extensive VHMS-style cupriferous hydrothermal system among rhyolitic pyroclastic rocks of the Wakeham Group at La Romaine, Québec. The volcanic rocks outcrop sporadically along a < 10 km-wide by about 100 km-long belt correlated with the south-eastern extension of the Wakeham Group. This belt occurs among voluminous, magnetite-bearing, granitic gneiss. At Lake Musquaro, 1.51 Ga metarhyolitic to dacitic lapillistones and flows, locally with aluminous nodules and veins, are intruded by 1.49 Ga feldspar porphyries. This volcanic package was deposited on typical Wakeham Group arenite (< 1.52 Ga) interbedded with nodular, muscovite- and fibrolite-bearing gneiss, and minor marble hosting finely layered garnetiferous hornblendite, garnetite and magnetite-bearing coticule. The latter are interpreted as meta-exhalite and with the associated albitite (sodic alteration), aluminous veins (hydrothermal leaching) and magnetite-rich granitoids, they are key elements in the search for concealed mineral deposits in this area. At La Romaine, to the south, 1.5 Ga lapillistones outcrop structurally above metasediments and below a composite amphibolite unit of uncertain origin (lava or sills) with magnetite-rich (BIF?) units. An extensive zone of aluminous gneiss, with lapilli textures, provide evidences for severe hydrothermal leaching of the volcanic rocks prior to metamorphism. An adjacent siliceous vein-textured unit likely represent a zone of intense silicification (74 wt.% SiO2), while aluminous, hematite to magnetite-bearing veins in adjacent felsic gneiss (tuff?) preserve evidences for the sequence of alteration events. Despite granulite-facies metamorphism, the main characteristics of the amphibolite unit persist along the entire belt. This competent unit likely served as a cap rock; the garnetite, diopsidite and hornblendite it hosts provide effective guides to the sites of fluid discharge and mineralization. A number of Cu showings, modest in size, were discovered in this unit. Their systematic occurrence, in a structural-stratigraphic sense, indicates that this setting is attractive for mineral exploration despite high-grade metamorphism and deformation. Late-stage veins laden with fluorite crosscut these alteration zones, and are themselves metamorphosed, indicating that hydrothermal activity was polyphased. SHRIMP U-Pb ages obtained on detrital zircons (1 arenite) and on igneous zircons (5 volcanic rocks, 1 porphyry and 6 granitoids), pervasive arc-type geochemical signatures and presence of in situ rafts of barium-rich garnetite in the granitoids indicate that sedimentation and volcanism occurred between 1.52 and 1.49 Ga coevally with hydrothermal activity and emplacement of a sub-volcanic 1.5 Ga granitic batholith with early, 1.53 Ga tonalite intrusion. Such a geological context can sustain large-scale hydrothermal cells and development of VHMS, Cu-Fe oxides or SEDEX deposits.

May 1, 2003

By I. Stanoev, V. S. Stoilov, I. Gradinarov, E. D. Visariev, I. A. Bonchev, Aurubis Bulgaria

"Aurubis is the leading integrated copper group and the world’s largest copper recycler. In Copper smelter Aurubis Bulgaria (Pirdop), the residual copper in the slags from Flash furnace and Converters is recovered by flotation. The slag processing comprises: pit cooling, crushing, two stages grinding (autogenous and ball) and flotation. The copper concentrate is thickened and then is filtrated by vacuum disk filter. The thickener overflow is sent to settler for additional clarification. A resent throughput increase resulted in higher solid content in the thickener overflow due to insufficient thickener area. Different scenarios to overcome the issue were evaluated (new thickener, reagents and reconstruction). An increase of the thickening area by installation of lamella modules was chosen as the most promising option. Three lamella modules (1 m3 each) were installed in conventional thickener for the test. Number of sampling campaigns was done to evaluate the effect on solid content in overflow. Parameters of the dewatering cycle were collected during sampling campaign. The products grain size distribution was defined - thickener feed, thickener overflow with and without lamella. The thickener overflow with lamella modules has 2.12 g/L less solid content. The decrease was 71.8%. According to the tests results, the whole conventional thickener was reconstructed with lamella modules. The thickener area was increased by more than 400 m2.INTRODUCTIONIn Copper smelter Aurubis Bulgaria, the copper in slag from the Flash furnace and the Converters is recovered by flotation. The scheme of slag processing is crushing, two stage grinding (autogenous and ball) and flotation. Till 2010 the grinding cycle in the plant was in two stages: the first stage was AG Mill 70×23 working with a classifier and the second stage was ball mill 3.6/5.5 working with a hydrocyclone. In 2010 a new AG Mill 65×78 with hydrocyclone was put in operation in order to increase throughput of the plant. The second stage of the grinding cycle was not changed."

Jan 1, 2016

By Peter Godbehere, Christian Desroches, Viken Baboudjian

"Noranda Copper Smelting and Refining is a unit of Noranda Metallurgy Inc., comprising the Home smelter in Rouyn-Noranda, Quebec and the C.C.R. Refinery in Montreal East. The Home smelter provides custom smelting services for a wide variety of copper and precious metal bearing concentrates and recyclable materials, producing over 200 000 tonnes of anodes and 450 000 tonnes of sulphuric acid annually. The C.C.R. Refinery has an annual production of 360 000 tonnes of copper cathode, and is a major refiner of precious metals.Over the past twenty years, Noranda Copper has developed innovative processes and operating techniques to treat the ever increasing complexity of primary feed materials, while improving the quality of its final products, working conditions and reducing environmental emissions.This paper presents an overview of the operating practices of Noranda Copper with particular emphasis on the impact of impurities in the smelting and refining processes.IntroductionThe treatment of custom materials has been practiced by Noranda Copper since commencement of operations at the Home smelter in 1927 and the CCR refinery in 1931. Copper concentrates from a wide variety of regional, North American and overseas producers account for the bulk of the 800 000 tonnes treated annually, although recyclable and secondaries have increased in importance as feed sources in the past two decades. The geographical disadvantage of the Horne smelter compared with most custom smelters located on tidewater has provided an important incentive for Noranda Copper to develop the necessary technology and operating practices at its smelter and refinery to treat high value complex concentrates and other feeds containing significant concentrations of bismuth, antimony, arsenic, lead, tellurium, mercury, etc."

Jan 1, 1995

By W. B. Morrey

"In recent years, the major effort in detonator development has been concentrated on ""non-electric"" systems. Existing types all involve some form of explosive reaction to transfer ignition energy from outside the borehole to the pyrotechnic delay element contained within the detonator. These may be based on low-energy detonating cords having grained or plasticized explosive cores, shock tube energy transmission principals and explosive gas ignition systems. Each has properties of internal and external effects not present in electric conductors.The MAGNADET System introduces transformer coupling into electric blasting circuits. Safety features with respect to current leakage, stray currents of AC or DC source, electrostatic energy and radio-frequency radiation are comparable to ""non-electric"" systems, with advantages in simplicity, speed of hook-up and range of application.The transformer device used is a small ferrite ring or toroid which is an integral part of each specialized detonator. The detonator legwires form the secondary side of the transformer winding. The primary side is a single wire loop common to all units within the circuit. Power is supplied from a frequency-tuned portable exploder with unique circuit-sensing features.The MAGNADET System is expected to have particular application to shaft sinking, raising and tunnelling where the protective features as well as speed and efficiency are critical factors. Applications of the &apos;MAGNA&apos; booster in quarries, open pits and longhole deck charges offer control over vibration problems and elimination of surface noise.IntroductionFor many years, electric detonators and electric blasting systems dominated surface and underground applications where controlled delay times were required. Control over the instant of detonation by blasting machines or power-line switches is the major safety feature.Electrical energy exists in many forms. It may originate from many sources. Electrical energy can be difficult to contain. It may enter or escape through a variety of conductive paths. It may fluctuate, concentrate or dissipate to pose a most elusive potential hazard."

Jan 1, 1982

By Feng Tianran, Lu Shijie, Shen Zhengchang, Han Zhibin, Tan Ming

"As a kind of non-metallic material, high-purify quartz sand has been widely used in many fields. Flotation is a popular way to process quartz sand. But it is in difficult position for flotation to get high-purify quartz product due to large amount of coarse particles contained in the feed. In this paper, a design principle of special flotation cell for high-purify quartz sand has been put forward base on ore property analysis and laboratory test, and the pilot scale special flotation cell has been developed to meet the requirement of the quartz sand flotation process. The special flotation cell for high-purify quartz sand is featured by middle positioned impeller, false bottom and draft tube, which could decrease the rising distance of mineralized bubble and strengthen the circulation capacity of the lower part of the flotation cell. Hydrodynamic study indicates that high air dispersion degree and strong lower slurry circulation could be produced by pilot scale special flotation cell, which is helpful to create a suitable hydrodynamic environment for quartz sand processing.INTRODUCTIONNatural quartz is a non-metallic mineral, which is widely used as raw material in multiple industry process (Shifu, 2006). High purity quartz, especially containing more than 99.9% silicon dioxide, is characterized by high temperature resistance, small thermal expansion coefficient, highly insulating and so on. The demand of high purity quartz has been rising along with social and economic development, now high purity quartz is widely used in the field of photovoltaic industry, electronic information, communications and aerospace industry.Quartz is a kind of main rocking-forming minerals in the nature. There are seven genetic types, such as natural crystal, quartz sandstone, quartzite, vein quartz, konilite, natural siliceous sand, granite quartz (Baolei, Shuilin, & Dianchao, 2012). The natural crystal is primarily used as raw material to refine high purity quartz, but it is not available for two reasons. On the one hand, the natural crystal is extremely expensive and poor in resources reserves, which can not satisfy the need of large-scale industrial production. On the other hand, the chemical component of natural crystal is instability, it may lead to low stable product performance in large industrial applications, and it is also difficult to achieve raw materials standardization. Therefore, there are a lot of studies to search for other technological methods to obtain high purity quartz from other genetic quartz types."

Jan 1, 2016

By Jan Rosenkranz, Anders Sand, Lisa Malm, Nils-Johan Bolin

Within flotation technology the general trend is towards very large cells. Scale-up is usually done by postulating geometrical similarity, which implies keeping the aspect ratio constant when increasing cell volume. Consequently, the design of flotation circuits typically involves several cells of identical geometry within a bank. Using a few standard sizes in a flotation plant simplifies design, manufacturing and maintenance of the cells, but does not necessarily guarantee optimal performance and selectivity of the flotation process. Geometry parameters for a given cell volume that influence flotation cell performance include cell height, which causes changes in the hydrostatic pressure and suspension hydrodynamics, and also influences the travel distance of particle-bubble agglomerates as well as the homogeneity of the mixing. Also the thickness of the froth layer depends on the aspect ratio of the cell. The objective of this work is to gain a better understanding of material distribution and properties within a flotation cell and, based on this information, elucidate how alterations of the cell geometry can influence separation efficiency. For this purpose systematic measurements and analyses of the spatial distribution of the different phases within a 160 m3 flotation cell have been carried out with a particular focus on an industrial, low-grade copper ore beneficiation process. The concepts for sampling at different vertical and lateral positions of the flotation cell are introduced. The results from the experimental work give an understanding of internal material distribution within flotation cells. Based on the measured phase distribution and concentrations as well as particle properties at various positions within the cell, the implications for an optimized scaling and design of individual flotation cells within a flotation circuit are discussed.

Jan 1, 2016

By Neil Schofield

"The estimation of recoverable ore reserves for feasibility in precious metal deposits such as Pine Creek must account not only f or the extreme variability of the ore grade but also for the complexity of the geology. Compatible models f or both must be adopted. Further, very selective mining demands reserve estimates be based on small selection units whose individual grades cannot be estimated reliably from the exploration drilling data.Multigaussian kriging is one method based on a multivariate normal model for estimating recoverable reserves under such conditions. In this paper, a non-mathematical description of the multigaussian model is presented together with its application to the Pine Creek Gold Deposit. The results, when compared to the first year of production, are encouraging for the model but not without surprises.Together, Part 1 and Part 2 of this study combine a detailed and geologically conditioned variogram analysis with an appropriate estimation method for a highly variable low-grade gold deposit. This and other studies of gold deposits familiar to the author show convincingly both that while the appropriate geostatistical skills and techniques are necessary to tackle the question of reserves, equally important but often discounted is the need for an appropriate and compatible geological model. IntroductionThe Pine Creek gold mineralization is associated with saddle reefs, and quartz and quartz- sulphide veining within the Enterprise Anti cline. The anticlinal structure is complex and, prior to mining, the mineralization was considered to be mainly strata controlled. Grades vary up to 160 grams in l .5rn core samples with coefficients of variation in excess of three.The estimation of the recoverable reserves for such a depo sit must account for both the geological complexity and the extreme variability of the gold grade.Part 1 of this work presented the geological model for the deposit and summary statistics 0 f the gold data. A detailed structural and variogram analysis considered both gold grades and the normal score (or gaussian transform) of these gold grades for different composite sizes."

Jan 1, 1988

By K. E. Waters, J. E. Nesset, F. Rosenblum, J. A. Finch, S. Moon

"Some materials when exposed to various conditions can exhibit a rise in temperature without requiring an external heat source. Generally referred to as pyrophoric or self-heating substances, they challenge the safety of materials handling, storage and transportation. Reliably assessing the self-heating potential of materials is thus essential. Over the years a number of test protocols have been developed. A widely accepted method is that recommended by the United Nations to certify the safety of shipping pyrophoric goods. Our test work on sulphide materials has shown that the U.N. test can give false negatives if the sample oxidation history is not considered. Depending on the degree of oxidation (“weathering”), the same sulphide material can exhibit self-heating ranging from safe to hazardous. For concentrates, oxidation can occur during storage and transport making the sample weathering history an important consideration in the test work. To make the U.N. test, and other single-stage self-heating procedures, more reliable in assessing self-heating potential when testing sulphide materials, it is suggested that a weathering step be incorporated in the test protocol. This test work for two sulphide samples, an ore and a concentrate, demonstrates the impact of incorporating a weathering stage in the test protocol. INTRODUCTIONSelf-heating occurs when exothermic reactions produce heat faster than can be dissipated to the surroundings. Numerous substances self-heat, ranging from wood chips and powdered milk to coal and sulphide minerals (Beever & Crowhurst, 1989; Hudak, 2002). Mixtures of sulphide minerals, most notably those containing the iron sulphide pyrrhotite (Fe(1-x)S), commonly encountered in the extraction of base metals (e.g., copper, zinc, lead, and nickel), are particularly prone to self-heating (Rosenblum, Nesset, & Spira, 2001; Payant, Rosenblum, Nesset, & Finch, 2012). In the mining and subsequent processing stages, the minerals are progressively liberated and finely ground, then separated, usually by flotation, with the resulting concentrates stored and transported to smelters for metal extraction. At most of these stages the sulphides are exposed to both moisture and oxygen, conditions that promote partial sulphide oxidation and the formation of elemental sulphur. Studies have shown that pyrrhotite, in particular, readily oxidizes to form elemental sulphur (Bernier & Li, 2003; Belzile, Chen, Cai, & Li, 2004; Somot & Finch, 2010). The elemental sulphur becomes fuel for further self-heating as the temperature of the mineral mixture increases above 100 oC (Rosenblum & Spira, 1995; Somot & Finch, 2010). It is believed the propensity of pyrrhotite to self-heat is a result of its iron-deficient, and hence somewhat unstable structure. It is worth noting that pure metal sulphides (with the exception of pyrrhotite) do not exhibit appreciable self-heating. A mixture of minerals sufficiently different in their electrochemical rest potential is required to initiate self-heating at ambient temperatures (Payant et al., 2012)."

Jan 1, 2016

By M. G. Rylatt, G. M. Popplewell

"Production from Canada's first diamond mine is planned for the last quarter of 1998. The climatic conditions and the variation in kimberlite types to be treated have lead to the development of a compact and flexible processing plant.High kimberlite moisture contents and winter temperatures below -40°C have dictated a process flowsheet with limited in-circuit storage to reduce materials handling difficulties. The latest developments in High Pressure Grinding Roll technology will be used to liberate the valuable diamond, reduce diamond breakage, and increase fines production to reduce the amount of material for down stream processing in the Heavy Medium Separation section.A varying heavy mineral concentrate yield has lead to the development of a final Recovery section that will incorporate Attrition Milling and Wet High Intensity Magnetic Separation for concentrate reduction. The latest developments in diamond X-ray sorting will be used to produce a final diamond concentrate for mechanical sizing, weighing and packing.Fine tailings thickening will utilise Deep Bed Compression type thickeners. This relatively new technology can produce;i) high underflow densities at low flocculant dosage rates, andii) clear overflowswith a smaller thickening area than conventional high-rate thickeners."

Jan 1, 1998

By Zhiqing Zhang, Changyun Chen, Qing Liu, Lin Lin, Zhihong Jia, Guangjie Huang, Lipeng Ding

The effect of interrupted quenching (IQ) treatments on natural aging and bake hardening response of Al-Mg-Si alloy was investigated by hardness measurements, tensile test, differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The results show that interrupted quenching at 100oC could effectively suppress natural aging and improve bake hardening response. The optimized interrupted quenching treatment is 100oC for 45min, which gives the alloy a relatively low T4 temper strength and higher bake hardening response. The formation of highly dense cluster(2) during the interrupted quenching could be the reason for suppressing the natural aging and accelerating the precipitation of ß? phase during the paint bake treatment. In addition, interrupted quenching at higher temperature (170oC) results in unfavorable properties in both T4 temper and paint bake treatment. The formation of large precipitates is responsible for these undesired effects.

Jan 1, 2015

Accurately modeling and predicting long term mill throughput is one of the challenges facing metallurgists, geologists and mine engineers in their quest to consistently deliver accurate life of mine business plans. Batu Hijau has systematically improved long and short term mill throughput predictions since feasibility and commissioning in 1999. This has been achieved through a combination of ongoing improvement to the geology ore hardness and grade characterisation model, drill and blast optimisation and, by application of these data to model mill throughput. Batu Hijau has demonstrated the ability to consistently estimate long term mill throughput within ±2% accuracy. Aside from reliably predicting expected production rates with the existing plant configuration, this predictive ability provides a solid foundation for identifying operating and design criteria for short term grinding circuit optimisation and future expansions. This paper discusses ongoing throughput prediction model development at Batu Hijau based on geo-metallurgical characterisation. Also discussed are tools used for day to day production performance management. This includes on line "Mine to Mill" variable monitoring to improve operations parameter ecision making and performance assessment.

Nov 1, 2011

By F. Wirfiyata

"Accurately modeling and predicting long term mill throughput is one of the challenges facing metallurgists, geologists and mine engineers in their quest to consistently deliver accurate life of mine business plans.Batu Hijau has systematically improved long and short term mill throughput predictions since feasibility and commissioning in 1999. This has been achieved through a combination of ongoing improvement to the geology ore hardness and grade characterisation model, drill and blast optimisation and, by application of these data to model mill throughput.Batu Hijau has demonstrated the ability to consistently estimate long term mill throughput within ±2% accuracy. Aside from reliably predicting expected production rates with the existing plant configuration, this predictive ability provides a solid foundation for identifying operating and design criteria for short term grinding circuit optimisation and future expansions.This paper discusses ongoing throughput prediction model development at Batu Hijau based on geo-metallurgical characterisation. Also discussed are tools used for day to day production performance management. This includes on line ""Mine to Mill"" variable monitoring to improve operations parameter decision making and performance assessment."

Jan 1, 2012

By Nessetech Consulting, L. A. Cisternas, E. D. Galvez, S. H. Kuan, L. H. Saw

"In Malaysia, there were two rare earths processing plants namely Asian Rare Earth (ARE) and the Malaysian Rare Earth Corporation Plant (MAREC) in Perak, which were operated until 1992 and were subsequently closed due to problems pertaining to disposal of large amount of radioactive waste. Recently, Lynas Advanced Materials Plant (LAMP) has become one of the largest rare earths processing plant in the world producing rare earth elements (REE) in Gebeng, Pahang. The primary raw material is lanthanide concentrate (LC) which is imported from Mount Weld mine in Australia and shipped to Malaysia. LC is produced from lanthanide ore after mining and mineral processing. The ore has a lower impact than Bayan Obo, Mountain Pass and adsorbed clay deposits, given the small footprint of the mine itself and the remoteness of the location. The type of ore being mined (rare earth phosphates: carbonatite, monazite) may have higher thorium content than bastnasite ore from the Chinese or American mines but still far below radiation concerns. This paper was written to review the processing flowsheet at the Lynas Advanced Materials Plant (LAMP), the environmental impact associated with the processing of the said ores and the sustainability of the operation.INTRODUCTIONRare earth minerals are one of a set of 17 minerals or chemical elements which consists of yttrium and scandium, as well as the 15 lanthanide elements (lanthanum, cerium, praseodymium, neodymium, promethium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). Despite their importance, rare earth minerals rarely exist in economically viable concentrations and they are usually difficult to extract. Rare-earth minerals create strong magnets when added to magnetic elements such as iron, and are useful for the production of electronics systems as well as electric cars. They are also used extensively in automotive catalytic converters, fluid cracking catalysts in petroleum refining, wind turbines, phosphors in colour televisions and flat panel screens, displays for mobile phones and laptops, rechargeable batteries, and various medical devices. The elements are typically split into two subgroups: the cerium sub-group of ‘‘Light’’ rare earth elements (LREEs) which includes La to Eu and the yttrium sub-group of ‘‘Heavy’’ rare earth elements (HREEs) which include the remaining lanthanide elements, Gd to Lu, including yttrium (Gupta and Krishnamurthy, 1992; Jordens et al., 2013; Trifonov, 1963). Scandium, however, when it is classified as a rare earth element, is not included in either the LREE or HREE classifications (Gupta and Krishnamurthy, 1992; Jordens et al, 2013). Half of the world’s 110 million tons of reserves exist in China while other sizable deposits are found in Russia, United States, Brazil, India, Australia, Canada, and Greenland. The countries known to be actively mining REE are China, Russia, India, Brazil and Malaysia (Hao et al., 2015). Among these countries, China has the largest REE production, accounting for more than 93% of global supply (Yap, 2015). The critical metal report (Moss et al. 2011) listed 14 economically vital raw materials that are prone to supply disruption and concluded that supply disruption would threaten the goal for cleaner transport and sustainable energy since rare earth metals are used in products using green technology, such as hybrid/electric vehicles, carbon capture systems, wind power generation, low-energy lighting, and energy efficient flat-screen displays."

Jan 1, 2016

By A. S. H. Kabir, I-H. Jung, J. Su, Yue. S., M. Sanjari

One of the major problems associated with conventional wrought magnesium alloys is the unwanted basal texture that forms during plastic deformation which generally does not change markedly after post-deformation annealing. Formation of precipitates on the recrystallized grain boundaries during annealing may affect the usual rotation of grains towards preferred basal direction resulting in texture weakening. In this study, Mg-Al-Sn alloy was hot compressed at 250°C and annealed at 350°C for various times. The initial as-deformed microstructure was partially dynamic recrystallized with dynamic precipitates on the grain boundaries. After annealing at 350°C, static recrystallization of the bimodal microstructure took place where at this temperature no static precipitates formed. The goal of this work was to study the effect of dynamic precipitation on the texture evolution during the annealing process. Texture evolution was studied during annealing by electron backscattered diffraction (EBSD) technique through a microstructure tracking process. It was found that precipitates on the recrystallized grain boundaries have significant effect on the usual rotation of the grains towards the basal direction, meaning significant texture weakening, which is beneficial for final mechanical properties.

Jan 1, 2015

By A. J. Hyett, R. D. Reichert

"A laboratory and field research program was conducted to investigate the major factors influencing bond capacity of grouted cable bolts. The results indicate that cable bolt capacity most critically depends on the grout uniaxial compressive strength (UCS), the radial confinement, and the embedment length.In the laboratory &apos;split-pipe&apos; tests were conducted using P VC, aluminum and steel pipes to provide radial confinement, and field test sites were chosen in granite, limestone and shale rock masses. For both datasets higher capacities were obtained under conditions of higher radial confinement. A correlation between the two was obtained through a comparison of the radial wall stiffness of the laboratory pipes with that of the field boreholes as measured using a high pressure dilatometer. Cable bolt capacity was found to increase with embedment length though not in direct proportionality.The use of low water cement ratio grouts (<0.40) can increase cable bolt capacities by 50% to 75%. This effect is maximized under conditions of high radial confinement. However, the use of super thick grout paste (0.30 and less) may be both impractical and undesirable, first because of their limited pumpability and second because of their inconsistency in strength. Grouts with a water cement ratio of between 0.35 and 0.40 are recommended for practical cable bolt applications."

Jan 1, 1992

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By David M. Parkes, George E. Davies

"Mathematically, the proposed formula is: ""Human Effectiveness + Technological Improvement = Success in the Nineties"". A brief review is made of geology, level of technology, management and labour situations, and range of production costs in coal producing countries. This comparison shows keen competition for Canadian coals, especially from the People&apos;s Republic of China, South Africa and Australia. Domestic competition comes from nuclear energy, hydro-electric generation, natural gas (if permitted) and eastern United States coal.The huge increase in the size and power of surface mining equipment in the last forty years led to modern large-scale open pit mining. While conventional truck and shovel operations will continue to be widely used, more continuous mining and conveying systems will be installed as pits become deeper and haul distances longer. Computer systems will become more sophisticated and their applications more widespread, leading to higher productivity and closer control of all operations and equipment performances and to partial or complete automation of certain operations.The underground revival will be driven by a new generation of mining people, cooperating to produce over 3 million t/y from 300 m longwall faces retreating over 3 km resulting in mine productivities of over 40 tonnes per man shift, as is already achieved in several mines throughout the world. Continuous operation using on-line control system will assist in consistent production with availabilities over 75%."

Jan 1, 1991

By Q. Ricoux, F. Goettmann, A. Maihatchi

"Electrodeposition processes are widely used in the metallurgical industry to produce, extract and refine metals from various feed materials. However, raw materials used to provide non-ferrous metals often contain high amounts of iron. In the presence of iron, while metals are plated at the cathode, electrowinning processes produce corrosive and highly oxidative ferric ions at the anode that are harmful for the process sustainability. In fact, these ferric ions cause dramatic current efficiency loss, induce high maintenance expenditures to limit the corrosion of devices and it results in the formation of impure and dendritic deposits on the cathode. Consequently, the management of iron in electrodeposition process became a major issue in non-ferrous metals production. Actually, numerous methods have been developed to limit the ferric ion concentration in the electrolyte or, at least, to limit its harmful effect. Many methods aim to limit the iron(III) concentration in the electrolyte, generally by coupling electrowinning to extraction process such as solvent extraction (SX) (Bender & Emmerich, 2015), ion exchange (IX) (Gula, Dreisinger, & Horwitz, 1996) or cementation (Kust, 1979) processes to remove ferric ions. Other routes consist of (i) using the ferric ions oxidant properties to leach raw materials, either directly in the electrolytic cell (Fanta & Tributsch, 1975) or through a secondary circuit (Cain, 1950), or (ii) reducing ferric ions through periodic reversal of direct current to enhance the formation of Fe2+ (Loutfy & Bharucha, 1980). On the other side of the spectrum, papers discuss methods to valorize the iron from by-products of the non-ferrous metal industry, that generates vast quantities of iron containing wastes (A. Agrawal, Sahu, & Pandey, 2004). Many studies on iron electroplating and electrolytic iron production from ores have been carried out (Cain, 1950; Mostad, Rolseth, & Thonstad, 2008), but very few have been conducted on waste or by-products. Therefore, we propose to build on the previous literature review to develop a process for the production of electrolytic iron from by-products.INTRODUCTIONNon-ferrous metals and their alloys are used in a large variety of applications. Aluminum and titanium are used for their strength, light weight and corrosion resistant properties in structural applications. Copper has been used in various applications requiring high thermal and electrical conductivity, as kitchen products and electrical wires. Nickel and zinc are commonly used as plating materials; nickel offers a wide range of working temperature and zinc is used for steel plating. Gold, silver, and platinum group metals are used in electrical/electronic applications, jewelry and chemistry as catalysts."

Jan 1, 2016

By Tatyana Alexandrova

The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Technological aspects of processing precious metal ores are examined in two respects: enhancing gold recovery from double refractory ores; and using carbonaceous ores on a production scale. The dispersed carbonaceous matter (DCM) present in concentrates causes the adsorption of [Au(CN)2]- complex on their surface during cyanidation process. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The possibility of rare metals recovery, including rhenium, from black-shale rocks, has been examined. Comparative assessment of analytical methods of rare metals detecting has been carried out. It has been proved that neutron activation analysis is a promising technique. It has been shown that colloid-salt fraction (nanofraction) with particle size less than 1000 nm makes up to 3 wt% of black shale samples and is extracted by water under special conditions. The use of water instead of chemically active reagents provides insolubility of the mineral matrix and fully reflects the colloid-salt element of the samples. To sum up, the justification of the choice of technology for processing of carbon-bearing ores is based on examining the type of carbonaceous matter and its adsorption behavior. When the content of carbon of high degree of metamorphism is considerable, it is possible to recover platinum group elements and rare elements from this type of ores. The obtained results predetermine the general guidelines for creating new methods and techniques of processing carbonaceous material for integral development of solid minerals in the mining and oilfield areas of Russia.

Jan 1, 2016