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By John Hughes

1. De Beers, Diamonds and Canada 1.1. De Beers was founded long ago (1888, the same time that Canada became a country) in a rural mining village in South Africa. Today, we employ 22,000 people across 19 countries and have 14 mines including open pits, shafts, beach-sands and seabed. 1.2. Last year our sales were US$5.7 billion and our total production amounted to 47 million carats which means a 40% global market share. For the Kyoto buffs in the audience, the company consumes 66 million cubic metres of water per annum, 210 million litres of hydrocarbon fuel and 1,600 GWh of electricity. Stats are good, but aren?t as expressive as a movie. This one is 2 minutes long, which is quicker than I could elaborate. (Video 1 - 2 minutes) 2. De Beers in Botswana is the leading source of diamonds 2.1 Today Botswana is the Jewell in the Crown. There are three big open pits that enjoy economies of scale that make them the lowest cost producers. Last year 60 million tonnes of overburden and 30 million tonnes of ore were moved in Botswana alone. Botswana produced 31 million carats, compared to 14 million carats in South Africa and 2 million very high quality carats inn Namibia. 3. Diamond Mines provide feedstock? ?.to jewellery stores

Apr 1, 2005

By P. L. Claessens, S. Belisle, C. Bowen

"Use of zinc shot feed is a well-established procedure among North American electro-galvanizers. This form of zinc is easy to handle and relatively inexpensive when compared with zinc oxide. This paper reports results on the kinetics of zinc shot dissolution in traditional pure zinc solutions and in electrolytes used for the plating of nickel/zinc alloys. Despite the cementation of minor amounts of nickel in the latter solution, acceptable dissolution rates of the zinc shot can be achieved through proper adjustment of the solution velocity. Under these conditions, the nickel shell produced by cementation is continuously abraded, exposing the underlying zinc.IntroductionThe use of insoluble, noble metal-containing anodes rather than soluble zinc anodes for the operation of high current density electro-galvanizing lines has gained almost universal acceptance. Two major reasons for this trend are:• improved control of the process by virtue of constant inter-electrode distance; and• increased productivity because the operation of the lines does not require the relatively frequent interruptions for replacement of consumed anodes .The results of the principal anode and cathode reactions are, respectively, depletion of the zinc content of the electrolyte and the increase on its acidity;"

Jan 1, 1991

By J-S. Marois, F. Cappucitti, Y. Dodier, D. Downey, G. Matton

"The flotation processes of the Niobec Mine have been affected by a seasonal loss of recovery and a significant increase in reagent consumption over the past few winters. This paper discusses the problem-solving methodology that was used to identify the root causes, to develop solutions and to implement changes that resolved the problem to restore the process to summer-like conditions year-round. Mainly, it was found that the process water was contaminated by phosphates ions, which adversely affected the carbonate pre-flotation, and caused detrimental effects on the subsequent niobium flotation. The phosphate ions were being generated by the process itself, but were consumed by algae in summer conditions. It was determined in laboratory studies that concentrations as low as 5 ppm were enough to affect the circuit and that the multiple additions of process water throughout the circuit was worsening the effect. Also, temperature was found to have an impact on the reagent performance. The performance of the plant was restored by implementing a natural treatment of our process water with a simple cost-free rearrangement of our circuit streams. In addition to that, our extensive geometallurgical program was used to provide ore to the plant restricting phosphate generation in the process. Also, a modification of the collector was developed and introduced in the carbonate pre-flotation that provided improved performance during the periods of low pulp temperature.INTRODUCTION Niobec is one the three major global producers of niobium presently in operation. Situated in the Saguenay-Lac-St-Jean region of Quebec and in operation since 1976, the site produces ferroniobium (FeNb) to be used mainly in High Strength Low Alloy (HSLA) steel, which is known to have better mechanical properties than carbon steel. The Niobec operation consists of an underground mine, a concentrator and a converter plant. The concentrator concentrates niobium-bearing minerals, mainly pyrochlore and columbite, to produce a high-content Nb2O5 concentrate which is then converted to FeNb in the converter plant by an aluminothermic reaction. The Niobec concentrator flowsheet, which has gone through many expansions and optimisation over the years, consists of grinding, desliming, flotation and leaching steps. The flotation steps are numerous, sensitive and difficult to operate due to the non-selective nature of oxide mineral collectors. Thus, the pyrochlore concentration process at Niobec still faces many challenges and is constantly going through periods of continuous improvement."

Jan 1, 2018

By J. F. K. Brown

WHEN I first received the kind invitation extended to me by the Mining Society of Nova Scotia, I read over very carefully the suggested title-"The importance of long-distance planning and budgetting in modern methods of mining, and the advisability of working to some definite plan". I came to the conclusion that I might as well confess my inability to handle properly such a vast and intricate subject within the scope of any one paper. More properly, I think a round-table discussion should be indulged in-a sort' of symposium carried on in similar fashion to the World Power and Coal Conferences- you know, a committee for this, a committee for that, and, finally, a committee to see what the committees are doing. Weil, your Secretary's suggestion is just like that- much too comprehensive for any half-hour's presentation. As a paper, also, it either becomes too general and therefore uninteresting, or i.t descends into detail and describes means and methods to the end desired, which have little attraction because they were designed to meet quite different conditions than those my audience would mentally be considering. Of the two evils facing me, I have chosen the one that sticks to the generalities. Your Secretary's query almost automatically divides itself into two distinct phases: First, the importance, and second, the advisability, of planning. Let us dwell for the moment on the second, because, if we can prove advisability, that leads to desirability and, finally, to doing. Proving is the difficult part of the little problem. Here was something I, personally and as a mining engineer, had been battling for all my corporate life without being able to prove it to anybody. Then I saw the way out of that. I perceived I could put that little question of advisability on another basis altogether-:put it in the class of "coming- some day- soon" whether you or l or anybody else liked it or not; call it, if you please, mandatory, certain, necessary, enforceable planning. All of which means that the problem of advisability has rather suddenly become the very practical one of "how to do it". Why?

Jan 1, 1937

By M. Turek

Cost management in the conditions of increasing competition and unforeseen market turbulence constitutes one of the key areas of the enterprise?s activity. In the last two years the demand for hard coal on the domestic and global market of non-renewable resources has increased significantly. Polish hard coal mining industry, as an industry in the stage of decline, received a chance for rejuvenation. However, one of the most significant conditions of seizing this opportunity is the rationalization of mining costs and improvement of production effectiveness. Due to the significance of this issue, the main objective of the paper is to identify the possibilities of improving the production effectiveness in the hard coal mining industry. In order to meet such an objective, in the first part of the paper we measured effectiveness in the Polish hard coal mines in years 2006- 2011. The research encompassed three out of five mining enterprises operating in the country. Then based on the received results, guidelines concerning the improvement of effectiveness of production were created, taking into consideration infrastructural, technical, economic and organizational determinants. Furthermore, opportunities and threats for improving the production effectiveness, stemming from the external conditions have also been indicated.

Aug 1, 2013

By D. KEYS, D. E. Gemmell

The portion of the earth's surface covered by peatlands has been conservatively estimated at over 420 million ha (Kivinen and Pakarinen 1980). It is estimated that there are about 170 million ha of peatland in Canada. New Brunswick contains about 140,000 ha. Harvesting of peat for horticultural purposes has been carried out in New Brunsiwck since 1942. This industry, and the potential for using peat for energy purposes, indicated the need for an accurate assessment of the resource. In 1975, therefore, the New Brunswick Department of Natural Resources began a detailed peatland inventory. Assistance from the Canada Department of Regional Economic Expansion permitted acceleration of this program and field work was completed in 1982. Information gathered by the program will form the basis for a management plan for future use of the resource.

Jan 1, 1984

By Sejong Kim, Younghoon Moon, Youngseon Lee, Eunyoo Yoon, Yonghyun Song

"Mg alloy has a high specific strength, however, their thickness reduction was limited on most parts because of their poor stiffness. Since the modulus of rigidity is an intrinsic property, improvement of modulus of rigidity to the enhancement of stiffness is impossible. Therefore, the modification of shape and structure is available method to enhance the stiffness of real part fabricated by Mg alloy sheet. There are many thin walled parts which are located in outer section of electromagnetic system.Poor stiffness is often shown on wide surface area part with steel sheet, which has also high modulus of rigidity. In these cases, various groove patterns are used to increase the stiffness of part. However, some different methods have to be used when general groove pattern can’t be used. So, we would like to propose some new method to high stiffness on thin walled precision forging of Al or Mg alloys.An effect of proposed method on stiffness enhancement can be confirmed by fabrication of prototypes as well as structure and forming analysis based on FEM."

Jan 1, 2015

By J. A. Espinosa-Guillen, J. A. Lopez-Molina, S. García, J. A. Valencia-Quintanar

"The design and implementation of grouting treatments in rock masses are procedures that require continuous adjustment of parameters and criteria to optimize the results. In this proposal we describe a set of tools that enhance decision-making for this type of jobs particularly in dam projects. The methodology is focused on hydrogeological zoning of the site and its constant update combining engineer’s experience with artificial intelligence techniques to integrate the site knowledge; as well as the evaluation of grouting results for different scrutiny scales, with special attention on the relationship between water absorption and grout consumption. INTRODUCTIONSeveral methodologies for design, implementation and evaluation for grouting rock masses have been developed for the solution of specific problems and tested in diverse geological conditions. Each of these methodologies is focused on results evaluation for different scrutiny scales (Table 1) and is employed to assist decision-making before or during the grouting process.Some methods define specifications for grouting each stage of the borehole, making theoretical, semi empirical or experience-based considerations to define basic parameters as maximum pressure, maximum volume, grouting time, flow rate, etc. Ultimately each approach aim to optimize the injection process, adjusting volumes or the grouting time required to obtain satisfactory results, reducing risk of creating new flow paths or unnecessary grout travels, and enhancing the mixture properties to achieve adequate penetrability and long-term behaviour. Some of these criteria have been widely used in dam projects, for example the concept of Grouting Based on Facts to define the maximum pressure and volume (Ewert, 1997), the GIN method (Lombardi & Deere, 1993; El Tani, 2012), or the North American standards based on Apparent Lugeon measures (Naudts, 1995; Bruce 2011); on the other hand, there are relatively new criteria that have shown good results for dam grouting as the Aperture Control Method (Bonin et al., 2012; Carter et al., 2012) or the Real Time Grouting Control Method (Stille et al., 2012)."

Jan 1, 2015

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Abstract-Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last five years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the seafloor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radionuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidaland intertidal sediments. For such work the multi-sensor detector probe is towed on the seafloor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS, enables the production of detailed maps of bathymetry, bottom roughness, and seafloor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with seabed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the seafloor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has significant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last ?ve years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the sea?oor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radio nuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidal and intertidal sediments. For such work the multi-sensor detector probe is towed on the sea?oor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS,enables the production of detailed maps of bathymetry, bottom roughness, and sea?oor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with sea-bed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the sea?oor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has signi?cant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

"A 3-dimensional finite element model for stress/stability analysis of rock excavations in underground mines is presented. Developed for use on personal computer under OS/2 operating system, the model employs the 8-node isoparametric brick element and accounts for such loading conditions as in situ stresses and gravity loading of the rock mass. In addition, modelling of backfill in mine stopes as in situ stress-free material is incorporated. Material failure is assessed by Mohr-Coulomb or Hoek-Brown failure criterion. A mine design example is presented to illustrate the potential use of the model as a tool for stope design.IntroductionNumerical modelling of mine structures has become a vital tool for mine design in recent years. The need to maximize ore extraction ratio and to reach deeper mineral deposits underground has led the mining industry to employ numerical methods of analysis to undertake complex ground control studies in order to better understand the ground response to mining excavations and to evaluate the ground support requirements. Thanks to the rapid developments in computer technology, it is now possible to perform very comprehensive analyses including, but not limited to, 3-dimensional, elasto-plastic, or large deformation or time dependent nonlinear analyses on personal computer.During the past ten years or so, many researchers undertook 3-D finite element analyses of rock mechanics problems in mining engineering. The following is only a sample review. For example, Chan'!' used three-dimensional finite elements to study the mechanical response of jointed granite during shaft sinking at the Canadian Underground Research Laboratory. Wang et al.(2) performed 2-D and 3-D finite element analyses of room-and-pillar mining system with flat and rolling coal seams. Thatejatu used three-dimensional finite element method to examine the problem of branching tunnels. Dolezalovaw used three-dimensional finite elements for the analysis of tunnel-face advance with partial excavation as well as full-face excavation in combination with rein for cement of the face by long anchors. Peili (5) used three-dimensional finite elements for the simulation of rock-liner interaction near the tunnel face."

Jan 1, 1992

By J. B. Hamilton

The advantages of generating and distributing electrical energy direct from the coal-fields so closely affects the mining industry that a few remarks on the unbalanced phases of coal distribution is worthy of attention. The value of coal imported into Canada from 1912 to 1921 exceeded the sum of $580,000,000. In 1922 Ontario imported 1,640,000 tons of anthracite and 9,440,000 tons of bituminous coal. I submit that the use of Saskatchewan lignite in an electrical super-power plant equipped for the carbonizing of coal, and disposal of excess gases would be the commencement of a solution of the fuel shortage in Ontario. As Saskatchewan becomes more and more populated and manufacturing increases, the amount of by-product carbonized fuel available for shipment to Ontario will increase, and its shipment to that province would decrease the trade deficit of the national balance sheet. If and when this is carried out it will mean a better and wider market for Alberta fuels in Saskatchewan and Manitoba.

Jan 1, 1924

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By J. D. Bateman

DURING the summer of 1942 several chromite deposits were discovered in the Lac du Bonnet district about eighty miles northeast of Winnipeg. The deposits are confined to the Bird River complex, a folded composite sill of basic and ultrabasic igneous rocks of early Precambrian age that lies to the north of Bird river (1). The outcrop of the sill represents the trace of an easterly plunging anticline, the south limb extending from the northeast bay of Lac du Bonnet eastward to Bird lake, and the other limb, 6 to 12 miles north, lying between Maskwa river and Euclid lake. The south limb of the sill is 20 miles long, and the northern counterpart 15 miles; but its continuity is interrupted by faulting and by the intrusion of younger granite, so that the total length of outcrop of both limbs does not likely exceed 25 miles. The sill is intrusive into early Precambrian greenstones and associated sedimentary rocks. The chromite discoveries have been made at several localities on both limbs of the sill, and in each case at the same geological horizon. The sill comprises an upper layer of hornblende gabbro and a lower layer of serpentinized peridotite, and altogether is from 500 to 3,500 feet thick. The chromite zone is within and near the top of the peridotite layer, and thus about midway of the sill, both of the limbs of which stand nearly vertical. This geological relationship was established early in the exploration of the initial discoveries and served as the basis for successful predictions of later discoveries. The chromite zone probably persists throughout the length of the sill, but its width and chromite content are not everywhere the same. The initial exploration along both limbs of the sill has shown a combined total length of about 12,000 feet of chromite ore varying in width from 6 to 12 feet. In many places the overburden is thick and obscures the continuity of the chromite zone; but as investigation proceeds the known deposits will be extended and new ones will be found. Thus, although a total length of 12,000 feet of ore has been investigated up to the present time, there is an indicated length of approximately 31,000 feet along which the ore is more than 4 to 5 feet wide. This estimate is based on geological considerations and represents a total tonnage in the order of 15,000 tons per vertical foot of depth.

Jan 1, 1943

By G. G. Hatch

FOLLOWING World War II there was an urgent need for the development of domestic sources of ilmenite to take care of the expanding needs of the titanium dioxide pigment industry. In addition, there was the interest by the pigment manufucturers and others in titanium metal. Prior to the war the pigment industry in the United States had obtained its major tonnage of ilmenite, analyzing 55- ?60 per cent Ti02, from India. However, as a result of the shipping situation which developed during the war, the pigment manufacturers had to consider the use of lower grades of ilmenite located on this continent .and several companies undertook extensive exploration programmes to locate and develop such orebodies. Probably the most significant deposit that was found as a result of these ?programmes was the orebody .at Allard Lake, Quebec, owned by the Quebec Iron and Titanium Corporation. This ?Company was formed in 1948 by the Kennecott Copper Corporation and the New Jersey Zinc Company to mine this ilmenite ore and treat it in electric furnaces to produce titanium dioxide slag for the pigment industry and iron for the steel industry.

Jan 1, 1956

By M. Desjardins

The Hoyle Pond underground mine, located in the Porcupine Gold Camp, east of the city of Timmins, Ontario, Canada, is the cornerstone of Goldcorp Canada Ltd?s Porcupine Gold Mines. Cut and fill, shrinkage, longhole and panel mining methods are employed to excavate the narrow gold bearing structures. In order to meet increased flow requirements of 256 m3/s at the mine, a new Fresh Air Raise (FAR) and new surface fans were commissioned in early 2005. The newly acquired fans were capable of supplying the desired volume of air within a range of 1.5 and 2.0 kPa. Upon commissioning of the surface fans the total pressure was found to be exceedingly high; far beyond the design capabilities of the new installation. Consequently only one surface fan could be operated at any given time providing about half the required volume of air. Extensive work was immediately started aimed at reducing the system resistance in order to permit operation of the two fans in parallel and achieve the required mine flows. Larger booster fans were installed in parallel at the 900 m level, a 3 m raise bore linking the 450 and 900 m levels was developed to twin the existing fresh air circuit, and the FAR from surface to the 450 m level was twinned with the original FAR. This strategy, completed in 2012, resulted in a drastic reduction in system resistance and pressures, allowing the two surface fresh air fans to be safely operated in parallel and meeting the flow requirements. This paper describes details of the engineering design work and commissioning of the modified ventilation system, successfully ensuring the long term viability of the project.

Aug 1, 2013

By N. Nemeth

A brief summary of available filtration research is given. Its usefulness and shortcomings to practical application are examined and suggestions for new avenues of research outlined.

Jan 1, 1967

Training by Inclusiveness ?Background ?Video ?Results ?Partners ?How SEM works ?Future of SEM Background: Inclusivity partners ?Northwest Community College ?Smithers Exploration Group ?With support from the Province of BC ?Federal government ?And First Nations across the northwest

May 1, 2010

By J. Edwin Van Buskirk

For a country that is as important a gold producer as Canada, the return to the gold standard of the major commercial countries of the world during the past five years is of particular significance. To the Canadian gold mining industry, the advantages of the gold standard are a matter of more than theoretical importance. According to economic theory, prices are determined by the relation between the demand for, and the supply of, money. The demand consists of the offering of goods for money; the more goods offered, the greater the demand. The supply consists of the total money available for the purchase of goods. The total supply of goods to be exchanged through the instrumentality of money remaining the same, an increase in the supply of money will, according to this theory, raise prices; conversely, a decrease in the supply of money will lower prices. Let us imagine that everyone in the world suddenly had twice as much money, and that the sum total of all goods remained the same. Is it not obvious that we would pay just double the price for these goods? In Canada today, most people have approximately 50 per cent grea.ter income than in 1913, and the average price for all articles sold in Canada is 50 per cent above those in 1913.

Jan 1, 1928

By J. D. T. Steyl

"This paper presents a phenomenological model of the rate of iron(III) precipitation in batch and continuous autoclaves at medium temperature operating conditions. The rate expressions are based on information obtained from the literature and experimentation at low and high pulp densities. Special allowance is made for the formation of surface nuclei, which appears to be promoted at a higher iron(III) precipitate surface area, especially in suspensions of lower terminal acidity. This leads to the formation of secondary particulates and provides the required link to simulate high pulp density leaching-precipitation systems, using low pulp density batch precipitation data. In particular, the model allows direct application of the simulation to the autoclave oxidation of iron-containing copper sulfide concentrates and provides a good estimation of the relative precipitation rate of hematite, the preferred product, compared to hydronium jarosite. Some interesting mechanistic understandings of iron(III) precipitation in autoclaves are further elucidated.INTRODUCTIONThe objective of this work is to describe the rate of iron(III) precipitation and the relative amounts of hematite compared to hydronium jarosite precipitation during batch and continuous chalcopyrite oxidation under medium temperature (MT) (~130 to 160ºC) autoclave conditions. Published information has not yet revealed sufficient mechanistic insights about this sparingly soluble salt system under these conditions. The rate expressions in this paper are based in part on current literature information, supplemented by qualitative experimental observation at low pulp density conditions, in particular the high-resolution backscatter electron (BSE) images and particle size distributions (PSDs) of the precipitates. A summary of this work and insights from the literature are presented first, after which the behaviour of iron(III) in high pulp density leaching systems is used to derive a phenomenological expression of the effect of existing iron(III) precipitate surface area on the precipitation rate. The overall regression encapsulates all the experimental results, i.e., those obtained in both batch and continuous autoclave configurations (Steyl, 2012a)."

Jan 1, 2012