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By Rankin W. J

Increasing concern with the emission of sulphur dioxide from smelters and roasters has caused renewed interest in processes which can use waste sulphur dioxide, such as the sulphation of nickel laterite ores. The process described here proposes to by-pass the production of sulphuric acid and react laterite directly with a sulphur dioxide containing atmosphere. A thermodynamic analysis identified operating windows in which nickel sulphate forms while iron oxide (the major impurity in most laterite ores) remains stable. The initial assumptions included unit activity of all species except nickel oxide. The lowest possible nickel oxide activity (while maintaining selectivity) increased with increasing temperature, indicating that selective sulphation is favoured by low temperatures. The temperature of interest was found to be between 500 and 800¦C. Calculations show that a feed gas containing ten per cent SO2, five per cent 02, balance N2 requires a temperature greater than 650¦C for selective sulphation of nickel. Laboratory experiments showed that the assumption of unit activity of ferric sulphate was unrealistic above about 680¦C due most likely to the formation of solid solutions which decreased the ferric sulphate activity. Results are presented which illustrate the limiting equilibrium sulphur trioxide partial pressures at 700 and 730¦C below which selective sulphation occurs. Cobalt extraction was usually between 80 and 95 per cent under conditions yielding selective sulphation, whilst nickel extraction was about 50 to 75 per cent depending on temperature and choice of upper limit of iron extraction. An operating diagram is presented for a limonite ore and shows that the optimum reaction conditions are 680¦C and an input gas containing 20 per cent SO2. Under these conditions nickel, cobalt and iron extractions are 73, 95 and two per cent respectively.

Jan 1, 1996

By Tapp B. A

The minerals industry in Australia is currently regarded as the country's economic saviour; the bastion of economic security. As Fitzgerald (1974) stated, 'Australia's natural endowments in minerals are the envy of most countries of the world'. As a result the proposed new mineral developments are on a scale that hitherto in the sixties would have been completely unenvisaged. It is reported that Australia is poised on the verge'of a sixteen billion dollar mining-based investment boom: a boom that will see Australia dominate the energy export field, the mineral processing field, and create the 'coal dollar'. This growth scenario has many inherent dangers, and it is the authors' contention that these should be carefully considered before further development proceeds. Two of the major problems related to the mineral industry growth scenario are the predictability of the future metal market, and the energy cost of mining. The latter problem is the one discussed here. The mining-mineral processing industries in Australia currently use about 36% of Australia's primary energy

Jan 1, 1980

By Muller GP, van Deventer JSJ

A mineralogical analysis has shown that in the Hartebeesfontein ore studied, uranium is associated mainly with uraninite, sulphides such as pyrite and to a lesser degree carbonaceous material such as thucolite. Little could be learned from the literature regarding the mechanism of flotation of these uranium-bearing minerals. A wide variety of reagents were used so that conditions enhancing the flotation of either the sulphides, carbonaceous material, oxides like uraninite, or combinations thereof, were created. As could be expected, the xanthate based floats gave-better selective recovery of sulphides than oleic acid. A substantial fraction of the uranium is associated with pyrite, so that addition of oleic acid to a xanthate float did not enhance the recovery or grade of uranium. After a pre-leach with sulphuric acid in which the pH and Eh were controlled so as to destroy the uraninite, higher uranium recoveries were obtained for the combined float (xanthate, DTP and oleic) and the DTP float. This was most evident when iron was added before flotation. Roasting, which destroyed the sulphides and thucolite, caused a significant decrease in uranium recoveries. The uranium liberated in this way was obviously not flotable in the same way as the uranium liberated from uraninite. A small amount of iron (2 kg/t) added before milling resulted in slightly higher grades and recoveries of sulphur for xanthate based floats. Higher iron additions had a detrimental effect on sulphur recoveries. Even in the case of oleic acid the addition of small amounts of iron had a positive effect on the recovery of sulphur and uranium.

Jan 1, 1993

The economic significance of a fundamental understanding of the mineral pyrrhotite is dis- cussed. Particular emphasis is placed on the relationship of other sulphide minerals to the pyrrhotite when it is the major sulphide mineral present in an ore body. Studies of the Kambalda nickel deposit are used to give a better under- standing of (a) the genesis and other character- istics of a particular ore body (b) the textural relationships between pyrrhotite and other sul- phide minerals (c) magnetic properties of natural pyrrhotite, and (e) the oxidation and supergene processes that take place in a sulphide ore body.

Jan 1, 1972

The approach to this subject is a very general one, but an attempt has been made to cover briefly a very wide field in the nationally important job of manufacturing iron for the iron and steel industry.Some historical data concerning the development of the furnace itself from early days have been followed by the modern ideas on raw materials and their beneficiation. Recent furnace design and modern auxiliaries have been given attention with, finally, some developments in practical operation.HISTORICALWhen dealing with such large 'and costly operating units as blast furnaces, there is not the same opportunity for research in design as in most other metallurgical processes. Over past generations the development of furnace design, or "lines" as it is usually termed, as well as most radical operating changes, has been very gradual.However, there have been some periods of rapid progress due to revolutionary changes. One such was the adoption of the steam engine for blowing and charging operations, and also, during this same era, about 1750, coke was first used as fuel in place of charcoal. Another revolutionary change came some 100 years later, when heating the blast became usual practice.Since then there have been great improvements in mechanical equipment and in the preparation of raw .materials. These factors, together with a better understanding of what happens inside the furnace, have led to the development of those large mechanically operated structures which are the most modern in blast furnace design.For many, years America has led the world in pig iron production and in furnace development, so that American design and practice is now recognised almost as standard. This type of furnace replaced the older stacks in England, Russia, Germany, South Africa and India, as well as here in Australia.

Jan 1, 1947

Gold mineralisation at the Enterprise Mine, 230 km south of Darwin, occurs within folded and metamorphosed sediments of the Lower Proterozoic Burrell Creek Formation adjacent to the Cullen Granite. The mineralised zone, which occupies an area of approximately 800 m x 300 m is local- ised by a moderately tight, upright symmetrical anticline which plunges shallowly southwards. The anticline has been disrupted by numerous faults on which the maximum movement is 40 m. Gold is associated with quartz and sul- phide veins which are present as saddle reefs, inter-reef veins and fault controlled reefs. it occurs within the veins or their alteration haloes, either as free gold (2 - 50 per cent of total gold content) or intimately associated with sulphides, principally arsenopyrite and Pyrrhotite.

Jan 1, 1984

By Mankosa MJ, Yoon R-H

A reliable scale-up procedure for column flotation must address three important areas of column design, ie column geometry, sparging system and wash water distribution network. The column geometry is dictated by the maximum froth carrying capacity (which determines column diameter) and the bubble-particle attachment rate and particle retention time (which determines column length). The most important factor in the scale-up of an air sparging system is the ability to produce small bubbles in both laboratory and full-scale columns. Other factors, such as energy consumption and maintenance requirements, should also be considered in the scale-up of bubble generators. It is also important to design a wash water distribution system that can properly control the froth stability and maximise the column throughput. Based on these criteria, a successful scale-up example is given.

Jan 1, 1993

By Carter NB

A statistically-designed experimental program has been used to study compositional and processing variables which influence the development of strength and reducibility of iron ore pellets. The effects of chemical composition and processing variables were investigated by indurating laboratory-made green pellets, of known composition, under approximately isothermal conditions in a pot- grate simulator. Some findings from a six- variable study are summarized in the form of contour diagrams and emphasize the importance of interactions between the variables. Production of strong, highly reducible pellets is possible over a considerable range of combinations of temperature and firing time. Abrasion index (AI) and cold compression strength (CCS) improve as both these variables increase, but reducibility (R) declines, so a compromise is required. When the lime level is too low to form enough slag for bonding, the AI and CCS may be inadequate. Larger additions of lime tend to improve AI and CCS, with only slight effects on R. Finer grinding of the balling feed (i.e. higher Blaine index) tends to improve Al and CCS without

Jan 1, 1980

The population and the per capila consumption of mineral resources have both grown dramatically during the century past. It is argued that growth will continue through the century ahead but that the magnitudes of undiscovered resources are probably adequate to meet demands. The challenge that the mineral explorer of the future will face is finding deposits beneath several kilometres of barren rock.It is further argued that the principal challenge that society will face in the century ahead is the amelioration of environmental stress.

Jan 1, 1993

Discontinuities often have a very detrimental effect on the stability of mine highwall faces. The west wall of the Muja open cut is remarkable for the number and variety of discontinuity sets which occur over a relatively small area. To-date 14 separate structural domains have been identified over an area measuring approximately 560 m by 120 m.The structural domains have been grouped into four structural assemblages on the basis of their angular relationships to each other and to regional folding and faulting. The distribution of these structural assemblages appears to be erratic and no controlling factors have been identified to explain or predict them other than in the most generalised terms.

Jan 1, 1993

By Large RR

Underlying the 15 million tonne, high grade Hellyer volcanogenic massive sulphide deposit of western Tasmania is an extensive, well developed, and well preserved stringer system. Pervasive alteration of the footwall mafic volcanics occurred as the hydrothermal system initiated. Mineralogical zoning exists within the footwall alteration pipe, with a central siliceous core giving way to zones of chlorite, chlorite-carbonate, sericite-chlorite, and finally sericite-quartz on the margins (stringer envelope zone). However, the alteration morphology and zonation is not symmetrical around the central siliceous core; eastward the alteration zones are steeply dipping and terminate abruptly under the massive sulphide, while westward they extend out under the ore body in a blanket fashion. Geologic evidence indicates that the pervasive alteration started with the development of sericite-quartz which was subsequently overprinted by chlorite and finally quartz-sericite as the hydrothermal system became focused towards the centre of the stringer system.

Jan 1, 1990

By D Purdy, K Wilkinson, P Blake, M Fitzell, J McLellan, L Feltrin, O Dixon

The northern Drummond and Bowen basins region represents one of AustraliaÆs most prospective areas for epithermal vein and stockwork style gold deposits, with both low and high sulfidation epithermal mineralisation known in the region. 3D-GIS reconstructions, numerical and probabilistic modelling (UDEC, FLAC 3D and WofE) are used here to develop a better understanding of the controls operating on the mineral systems of the region and are aimed at enhancing predictive capabilities. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

Japanese pig iron production in 1973 registered about 90 million tons. As clearly seen from the productivity (2.04 t/m3/D), and fuel ratio (494 kg/t-pig), the Japanese steel industry has maintained quite high levels of efficiency in blast-furnace (BF) operations. Among the many factors which have contributed toward these high levels of efficiency, the use of high quality coke is very important. The Japanese steel industry imports about 85% of its metallurgical coals from various countries of the world, including Australia. The effective use of these metallurgical coals of various origins in accordance with their re- spective properties is most essential for maintaining coke quality. This paper describes coking properties of various metallurgical coals and blending techniques based on these coking properties, in relation to the specifications of coke quality required for efficient BF operations. This paper also describes briefly new technology for expanding the scope of the use of coking coals.

Jan 1, 1975

By Schmidt CG

Parameters affecting gold elution using the AARL process are reviewed and critically analyzed in an attempt to optimise metallurgical efficiency and minimise costs in both current and future carbon adsorption operations. Such factors as acid washing, column geometry, elution temperatures and pretreatment reagents are discussed together with eluant water quality and eluate flowrates. Hot acid washing of carbon prior to gold elution has many benefits. Besides improving elution efficiency when eluting with regional water, a hot acid treatment preheats the carbon without causing any gold leakage. Laboratory data indicated that hot acid washing reduces the mass loss of carbon during thermal regeneration. The eluate going to either zinc precipitation or electrowinning is also relatively free of troublesome impurities (organic contaminants and ferrocyanides in particular). Because of the chromatographic character of the AARL elution where an ionic strength gradient is used to inhibit the readsorption of gold, column geometry plays a significant role. While practical considerations and capital costs may restrain the length of the elution column, high length/diameter ratios are advocated in order to promote the plug flow of column eluate. From both a metallurgical and costing viewpoint, the two significant factors affect- ing the AARL gold elution are temperature and cyanide addition. High temperature and high reagent additions within prescribed limits will improve metallurgical efficiencies, but a balance between energy and reagent costs is required in order to minimise overall elution costs. As pretreatment reagents constitute a considerable portion of the total elution costs, both the addition and consumption of sodium cyanide must be carefully considered. Lower cyanide additions may be effective in certain instances, but the more practical use of 0,6 bed volume of a 2-3 per cent NaCN reagent containing 2 per cent NaOH is advocated. This is equivalent to an addition of 20-30 kg NaCN and 20 kg NaOH per ton carbon Treated.

Jan 1, 1986

Conventional narrow vein mining, utilising hand held methods, is expensive and requires specialised miners who are becoming a rarity. Hand held mining techniques (shrinkage stoping, leading stoping and cut and fill) have the advantage that they can be selective. The methods allow continued sampling of the face, control of hanging wall conditions and are adaptable to changes in strike and dip. On the other hand, more productive longhole stoping methods can allow excessive dilution due to drill hole deviations and changes in orebody dip and can be subject to unexpected hanging wall or footwall failures. Development of small scale equipment (as narrow as 0.8m wide) used for drilling or bogging very smallaccess drives has been ongoing over the past decade. In this paper, types of equipment are examined and compared, particularly with respect to their produc- tivity, size, and working environment. The introduction of electric hydraulic equipment has provided a better working environment with reduced noise, exhaust fumes and heat. The concept of the "hydraulic cherry picker" may have application in mining steeply dipping orebodies. The system requires orebodies to be reasonably consistent in dip over 15 metre sub-level intervals. The system involves the basic concept and skills of machine and airleg mining, combined with the safety and productivity of a mechanized work platform. The platform or basket is stabilized between the hanging wall and foot- wall by hydraulic rams and is extended by a tilting hydraulic boom mounted to a small prime mover or trailer. Design concepts (including remote controlled charging of explosives, adaptation to the boom for rock cutting and the overall electric hydraulic mining concept) are put forward in the paper as a view as to how narrow vein mines will be mined in the future.

Jan 1, 1987

The recovery of Copper by solvent extraction was arguably the most significant hydrometallurgical development of the 1960's. However, only dilute solutions at relatively high ph. could be treated effectively. ICVAcorga introduced in the 1970's the much stronger salicylaldoxime based reagents, which resulted in a dramatic change in plant configurations. So for example plants which normally use 3 extraction stages and 3 stripping stages could be reduced to 2 + 2 staging or 2 + 1 staging, even for high copper tenors at low ph. Leach liquors up to 40 g A copper are being treated at some locations so that almost any copper bearing liquor can now be purified by solvent extraction. Following a considerable amount of research and development effort ICI/Acorga have made further significant advances in the application of copper solvent extraction. The first of these is in computerised flowsheeting. In conjunction with ICI's Process Technology Department, Acorga have developed the Minchem Computer program, which uses laboratory generated equilibrium data to facilitate optimisation of metallurgical operating parameters. The program can operate in two modes, prediction and assessment so that given suitable extract and strip isotherms plant performance can be predicted for a given set of conditions. Alternatively existing plant performance can be assessed rapidly and accurately, thus providing a valuable quality control tool. Pilot plant work can now be restricted to evaluation of the physical aspects of the SX circuits, and to looking for the unexpected. Secondly using the patented 5-Nonyl Salicylaldoxime in precise admixture with a number of carefully selected strip modifiers, the Acorga M-range has resulted. Reagent selection from these new extractants can now be based on how the reagent can alleviate the remaining problems such as hydrolytic stability, transfer of iron, and organic losses by entrainment which may be related to particular features of the operating plant. Thus the Acorga M-range has enhanced and significantly extended the use of solvent extraction for copper, whilst refinements in the processing of metallurgical data has considerably simplified circuit design and analysis of results.

Jan 1, 1989

Revegetation at Perseverance Mining's Nagambie Gold Project is an excellent example of cost effective revegetation in the Central Victorian Goldfields. Work has centred on waste rock dumps, vegetative screens, amenity planting and revegetation trials on cyanide heap leach pads. A wetland is under construction and in consultation with farmers, waste heaps were planted with perennial pasture species.The area treated to date is 18 hectares comprising: 16 hectares of pasture and two hectares of trees/understory. Direct seeding and tubestock planting has cost $16,464. Cost effective revegetation demands careful planning from the EES stage onwards. The Government agreed rehabilitation plan should be comprehensive, realistic and above all flexible. This document must be kept in mind during the mining operation.

Jan 1, 1992

By Martin T

High methane content of the medium volatile metallurgical coal mined from the Coal Basin mines causes very difficult mining conditions. Rapid desorption into the mine ventilation system limits coal production, requires huge fresh air quantities and creates mine safety problems. In workings deeper than 2000 ft (600m) gassy coal and heavy cover create outbursting conditions. Cross-measure methane drainage has reduced ventilation requirements on advancing faces, but degasifica- tion of virgin coal is needed to improve mining Conditions.

Jan 1, 1982

Studies of Theological effects in grinding hold promise for improving this energy-intensive process. Six surveys of the Hellyer ball mill were conducted. The stream and sizing data from these surveys were balanced by JKMbal to compare the mill

Jan 1, 1994

By Mimura K

The carbon reduction of tantalum pentoxide was investigated in a plasma-arc furnace. The sample was a mixture of tantalum pentoxide and graphite, vacuum pressed into a briquette and was reduced at about 3100¦C. Argon was used as the are gas. The optimum mixing ratio of carbon and tantalum pentoxide, C/Ta205 is 5.10--5.15. The sample, weighing 7 g is fused within 60^ 70 seconds by plasma-arc heating and the reduction of molten tantalum oxide with solid carbon pro- ceeds rapidly to approximately 99.5 % Ta during this period. The reduction that follows in the molten state is slow. Within about 10 minutes, the maximum tantalum content of the massive metal product reaches 99.9 % and the oxygen and carbon remaining in the product are 50 ppm and 400. 500 ppm respectively.

Jan 1, 1980