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South Africa is a semi arid, water scarce country that has undergone recent major political and social transformation. This transformation has ensured that water management has become a primary environmental concern in the South African mining industry, raising the status of water from an ancillary service to a fundamental factor in mine planning. The coal mining industry has been involved in the development of integrated catchment management plans since the late-1980s when a series of initiatives commenced in catchments where collieries operated. The plans focused attention on water supply and water demand management, the equitable access to water supplies, and intersectoral approaches to decision making, before the promulgation of new legislative and policy frameworks. Development of an integrated watershed management plan for the Olifants River basin, located in the Mpumalanga province, commenced in 1990. The Olifants River is an international river basin of 54 570 square kilometres and shared by South Africa and Mozambique. The upper watershed, locally called the Witbank Dam catchment, will be the focus of this paper. It has an area of 3400 square kilometres and is the major coal mining, power generating, and maize-growing region of the country. The processes embodied in the integrated watershed management plan had no formal guidelines but rather developed in an ongoing fashion over time. The plan commenced with a situation analysis involving the major stakeholders that identified principal technical shortfalls. These shortfalls were investigated under the guidance of multisectoral committees. The Olifants River Forum was started to extend awareness of the initiatives on an informal level throughout the whole watershed. The results of the investigations enabled water quality guidelines to be established for the upper catchment. To achieve the guideline levels additional initiatives were developed including a scheme to manage mine water discharges into the river system, the development of a standard four-step water management process, investigation and development of innovative mine water treatment processes, specifically sulfate reduction technologies, the use of gypsiferous mine water for irrigation, river and dam hydrological models, groundwater models and biomonitoring. Significant outcomes from the process have been achieved including the improvement in water quality in the Witbank Dam catchment. Equally significant have been the development of partnerships between businesses and between businesses and the community specifically in the use of mine water for irrigation. The plan realised a number of requirements for success including, the development of trust, openness and transparency with information, the essential need for consultation and negotiation and the involvement of third parties to validate information. The future still holds the potential for disputes between upstream and downstream water users but understanding, transparency and accountability between all players have, and will in future, enable the matching of the increasing demands on a scarce water resource to the needs of all.

Jan 1, 2003

Prior to the merger of BHP and Billiton, both companies had a keenfocus on improving their performance in health, safety, environment and community (HSEC) matters. This shared intent, albeit executed insomewhat different ways, provided an excellent foundation for the newCompany. During the integration planning phase, a team was formed toconsider the organisational design for consistently achieving world class HSEC performance. The design included the policy platform, resources, structures, standards and procedures to be implemented in the merged entity. A key aspect of the design was the fully integrated HSECManagement Standards. These Standards create the framework for theconsistent application of BHP BillitonÆs HSEC Policy at all of ourmanaged operations across the world. The Standards have their origin in similar frameworks adopted by BHP during the 1990s, as well as thewell-known quality related standards (eg ISO 14001). However, they areunique in that they combine all aspects of HSEC management into asingle integrated set of auditable standards. By combining these areas and integrating our HSEC Management Standards with other aspects of the æBHP Billiton WayÆ, we are establishing a holistic, line management driven improvement approach. Over time, the BHP Billiton Way will embed a systematic improvement philosophy that we expect will become a key source of competitive advantage. The HSEC Management Standards are consistent with ISO 14001,OHSAS 18001, the Australian Minerals Industry Code for EnvironmentalManagement and generally aligned with SA8000. While compliance withthese external standards ensures that a systematic approach andimprovement plans are in place, BHP BillitonÆs HSEC Standards gofurther to include minimum performance requirements that reflect theintent of our HSEC Policy. Therefore, implementation at site levelensures that robust systems are in place to implement our Policy and that accreditation can be achieved to external standards if required.To assess implementation of the HSEC Management Standards anaudit system has been designed which incorporates both self-assessmentand peer review. Each site is required to undertake an annualself-assessment of compliance with the Standards using a commonassessment protocol. Every three years a peer review is conducted at each site to confirm the results of self-assessment and to provide a means of sharing knowledge throughout the Company. The review teams are composed of line managers and HSEC professionals from around theCompany, representatives of our joint venture partners and independentspecialists as required. The Company has committed to public reportingof the audit results through our annual HSEC report and this is reflected in our published targets. From a wider perspective, as we in the resources industry strive tocollectively raise our HSEC performance and reputation, there may be arole for industry based HSEC Management Standards complemented bya level of independent review.

Jan 1, 2002

By I Doye

Acid mine drainage is a serious environmental problem caused by the oxidation of sulfide minerals responsible for highly acidic, sulfate and metals-rich drainage. Several methods of mine waste management have been developed that reduce liabilities on environment. Layered co-mingling of waste rock with compacted tailings, covers with capillary barriers effect, and co-disposal of waste rock and tailings are these new methods which are used to reduce the formation of acid mine drainage. These methods shield waste rock dumps from oxygen. These techniques could prevent oxidation reaction. In this study, alkaline industrial wastes are used with acid generating tailings to inhibit acid mine drainage. The alkaline wastes selected are cement kiln dust (CKD) and red mud bauxite (RMB). These alkaline materials are used to keep neutral conditions in the fine material layer and to inhibit the metabolic activity of Thiobacillus ferroxidans which catalyses the oxidation of sulfide minerals. A series of timed static leaching tests were performed by reacting samples of mine tailings with two, five and ten per cent alkaline material in order to characterise geochemical balance between liquid and solid phases. Column tests have been set up with oxidised tailings, waste rock, CKD, and RMB. Column tests have been carried out to simulate layered co-mingling, covers, liners, and co-disposal of waste rock and tailings. Column leach tests were conducted in order to investigate the long-term neutralisation potential of alkaline materials and the drainage water quality. Bacteria counting were performed on each sample after testing. The results obtained show that the addition of alkaline materials permit the retention of near neutral conditions in the fine material layer, thus increasing water quality and preventing bacteria development. In fact, the pH results show that the use of five per cent, ten per cent CKD or ten per cent of a mixture of CKD and RMB permit the retention of neutral pH conditions in the reactive layer. At these percent rates, the concentrations of Al, Fe, Cu, Zn, and SO4 in solution are significantly reduced compared to those obtained with the tailings only. In presence of waste rock, the relative position of the fine material layer is important. When the fine material layer overlaying reactive waste rock is composted of reactive tailings with ten per cent CKD and ten per cent (CKD:RMB), a delay was observed before achievement of near neutral pH. The neutral pH conditions remain stable over time. The mixture of CKD and RMB provides a better short-term neutralisation than the use of CKD alone. The use of alkaline materials is beneficial in order to reduce the concentrations of Fe and other metals such as Cu and Zn as well as the number of viable bacteria. The use of ten per cent RMB alone does not involve the neutralisation of reactive tailings. In the cases where the fine-grained layer are below or mixed with the waste rocks, the near neutral pH values are directly reached with ten per cent CKD. However, the pH values decrease rapidly and the number of viable bacteria increases.

Jan 1, 2003

The fluorspar deposits at Okorusu, Namibia are closely related to an alkaline igneous ring complex of late Cretaceous age (125¦7 Ma). The fluorite ores consist of relatively fine-grained purple replacement fluorite and subsequent coarser-grained purple and green vug-filling fluorite crystals. Homogenisation temperature measurements for 38 primary fluid inclusions shows that main stage purple to green fluorite crystals were deposited over a temperature range from 166¦C to 144¦C, and minor late yellow fluorite was deposited at lower temperatures from 132¦C to 128¦C. Homogenisation and freezing temperatures measured for 18 primary fluid inclusions shows that the fluorite-depositing fluids were less saline than Mississippi Valley-Type (MVT) ore fluids and overlap the lower temperature range of fluids that deposited epithermal ore deposits. Mining in three open pits (A, B and C) at Okorusu has gradually provided exposures which reveal that the fluorite orebodies have been emplaced primarily by the preferential replacement of carbonatites. Evidence for the replacement of carbonatite includes: replacement remnants of carbonatite within the fluorite ores; goethite pseudomorphs after the carbonatite minerals, pyroxene, pyrrhotite and magnetite, which are disseminated in the fluorite ores; andpartial replacement by fluorite of a large sill-like carbonatite body in the A pit. Electron microprobe analyses of minerals in unreplaced portions of the carbonatites show that their mineralogy consists of titaniferous magnetite, diopside pyroxene, apatite, biotite and calcite. Magnetite contains 6.97 per cent to 10.46 per cent TiO2, averages 8.44 per cent TiO2, and has an average V2O3 content of 0.35 per cent. At high magnifications under the scanning electron microscope (SEM), the magnetite shows abundant fine ulv÷spinel exsolution lamellae arranged in a cloth texture. Apatite contains moderately high fluorine contents that range from 3.21 to 5.0 per cent and average 4.2 per cent, and apatite crystals range in total rare earth oxides from 1.7 per cent to 2.61 per cent. Pyroxenes in the carbonatites are iron-rich diopside, and they contrast to pyroxenes in the fenites that are aegirine-augite. All of the microprobe analyses for mica crystals in the carbonatites give biotite compositions. Microscopic examination of fluorite concentrates from Okorusu provides mineralogical information important to the resolution of beneficiation problems. Fluorite ores that are related to carbonatites are typically accompanied by phosphorus benefication problems. The cause for the presence of phosphate in some of the Okorusu fluorite concentrates is a function of the presence of binary locked fluorite-apatite particles. The fluorite ores have also replaced marble locally in the A pit, especially along the A band in the B pit, and dominantly in the orebody proposed for the new C pit. Those ores are characterised by fine grain sizes, faint remnant bedding, lack of carbonatite mineral pseudomorphs and local presence of remnants of unreplaced marble. Concentrates derived from those fluorite ores are devoid of phosphorus, but commonly have elevated silica contents due the presence of free quartz. Carbonatite and marble were preferentially replaced by fluorite because the calcite was readily soluble in the presence of the fluorite-depositing fluids and the dissolution of calcite provided calcium for the formation of fluorite. 

Jan 1, 2008

By E Ferrow, R Herbert, M E. Malmstr, M Fuchs

The study of microbial sulfide oxidation and oxidation rates of tailings requires the use of sterile control samples in laboratory experiments for comparison purposes. The need for sterile tailings sand is also apparent in the study of microbial communities and processes. This study compares six different methods with regard to sterilisation efficiency and investigates chemical and mineralogical changes in the samples as the result of sample treatment. In addition, the effect of sterilisation on mineral weathering rates is also studied. The efficiency of the different methods with regard to sterility is estimated by most probable numbers (MPN) of both sulfur and iron oxidising bacteria. The sterilisation methods that were compared are: washing with sterile water, washing with ethanol, applying antibiotics, repeated heating to 70¦C, autoclaving, and γ-irradiation. There are several possible drawbacks with the different methods, including the risk of an applied chemical acting as a substrate for micro-organisms in the system, and the risk of altering the tailings. The results show a substantial difference in sterilisation efficiency between the treatments. For example, autoclaving, repeated heating, ethanol and irradiation efficiently kill micro-organisms, rendering an undetectable amount of bacteria after one month of incubation, whilst washing with water exhibits virtually no microbiological effect, with a bacterial content comparable to the control. The use of antibiotics for sterilisation ranks intermediate: the lag-phase was twice as long in the antibiotics treatment compared with the controls. X-ray diffraction, optical and electron microscopy, M÷ssbauer spectroscopy, and mineral magnetism indicate no significant change in the bulk mineralogical composition. However, X-ray photoelectron spectroscopy analyses show that with some of the treatments, sulfides are partially oxidised, as indicated by the formation of sulfate and partially û oxidised sulfur species at the tailings surfaces. Aerated batch weathering experiments performed on sterilised tailings samples and untreated controls indicated that while the initial rates of element (S, Fe, Cu, Zn, Mg, Na, K, Ca) release may differ between the samples, over the course of ~100 days of experiment at pH 2 and room temperature, the rates declined toward a similar value for all samples. To conclude, there does not appear to be one perfect method for tailings sterilisation. Autoclaving and heating damage the mineral grain structure and oxidise the sulfide surfaces. Ethanol, antibiotics and rinsing greatly alter the pore water chemistry through the washing procedure. In addition, ethanol and denatured antibiotics might serve as a substrate and also, in the case of antibiotics, adhere to mineral surfaces thus obstructing chemical reactions. Irradiation seems to be the preferable method on an overall basis, although the formation of surface Fe3+ was suggested by M÷ssbauer spectroscopy.

Jan 1, 2003

By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

By T Sparks

The Collie River catchment, located approximately 200 km south of Perth, covers an area of around 2830 km2 and is the source of run-off to the Wellington Dam, an important irrigation water resource for the Collie Irrigation District. The salinity of the Wellington Dam has increased due to historical clearing and irrigators currently use water with salinity levels approximately twice that of the Murray River in South Australia (Water and Rivers Commission, 2001). The Collie River Salinity Situation Statement (2001), released by the Water and Rivers Commission (now the Department of Water), identified realistic actions that could achieve the salinity reduction target. Subsequent benefit-cost analyses and prefeasibility studies recommended the diversion of the most saline flows in the Collie River away from the dam as an immediate intervention (URS, 2003). The East Branch of the Collie River above the locality of Buckingham (20 km east of Collie) contributes around half of the salt that flows into the Wellington Dam and the diversion and storage of the saltiest flows from the East Branch at Buckingham was identified as a viable option for reducing salinity in Wellington Dam. The proposal had one problem û the water could not be disposed of as quickly as it was diverted. However, in the vicinity of the diversion site were a number of coal mine voids and after preliminary discussions, the Government/Griffin Coal alliance was formed and from this the opportunities have continued. Diverted water would be stored temporarily in an adjacent mine void (Chicken Creek 4 void) and then disposed of to the sea. The disposal options included Western Power CorporationÆs saline discharge pipeline from Collie Power Station, or a new pipeline. The diverted water was also identified as a potential raw source for treatment and use in industry. This has opened up opportunities including desalination, water efficiencies in the power stations, increased reliability of water supply for the power stations, water for new industries, wastewater disposal options and extra water for PerthÆs water supply. In the process of solving the water storage problems the project introduced a range of mine water quality problems û heavy metals and pH û and the Department of Water (DoW) is now working with the mining industry and the Centre for Sustainable Mine Lakes (CSML) to develop treatment and management technologies. The project has received support and funding through the National Action Plan for Salinity and Water Quality (NAP) and it has been possible to accelerate and enhance this project as a result of NAP. The DoW has developed the proposal to an advanced stage and gained approvals for the capital diversion program to go ahead. The partnerships have expanded to include the second mining company, Premier Coal, the Water Corporation, Western Power and the Harvey Irrigation Cooperative. The proposal could feasibly result in a $90 million integrated water management initiative for Collie using the latest technology, mining operations and providing water for value adding industries in the local area. The DoW is not a mining company; however, our experience in managing water in times of shortage, environmental water quality criteria, competition for water and managing community expectations will have the same success factors:consultation and knowing your community and stakeholders, sharing issues and working in partnership can provide results far greater than the initial issue, even brackish water has value, every sector is in competition with each other and has to have a share of the water, an integrated approach can provide opportunities for development in areas of water shortage, and never think of water as wastewater.

Jan 1, 2006

By V P. Beskrovnaya

Tests for the development of a metals recovery technology from samples of a Russian gold-bismuth deposit were carried out. Gold, silver and bismuth assay reported 5.6 g/t, 3.0 g/t and 0.08 per cent, respectively. Two flow sheet options were pilot plant tested: gravity/cyanidation of gravity tailings with subsequent flotation of cyanidation/carbon-in-pulp (CIP) tailings, and gravity/flotation concentration with cyanidation/CIP of concentrates. Option 1 results showed lower gold, silver and bismuth recoveries (81.3 per cent Au, 55 per cent Ag and 74.0 per cent Bi) due to low flotation efficiency for cyanidation tailings. Therefore, a flow sheet involving gravity/flotation concentration to produce bismuth-gold concentrates (0.8 per cent Bi) with subsequent cyanidation/CIP was recommended. Gold, silver and bismuth recoveries obtained by this method to the combined gravity/flotation concentrate were 90.2 per cent Au, 83.3 per cent Ag and 80.2 per cent Bi of the ore, respectively. Overall gold, silver and bismuth recoveries were 83.0 per cent Au, 40.5 per cent Ag and 80.2 per cent Bi, respectively. Gold and silver recoveries to the cathode precipitate were 92 per cent Au and 48.6 per cent Ag (per operation). Reagents consumed for flotation were 0.1 kg lead acetate/t ore, 0.4 kg butyl xanthate/t ore, 0.2 kg T-80 frother/t ore, 0.02 kg sodium hexametaphosphate/t ore, 0.15 kg copper sulfate/t ore. Reagents consumption for cyanidation was 0.42 - 0.48 kg NaCN/t ore and 0.2 kg CaO/t ore. It was recommended to deliver bismuth concentrates after hydrometallurgical treatment to a smelter. Overall bismuth recovery including bismuth recovery achieved by pyrometallurgy was 60.0 per cent. However, it was obvious that delivery of bismuth concentrates to a smelter and their commercial treatment would be very expensive due to relatively high mass pull of bismuth concentrates (7.6 per cent of the ore weight). For this reason, thiourea leaching and hydrochloric acid leaching with subsequent cyanidation/CIP were investigated as alternatives to cyanide leaching. These two alternatives were proposed to enable optimal recovery of valuable metals from concentrates on-site. Recoveries obtained by thiourea leaching were 91.2 per cent Au, 90.5 - 91.9 per cent Bi and 77.0 - 78.1 per cent Ag. However, that method required considerable capital and operating costs. As an alternative, hydrochloric acid leaching with subsequent cyanidation was investigated. Test results showed improved gold, bismuth and silver recoveries, which were 94 - 95.9 Au per cent, 94 - 96 Bi per cent and 76 - 78 Ag per cent, respectively. Hydrochloric acid consumption was 100 kg/t concentrate or 7.6 kg/t ore. Current efficiency during electrowinning was about eight to 12 per cent. A recommended flow sheet involving hydrochloric acid leaching of concentrates, electrowinning of bismuth from solutions, recycling solutions after electrowinning and cyanidation of hydrochloric acid leaching cakes is described. Overall recoveries achieved by the proposed flow sheet were as follows: 84.8 - 86.5 Au per cent, 75.8 - 76.9 Bi per cent and 63.2 - 64.9 Ag per cent. Based on results from these tests, initial data for a bankable feasibility study and plant designing were developed.

Jan 1, 2007

By L Richards, R L. Brathwaite, C Mazenga

Underground mining of gold-silver bearing quartz lodes was carried out in the great mines at Martha Hill, Waihi over 70 years from 1882 until 1952. Shafts and stopes reached a total depth of 600 m on 16 levels, with workings extending laterally some 1.6 km, and as new reefs were discovered the workings extended beneath parts of the township. Over their long life the mines produced 1217 tonnes of gold-silver bullion from processing 12.2 million tonnes of mined ore. In the early-1980s drilling proved large reserves of gold and silver ore remaining in stock-work zones between the previously mined lodes. This led to a new era of mining at Waihi with the opening of the Martha Hill open pit in 1988. A series of three sink holes have formed above unfilled stopes of the Royal lode. In 1999 a sudden collapse crater 40 m in diameter occurred near an occupied part of Waihi, placing in danger several houses and a busy street. This crater formed close to a similar crater that occurred in 1961. The 1999 collapse resulted in subsurface investigations and risk assessment studies being commissioned by the local Hauraki District Council. However, a further 50 m diameter collapse crater in December 2001 formed in a residential area, swallowing and wrecking an occupied house, fortunately without injuring its five occupants. Two other houses were perched on the crater rim. The 2001 collapse led to an acceleration of the work being carried out by the Institute of Geological and Nuclear Sciences Ltd. (GNS) to identify the extent of the old underground workings at Waihi. For the risk assessment detailed rock mechanics analyses were made to consider the stability of the underground mine stopes, in terms of the stope back, hangingwall, footwall and crown pillar failure mechanisms, as well as void migration. The collapse crater areas were analysed using using several methods, including analysis to simulate the probability of void migration from unfilled stopes to the surface using the @Risk program. The analyses show that in the cases of the actual collapse craters, the voids have a high probability of migrating to the surface, thus providing a method of testing the void migration modelling. Modelling analysis applied to the remaining stopes of the old underground mines show there are further areas where void migration from unfilled stopes has a high, medium and low probability of reaching the surface as a collapse crater. The locations of these probabilistic hazard zones were outlined using the @Risk modelling and deterministically by using the dimensions of the historical collapses applied along the length of the stopes. Consideration of the æincubation periodÆ (the time interval between the cessation of mining and the occurrence of collapse) and comparisons with mine subsidence histories overseas, indicates that further collapses are likely to occur over the next 50 years. Risk assessment estimates made using property values and occupancy levels within the three hazard zones, were compared with Societal and Individual Risk criteria. Results indicate that safety within the high and medium zones may be unacceptable.

Jan 1, 2003

The world is getting flatter through internet, mobile phone technology, relatively low cost travel, massive outsourcing of manufacturing to China and the transfer of company backroom operations to India. In the iron and steel industry, however, things will remain relatively the same with slow gradual improvements in technology; only the geographic location of plants may change over time. Or will it? The blast furnace smelting process has remained largely unchanged since 1828 when James Neilson came up with the idea of preheated air being delivered to the tuyeres. Likewise, oxygen steelmaking that takes molten iron from such blast furnaces has remained conceptually unchanged since Sir Henry Bessemer invented an air-based system in 1856. These two processes are the core of integrated steel mills that we know today. Typically such mills consist of coke ovens, sinter plant, blast furnace, oxygen steelmaking, continuous caster, rolling mills and metal coating lines. In the intervening 150 years the only real disruptive technology to the integrated steel mill has been the minimill. Based on the use of the electric arc furnace (EAF), in conjunction with a continuous caster and rolling mill, the term minimill is used because steel products are produced at down to one-tenth the scale required for economic operation of an integrated mill, with the EAF producing molten steel using largely scrap steel as its feed, as against transforming coal to coke (coke ovens), iron ore, coke and limestone into molten iron (blast furnace) and molten iron to steel (oxygen steelmaking). There are, however, a number of technologies in development that may cause a paradigm shift in the way steel products are produced and perhaps push the evolution of the minimill as a disruptive technology. Two examples are direct iron smelting, where iron is produced in a matter of seconds by injection of ironmaking feed materials into a molten bath, and thin strip casting, where molten steel is cast into 2 mm strip or less, in similar time. Both have Australian connections. A leading iron smelting technology is the HIsmelt« process, which has its first commercial application at Kwinana, Western Australia, where a joint venture of international parties, consisting of Rio Tinto and the Nucor, Mitsubishi and Shougang corporations, are in the stage of ramping up commercial production. The leading strip casting technology is the Castrip« process that arose from development work done by then BHP Steel, with IHI of Japan, at Port Kembla, New South Wales in the 1990s. Nucor followed this work up, building the first commercial plant for the technology at its Crawfordsville site in Indiana in 2001 and has recently announced an intention to build a second plant in the USA. While both technologies are only into the early stages of commercialisation they are likely to change the face of iron and steelmaking as we know it over the next 20 years. This paper elaborates on the technology of the two processes, why they could change the face of the iron and steel industry forever, what might drive the rapid change and what the changes may look like.

Jan 1, 2006

By M Skead, H Michael, R Chase, A Davidson

Ashanti Goldfields CompanyÆs (AshantiÆs) most recent development is the Geita Project in the Lake Victoria Goldfield of NW Tanzania. It comprises six distinct gold deposits within two mineralised trends: Nyankanga, Lone Cone, Geita Hill (Geita trend) and Matandani, Kukuluma and Area 3 West (Kukuluma trend). Between 1936 and 1966, the Geita area produced an estimated 5.5 M tonnes of ore from five underground deposits at an average recovered grade of 5.3 g/t. The discovery of Nyankanga was made by Ashanti in 1996 from RAB drilling of a +100 ppb Au anomaly in laterite soil above ferricrete cover. The Kukuluma trend was discovered by SAMAX Resources (taken over by Ashanti in 1998) between 1996 and 1997 from RC drilling of a +80 ppb Au laterite soil anomaly. Oxide facies banded iron formation (BIF) of the Upper Nyanzian System forms prominent topographic ridges and is the dominant host lithology for gold mineralisation. The ridges are flanked by felsic tuff units which lie stratigraphically above. Syn-genetic lamprophyre (vogesite) and post-genetic felsic dykes are also seen in the Geita trend. At Nyankanga a granodiorite-diorite suite has intruded as dykes and sills into BIF from a plug centred on a WNW fault and has produced wallrock alteration assemblages similar to those seen in Cu-porphyry systems (potassic, propylitic, etc) as well as sulphide and gold deposition. However, the main ore-grade mineralisation (as in the rest of the Geita trend) is controlled by low-to-medium angle structures dipping north-west and north with numerous splays in the hanging wall. High-grade shoots at Nyankanga plunge to the west and to the north-west, being lithologically and fault-controlled respectively. At Geita Hill the higher grade shoots are controlled by fold noses in BIF dipping to the north. Free gold occurs within fractures of sulphides. The deposits of Kukuluma and Matandani occur on an ancient (possibly Cretaceous) erosional plateau and are related to two WNW to NW trending shear zones, discordant to the local strike of the BIF sequence. Complete oxidation occurs up to 120 m depth and there is a strong supergene component to the gold distribution. Primary gold mineralisation is divisible into two distinct assemblages: arsenopyriteûpyrrhotiteûmagnetiteûchlorite associated with brecciated cherts and pyrite associated with shaley banded ironstones. Area 3W is most likely the fault-displaced extension of the same mineralised trend and comprises thin, intermittent zones of high-grade gold mineralisation occurring adjacent to a ridge in banded cherts and minor BIF. Current resources (measured, indicated and inferred) for the project are estimated at 89.24 Mt at an average grade of 4.17 g/t (11.97 Moz of contained gold) at a 1.0 g/t cut-off grade. Of this 9.83 Moz is within the Geita trend and 2.14 Moz is within the Kukuluma trend. A resource of 2.74 Moz is from an inferred resource at depth at Nyankanga where the viability of an underground operation is being studied. Proven and probable reserves are 49.77 Mt @ 3.46 g/t (5.54 Moz) based on a $325/oz gold price providing a mine life of ten years at an average production rate of 500 000 oz per year. Reserve estimation was carried out using mineable polygons to select resource blocks based on a series of mining and costs parameters. In addition key cost parameters were tested to provide sensitivities for pit optimisations and pathfinders for negotiations with suppliers and contractors. Construction began in March 1999 and first gold is expected to be poured in the second-quarter 2000.

Jan 1, 2000

By M Logsdon, T R. Clark, T I. Mudder

Oxidation of pyrite and other metal sulfides is accelerated by the activity of acidophilic iron- and sulfur-oxidising microorganisms. The ideal biocide for controlling biocatalysed acid rock drainage (ARD) would be inexpensive, inhibitory toward sulfide-oxidising bacteria at low concentrations, relatively non-toxic toward non-target organisms, degradable in the environment outside the zone of application, stable and long-lived in the impacted environment, sufficiently mobile to penetrate into piles of waste rock or tailings, and effective regardless of the metal sulfides present. A potent agent for combating ARD that fits these criteria is the thiocyanate anion (SCN-). The objective of this study was to determine the effectiveness of thiocyanate in controlling or preventing ARD within several types of sulfidic waste rock and tailings. Results were evaluated within a context encompassing process water and solids management strategies employed at different precious and base metal mines. Sulfidic rock was treated with solutions of potassium thiocyanate and subjected to accelerated weathering tests in lab-scale humidity cells, trays, and columns. Certain tests also utilised solid phase copper thiocyanate (CuSCN) to evaluate a ærelease on demandÆ strategy. Leach solutions were analysed for parameters indicative of ARD including pH, redox potential, conductivity, acidity, sulfate, iron, and certain heavy metals. Two larger scale field tests were also initiated by personnel at separate mines using, in the first case, ore containing a pyritic component in large columns and, in the second case, waste rock containing base metal sulfides in lined pits. Humidity cell tests showed low concentrations of thiocyanate solution applied to pyritic waste rock could reduce ARD formation by 90 per cent or more compared to untreated controls, with the residual release of ARD components (eg sulfate, Fe, acidity) probably reflective of strictly chemical oxidation of the sulfides by molecular oxygen. Thiocyanate applied at a concentration of 22 mg/kg to waste rock from a base metal mining operation in large laboratory scale columns reduced acidity and sulfate release by 75 per cent to 80 per cent compared to untreated controls. This extent of reduction in ARD may not meet discharge water quality criteria, but has the potential to significantly reduce lime consumption and sludge production in a conventional neutralisation facility. The use of a solid-phase metal thiocyanate compound (CuSCN) at a dosage of 194 mg/kg pyritic ore resulted in the following per cent reductions in leach solution parameters in comparison to controls: sulfate (78 per cent), acidity (93 per cent), dissolved Fe (99.4 per cent), and dissolved arsenic (99.9 per cent). This compound has the further advantage of being relatively stable until needed, dissolving only in the presence of an acidic and oxidising ARD solution. If this line of investigation progresses favorably, it offers the possibility of an ARD prevention technique that may be applicable in some settings. Mine-site pilot scale tests with pyritic ore resulted in reductions in sulfate (56 per cent) and Fe, As (66 - 68 per cent). In sum, thiocyanate at relatively low concentrations dramatically reduced ARD from sulfidic rock in a simulated heap. The pilot test using waste rock containing base metal sulfides has begun only recently. A preliminary process design and cost estimate was made for fullscale application of thiocyanate to waste rock at a hypothetical gold mining operation producing 5000 tpd of ore and 10 000 tpd of sulfide containing waste rock. The combined capital and operating costs for the full-scale thiocyanate application facility were about $US 0.25/tonne of waste rock and $US 0.50/tonne of ore. Although thiocyanate is readily available commercially, it also occurs in process solutions associated with certain types of mining processes. Such solutions after selective treatment might be recycled to sulfidic waste rock or tailings, rather than being treated for thiocyanate degradation.

Jan 1, 2003

This address was delivered at the Annual Conference Presidential Dinner held in Sydney on 11 July 1988.The Australasian Institute of Mining and Metallurgy brings together, voluntarily, people with a professional interest in the disciplines and skills which are employed in the mineral industry, and in relation to that industry.We come together because we have a mutual interest in improving what is done by the mineral industry, in all its aspects. It is this sense of continuing improvement, of doing better, of doing as well as we can, as our knowledge and skills improve, that unites us in creating and fostering a professional association of likeminded people.We know from our professional training and experience that enormous progress has been made, at an ever-increasing rate, in the mineral industry, particularly this century. We know that the mineral industry has played a very major role in providing the means by which so many more people survive to live longer, healthier ,and more interesting lives, than ever before. Indeed, together with the oil and gas industry, which is an integral part of the mineral industry but has achieved its own commercial distinction, it is fair to claim that the mineral industry has played the major role in providing the means for the advancement of the human, quality of life.We do not need to make any great claims on human society in consequence of our statement of these contributions. The facts, for those who are aware of them, speak for themselves. Our more modest interest, as members of our professional association, is to look to the future, while conscious of our heritage as a guide to what more might be done, in that future.We certainly do not claim that this indisputable contribution made to human welfare by the mineral industry gives us some moral position of superiority from which to claim greater support or understanding from the wider community of people.On the other hand we know that as members of the mineral industry we have a responsibility to do what we can to help other people to be aware of, and to understand the significance of, those facts which will only speak for themselves if we take the trouble to make them known. And we have a number of organisations. The Institute itself, The Australian Mining Industry Council, the various State Chambers of Mines, the industrial relations body, The Australian Mines and Metals Association, and others, each of which in its own way endeavours to add strength to the individual efforts which we each should make.We may look at these facts about our mineral industry as simple dry statistics, even with their undoubtedly improving trends, or we can see them, and portray them to others, as expressing something which is much more. We can portray them as expressing the outcomes of our professional determination to strive to do better, whatever it i,s we find ourselves doing in this mineralindustry.We may seek to describe our efforts as being in pursuit of excellence, or by other such high-sounding phrases, but I prefer to describe those efforts as simply our strivings to make everything we do better next time-much as the dedicated golfer tries to do, but with, may I suggest, more evident success achieved in the mineral industry; which is one reason why I don't try to play golf.May I suggest to you that trying to do better, is very simply the true basis of professionalism? We are trained and practised to see the opportunity for improvement-not to be static in a world which we know is changing so rapidly in every aspect around us. We must be dynamic, which means optimistic, about improving the world in which we find ourselves.

Jan 1, 1988

An on-stream iron ore analyser has been developed in collaboration with Hamersley Iron Pty. Limited for determining the iron content of both lump (- 30 + 6 mm particle size) and fines (- 6 mm particle size) on conveyor belts. The analyser, which is called IRONSCAN, is based on pair production, and is now commercially available from Mineral Con- trol Instrumentation Limited (MCI) in Adelaide. It can be mounted under existing conveyor belts with minimal modifications to the conveyor struc- ture, and the presence of steel cables in the belt does not interfere once the analyser has been correctly calibrated. The analyser has been exten- sively tested on both lump and fines on the shiploading conveyor at Damp- ier, and typically the root mean square (r.m.s.) deviation between single IRONSCAN measurements and conventional chemical analyses is better than 0.5% Fe. It is currently being evaluated on - 150 mm ore from the primary crusher at Mount Tom Price, and initial results are encourag- ing. The principal advantage of IRONSCAN is that it provides rapid infor- mation on ore grades. But perhaps its greatest potential is at the primary crusher where conventional sampling and analysis is very expensive to Implement. at the University of Melbourne, and those of us who were his students had learnt of the application of physical chemistry to pyrometallurgical processing, pioneered by Chipman in the USA, Wagner in Germany, and Richardson in the UK. It was possible, by applying this theoretical insight to the equilibria between metal, speiss or Legierung, matte and slag phases, to find a practical and effective way to recover metal values in some residues which had been accumulating for many years at the NA, but which had defied all attempts to treat them to that date. There was also an opportunity to study the batch lead refining methods still in use at all lead refineries apart from Port Pirie, and to devise optimis- ing techniques which greatly improved the operations and effected considerable savings. Next the writer spent some six years alternating between the BHAS, Port Pirie, and Imperial Smelting at Avonmouth in the UK, concerned with lead or lead-zinc smelting, and the develop- ment of several further continuous lead refining processes, before returning to Australia as Section Leader, Process Development in the CSIRO Division of Chemical Engineering, Fisherman's Bend, Victoria. Metallurgical opportunities which arose during this last period included the problem of tin smelting which had developed over about a decade: the world's tin smelters had been accustomed to treating fairly high grade tin concentrates, con- sisting of almost pure cassiterite, with very little impurity-mostly quartz, limestone, iron oxides, and sundry other silicates. Most such concentrates had been produced from alluvial deposits, where nature had already done some of difficult part of the mineral processor's work-at who knows what recovery-so that he could now produce high grade concentrates at high recovery. The smelters were not really set up for the treatment of lower grade concentrates, such as could be made with reasonably high recoveries from rock mining. Thus they imposed such penalties on impurities and lower than desired tin grades, that whenever a mineral processor improved tin recovery at the expense of lower- ing grade, such an improvement entailed a lower financial return to the miner. There was clearly a need for improved understand- ing of tin smelting, (at that time shrouded in secrecy) and develop- ment of techniques better suited to the treatment of lower grade concentrates. As well as the practical development, a start was made with the computer modelling of the smelting process, with the obiect of optimising the process parameters.

Jan 1, 1988

Forty two new apatite and zircon fission track analyses on the Kubor-Marum-Bena Bena area of northern Papua New Guinea severely constrain the timing of tectonic events and hence the tectonic models for New Guinea, particularly arc-continent collision. In addition, the data can be analysed regionally in terms of known and assumed lithospheric fault zones inferred to control mineralisation (eg. Corbett 1994; Kendrick et al 1995; Hill et al 1996) to determine reactivation of these zones. When combined with the new kinematic plate models for the evolution of New Guinea (Hall 1997) there is the potential to predict likely zones of mineralisation. The low-medium grade? Palaeozoic rocks of the Bena Bena terrane yielded a zircon fission track age of 17 Ma, indicating the time of cooling below 200¦C. The age is consistent with `the shift, at about 16-18 Ma, from volcanolithic sediments to mixed provenance sediments rich in quartz and metasedimentary lithic fragments in the southern Finisterre Ranges (Abbott et al. 1994). This shift was recorded in the Sukurum Formation, which ranges in age from Middle Miocene to Pliocene with quartzose and metasedimentary grains in all samples. Although recording rocks at temperatures of 200¦C and hence depths of ---5km, the 17 Ma age suggests the Bena Dena terrane was rapidly cooling at that time due to uplift and erosion, supplying metasediments to the southern flank of the Finisterre Range, currently 100 km to the east. Significantly, the Middle Miocene Akuna Intrusive Complex, dated 14-17 Ma by Page (1976), lies almost entirely within or adjacent to the Bena Bena terrane. Potentially the uplift, erosion and cooling of the terrane at 17 Ma may have been caused by the rising plutons. If so the 800 sq km exposure Akuna Intrusive Complex at the SE end of the Bena Bena terrane may have been the focus of uplift and supplied the metasedimentary detritus to the Finisterre Range. This suggests that the Finisterre Range was not far removed from the Bena Bena terrane, perhaps less than the 200 - 400 km indicated by Abbott et al (1984). The Akuna Intrusive Complex probably resulted from subduction of the Solomon Sea Plate beneath the PNG margin. In order for the subducted slab to reach depths of -100km below the area to facilitate partial melting and plutonism (Hamilton 1994), subduction probably commenced 3-5 Ma Ma before plutonism, ie at or prior to 20 Ma suggesting a significant change in the tectonic regime at -20 Ma, perhaps related to collision of the Solomons - Ontong Java Plateau collision (eg. Hall 1997). The main result to emerge from the 28 apatite fission track analyses is that the whole of the study area underwent rapid cooling due to uplift and denudation in the Late Miocene, mainly between 7-10 Ma. Results from several samples indicate that they were not totally overprinted prior to uplift indicating maximum burial of -3 km in the Middle Miocene, assuming normal temperature gradients. The burial is less if higher gradients are assumed, allowing for Middle Miocene plutonism. The Late Miocene cooling in the Mobile Belt agrees well with the Pliocene to Recent cooling in the Fold Belt to the SW, interpreted to be due to uplift and erosion associated with fold and thrust deformation of the Miocene Limestones (Hill & Gleadow 1989). This timing relationship suggests, that compressional deformation in the Mobile Belt occurred in the Late Miocene, at 105 Ma, and that the deformation migrated towards the undeformed foreland in the southwest in the Pliocene, at 5-2 Ma. The regional Late Miocene uplift and denudation in the Mobile Belt is also consistent with that postulated by Crowhurst et al (1996; 1997) for northwest PNG, although they considered the event to have occurred mainly from 8-5 Ma. If so, then the uplift and denudation may have been migrating from east to west as well as to the south into the Fold Belt. These timing relationships place significant constraints on tectonic models for the area, indicating that the major compressional pulse in PNG commenced in the northeast at -10 Ma and migrated to the southwest and west in the latest Miocene to Pliocene. This suggests that the initial arc-continent collision and associated shortening occurred in the Late Miocene around -10-12 Ma. This immediately followed intrusion and cooling of the Akuna Intrusive Complex at -17-14 Ma and the Bismarck Intrusive Complex at -12.5 Ma (Page 1976), indicating a linkage between the end of plutonism and the start of compressional deformation. The timing is consistent with the observation of Hamilton (1994) that in areas of subduction `the common regime in overriding plates is extensional and leading edges are crumpled only in collisions. This suggests that the Middle Miocene magmatism in northern New Guinea occurred during extension above a subducting slab and was terminated by Late Miocene arc collision and resultant compression commencing at -10-12 Ma. In general, these data indicate that the acme of denudation and cooling in the Mobile Belt was in the Late Miocene, with relatively little denudation there since. In contrast, Hill & Gleadow (1989) found that the peak of denudation in basement outcrops in the Fold Belt was in the Pliocene at -4 Ma. However, in this study some samples from the Mobile Belt yielded Pliocene ages or high

Jan 1, 1997

In the current climate, there is a real need to bridge the gap between theory and the real world mining considerations, and develop viable, cost-effective, high performance thickeners. With a greater need to extract profits from both difficult-to-process ores and lower grade orebodies, coupled with the necessity to produce 'greener', less water intensive technologies, suppliers need to take current thickener designs to the next level and into the 21st century. The complexity of 'getting it right' within a thickenerÆs feedwell, the 'nerve centre' of the thickener, is no small task. Delivering dilution water and mixing this water with incoming feed slurry, addition of flocculant, maximising flocculant-slurry interaction to build aggregate size, minimising unabsorbed flocculant percentage, volume average of solids volume fraction, momentum dissipation ratio, dilution recycle ratio, volume average shear, maximum shear rate at exit, aggregate size on exit, uniform discharge profile and more ù all of these need to occur in the right order and in the right proportions within the feedwell. This paper discusses the genesis and evolution of a new feedwell design, the first major innovation in the thickening industry in over 15 years.

Jan 1, 2008

By J Finlay, P Betts, D Milton, H Williams

The aim of this paper is to present an innovative method to help delineate potential target volumes for haematite-goethite mineralisation as opposed to more magnetic ores. This is achieved through interpretation and modelling (2.5D and 3D inversions) of ground magnetics and gravity surveys over the Koolanooka South prospect in Western Australia. The targets are assumed to be dense and weakly magnetic and hosted within banded iron formation (BIF) horizons. Geophysical interpretation (2D map) was performed using a variety of processed magnetic and gravity images (Betts et al, 2007) to determine the distribution of lithologies, to understand the structural architecture and to map out any anomalous areas of excess density (possibly indicating goethite alteration). The created geological map is used to build geological cross-sections (geometrically consistent) that were modelled (in 2.5 D) against both potential field datasets. The crosssections are consequently used as the framework to build a 3D geological model. The model defines 3D volumes of rocks including several BIF horizons. The distribution of densities and magnetic susceptibilities of the BIFs is inverted within the GOCAD«-VPmg environment to reduce the misfit between the response of the model and the observed gravity and magnetics. By combining the results of both petrophysical property distribution it is possible to map out (using classical GIS type queries in 3D) volumes of higher density and lower magnetic susceptibility.

Jan 1, 2009

Current models for the origin of banded iron-formation (BIF) derived in situ iron ore deposits assume that the typical chert and iron oxide banded BIF is the primary rock from which enriched iron ore deposits arise by the selective leaching of quartz and the residual accumulation of the iron oxides. Weathering extends to the base of all the hematite deposits of the Hamersley Province, which lie within the saprolitic weathering zone, as shown by the preservation of the primary textures, and are overlain by a hydrated goethite zone representing the solum. Since groundwater typically contains dissolved silica, derived from the hydrolysis of silicate minerals, greatly in excess of the saturation solubility of quartz, it is incapable of removing quartz from below the watertable, and quartz is preserved in all saprolites derived from quartz bearing rocks. Quartz may be dissolved in the solum due to the influx of meteoric water having little or no dissolved silica, but soil-forming processes that dissolve quartz likewise alter the oxides by hydration and transposition with consequent destruction of primary textures, and there is no suggestion of soil-forming processes having produced the deposits, which typically extend to considerable depths below the water-table. A characteristic feature of the typical hematite orebodies is the unaltered nature of the iron oxides in the ore compared to those in the adjacent cherty BIF. Although the solubility of ferric iron at >10 ppb is much less than quartz, any process capable of dissolving the huge volume of quartz must also affect the iron oxides, but evidence of this is completely lacking in most ore deposits. Hydrothermal alteration at Koolyanobbing in the Southern Cross Province affects both cherty BIF and ore, and clearly shows equal mobilisation and recrystallisation of hematite within quartz/hematite veins and in the surrounding cherty BIF, which shows no evidence for the selective leaching of quartz. Similarly, any metamorphic process capable of removing all quartz from BIF would leave characteristic evidence in the remaining oxides. However, a hydrothermal process may account for at least portions of certain ore deposits, in which the chert bands have been replaced by carbonates at comparatively low temperatures, to produce a quartz-free magnetite/ carbonate rock that is readily upgraded to high-grade ore by supergene dissolution of the carbonates. This process is interpreted to have formed high grade ore at Mt Gibson, Koolyanobbing æAÆ Deposit and Mt Tom Price North Deposit. In addition to carbonate replaced cherty BIF at Mt Gibson in the Murchison Province, there are extensive sequences of magnetite BIF without chert bands, and this chert-free facies of BIF is interpreted as the precursor to the majority of in situ hematite ore deposits, through oxidation and weathering of magnetite and iron silicate and carbonate minerals. The world-class martite/microplaty-hematite deposits of the Hamersley Province are a special case of BIF-derived iron ore deposits that were initiated during the Proterozoic era. Evidence from overlying Wyloo Group conglomeratic horizons containing clasts of Hamersley Group BIF indicates that microplaty-hematite formed within the clasts before deposition, and that Proterozoic subaerial oxidation and weathering of uplifted Hamersley Group formations produced the microplaty-hematite in both chert-free and cherty BIF.

Jan 1, 2002

By I M. Platten, Y Xie

Narrow vein gold mineralisation generally contains both fine (<100 ¦m) and coarse (>100 ¦m) gold particles. The in situ size and shape, deportment, distribution and abundance of the particles controls deposit sampling characteristics, grade distribution and metallurgical properties. Particles can range from individual disseminated grains, clusters of particles and masses above 1 cm in size. At each end of the coarse-gold to fine-gold spectrum, the samplability of a deposit ranges from relatively simple for fine-grained disseminated gold particles, through to extremely difficult for very coarse particles. Deposits generally show a background grade of mineralisation dominated by disseminated fine gold particles. Drilling will resolve the background grade well, though is likely to considerably understate the grade related to the coarser gold particles. Gold mineralogy has a significant impact on metallurgy, with key factors affecting recovery being particle size, deportment, liberation parameters and silver content of gold minerals. For coarse gold particles the focus should be on liberation and the early removal of the particles from the mill circuit by gravity concentrators and gold traps. Finer particles will require more grinding to liberate prior to flotation or cyanide extraction. The determination of gold particle sizing is thus required to minimise evaluation and geometallurgical uncertainty and lower project risk.

Jan 1, 2008

A novel approach to validate size distributions obtained from bubble sizing techniques is introduced. The experimental rationale consists in verifying whether the output features the anticipated bi-modality when two uni-modal populations (ca. 0.5 and 5 mm) are mixed in a bubble column. The degree of deviation is quantified by comparing the calculated and real proportions on a volumetric basis. A sampling-followed-by-imaging technique was used to proof the concept. The results showed the anticipated bi-modality in which the real and calculated proportions corresponded with a deviation of less than 15 per cent, considered good given the severity of the test. However, the deviation was correlated to the superficial gas velocity (Jg) in the column and was consistently against smaller bubbles. Possible sources of bias are suggested.

Jan 1, 2005