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By Forster G, Datta P. K

Many high temperature industrial processes involve gaseous halogen-bearing environments. Essentially, these fall into three subject areas: power generation, waste incineration and especially extractive metallurgy. Fundamental to any understanding of the process chemistry and efficiency in the process technology is an adequate knowledge of background thermodynamics relating to metal-chlorine reactions. In this context, existing free energy/temperature diagrams for metal chlorides do not include many elements, in particular the so called refractory elements from Group V and Group VI of the Periodic Table, namely niobium, tantalum and vanadium, and molybdenum. This paper reports estimation and calculations of the free energy values for these chlorides. The data is discussed in the context of high temperature chlorination processes.

Jan 1, 1991

By Hussey K. J, Morrison R. S

Recent mapping (1989-1992) by the Northern Territory Geological Survey in the Tennant Creek 1:250 000 map sheet area has resulted in substantial revision of the lithostratigraphy of the Tennant Creek Block (Donnellan, Hussey, and Morrison, in press). Briefly, the former Warramunga Group (Dunnet and Harding, 1967; Dodson and Gardener, 1978) is divided into the Warramunga Formation, and an overlying less deformed volcano-sedimentary succession, the Flynn Subgroup. The latter is conformably overlain by the Tomkinson Creek Subgroup of the Tomkinson Creek province in the north of the Tennant Creek Inlier. These two Subgroups constitute the Churchills Head Group which is essentially equivalent to the Hatches Creek Group of the Davenport province to the south of the Inlier.

Jan 1, 1994

By Biswas AK, Hayes P

During the reduction of iron oxide pellets in the blast furnace it has been found that catastrophic swelling (up to 300% volume increase) can occur. Although the burden preparation conditions can be designed to avoid this phenomenon the exact reason and mechanism of the swelling has yet to be clearly identified. Swelling of the burden is undesirable since it reduces the interparticulate voidage in the blast furnace thus reducing gas flow through the stack resulting in low production rates of iron. The present study differs significantly from previous experiments in that reduction is carried out on single crystals of wustite thus the problems of control of gas composition and specimen preparation are minimised. The microstructures formed on reduction have been examined by optical and scanning microscopy. Pure wustite and wustite doped with various levels of CaO have been examined after reduction in controlled CO-CO 2 gas mixtures at 968¦C. The catastrophic swelling on reduction coincides with the formation of an unusually open iron structure in which the iron appears as whiskers or needles as previously reported. The spacing and thickness of the needles are shown to vary with impurity content and gas composition. Metallographic examination has shown in addition, however, that the whiskers do not necessarily constitute the only product form of the iron produced and in CaO containing wustites with less than - 2% CaO there is a transition from needle growth to porous growth of iron. Thus the % swelling of the oxide particles is dependent on the initial size of the oxide grains. Samples of FeO - 10% CaO exhibited a previously unreported product inorphology associated with the nucleation of 2CaO.Fe203.

Jan 1, 1980

By Fry P. R

Dragline operations have played a major and successful role in coal mining around the world for more than 30 years. Because of this long history, many of the operating draglines are reaching an age where maintenance and downtime costs are prohibitive, and decisions need to be made to either replace or refurbish them.In the current economic climate, refurbishment is a popular choice and this usually involves major structural repairs above and below the roller circle, together with replacement of the roller circle components. Often, the dragline tub is also replaced by a completely new one.

Jan 1, 1992

By Chowdhury P. J R, Biswas S. K

Recovery of metallic values from lean-grade raw materials as well as from secondary/intermediate industrial products is of immense importance to a country like India which is not endowed with extensive sources of copper and nickel. The results of a few studies carried out in this area are described in Part-I and Part-II in this article. A novel anode casting system, specially designed for a small copper refinery which had been set up to produce copper wire bars/rods is described briefly in Part-III.

Jan 1, 1992

By Bolton G. C

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCi in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

This paper outlines the thermodynamic and mass balance principles which affect the distribution of cobalt between matte and slag during the pyrometallurgical treatment of nickel-copper sulphides and considers the implications with regard to maximising the recovery of cobalt from the smelting and converting circuit.

Jan 1, 1994

Botanical exploration has identified many plant species that naturally accumulate very high concentrations of elements, particularly heavy metals. The enormous potential applications of some of these species to remove metals from soil (phytoextraction) are slowly being realised. The discovery of hyperaccumulation has resulted in considerable research into applications for removing contaminants (phytoremediation) or more importantly, in the context of this discussion, for commercially æfarmingÆ metals (phytomining) from metal-bearing soils. Currently published phytoextraction models estimate Ni yields using Berkheya coddii (a South African nickelophyte) are approximately $US 750 ha-1, excluding the cost of processing. Research indicates that B. coddii will also accumulate significant amounts of Co, resulting in a considerable increase in the value of the crop. Modification of the substrate by acidification, fertilisation and/or chelation indicate fruitful avenues for improving this yield by increasing the extractability of the target element, elevating biomass production rates and/or rendering other contained heavy metals extractable. Plant uptake of more insoluble elements, such as Au, may be induced in many plant species using chemical compounds. These chelates applied to the soil, form soluble complexes with poorly soluble metals forcing them into the soil solution. Plants may then accumulate these metal complexes through transpiration. Research has achieved foliar Au concentrations of 78 mg kg-1 in Iberis intermedia, 56 mg kg-1 in Brassica juncea and 9 mg kg-1 in B. coddii (on a dry weight basis). Therefore in theory B. coddii could phytomine a soil containing modest concentrations of Ni, Co and Au to yield 116 kg Ni, 36 kg Co and over 6 oz Au ha-1 at a current value of $US 4000. Root crops have also shown promise in chelate assisted Au accumulation (eg 6.8 mg kg-1 in Beta vulgaris and 118.5 mg kg-1 in Raphanus sativus). Phytoextraction, in its varied applications, is rapidly coming of age as a technology having considerable potential for application in environmental science and the minerals industry. Phytotechnology employs unique plant biochemical behaviours in the rhizosphere, driven by the sunÆs energy, to seek out and concentrate low levels of heavy metals at very low cost.

Jan 1, 2002

By Korsch RJ

Permian oroclines in eastern Australia must have formed by sliding on a detachment surface. It is identified as a westward- dipping Devonian and Carboniferous sub- duction zone. Major strike-slip faults probably sole out on the same surface. One major fault with an associated serpentinite belt was pulled away from the craton abd bent into loops. Basins formed in the loops.

Jan 1, 1987

By Kelly GD

Prior to 1986, users of satellite based remotely sensed data were almost exclusively reliant on the United States Landsat series of satellites to monitor our Earth's resources. This situation changed when France, Belgium and Sweden launched SPOT-1 in 1986. The year of 1988 saw the Japanese also enter into the earth resource satellite business. The Japanese launched an earth resource monitoring satellite with an emphasis on marine resources, hence the name MOS-1 (Marine Observation Satellite). Many more remote sensing instruments are planned for launch by these nations and others in the next 10 years.

Jan 1, 1990

Grade control is an important factor in the on-going success of a mining operation. Grade control criteria will vary depending on the commodity being mined. Financial considerations determine the actual grade control criteria at any one mine site. Mining and metallurgical capital and operating costs are ultimately used in ascertaining cut-off grades employed in grade control. The metallurgical characteristics of the ore, and ultimately the equipment selection and design of the plant, are based on samples provided by the exploration geologist. Ore variability is an important factor in designing the process plant. Ore variations, outside of those catered for in the design, as well as large ore changes on a daily basis, will impact on the metallurgical performance, and hence the economics of a mining operation. Therefore good liaison between the grade control geologist and metallurgist will undoubtedly lead to a more consistent, and more profitable mining operation.

Jan 1, 1993

By Goldstone A

The paper introduces a newly developed multi-function test rig for fracture grouting. This test rig has many functions and its performance is consistent. It can control and adjust accurately the opening degree of fissures and static pres- sure; it can measure automatically the quantity of grout injected; it can measure precisely pressure drop of grout in fissures; it can test the results of injection, including effective dispersed distance, anti-filtration capacity of consolidated body, mechanical strength, etc. It can inject a single or two grouts into one or several fissures at a pressure of 16 MPa. Therefore, it is an ideal test rig for fracture injection. The paper depicts all the components of the test rig, its performance and application of the results obtained from fracture grouting tests. Examples are briefly described.

Jan 1, 1988

I In an optical microscope, mild attack by cyanide solutions on various minerals can be observed by means of colour changes as well as etching patterns. However, the mineral may not be identifiable due to the coloured film. In some cases, a transfer algorithm between mechanical stages enables the surface-altered mineral to be identified in the SEM. A more severe attack may not be so informative, as it is not known whether the mineral attacked has been completely dissolved away. The leaching behaviour of some common minerals is described.

Jan 1, 1991

By A T. Owen, F A. Benn, J D. Swift, D M. Labbett, A F. Grabsch

The AMIRA P266 æImproving Thickener TechnologyÆ series of projects has sought to provide a firm scientific basis for feedwell and thickener design, a requirement as pressures on water usage in the minerals industry increase. While advanced computational fluid dynamics modelling of feedwell processes has generated the most obvious and successful applications to improving the performance of operating units, such outcomes have drawn heavily on parallel studies into flocculation fundamentals. Central to this has been the development of a linear pipe reactor system that allows the kinetics of flocculated aggregate growth and rupture to be measured for thickener feeds under turbulent pipe flow conditions. This ensures much greater control of the intensity and duration of applied shear than is possible with conventional flocculation test procedures, offering insights into flocculation processes that would be otherwise hidden in time-averaged measurements.

Jan 1, 2009

By Paton T. P

In the technical sense, as well as in the professional sense, the word 'model' can have many meanings. More than 23 000 references were uncovered by a simple literature search on keywords ' MO D EL#. and. (META LLURG#. or. M I NERAL#)' . For the purpose of this paper, 'models' will be considered to be mathematical formulations which attempt to represent or approximate a process. The model may be purely, or a combination of: ò fundamental models, based on the laws of physics, chemistry and thermodynamics; ò semi-empirical or phenomenological models, where an intuitive concept of the process is formulated and found by testwork to fit observed behaviour; and ò empirical or 'black-box' models (including neural networks), where a mathematically convenient form is proposed and fitted. Even under this more restricted definition, which eliminates heuristic and statistical 'models', it is clear that the efforts expended in devising and using models have exploded during the years since the first APCOM Conference in 1961, benefiting from the dramatic decrease in the cost of computer power. This paper reviews the areas of usage of computer modelling in the metallurgical and mineral processing industries, from plant design, through off-line support, to on-line modelling and automatic control. In each area, frontiers of new development of the technology are mentioned. It is noted that, while modelling is now standard practice in design, it is not yet the norm in operating and controlling plants. The reasons for this partial acceptance are, it is argued, less related to the limitations of the technology than to the human and organisational factors involved in transferring technology to implementation.

Jan 1, 1995

By McKendry J. B

Gretley Colliery is situated at Wallsend, a suburb of Newcastle in New South Wales and is owned and operated by the Newcastle Wallsend Coal Ccnpany, a wholly owned subsidiary of Peko Wallsend Limited. The mine has been an efficient bord and pillar producer by industry standards. However, its continued economic viability was threatened because the bulk of remaining reserves lie in more difficult mining conditions and are of poorer quality. Alternatives were examined to improve productivity and allow Gretley to become more competitive in the current difficult market Environment.

Jan 1, 1988

By Patridge A. C

Hydrocyclones have widespread use as classifiers in applications such as mine fill preparation and coal preparation. A fundamental conflict often exists between recovery of all of the valuable material and maintaining the quality of the product. This conflict is a result of a portion of the feed material passing through the cyclone, effectively without undergoing any classification. This paper describes an investigation, undertaken as an undergraduate project in mining engineering at the University of NSW (Brook, 1994), into aspects of cyclones in which supplementary water injection is used in an attempt to reduce the amount of misplaced fine material reporting to the coarse product and hence improve the overall classification efficiency. In particular, the study concentrated on the effects of different modes of water injection. Two methods of introducing wash water into the cyclone body were investigated. A series of tests were performed on a laboratory hydrocyclone having provision for radial water injection at different levels through small orifices in the wall of the conical section, and a preliminary study was made of the performance of a novel cyclone in which the conical section had walls of a permeable polyethylene, permitting a uniform introduction of wash water over the entire surface.

Jan 1, 1995

Low tonnage quartz vein-hosted stibnite lodes are widely distributed in rocks of the Tasman Fold Belt System in eastern Queensland, with particular concentrations in the Hodgkinson - Broken River Fold Belt and to a lesser extent in the Gympie Province of the New England Fold Belt: Higher grade deposits have been worked intermittently on a small scale since 1873, resulting in the production of about 5500 tonnes of antimony ore/concentrate with an estimated grade of about 55% Sb. Future production of antimony may be as a by-product from deposits, currently being explored/mined for gold in the Hodgkinson/Mitchell River area and the Amanda Bel goldfield. Establishment of an antimony processing plant in Queensland using the Quelar Process would provide a more reliable market for small producers and could stimulate future exploration and production.

Jan 1, 1990

A portable surface impedance meter has been tested extensively over a wide variety of geological formations both in Australia and elsewhere. It has proved a useful geophysical too] for relatively shallow mapping (i.e less than 100 metres depth) of faults, intrusions, dykes and conductive ore veins and can be used as a depth probe for overburden and glacial ice. Case studies involving coal seam mapping at Collide (Qld. Australia), galena ore vein location at Zeehan (Tas. Australia) and glacial ice probing on the Brewster Glacier (South Island, New Zealand) are detailed. The first results of a similar unit using a lower frequency with consequential increase in depth of penetration will be presented. The application of VLF measurements to monitor blasting in mines and in the location of earthquake epicentres will also he introduced.

Jan 1, 1987

By Yushan Ma, Jiqing Wang, Hanyi Jia

The Hedong Gold Mine is located in the Yantai area, Shandong province, China. It is an underground mine with an annual gold output of some 700 000 grams. The orebody is located on the edge of the Wanger Shan metamorphism zone, and the hangingwall of orebodies is thus defined by a prominent set of fractures. The proximity of the metamorphism zone and the inclusion of the fracture set ensure that both the orebody and the country rocks are unstable. The main orebodies dip at an angle of between 40 to 45¦, with a strike length of 160 metres and a horizontal width of 50 metres. Surface subsidence in the area is not permitted. Cut and fill mining is usually practiced. As the mining operation proceeds to greater depths, the ore grade is diminishing and it is necessary to find a more efficient stoping method. Sublevel open stoping with sequential extraction and filling of each sublevel has been designed and applied in situ. This new mining method is called æsublevel open and fill stoping methodÆ in the mine. Experience to-date is that new mining method is satisfactory.

Jan 1, 1998