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By D. B. Dreisinger, M. R. Tavakoli

"Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the pregnant leach solution, and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. This paper reviews the purification of vanadium leaching solution using organophosphorus, solvating, and amine extractants. This review focuses on vanadium separation from iron, molybdenum, and uranium, which are often present in vanadium resources such as primary ores, fly ashes, and spent catalysts.RÉSUMÉ Le vanadium est produit à partir de diverses sources. Ce métal est connu pour permettre des solutions aqueuses de spéciations complexes en fonction de la concentration du vanadium et du pH. En tenant compte de la méthode de lixiviation, des impuretés dans la solution mère de lixiviation et du produit de vanadium planifié, divers agents d’extraction et schémas de traitement peuvent être mis en oeuvre pour purifier la solution. Le présent article étudie la purification de la solution de lixiviation du vanadium au moyen d’extractants organophosphorés, solvants et aminés. L’étude cible la séparation du vanadium du fer, du molybdène et de l’uranium, lesquels sont souvent présents dans les ressources de vanadium telles que les minerais primaires, les cendres volantes et les catalyseurs usés."

Jan 1, 2016

By Michael Magerstädt

Material loss by abrasion of contact surfaces of pipes, chutes, pumps, and other equipment in contact with ore is one of the main reasons for downtime of mining operations. Abrasion protection materials in use range from expensive tungsten carbide overlay to hardened steels, ceramics, as well as polymers, particularly polyurethanes (PUR). This paper describes abrasion protection products made from High Performance Polyurethane Elastomers. An interior pipe coating was developed that exhibited outstanding abrasion resistance and an extremely high adhesion to steel. Years of field testing in oil sands tailings as well as applications in slurry lines (e.g., phosphate slurries) have proven the performance of this material. A proprietary field joining process was developed and successfully applied in the field. This joining process requires only one field weld per joint very similar to the joining of uncoated pipe. No internal re-coating is necessary adding savings during pipe laying to the significant savings of reduced down time. Using the building-kit chemistry of polyurethane synthesis, similar high performance elastomers were used to extend the life time of ball mills. An intelligent system was developed in which wear parts contain sensors reporting the actual wear thereby optimizing maintenance interval leading to significant cost savings for the operator. Test data as well as field experience with High Performance PUR Elastomers for abrasion protection in mining are presented.

Aug 1, 2013

By A. B. Walker

The effects of the injection of dry limestone additives into boilers for the sorption of sulphur dioxide have been studied in pilot and full-scale systems. The effects of such injections on boiler mass particulate emissions as well as collectability characteristics of the fly ash and reaction products are presented. Implications of the effects on the design and economics of particulate collectors, in particular electrostatic precipitators, are discussed.

Jan 1, 1971

By Stanley W. Holmes

"The discovery of extensive uranium mineralization on the Pronto property in April 1953 initiated a program of staking, exploration, and development unparalleled in Canadian mining history. Within twelve months of the discovery hole, sufficient ore had been blocked out to merit a 55-million-dollar contract with Eldorado Mining & Refining Co. On October 15, 1955, two years and four months after discovery, Pronto went into production with a mill rated at 1,000 to 1,500 tons per day. The property is on the southern edge of the Algoma uranium district, 10 miles east of the town of Blind River and close to the Canadian Pacific Railway and Highway 17. Docking facilities for Great Lakes steamers are avail-able at Spragge, 4 miles to the east.The data and conclusions presented in this paper are based on field studies, drill hole information, and underground development. The ideas of ore genesis are those of the writer, and will undoubtedly be modified as more detailed studies and research are carried out. Because of security regulations, information pertaining to grade and tonnage will not be discussed.GeologyThe general geology of the Algoma basin has been outlined in a pre-ceding paper (Joubin and James). The description below is concerned essentially with the rocks most closely associated with the Pronto deposit. They may be grouped in three structural and lithological units: (1) the pre-Huronian basement, (2) the Mississagi formation, the lowest member of the Huronian sediments lying unconformably on the basement, and (3) a series of basic intrusives cutting (I) and (2). Most of the uranium mineralization occurs in a quartz-pebble conglomerate forming the basal member of the Mississagi quartzite."

Jan 1, 1949

By James Mackie

The Vancouver Stock Exchange (VSE) has been providing venture capital for start-up companies since 1907. Ninety years' experience in the junior mining industry has enabled the VSE to develop policies and procedures tailored to the unique needs of start-up companies. Policies and procedures applicable to listed companies are documented in the Corporate Finance Services Department "Policy and Procedures Manual." Approximately 50% of the companies listed on the VSE are in the mineral exploration and development business. The largest number are exploring base metal, precious metal or diamond properties. A recent count shows that about 20 companies are exploring industrial mineral or non-metallic deposits. The minerals sought by these companies include limestone, decorative stone, building stone, lava rock, wollastonite, zeolite, garnet and graphite. There are two basic routes to obtaining VSE financing for an industrial mineral property. The owner can either sell an interest in the property to a listed company or form a company and have it listed on the VSE. In each instance, the listed company is responsible for raising funds to develop the property. A typical financing consists of the sale of company securities byway ofeitherprivate placement or prospectus offering.

Jan 1, 2001

By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By J. Cayouette, . Blatter, P. Cousin

The Laronde mill was commissioned in 1988 and has been treating the Laronde Perim ore since 2000. The Laronde plant, situated in the Abitibi region of Quebec, has experienced mill expansions to accommodate 7500 mtpd and to recover gold and silver as well as important amounts of base metals (Cu, Zn, Pb). Ten sequential metallurgical and environmental processes are responsible for metals recovery and process viability. Over 200,000 ounces of gold, 4,5 million ounces of silver, 7000 tonnes of copper, and 78,000 tonnes of zinc are produced annually. In 2008, the Goldex plant began trucking high wade (35-45 Wt Au) pyrite sulphide concentrate (TCGO) for gold extraction at a newly constructed treatment plant, increasing gold output at Laronde by 40,000 ounces. In 2009, the high gold wade Lapa ore processing facilities were annexed to the Laronde plant increasing output by 120,000 ounces of gold. TCGO and Lapa productions are forecasted until 2018 and 2015 respectively, with known reserves of each mine. Today, up to 140 permanent employees run and optimise the Laronde plant operation. As a result, Laronde has intricacies intrinsic to a large and varied operation. The paper will outline the metallurgical highlights, challenges, and future outlook related to the treatment of each ore type (Laronde, TCGO, and Lapa)

Jan 1, 2011

By E. Best

In 2003, Phelps Dodge Mining Company decided to pursue the design and construction of a Central Analytical Laboratory to provide chemical analyses for their Arizona and New Mexico operations. This centralized approach was selected in place of refurbishing six (6) older laboratories that operated at the various Phelps Dodge sites, and which would not have permitted full automation and use of robotics. The new lab was designed by the Process Technology Center (PTC) Material Characterization Group in cooperation with IMP Group. The Central Analytical Service Center (CASC) encompasses fully automated sample preparation of blast holes and geological samples weighing up to 15 kg/sample. The CASC also includes the first "wet chemistry module" worldwide to be operated by robotics systems to perform Total Cu, Acid Soluble Cu, and Quick Leach Tests (QLT), and a fully automated lab for electrowon copper cathode. The new lab also offers flexibility for handling specialty samples and analyses by either semi-automated or manual mode. Data handling and transfer is accomplished using the commercially available StarLIMS system. Commissioning was accomplished within five (5) months of startup during which the CASC also handled 86% of a full production load. The 24/7 lab operation has already exceeded its design capacity, has achieved considerable savings in operating cost, reduced sample preparation errors, and significantly increased analytical quality.

Jan 1, 2007

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949

The problem of thin and very thin coal seam extraction in a long perspective of Ukraine?s fuel and energy industry development was determined. Technical and economic benefits of coal seams selective mining technique including beneficial environmental impact were substantiated. The scientific and practical aspects of development of borehole underground coal gasification (BUCG) technology are considered. The technological scheme of underground gas generators is offered on the basis of the authors? criteria of fitness and adaptability to the mine and geological conditions. These charts foresee the preparation of gas generators from earth surface and directly from the present mine working by inclined horizontal boreholes. Basic research is directed at abandoned supplies extraction in coal mines. Concepts of technological decisions and technical implementation of the underground part of the gasification system are worked out with analytical models, with subsequent test verification on special options and a mine experimental gas generator. Forming the technological scheme of gasification is founded on the basis of tying up spatial and sentinel factosr of coal seam gasification taking into account sufficient impermeability of the system a «gas generator ? rock massif» and to dirigibility by thermochemical processes that flow in a rock massif. The offered solutions contain the possibility of creation of the power and chemical enterprises of gasification, taking into account the complex use of BUCG products in the ecologically reserved technological cycle. Gas generator efficiency is evaluated from an economic standpoint.

Aug 1, 2013

By John L. Mero

"The ocean has served humanity as a source of raw materials for thousands of years, but only on a minimal scale relative to its potential. Exploration programs have shown the ocean to contain a large number of mineral deposits of great extent and attractive grade. Recent research has indicated that a number of these deposits can be economically exploited with present-day technology and that the cost of winning many industrially important minerals from the oceanic deposits is potentially much less than that of winning similar minerals from land deposits. Although the finding of mineral deposits in the sea is a relatively simple matter at the present time, the exploitation of many of these deposits has lagged due to the lack of the availability of specific mining techniques for the individual deposits. Within the past two years, however, several developments have taken place in the design and testing of ocean mining systems in depths of water as great as 12,000 feet which indicate that the problem of mining in the ocean may soon be solved.Within the next decade, the ocean should prove to be a major source of many minerals for society and should come to dominate as a source of such metals as copper, nickel, cobalt, manganese, etc. Within a few years of the initiation of the mining of the deep-sea metalliferous nodules, land sources of such metals as nickel, cobalt, copper, manganese, etc. will be seriously affected and it is conceivable that the present structure of the world mining industry will undergo a substantial change in character."

Jan 1, 1972

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016

By Y. Jiang, B. Li, R. Liu

"In this study, laboratory flow tests were conducted on 2-D artificial rock fracture network models containing a single intersection constituted by two inlet and two outlet branches. Three models with different intersecting angles of 60°, 90° and 120° were tested using both dye solution and distilled water. Constant flow rates were imposed on one inlet, and the flow patterns in the fracture intersections were captured by using a CCD camera. The test results were compared with the predictions made by numerical simulations that solved the Navier-Stokes equations. The results revealed that when Reynolds number (Re) is as low as less than 1, the intersecting angle has negligible influence on the flow rate of each branch and the flow patterns within a fracture intersection. As the interesting angle ? and Re (e.g., from 10 to 200) change, the normalized flow rates of different outlet branches change significantly, due to the inertial effect of fluid flow. These changes could be represented by a series of mathematical expressions involving Re and ?, which could be applied to fracture network models to improve their prediction accuracy on hydraulic properties (e.g., permeability and breakthrough curves of particles) of rock masses. INTRODUCTIONCoupled stress, flow, heat and mass transport are the corner stone subjects for many geoscience and geo-engineering disciplines, such as geological disposal of radioactive waste and geothermal energy exploitation. Many outstanding issues need to be investigated to enhance the knowledge on these subjects, and specifically more in-depth research in testing and modeling of the fluid flow in fractured rock masses is needed. In recent years, discrete fracture network (DFN) models have been extensively used to study the fluid flow and mass transport behaviors of fractured rock masses (e.g., Min et al., 2004; Zhao et al., 2011). In these models, each fracture is usually represented by a parallel-plate model, in which fluid flow exactly follows the cubic law. Therefore, comparative flow rate in each outlet branch of an intersection in these models only depends on its aperture. In reality, due to the surface roughness of fractures, the magnitude of mechanical aperture is usually larger than that of the hydraulic aperture of each fracture (Li et al., 2008; Xiong et al., 2011), and abundant flow patterns could exist in an intersection, influenced by its geometry, varying with changing Reynolds number (Re) (Kosakoswski & Berkowitz, 1999). Recent studies have also revealed that different mixing patterns might exist at a fracture intersection, bounded between streamline routing model and complete mixing model, that determine the final distribution of solutes in fractured rock masses (Johnson and Brown, 2001; Park et al., 2001). Numerical simulation has been the principal method adopted in previous studies, and the studies conducting flow tests on intersected fractures are less reported (Wilson & Witherspoon, 1976; Johnson and Brown, 2001). In this study, laboratory flow tests and numerical simulations by solving the Navier-Stokes equations were conducted on 2-D models containing a single intersection constituted by two inlet and two outlet branches, intersected at different angles. The main objective is to study the influence of intersecting angle on the flow behavior of the intersected fractures and the variations of flow patterns and fluid redistribution in each model along with the changes of the Re and the intersecting angle ?. The influence of surface roughness was not considered."

Jan 1, 2015

By B. Holaday, H. McLaughlin

Orano Canada Inc. (Orano) operates the McClean Lake mill, located in the Athabasca Basin region of northern Saskatchewan. It processes high concentration uranium ore, delivered in slurry form from the Cameco Corporation operated Cigar Lake mine. After the ore slurry is leached at the McClean Lake mill, the leach residue solids are washed in a process known as counter-current decantation (CCD). This process uses six thickeners to facilitate counter-current washing of solids with diluted acid, flocculation and settling, as well as pumping the washed leach residue to the tailings neutralization circuit (TN), and the uranium laden aqueous to the solvent extraction circuit (SX). Challenges in settling the slurry in CCD started in early 2017. This is largely due to the variation in fines content of the slurry (D80≤75μm), and clay content. There are several changes that have allowed the mill to adapt to the evolving challenges of settling leached Cigar Lake leach residue. Flocculant selection and mixing, temperature effects, bed level management philosophy, and centre-well feed density are key parameters that have been explored as part of adapting to changes in Cigar Lake ore quality.

Jan 1, 2020

By M. Kataoka, Y. Obara

It is known that compressive strength and tensile strength of rocks vary significantly with specimen size. Rocks are composed of crystals and grains in a fabric that includes flaws such as microcracks, grain boundaries and pores. As the likelihood of including severer flaws becomes greater for a larger specimen, the strengths are small. On the other hand, the size effect in the fracture toughness of rocks has not been made clear until now because there are few studies focused on it. In this paper, Semi- Circular Bend (SCB) test was performed using Kimachi sandstone with various specimen sizes. A shape of the specimen is a semi-circular disc with an artificial notch. The specimens were prepared with various thickness t and radius r as the following two groups; t was changed from 10 to 37.5 mm with r = 37.5 mm in the specimen of group (a), and r was changed from 12.5 to 150 mm with t/r = 0.8 in the specimen of group (b). As a result, there was no significant change in the fracture toughness with different t. On the other hand, the fracture toughness increased with increasing r and converged on a certain constant value in a range larger than approximately 70 mm of r. Consequently it was clear that the size effect in the fracture toughness of the sandstone exists.

Jan 1, 2015

By D. L. Morgan, J. A. Butterfield

"Geological data, production trends and current projects underway suggest that enough molybdenum will be available from more diversified sources to meet the world's growing demands. The growth in molybdenum consumption has been primarily related to its beneficial effects as an alloying agent in steel. This rapid growth has been deliberately fostered by stable prices, adequate supply and application research. The molybdenum industry is now in a process of change which has been seen in several other metals, such as aluminum and nickel. As supply sources have become more diversified, the market has become more competitive. The recent drop in consumption has led to excess production capacity, accumulation of substantial producer inventories and increased market uncertainties. While consumption is expected to increase in the next two to three years, it will take some time to absorb the excess capacity and inventory. The increased proportion of by-product capacity indicates that prices may become more variable. Producer discipline will be required to prevent serious price erosion in times of surplus. Future prices may not continue to increase with inflation. For the longer term, several factors favour the increased consumption of molybdenum. Engineering requirements are becoming more severe and molybdenum alloys can help to meet these changing needs. In addition, consumers can rely on a large and increasing supply of molybdenum. A 7 per cent growth rate in consumption can probably be sustained through the next decade, but new applications and reasonably stable prices will be needed to make this possible."

Jan 1, 1972

By I. M. R. Duarte, J. A. Rodrigues-Carvalho, F. R. S. Rosa, A. B. Pinho

"This paper aims to contribute to the knowledge of the mechanical properties of the shales and greywackes which constitute the flysch-type deposits of the Baixo Alentejo Flysch Group, in the south of Portugal. These formations are flysch-type deposits constituted by sequences of usually thick greywacke beds alternating with thin shale beds, which include sometimes intercalations of conglomerate beds. All the sedimentation of these flysch formations was controlled by tectonics. At the same time, should have occurred along with the first Hercynian deformation phase, a low-grade metamorphic event (chlorite zone), that affected these flysch deposits. This study highlights the influence of anisotropy and heterogeneity of these flysch rocks on their physical and mechanical characteristics. The anisotropy verified in some physical properties and on mechanical properties, due to the foliation makes difficult the sample preparation for the laboratory tests. Besides, it induces a scattering of the properties values measured, as for example, the strength and the deformability. The heterogeneity is related to the main features of these geological formations, which are constituted mostly by thinly stratified greywackes and shale beds, which sometimes may affect the results of the laboratory tests making them less representative. The study is made by using both shales and greywackes that constitute these flysch-type deposits in order to evaluate their geotechnical properties, mainly of the shales. Samples of these two rock materials, are tested accordingly a laboratory testing programme, which includes which included mineralogical analysis (X-ray diffraction), physical tests (bulk density, porosity, and void index) and mechanical tests (uniaxial compression, and deformability tests). INTRODUCTIONOne of the factors that most influence the geomechanical behavior of rocks, as well as rock masses is the anisotropy. The word anisotropy comes from two Greek words ""anisos"" (meaning uneven) and ""tropos"" (meaning direction). A body or material is considered to be anisotropic, where the same property has different values depending in which direction it is measured, therefore, an anisotropic material is one whose magnitude of the properties depends on the direction in which these are studied or measured. Otherwise, it is about an isotropic material. However, the fully isotropic materials are quite rare in nature."

Jan 1, 2015

The Bluebell mine of The Consolidated Mining and Smelting Company of Canada Limited extends under Kootenay lake, in southern British Columbia, and water control underground has always been a major problem. This paper gives a brief history of the operation, and then de-scribes the methods used by Cominco to keep the combination of lake seepage, ground water and thermal spring water under control. The pumping arrangements are de-scribed in considerable detail, with illustrations to show the various stages of development, and the power supply sys-tem is outlined.

Jan 1, 1966

By X Dai

This paper investigated the loss of cyanide via oxidation in CIP or CIL processes by relating the cyanide oxidation to its major oxidation product, cyanate. The results showed that the oxidation of both free cyanide and copper cyanide complexes are substantially enhanced by the presence of carbon. The rate of cyanide oxidation was found to occur in the order: Cu(CN)32- > CN- > Cu(CN)2-. The cyanide oxidation rate in the presence of copper and carbon increased significantly with increasing dissolved oxygen concentration, typical of CIL vs. CIP conditions. Cyanide oxidation rate of iron, zinc or nickel cyanide complexes was minimal.

Jan 1, 2011

By R. M. S. Häggblad

The article deals with stabilisation and regeneration of Ce02 and Ce02/Zr02 based Pt water gas shift catalysts, subject to high initial deactivation. The reaction gas species effect on the catalyst deactivation was investigated by H2-TPR. Activity measurements enabled the effect of different promoters, some added to the Ce02 based catalysts and some to the Ce02/Zr02 based Pt catalysts, to be investigated. The catalysts were also characterised by BET and CO-TPR. Deactivated catalysts activity was restored by using various regeneration methods. Of the two selected carriers the Ce02/Zr02 based Pt catalyst showed the highest resilience to deactivation. For the two different carriers, Ce02 and Ce02/Zr02, Wand Re were the best promoters when the catalyst was subject to deactivation. Experiments with Hr TPR indicate a fast initial change in the platinum oxides concentration and composition. The CO-TPR was used to make conclusions about the various regeneration effects of water and oxygen on the catalyst. Finally it is suggested that not one deactivation mechanism is possible and which mechanism that dominates is dependant on the catalyst and the reaction gas composition.

Jan 1, 2005