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"2.1. General Considerations and Properties2.1.1. IntroductionOur present knowledge of the platinum-group elements (POE) is extensive, the reason being two-fold. The elements have many uses and, moreover, they exhibit extremely varied chemical behaviour, depending on their state of oxidation and chemical environment. The present chapter reviews a selected body of material which is of particular relevance to mineralogy and geochemistry.Comprehensive treatises on the POE include those by Mellor (1956-1957), Gmelin (1938-1957) and Pascal (1958). The inorganic chemistry, particularly coordination chemistry, has been dealt with in works by Griffith (1967), Hartley (1973) and Livingstone (1975), and the analytical chemistry by Walsh and Hausman (1963), Beamish (1966) and Beamish and Van Loon (1972, 1977). Darling (1973) and Savitsky (1978) have reviewed the metallurgical properties and applications of the metals. Goldberg and Helper (1968) have reviewed the thermochemistry and oxidation potentials of POE systems, and Wagman et at. (1969) have also provided selected values of their thermodynamic properties. The geochemistry of the POE has been reviewed by Yushko-Zakharova et at. (1967), Cousins (1973), Cabri (1974), and Naldrett and Duke (1980).Platinum was used briefly as a coinage metal in ImperialRussia. Otherwise, the principal early use for platinum and its alloys was in the fabrication of chemically resistant apparatus. Subsequently, a large part of platinum production was utilized for catalysts in the sulphuric acid and ammonia industries. Platinum has been replaced by vanadium pentoxide in the manufacture of sulphuric acid, but, in recent times, catalytic upgrading of petroleum and emission control systems for automobiles have opened further huge markets for the metal. All of the POE find uses either as reagents or catalysts in the synthesis of organic compounds, e.g., in the Wacker process, which uses palladium chloride to catalyze the production of acetaldehyde from ethylene. There are, of course, a large number of specialized uses for the elements, particularly in alloys, temperature measurement devices, cancer therapy and so on."

Jan 1, 1979

By B. Friedrich, N. Anastasijevic, S. Stopic

The extraction of nickel from Serbian and Western Australian lateritic ore by sulphuric pressure acid leaching (PAL) has been studied. The following parameters were tested: stirring rate, acid to ore ratio, reaction time, pressure and temperature. These studies were performed with ore samples from the Rudjinci, Serbia and Silcrete, Australia, both belonging to the laterite-silicate group of deposits. An increase of the reaction temperature and the stirring speed at a fixed acid/ore ratio showed a positive influence on nickel extraction. The decrease of the oxidation potential with time correlated with the increase in Fe(II) in solution and nickel extraction as the reaction went to completion for both ores. The target values of 95 % Ni extraction and 60 % Co extraction were attained in 5 min at 250°C for the Serbian silicate ore, at an agitation rate of 1500 rpm, 10 % solids, and acid/ore ratio of 0.40. Under similar conditions only 60 % Ni, but 69 % Co could be extracted from the Australian Silcrcte ore due to different mineralogy. The nickel extraction was shown follow a diffusion-controlled reaction model.

Jan 1, 2004

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By Philip J. Bangerter, Chris Twigge-Molecey

Design for safety is critical to metallurgical plants, due to the inherently dangerous nature of their processes. Two significant areas of concern are: 1. preventing catastrophic process failures that cause damage or injury; and 2. operational safety that directly affects those working in or living near the plant. Process safety involves human behaviour, but the designer can eliminate or control hazards by engineering approaches, and control impacts through the design of the operating procedures. The tools available to guide safe facility design include bowtie analysis, hazard analysis, and hazard and operability studies. Clean plant design principles can guide the design process to address in-plant occupational health and safety issues. Auditing and review is a key part of the overall design process.

Jan 1, 2015

By J. F. Boux

"The study of the total utilization of fly ash has involved all of the known technology in the processing of this waste material into useful products. In addition, a complete knowledge of all the possible uses of fly ash and its products in the market area was probably the most important factor in evaluating the theory and practical feasibility of the total utilization of fly ash from a single large supplyLaboratory tests carried out on the separation of fly ash into different fractions were shown to improve its value and utilization. Four main fractions were studied: a fine pozzolanic low-carbon fraction; a coarse fraction for light-weight aggregate production by pelletizing and sintering; a high-iron fraction; and a carbon-rich fraction. The term ""beneficiation"" here refers to a process of separating fly ash into more useful components.Laboratory and pilot sinter strand tests were employed to optimize the sintering capability and the quality of the heat-hardened pellets through a study of the agglomeration cycle in four principal heat zones, under controlled conditions of air flow, temperature and atmosphere, and including the controlled sizing of pellets.The suitability of the heat-hardened pellets as light-weight aggregate was evaluated in test batches of concrete, which were compared with concrete containing commercial lightweight aggregate of established quality.A study of beneficiated fly ash pozzolan as a partial cementitious binder component in normal and high-temperature cured concrete was reported in a paper at the re-cent Second International Fly Ash Symposium.Samples of raw and beneficiated Lakeview ash were compared with samples of other established high-quality fly ash pozzolans. The evaluation indicated the usefulness of beneficiated Lakeview ash as a pozzolan. Economic studies indicated that to accomplish the primary objective of total utilization of any single source of fly ash (in this case. fly ash from the Lakeview Generating Station, producing approximately 400,000 tons per year), a broad knowledge of the technology of various mineral processes was essential.The design of the fly ash processing plant had to be based on the disposal of all the raw fly ash produced by the generating station. This is contrary to the normal design of a processing plant in which raw materials are supplied and produced according to product demand. The design, therefore, had to be of such flexibility as to pro-duce as wide a variety of products as possible, and the ability to market them had to be well researched and understood."

Jan 1, 1970

By R. Q. Honaker

A significant problem in ultrafine particle classification is the significant amount of submicron particle by-pass to the coarse particle stream. In classifying cyclones, submicron particle by-pass to the underflow stream can be reduced by decreasing water recovery. Past studies have shown that a reduction can be realized when the feed solids concentration is increased or the apex diameter is reduced. However, both adjustments tend to increase the particle size cut point and negatively affect classification efficiency due to the impact on slurry rheology. The addition of a viscosity modifier to the feed stream of a classifying cyclone improved the classification performance and decreased the particle size cut point over a range of feed solids concentrations. The detailed test program investigated the use of the modifier in conjunction with varying apex diameters to identify conditions that minimize ultrafine by-pass. With small apex sizes, roping conditions were readily eliminated by the addition of viscosity modifiers. The addition of the modifier had no deleterious effect on froth flotation performance, which commonly serves as a downstream separation process. The fundamental and practical benefits of viscosity modifiers in classification processes are discussed in this publication.

Jan 1, 2006

By R. K. Rajamani

Discrete Element Method simulation of charge motion in ball, SAG and autogenous mills has become a standard for design of mill internals, power draft evaluation, etc. Both two-dimensional and three-dimensional codes are being used. The two-dimensional code dominates the user market since the code completes a simulation in one or two hours. On the other hand, three-dimensional codes have been in the domain of specialists who can handle the complexity of the code and have access to parallel computing hardware. For the first time, this barrier is overcome via computing with graphic processing units (GPU). Commodity graphics cards now allow parallel computation with hundreds of processors. It is shown that the computational time has been reduced by a factor of fifty using GPU computing. Hence, SAG charge simulation results in three dimensions are achievable in a few hours using affordable desktop machines. The GPU computing shown here enables the three dimensional simulation into a manageable daily task for mill designers and researchers. On the technical side, the simulations can be elevated to a higher level of complexity to simulate breakage and transport. First, the speedup factor of fifty is established for the Nvidia GeForce GTX 580 graphics card. Next, four simulation tasks, consisting of AG, SAG and ball mills are reported. The simulation of AG and SAG mills are completed in less than 8 hours. The ball mill simulation with 1.25 million spheres is completed in 27 hours. In the near future, as the graphic card hardware advances the compute time can be halved.

Jan 1, 2012

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016

"Pilot plants for pressure hydrometallurgy represent special design and project execution challenges. Over the past twenty years, Zeton has designed and fabricated a variety of world-class pressure hydrometallurgical pilot-plant facilities, and this paper discusses design considerations and strategies related to such projects. Project execution methods are also discussed, and guidance is given for the selection of materials of construction and for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical pilot equipment. The paper concludes with a discussion of the need for process similarity with future commercial operations and the realities of pilot-scale equipment.INTRODUCTIONThe process technology developer or owner and the designer/fabricator of a new pilot-plant facility are faced with some difficult technical choices even after the decision to build a dedicated plant has been taken. A pilot-plant project is usually on the critical path of a large commercial project involving investments many multiples greater than the capital cost of the pilot plant. Schedule savings in the design, manufacture, and commissioning of the pilot plant or in a rapid completion of the experimental program can be disproportionately beneficial to the overall development project. However, inappropriate shortcuts resulting in major oversights can be disproportionately problematic.A number of considerations and suggestions for both the project execution approach and the process engineering design of pressure hydrometallurgical pilot-plant facilities are presented as a guide for potential owners and operators of new pilot-plant equipment and facilities."

Jan 1, 2012

By K. B. Young

Possibly the most complex fatigue problem associated with the development of the axial-flow 'gas turbine is discussed in its broader aspects from the metallurgical viewpoint. Reference is made to nodal patterns, interference diagrams, etc. The use of such data in analysis of a turbine :blade failure is illustrated. Special attention is given to the influence of some metallurgical variables affecting fatigue strength and, in particular, heat treatment is shown to have a pronounced effect on .the relative fatigue and creep strength properties of a nickel-chromium-cobalt base alloy suitable for turbine blade applications.

Jan 1, 1958

By Wm. D. Jr. Sheldon

THIS paper presents practical data to aid in the selection of a mine ventilating fan, and outlines considerations to be made to ensure satisfactory operation and optimum efficiency of the fan. Much has been published on the general subject of mine ventilation, but the writer has found few specific data on factors and considerations which govern the selection of a fan-data which should be available to the operator if his fan is to give satisfactory service within the range of the high-efficiency portion of its performance curve and deliver the specified air capacity when operating against the anticipated range of resistance of the mine. The total quantity of fresh air furnished by the ventilation system must be adequate to provide, and to ensure at all times, safe and healthful working conditions in the mine. It is assumed that the mine operator is able to determine the air quantities required for the various parts of the mine.

Jan 1, 1941

By R. C. Fernandes, F. L. Santos

Aluminum alloys in particular, have certain limitations when subjected to welding process. This is mainly present because aluminum alloys have high thermal conductivity, high contraction in solidification and high hydrogen solubility. Taking this into account, the FSW process has great potential for this application, since it is autogenous, held without metal melting and without the use of slags or shielding gases. From this concept, the aim of this study is to evaluate the joining of thin sheets of aluminum alloy 3105 H26 with 0.7 mm of thickness. To performing of the tests, some parameters were analyzed, such as: tool penetration in the sheets, attack angle, the type of welding tool and penetration control mode (position or force). The results indicated that the force control mode is most suitable for thin sheets, and the transient state at the beginning of welding was the most critical part to control the welding quality.

Jan 1, 2015

By P. H. Agson Gani, T. Sitorus, N. P. Widodo

"PT ANTAM UBPE Pongkor underground mine use blasting to develop its tunnels which will cause poisonous and dangerous gases trapped inside mine. To analyze this case, a study of mine ventilation, the dispersion of carbon monoxide (CO) gas concentration and diffusion coefficient is commenced. At the end, the re-entry time formula will be determined. Results indicate that this study is site specific and could only be applied in the place this study executed. The aim of this study is to be further developed by applying Principal Component Analysis (PCA) to find a universal re-entry formula. KEYWORDS Mine Ventilation, Re-Entry, Smoke Clearing, Diffusion Coefficient, Carbon Monoxide Gas, Gas Dispersion INTRODUCTION Pongkor underground mine is using cut and fill as its mining method. Thus, its development and production processes require blasting to develop its tunnel. This process caused poisonous and dangerous gases spread and trapped inside the mine, one of them is carbon monoxide (CO) gas. CO is formed in an unbalanced reaction of explosives detonation and could be the cause of headache, blackout and death to people who inhale CO at certain concentration (McPherson, 2011; Hartman, Mutmansky, Ramani, & Wang, 2012). Mine ventilation system is installed in the mine to resolve this problem. Mine ventilation play an important role to disperse CO gas by absorb the poisonous/dangerous gases and deliver clean air into mine. The important parameter is diffusion coefficient, because diffusion is affecting particulates or gasses spreading from its sources throughout the mine. Diffusion coefficient is the total diffusion in axial direction of turbulent flow mainly by convection of bulk motion, advection and eddy diffusion, while the effect of molecular diffusion is appreciably negligible (Widiatmojo et al, 2015). Taylor (1953, 1954) develops a theory about the dispersion by inducing a slow stream of solvent into a capillary tube. Taylor used Reynolds assumption of radial diffusivity to be analogous with the transfer of the matter in turbulent flow as well as the transfer of momentum and heat. Then, Taylor proposed the formula of diffusion coefficient, D (m2/s), against pipe diameter and turbulent shear velocity are as follow:"

Jan 1, 2019

By H. C. L. Reemeyer

"The mining industry faces increasing economic, environmental and social challenges, as easier deposits deplete and ores become more difficult to mine and process; head grades decline; projects migrate to increasingly remote and difficult geographies; and the industry faces more stringent environmental and social standards. While these factors increase costs and risks, they also present opportunities for a more integrated approach to mining, processing, materials handling and waste management. Two key areas of risk are in tailings and water management. As mining and processing tonnage rates continue to increase, the disturbance footprints, water and energy consumption and scale of tailings storage facilities also rise. These factors can be mitigated by more selective mining, ore sorting and pre-concentration, and more intensive tailings dewatering. Such alternatives must be considered in conjunction with the selection of mining method, metallurgical flowsheets, major equipment selection, and key process design criteria. For example, increasing the grind size of a concentrator reduces energy consumption and eases tailings dewatering, but may cause challenges with metal recovery. Emerging technologies will be reviewed, and economic and environmental trade-offs for eco-efficient alternatives will be presented for metal sulfide mines.INTRODUCTION The metals mining industry faces significant challenges that can affect its financial viability and social license to operate. There has been a consistent decline in ore grades and a relentless push towards larger operations to capture perceived economies of scale. With these larger operations, the environmental footprint of mines has increased. Water and energy consumption, and resulting GHG emissions have also risen. In recent years, two issues have raised special concerns for stakeholders and companies: • Water scarcity, particularly in drier regions of the world such as Northern Chile, SW USA, Southern Africa and Australia • Tailings risks, following the high-profile failures of the Fundao tailings dam in Minas Gerais, Brazil in 2015 and the Mount Polley tailings dam in BC, Canada in 2014"

Jan 1, 2017

By A. M. Richmond

Introduction The apparent commonplace, and prosaic, nature of building-stones, lime, cement, gypsum, and clay products, and many other miscellaneous non-metallic minerals, such as abrasives, barite, diatomite, magnesite, mica, slate, salts, etc., and their everyday appearance and necessary in our lives, has removed much of the glamour, romance, and speculative attractiveness so frequently associated with our gold, silver, lead, zinc, and copper mining ventures. However, it will be readily appreciated, with but a brief study of the thirty-five or more non-metallic minerals and products which are mined, prepared, or are known to occur, in British Columbia, that the 'industrial minerals' industry in the Province has an abundance of interesting technical problems, is fraught with speculative possibilities, and, as such, fully deserves much more technical attention than it has hitherro received. The brief notes presented in this paper show, in summary form, the magnitude of the British Columbia industrial and non-metallic mineral industry; outline in synoptically form the principal deposits of non-metallic minerals presently known; and indicate in a general way a few of the possibilities which exist in the Province for the expansion of the industry. For convenience in presentation, the assembled material has been divided into four sections: 1.-Sraristical information 2.-Strucrural non-metallic minerals 3.-Miscellaneous non-metallic minerals 4.-Non-Metallic mineral possibilities in British Columbia 1. -Statistical Information The writer does not propose to dwell at length on the statistical comparisons and deductions which may be drawn from the four tables which have been compiled for this section of the paper, nor is it considered essential, as the figures present a most emphatic story in themselves.

Jan 1, 1935

By A. E. M. Warner, A. Vahed, P. J. Mackey

"Since early 2015, the price of nickel has dropped from the region of US$6/pound to current levels of around US$4.60/pound (March 2017), reflecting several market factors, but principally due to lower demand from China. Under such conditions, nickel companies have been under pressure to contain operating costs. In addition, labor and energy costs will continue to rise, while nickel ore grades will likely continue to drop. All major companies now accept the need for climate change action and consequently efforts are being made towards lowering carbon-based emissions. Nevertheless, meeting these challenges can also contribute to higher operating costs without parallel innovative developments - which at the same time, under current conditions, major companies are tending to curtail. In this paper, several productivity improvement opportunities to reduce unit operating costs at nickel sulphide and nickel laterite plants are reviewed. Opportunities include: (a) process technology and energy-type selection, production capability, optimization of process intensity and implementation of newer technologies; (b) improved productivity, equipment availability including maintenance best practice; (c) energy savings and recovery opportunities and use of energy surveys and, (d) process modeling and improved scheduling. Such improvements along with an uptick seen in nickel demand going forward should better position the world nickel industry.INTRODUCTION Nickel is an essential metal to modern society, primarily through its use as an important ingredient in stainless steel. Thus, stainless steel finds vital applications in food preparation facilities, as well as important uses in transportation and industrial applications. Canada has always played an important role in nickel production and nickel metallurgy. In the 1940s and 1950s, Canada supplied over 90% of the world’s nickel. However, this proportion has declined considerably to around 10% of the world nickel supply today. Still, Canada remains an important nickel supplier and contributor to nickel extractive technology. Due to the importance of nickel to society, nickel demand is expected to continually rise. On the other hand, nickel companies have been under pressure to contain production costs amid languishing nickel prices. While demand projections show nickel growth, there are uncertainties in actual levels of future market growth. Ore grades are dropping, while labour and energy costs, which are key cost contributors are rising, hence efforts to lower production costs will generally require innovative approaches."

Jan 1, 2017

By R. L. Dunsmore

Introduction If one had been called upon to describe petroleum oil refining seventy-five years ago, he could have acceded to the request quite satisfactorily in about fifteen minutes. Fifteen years ago, an hour and a half would have been sufficient to give a general idea of oil refining, and of the equipment used for this purpose. Today, so extensive has been the research into all phases of the refining and manufacturing of petroleum products, and so rapid the strides in improvement in technique and equipment, that I doubt if a week would suffice to give an adequate outline of ail the ramifications of present-day oil refining. I propose to only 'hit the high spots', dealing particularly with the equipment and methods employed at the Imperoyal refinery, which you are to visit. Crude oil, the refiner's raw material, contains essentially only two elements, hydrogen and carbon. These are not present in the free state but are combined in various proportions as 'hydrocarbons'. A given crude oil is not made up of just one hydrocarbon, but of myriads; some solid, others liquid, and still others gaseous at atmospheric temperature and pressure, ail dissolved one in the other. Moreover, the nature and the relative amounts of the several hydrocarbons vary very considerably in crude oils from different sources. That is, a 'crude' from Oklahoma will contain hydrocarbons not present in crude from Mexico, and is different again from the Venezuela crude. Not only this but oil in a certain well in, say, Peru may be differently constituted from that in a well half a mile distant from it.

Jan 1, 1931

By Paul Clark

Generation - Profile l 9,726 megawatts (MW) of capacity l 46,877 gigawatt hours (GWh) produced at an average plant availability of 88.4% l 47 facilities in four geographies: Canada; the U.S.; Mexico; and Australia l Fuel mix of coal (62%), gas (26%), hydro and renewables (12%) l 23.2 million tonnes of coal mined l 47.0 million gigajoules (GJ) of gas consumed

May 1, 2004

By A. Mitura

The paper presents the initial investigation of possible energetic applications of chosen wastes from groups: 06, 03, 05 and 01, including coal slimes being secondary product of hard coal processing. These categories of wastes are catalogued according to the polish law, where 06 ? wastes from production, preparation, purchasing and application of products of non-organic chemistry; 03 ? wastes from wood processing and from plates and furniture, celluloid mass, paper and card board production; 13 ? oil wastes and wastes from liquid fuels; 01 ? wastes produced by searching, extracting, physical and chemical processing of ores and other mineral raw materials. The change of combustion heat value was evaluated in produced energetic mixtures containing these types of wastes together with the change of their individual components. All combinations of ingredients were taken into consideration giving 256 various mixtures, from which 36 were selected to investigation. This allowed the performance of statistical factor analysis. For such prepared materials the application of regressive method was proposed in purpose of calculating combustion heat value and then the comparison of empirically determined and theoretically calculated heat values was performed. The change of regressive coefficients can be determined by the nature of Hess law (eq. 1) what was investigated and the attempt of its explication and validation was done.

Aug 1, 2013

By J. E. Dutrizac

"The end of an era in zinc metallurgy took place on July 31, 1976 when the horizontal retort furnaces of the National Zinc Company in Bartlesville, Oklahoma were permanently shut down (1) . For more than a century, horizontal retorting had been the most common method of producing zinc in the United States; it was a thriving industry in many parts of that country, especially in the natural gas belts of Oklahoma and Texas. With the Bartlesville closure, yet another metallurgical process has become an object of historical interest for North American metallurgists. Although shrouded in controversy, the origins of zinc metallurgy seem to date back at least 2000 years. Pyrometallurgical methods with carbon reductants are capable of producing zinc from oxidic zinc ores, but only above the boiling point of the metal. Although slow cooling results in re-oxidation of the zinc vapour by air or carbon monoxide, quenching yields liquid zinc; some form of rapid cooling, either accidental or intentional, was likely used by ancient metallurgists to liquify the metal. Zinc metal found in Athenian objects of the Roman era was likely of accidental origin. The Romans employed brass extensively for coins and ornaments(2) , and this was intentionally produced by the calamine process whereby oxidic zinc ores were added to molten copper under strongly reducing conditions. Zinc appears to have been known in China and India as early as 1000-1300 A.D., and was probably smelted commercially in those countries from the 14th century. Although the early metallurgical procedures were probably inefficient, they were able to produce zinc metal in significant amounts. The large heaps of zinc residues with clay retorts bear testimony to an early smelting industry of impressive magnitude. It is estimated that the heaps at Zawar, India alone represent the extraction of 100 000 tons of metallic zinc(2) In the 1730s the smelting of oxidic zinc ores was developed in England using a vertical retort method. In 1788 a British patent was granted for making zinc from zinc blends (ZnS) by roasting the ore in a coalfired reverberatory furnace, mixing the calcine with charcoal and smelting the mixture with suitable zinc condensation. The English process was very energy intensive, however, and early in the 19th century the Belgians developed a horizontal retort process for the reductiondistillation of zinc that was more fuel efficient. This technique was gradually developed into what came to be known as the Belgian process, the forerunner of the ""modern"" horizontal retort furnace."

Jan 1, 1999