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By L. Dorador

"In block caving projects, the rock mass fragmentation process plays a controlling role in the design and success of the operation. Poorly understood, however, is the secondary fragmentation that occurs as blocks of caved ore move through the draw column and interact with one another. The initial size of these blocks can be considerable, as can their strength and stiffness as the presence of non-persistent joints and veining will be variable. Intuitively, more planes of weakness within the blocks should facilitate early fragmentation, but this assumption could depend on additional factors such as contact type between adjacent blocks and loads imposed through varying heights of the draw column. This paper reports the findings from a laboratory investigation examining the role of block strength and planes of weakness on secondary fragmentation. Testing was carried out on small-scale concrete cubes of uniform size, with and without embedded planes of weakness. The results obtained demonstrate the significance of veining and other planes of weakness on secondary fragmentation under one-dimensional compression, and allow for the development and constraint of empirical guidelines.INTRODUCTIONThe fragmentation process during block caving involves the initial (primary) fragmentation of rock in the cave back through stress-induced fracturing, release and fall of individual blocks onto the broken ore muck pile. This is followed by secondary fragmentation involving splitting and rounding of blocks as they move downwards through the draw column towards the draw point. The degree of secondary fragmentation achieved involves many variables related to the mechanical properties of the rock blocks as well as different operational factors. With respect to the block properties, the presence of planes of weakness in the form of veining and non-persistent joints is a topic of special interest given the significant influence it potentially has on the overall fragmentation process. However, the inherent heterogeneity and variable size of individual blocks generated from the cave back makes it difficult to develop any empirical relationships relating secondary fragmentation to compressive loading based on insitu observations and mine data. More preferable would be to keep constant block parameters, such as shape (aspect ratio and angularity) and size, through controlled laboratory testing. This work presents an efficient technique to fabricate concrete cubes in order to keep constant different block properties. These are then tested under one-dimensional compressive loading. The objective of these tests is to emulate a tight packing condition of single blocks such as that which would occur when the air gap between the cave back and broken ore in the draw column is small. When the air gap is small, detached blocks are unable to fall and rotate but instead maintain a very tidy arrangement with minimal voids left between adjacent blocks."

Jan 1, 2015

By J. Laganiere

A considerable part of the sulphuric acid requirements of the Aluminum Company of Canada's Arvida smelter comes from the burning of 180-200 tons per day of zinc '"'sulphide concentrates in a 22-ft.-diam-eter fluidized bed roaster. The plant and its operation were fully de-scribed in a publication that appeared about ten year ago (1). A simplified flowsheet of the roasting and gas-cleaning sections of the plant is given in Figure 1. The wet zinc sulphide concentrates are un-loaded into a pug mixer, by means of a Pay loader, and mixed with water in a mixing tank to make a slurry of 80 per cent solids. The slurry is transferred to a .feed tank and then introduced into the roaster at a point four feet above the constriction plate, which is the height of the settled bed of zinc calcines. The roasting temperature is con-

Jan 1, 1963

By A. Bouchard

"Based on laboratory testwork, a two-stage cleaner / re-cleaner circuit with feed regrind was proposed to replace an existing single-stage middling circuit treating a scavenger concentrate at Inco’s Clarabelle mill. In order to effectively transfer the technology and implement the new flowsheet in the plant, an extensive on-site pilot plant campaign was conducted. After demonstrating the improved metallurgy, the two-stage middlings circuit was successfully implemented at the operation.The present paper describes the on-site pilot plant testwork and the plant metallurgical improvement after implementation of the new middlings circuit. The addition of TETA / Na2S03 greatly enhanced the pentlandite selectivity against pyrrhotite and the two-stage cleaning considerably improved the pentlandite selectivity against rock minerals. The improvement was immediate after the installation of the new middlings circuit. Size by size recovery analysis indicated that a finer regrind would further improve the metallurgy of the new two-stage cleanerhe-cleaner circuit and those modifications are in progress at the mill.INTRODUCTIONThe milling operation at Inco’s Clarabelle mill has been described elsewhere (Kerr and Kipkie, 1985; Agar, 1991). While maximizing the recoveries of chalcopyrite (Cp) and pentlandite (Pn), continuous effort has been directed toward improving pyrrhotite (Po) and rock minerals (Rk) rejection. Inco discovered diethylene triamine (DETA) and triethylene triamine (TETA) (Marticorena, et al., 1994) for pyrrhotite rejection. Falconbridge further improved pyrrhotite rejection using DETA and SO2 (Kelebek, et al., 1995). No special technologies are used in the rejection of rock minerals."

Jan 1, 2001

By Lin-fang Shen, Shao-jun Li, Zhi-liang Wang

"The meso-structure of real soil consists of numerous particles with different sizes, while the traditional reconstruction method of quartet structure generation set (QSGS) produce relatively uniform soil particles resulting in significant discrepancy between the actual structure and reconfiguration model. In order to remedy the deficiency, the QSGS is improved by considering the influence of porosity and autocorrelative function of soil, which make the models closer to the real soil. Based on the reconfiguration model, Lattice Boltzmann method is combined in the algorithm to conduct further simulation of fluid flow in soil pores. The D2Q9 model is applied to construct the two dimensional model for simulating mesoscopic seepage field of saturated soil by setting the non-equilibrium extrapolation scheme at the inlet and outlet boundary, and the bounce-back scheme at the soil particles boundary as well as the left and right boundary. According to the case study, the proposed program is realized to simulate mesoscopic seepage field of reconstructed soil with constant inlet seepage velocity. The results show that the seepage direction of soil is along the passage with good connectivity, therefore the permeability is controlled by these passages. The seepage velocity in such channels is faster than in bad connectivity channels. Even if the channel has larger pores, the seepage velocity is still small. INTRODUCTIONUnderstanding the seepage mechanism in porous materials is significant in both theoretical and engineering problems. As a typical porous media, soil consists of solid particles and voids, which form connected channels allowing water to flow through. Such seepage in soil exists widely among geotechnical project of slope, foundation pit, and tunnel, etc. Meanwhile, a number of engineering accidents are caused by limited knowledge of seepage characters in soil (Huang, 2006; Liu, 2013). The conventional method in describing seepage features mostly based on the parameter of permeability, which is a macro statistic mean evaluating the whole connectivity of soil. Obviously, this parameter cannot exactly reflect the details of how water flows through the inner soil structure, especially the flow velocity in local mesoscopic area, hence is unable to represent the actual seepage properties. Therefore, it is necessary to develop mesoscopic approaches to fully study the seepage mechanisms."

Jan 1, 2015

By M. S. Badollet

Introduction Very little fundamental research has been done on asbestos fibre to cake maximum advantage of its properties and to determine in what commercial products it can best be utilized. For the research chemist who is associated with asbestos development work, a thorough study of mineralogical information on asbestos deposits would furnish reliable information on the rock formations and the mineral impurities closely associated with the asbestos. Furthermore, ?he must have an intimate knowledge of the uses of the fibre in various products so that he can visualize the importance of the fibre and the role it plays in industry. Some of the properties of asbestos fibres such as strength, composition, length, harshness or softness, and mineral associates are of considerable importance to the manufacturer because they are responsible for many production difficulties. Fibre Strength It has been known for some time chat asbestos filaments have considerable tensile strength. These strengths have been referred to merely as 'weak' to 'very strong'. Not until recently have numerical values been applied to the strengths of asbestos fibres. But today we can take a thin fibre filament and mount it between two holders and apply a gradually increasing load or pull until the fibre breaks. By measuring the cross sectional area of the filament and the amount of load applied, we can calculate the tensile strength of the fibre in terms of pounds per square inch. This type of test is slow and rather difficult, but the fundamental data obtained furnish important basic information that can be applied to mechanical processing equipment and to certain asbestos products.

Jan 1, 1948

By D. Markwart, B. Volk

Anode effects are a phenomenon of the aluminium electrolysis process which produce potent greenhouse gases called PFCs (CF4, C2F6). With concerns surrounding global warming, and increasing regulation of GHG emissions, anode effects have become a significant sustainability issue for aluminium producers. In modem smelters, sophisticated computer control and automated alumina feeding systems allow for very tight control of the alumina concentration in the electrolyte and thus very low anode effect frequencies. Older smelters, however, do not have these systems and must either invest heavily to obtain them, or find other, innovative ways to reduce anode effect frequency. This paper will present the integrated approach to anode effect reduction used in the Vertical Stud Soderberg (VSS) potlines at Kitimat Works. Through an innovative combination of simplified signal analysis, modified alumina feed control logic, anode effect prediction, and anode effect prevention using a pager based communication system, Kitimat W arks has been able to make significant reductions to its anode effect frequency.

Jan 1, 2006

By J. H. Pee, Y. J. Kim, H. U. Lee, G. H. Kim

The general recycling process of tungsten scrap to produce tungsten raw materials (tungstic acid, ammonium paratungstate (APT) and WO3) have been carried out by the oxidation, milling, sodium-fusion, dissolution, and extraction processes. Many studies on the high temperature oxidation of tungsten scrap have investigated various aspects such as swelling kinetics, fracture resistance, and the effect of alloying composition. However, the accelerating factors on the scrap oxidation rate during oxidation were not considered here. In general, oxidized products were fused with sodium carbonate or sodium hydroxide to produce Na2WO4. Later in the process, solid Na2WO4 was dissolved in water. This process required considerable reaction time and was a costly process. Therefore, the aim of this study was to increase the solubility of solid oxidized products to produce Na2WO4 solution by hydrothermal reflux method. Na2WO4 solution was used to produce CaWO4 and H2WO4 by general chemical reactions with calcium chloride and hydrochloric acid. Ammonia solution was also added to the tungstic acid to produce APT. In this study, the effect of ammonia addition on the APT precipitation process was investigated in detail.

Jan 1, 2015

By W. R. Gunter

"INTRODUCTIONThis article documents the current non-metallic mineral s resources of Manitoba (Fig. I), and makes comparisons with currently producing deposits in North America and elsewhere in the world. Industrial minerals may lack the glamour of gold, silver or the base metals, but they contributed approximately 20070 to the value of Manitoba's raw materials, and even out-performed our petroleum industry, except during the oil boom of the early eighties (Fig. 2). Values per tonne of industrial commodities can be as high or higher than for base metal ores. Commodity prices (Canadian), listed in the February 1988 issue of Industrial Minerals magazine, are: talc $202.00 - $306.00, sillimanite $427.00; kaolin $69.00 - $270.00; garnet $175.00 - $250.00; and mica $405.00 - $540.00. The prices are converted to Canadian dollars using the prevailing exchange rates of February I, 1988. Some commodities are not sold by weight. Building stone, for example, is sold by the cubic foot. An average rough granite block, 4 ft by 4 ft by 8 ft, is worth approximately $2000 sitting on the quarry 1100r in southeastern Manitoba (Fig. 3).Thus, not all rocks that do not contain sulphides are worthless. Some may be extracted more profitably than either the base or precious-metal bearing varieties.Industrial Mineral CommoditiesThe commodities available in Manitoba are described in two categories: (1) those already in production that have additional development or expansion potential, and (2) those not in production logical information available at this time.Current Industrial Mineral ProductionThe commodities described herein are currently in commercial production in Manitoba (Fig. 4). These mineral products also have good market expansion potential provided additional geological and market research is conducted. The use of company names in reference to sundry products and locations should not be interpreted as specific endorsement by the Government of Manitoba. The numbers following the commodity name refer to Figure 1. that have good development potential on the basis of geo-"

Jan 1, 1989

By Neil Campbell

"The Pine Point area is on the south shore of Great Slave Lake, 510 air miles north of Edmonton and J JO miles south of Yellowknife, N.W.T. The occurrence there of lead and zinc was reported in J 899 by R. Bell (5) of the Geological Survey of Canada, and in the following years several claims were staked and some prospecting was done. In 1928 Atlas Exploration Co. took over the property containing the discovery occurrences. In 1929 The Consolidated Mining and Smelting Company of Canada Ltd. (""Cominco"") and Ventures Ltd. participated with Atlas in forming the Northern Lead-Zinc Co., which, under the direction of J. M. Bell, carried out 24,499 feet of drilling in the discovery and surrounding areas. Two shafts and many surface pits were also sunk. This work showed that the discovery deposits contain about 500,000 tons of lead-zinc ore, but no new orebody was found.In 1936 D. F. Kidd (11) drew attention to the highly significant space relations between the base-metal discoveries at Pine Point and the projections of certain major Precambrian faults mapped earlier by C. H. Stockwell. Geological work by Cominco in 1940 and subsequent years suggested the presence of mineable deposits within a belt of land including part of the area of earlier field work and extending far beyond it. Between 1946 and 1954 exploration financed by Cominco and Ventures Ltd. included 182,950 feet of diamond drilling, 383 feet of sinking, and 240 feet of drifting, raising, and crosscutting. This work was successful in finding substantial quantities of new ore in places where bedrock is completely concealed.The topography is one of low relief, characterized in many places by swampy muskeg and shallow, marl-bottomed ponds. The area where ore has been found is generally higher ground which, though not well drained, is comparatively dry. It is also marked by raised beaches and a few sand dunes overgrown by small spruce and pine. Bedrock is generally overlain by a variable thickness of hard, glacial boulder clay. This in turn is covered by silt, sand, and gravel, probably deposited from the waters of Great Slave Lake, which formerly extended many miles beyond its present southern shore."

Jan 1, 1949

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By R. St. C., G. E. Morris, M. Zbik, Smart

Effective flocculation and dewatering of slurry streams containing clays (particularly kaolin and smectites which are often <200nm in lateral dimension) is becoming increasingly urgent. Release of water (often >75 wt%), for recycle and reduced make-up water consumption, from slurries in tailings streams and dam beds is usually slow and incomplete. Changes in settling rates and solids density of tailings containing clays can be achieved in practice by changes in pH, dissolved cations and flocculant additions. To achieve fast separation of clays from water and minimization of retained water, individual particles need to be bound in the initial stages of thickening into large, high-density aggregates, which may sediment more rapidly with lower intra-aggregate water content. Quantitative STIMAN (STructural IMage ANalysis) cryo-SEM imaging, shows that the structure of aggregates formed before flocculant addition has a determinative effect on these outcomes. Without flocculant addition, 4 stages occur in the mechanism of primary dewatering of kaolinite: initially separate particles and aggregates are dispersed (<0.3GP, where GP is the gel point); a partially-gelled chain network then forms linking particles edge-edge (EE) still well below the OP but remains largely suspended; after an induction time, this network structure rearranges from EE to face-face (FF) contacts densifying, compacting and dewatering the aggregates with settling rates well above Stoke&apos;s Law estimates for >20µm particles or aggregates; the GP is rapidly reached during settling producing a network spanning the vessel with compressive strength. This sponge-like structure with EE oriented particles limits slurry dewatering because the steric effect in the resulting partially-gelled structure is much more dominant than the electrostatic effects predicted by DLVO theory. Van der Waal&apos;s forces at very close distances, as particles slide across each other, may be responsible for the EE to FF change in structure. In this way, the previously extended network contracts, and when the solid volume fraction is low, the continuous network breaks apart forming aggregates and aggregate associations as flocs which arc able to freely settle. These densified aggregates settle at increased rate, give lower bed density and retain less water after drainage. With flocculant addition, the internal structure and networking of the pre-aggregates is largely preserved but they are rapidly and effectively bound together by the bridging action of the flocculant(s). The STIMAN analysis shows that there is a inverse correlation of intra-aggregate porosity (and void permeability) with Darcian permeability (and extent of dewatering) whereas there is a strong positive correlation of Darcian inter-aggregate permeability with settling and primary dewatering rate.

Jan 1, 2004

By L. R. Plitt

A new simple correlation has been developed to evaluate the performance of classifiers. The new correlation has been tested on existing data from 150 different hydro-cyclone classification tests. It is shown that this model provides a meaningful improved method of mathematically describing the classification process.

Jan 1, 1971

By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By T. Feldmann, G. P. Demopoulos

The adsorption of gold complexes on inorganic metal oxides has been mainly discussed in geochemical literature, but it is also of interest to the hydrometallurgical industry. This is so because it could be responsible for valuable metal losses or because it could potentially serve as alternative adsorbent material to activated carbon in certain cases such as from hot and acidic process slurries. This paper constitutes an early investigation into this subject by focusing on the effectiveness of FeOOH, Fe3O4 and Al2O3 as sorbent materials. All tests were done in a batch stirred-tank reactor under atmospheric conditions with synthetic gold(III)-chloride solutions at 23°C and 80°C, in the pH range of 1.6 to 9.0. Detailed kinetic tests were performed at different pH values (3 and 6) on FeOOH and Fe3O4 with solutions having gold concentrations from 5 mg/L to 130 mg/L. The adsorption of gold was found to be best both in terms of kinetics and loading characteristics at 80°C and pH=6. This was explained by a change in Au(III)-Cl speciation from a gold(III)-chloride complex to a gold(III)-chloride-hydroxy complex. By far, magnetite (reagent grade chemical) yielded the best gold adsorption characteristics making it an interesting sorbent material for further development considering that it can be advantageously recovered from slurry streams via magnetic separation. On the other hand, the tendency of gold(III)-chloro complexes to adsorb on metal (hydro) oxides needs to be taken into account to minimize undesirable metal losses in chloride-containing leaching media.

Jan 1, 2015

By M. W. Grabinsky, P. B. Tomory, J. Carvalho, J. H. Curran

Many underground mining operations use Split Set friction stabilizer bolts for rock support. Currently, however, little has been done to quantify the effects of various rock mechanics and operational parameters on the capacity of frictional support systems. The strength of Split Sets is usually measured by means of a pull test wherein a jacking force is applied to the bolt and a slip load is obtained. In order to evolve a rational design procedure for this type of support, an extensive database of over 900 pull test results from more than 50 mines through- out North America has been assembled and analyzed. Associated relevant rock mechanics parameters (rock type and quality) and operational details (drilling method, bit size, drive time, time to pull test) were also obtained, as completely as possible, for each test. Analysis of the information has yielded several charts that relate pull-out strength to relevant parameters and simple statistical analyses were conducted where necessary. Quantified distributions for pull-out strength were also produced for several operating conditions. The factors that most significantly affect bolt strength have been identified and specific applications to design are discussed. The information presented will assist mining engineers in designing safer and more economic support using Split Sets.

Jan 1, 1998

By M. Somppi, Z. Yamak

"Gold producers invest significant effort in mining, processing, and creating an intermediate gold doré product. Nonetheless, equal effort should be extended to the final handling and processing of the doré bar, and managing the high-purity gold produced at the fine-gold toll refiner. This detailed attention to bullion handling and refining provides rigor and confidence that the mine site is achieving, through fair and controlled methodology, the most appropriate value for the final product. With the above in mind, the following study explores the importance of preparing a set of site best-practices for bullion handling and specifically, detailing the peculiarities of sampling methodologies and the impact on assays.INTRODUCTION Gold and silver handling practices are common place at mine sites and refineries. The practices include but are not limited to smelting, ingot casting, weighing practices, and secure transportation. Proper handling and processing of the bullion material ensures that the mine site is achieving the true value of the final product. Various handling aspects can critically impact the perceived value of the bullion. A few of these particulars include weight tracking, scale recertification and calibration, refining and melting practices, melt temperature measurement, sampling, pouring, bar cleaning, furnace technology and crucible selection, and assaying. Nevertheless, this report discusses and focuses on the importance of proper sampling and molten-metal temperature measurement and their potential impact on the final doré bar value. Refining or re-melting operations achieve a proper measure of the precious metal content of its bullion when the sample accurately represents the whole bar. At first this task appears seemly straightforward, however, taking a representative sample can be challenging and is also one of the most important tasks for valuing gold during the settlement stage at the precious metal refinery. Various bullion sampling methodologies exist; including: dip sampling, granulation, drilling, cutting, and vacuum pin sampling. The Royal Canadian Mint (2009) indicated in their technical review of refinery operations that pin sampling is one of the best methods for cases where representative sampling and accuracy are required, e.g. to determine the payable metal content. Pin sampling consists of inserting a sealed glass vacuum tube (Figure 1) into the molten metal; when the molten metal contacts a purposely-designed weak portion of the glass, the seal breaks and the metal is suctioned into the hollow centre (Figure 2)."

Jan 1, 2018

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By Dan Miners

"This presentation will provide an overview and understanding of Mine Safety and Health Administration (MSHA) and Ontario Regulations for Mines and Mining Plants. It includes discussions on the history and practical development of the standards and an overview of engineering best practices from a construction, maintenance and operational viewpoint. INTRODUCTION Ontario is one of the safest mining jurisdictions in the world and has some of the most comprehensive regulations for the construction, operation and maintenance of a mine. In the USA, several operators have adopted some or all of the practices prescribed by the Ontario Regulations as an internal procedure. Experience has demonstrated that these plants are indicating less unplanned downtime and fewer issues with MSHA inspectors in their hoist plants. HISTORY AND THE REGULATIONS Both Canada and the USA have had some form of laws governing the operation of mines since the late 1890s. The paths of legislation have run in reasonably parallel lines, continually improving the health and safety conditions in the mining industry. Ontario Mine Health and Safety In the 1970s the accident rates in mining were higher than any other industrial sector; this prompted a Royal Commission on the Health and Safety of Workers in Mines (the Ham Report). The recommendations of this report, published in 1976, generated several changes in the regulations regarding worker safety in mines. Following the release of the Ham report, the Occupational Health and Safety Act (OHS) was passed by the Legislature in 1978. The Act is a set of comprehensive laws governing almost all Ontario workplaces, and it replaced separate laws governing different industrial sectors. OHS is enforced by the Ministry of Labour (MOL), and this discussion will focus specifically on Ontario’s Occupational Health and Safety Act, R.R.O. 1990, Regulation 854, Mines and Mining Plants, Part X Mine Hoisting Plant (Ontario Regulations). USA Mine Health and Safety A coal mine explosion in West Virginia and medical studies on occupational disease led to the 1969 Federal Coal Mine Health and Safety Act (Coal Act). The Coal Act was the most comprehensive and stringent Federal legislation governing the mining industry to date. The Mining Enforcement and Safety Administration (MESA) was formed, following the 1973 Act, as a new departmental agency to assume the enforcement of safety and health in mines. The Federal Mine Safety and Health Act of 1977 (Mine Act) transferred enforcement responsibilities from the Department of the Interior to the Department of Labor and named the new agency the Mine Safety and Health Administration (MSHA). This agency enforces the Code of Federal Regulations (CFR), and this discussion refers to CFR Title 30 Mineral Resources, Chapter I Mine Safety and Health Administration, Department of Labor, Subchapter K—Metal and Non-metal Mine Safety and Health (MSHA)."

Jan 1, 2019

By Edmund C. Bovey

"AS I begin my remarks this morning, please let me say how honoured and gratified I was to receive your invitation to address you here during your deliberations in historic Quebec City. The high esteem in which your Institute is held is reflected in the respect and deference accorded to it by industry across Canada. I feel privileged to be here with you today.I would like to discuss with you some applications of natural gas in the mining industry and suggest to you, in closing, some possible avenues of future development.Natural gas first became avail-able for industrial purposes in Northern Ontario in late 1958. Acceptance of natural gas, as a source of energy by the industry of that area, has been both widespread and gratifying. The mining industry of Northern Ontario has in-creased its annual use of natural gas by approximately 35 per cent each year since 1958. We believe that this trend will continue, al-though we will probably have to accept a more modest 10 per cent annual gain as the market approaches saturation. I would like to explain how we were able to do this and where all this gas is used. Our first sales were largely a matter of price-and the savings we offered were substantial."

Jan 1, 1966