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A general outline of the significant features in the quality and manufacture of the more common refractories is given. Where possible, linkage between quality development and control and service applicationhas been shown and explained. INTRODUCTIONThe refractory industry is no stranger to change. New processes and revision of old processes in other industries are the harbinger of new and revised products in refractories.Few of the changes are dramatic; generally they are evolutionary rather than revolutionary. New developments are additional to, and inclusive of, established practice.Therefore in this paper it is necessary to repeat much of what is already known in order to show the development taking place.FIRECLAY REFRACTORIESGeneral technology Fireclay refractories are the most common, the most varied and the most versatile of all refractories. Virtually any composition of silica and alumina up to the composition of kaolin is possible. For purposes of comparison they may be classified in the Continental fashion in accordance with chemical composition or in the American way according to "duty". That the two methods are equivalent is shown by an inspection of the alumina-silica diagram of Bbwen and Greig (1924). 'Fireclay refractories are composed of a glassy and a crystalline component derived from the chemical and physical nature of the raw materials used in their manufacture.

Jan 1, 1961

By Hongyang Cao

The iron constituents selectively separated from the modified copper slags by magnetic separation and flotation.were studied. The results of magnetic separation for modified copper smelting slags show that the grinding size, current intensity and dispersant agent had great influence on grade, and recovery ratio of TFe in preparation concentrate; The results of flotation for magnetic concentrate show that the positive flotation of sodium oleate negatively upgrade the grade of magnetic concentrate, but the reverse flotation of lauryl amine and soluble starch are effective. The grade of TFe can reach 54% and the recovery ratio can reach about 90% in magnetic concentrate, when the grinding size is 45.8µm and the current intensity is 2.5A. The optimal effect is obtained by using lauryl amine as collector and soluble starch as depressant to reverse flotate magnetic concentrate, and the grade of TFe is upgraded 2.37%.

Jan 1, 2009

By Arnold M. Lansche

DOMESTIC OUTPUT of white arsenic, As2O3, was derived entirely as a byproduct of smelting arsenic-containing copper ores by The Anaconda Company at Anaconda, Mont., and American Smelting and Refining Company at Tacoma, Wash. Arsenic metal was not produced. Consumption, and Uses.-Most of the white arsenic produced in 1964 was consumed in manufacturing lead and calcium arsenate insecticides. In the 12 year period since 1951 the production of lead arsenate insecticide has varied between 7,800 tons and 4,900 tons, indicating that lead arsenate has maintained its position in competition with organic insecticides.

Jan 1, 1965

By O. R. Eckstrand, M. Asif, P. L. Schwann, A. J. Naldrett, R. J. F. Scoates

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. PGE-bearing sulphide mineralisation is contained in the lower 600 m of the Upper Central Layered Zone of the intrusion. There are four regimes with distinctive crystallisation characteristics. PGE content is low, both in bulk rock and in terms of metal in 100% sulphides, in the sulphide-rich cumulates but increases sharply in the sulphide-poor cumulates at the base of regime 1. Increases in regime 2 have no such clear relationship with incoming cumulus sulphides. PGE contents are low throughout regime 3, but regime 4 has sulphides with high PGE content, decreasing rapidly upwards, at the base of many of its cyclic units. The observations are interpreted as indicating that sulphide saturation occurred in the middle of a cyclic unit in regime 1, after which fractional segregation of sulphide caused a systematic decrease in PGE content. The resulting contrast between 40 000 ppb PGE in sulphides below the mineralised zone and less than 1 000 ppb above is of practical importance in exploration for such zones. In regime 2 the magma chamber was open to fresh influxes and PGE content was not so sensitive to sulphide saturation. In many regime 4 units influxes of new magma caused immediate sulphide saturation and PGE depletion, so that PGE-rich cumulates do not underlie PGE-bearing sulphide zones. Theoretical analysis indicates that regime 1-type behaviour is likely to characterise intrusions below the level at which plagioclase has entered as a cumulus phase and regime 4-type behaviour above

Apr 1, 1994

By Deepak B. Deshpande

This paper enumerates various difficulties encountered in the design and construction of deep caisson foundations for the Second Bassein Creek Bridge constructed over a creek with very difficult site conditions. The designer of the bridge had anticipated the problems associated with the construction of large diameter floating caissons and limited the maximum size of caisson to 12.5m O.D. facilitated by the means of Shock Transmission Units (STUs). This is the first road bridge in India where STUs are installed to distribute seismic horizontal loads among piers installed with fixed and unidirectional bearings. Besides the usual difficulties of tilts, shifts, and sinking in the construction of floating caissons, the paper also describes a novel methodology used to retrieve a circular 12.5m O.D. caisson which had been swept away during a storm and stuck into the creek bed.

Jan 1, 2002

By Alvin J. F

Tin in ores containing 0·025 to 1·5 per cent tin can be determined polarographically by the reduction of the chlorostannite ion at the dropping mercury electrode in 2M hydrochloric acid solution containing 15 per cent ammonium chloride. The tin is separated from interfering elements by distillation as the tetrabromide and collected from the distillate by co-precipitation with aluminium hydroxide. The method can detect 0·01 per cent tin in ore.INTRODUCTIONAn iodimetric method, suitable for routine analysis of titrating tin in concentrations down to 1 per cent, has been available for some years (Low, Weinig, and Schoder, 1939).As concentrations fall below 1 per cent tin, there is increasing difficulty in obtaining a distinct end point due to large amounts of iron and silica normally present after fusion of the ore. Since concentrations of tin down to 0·02 per cent are significant in ore dressing products it was necessary to examine methods to determine such low concentrations, and to adapt these to tin ores containing a wide variety of other minerals.EXPERIMENTALDigestion and separationCassiterite, the principal tin mineral, is refractory but readily attacked by a sodium peroxide flux to yield soluble sodium stannate. In a recognized procedure, a sample of ore is mixed with up to 15 g of sodium peroxide in an iron crucible and swirled over the full heat of a Meker burner for 7 min. The fusion is leached with water and acidified.This solution then contains tin, silica, and other soluble...

Jan 1, 1962

By E. Machaka, A. Cornah

"Mineral resources are typically informed by multiple data sources of varying reliability throughout a mining project life cycle. Abundant data which are imprecise or biased or both (‘secondary data’) are often excluded from mineral resource estimations (the ‘base case’) under an intuitive, but usually untested, assumption that this data may reduce the estimation precision, bias the estimate, or both.This paper demonstrates that the assumption is often wasteful and realized only if the secondary data are naively integrated into the estimation. A number of specialized geostatistical tools are available to extract maximum value from secondary information which are imprecise or biased or both; this paper evaluates cokriging (CK), multicollocated cokriging (MCCK), and ordinary kriging with variance of measurement error (OKVME).Where abundant imprecise but unbiased secondary data are available, integration using OKVME is recommended. This re-appropriates kriging weights from less precise to more precise data locations, improving the estimation precision compared to the base case and to Ordinary Kriging (OK) of a pooled data-set. If abundant secondary data are biased and imprecise, integration through CK is recommended as the biased data are zero-sum weighted. CK consequently provides an unbiased estimate with some improvement in estimation precision compared to the base case."

Jan 1, 2015

By Darcey Baker

Quarry Blasting is usually boring, and that is how we like it. By this, boring means routine, straightforward, meat and potatoes blasting. Quarries typically will not utilize cast blasting, coyote tunnels, or any of the other more spectacular blasting techniques – just plain, old day-in and day-out quarry production and possibly overburden blasting. Differences in material characteristics, mining method, equipment availability, and target markets all play a part in determining the blasting procedures employed at any given location. However, variables exist everywhere and with foresight and planning, effects of tangible variables can be minimized. Variables caused by geology, weather, neighbors, or limitations caused by major plant or mobile equipment are, generally speaking, intangible; and leave the operator with finite options to improve or modify blasting procedures.

Jan 1, 2009

By T. K. Perkins, L. R. Kern, R. E. Wyant

Many factors influence the results of hydraulic fracturing to stimulate well productivity. Most of these factors have been studied and their effects discussed in the literature. However, the movement of sand through the crack during fracturing has received little consideration. Exactly where the sand goes in the fracture, how it gets there, and how this might influence results have not been studied, judging from published reports. To get an answer to some of these questions we have studied sand movement through a simulated crack segment in the laboratory. Although the work is preliminary, we have answered some questions about sand movement in a semiquantitative sense. We are reporting our results at this time in the hope of stimulating interest and further study in this important aspect of fracturing. LABORATORY EXPERIMENTS Fig. 1 is a schematic diagram of equipment used in this study. A segment of a vertical crack 0.25-in. wide was formed between two Plexiglas plates, and movement of sand in fluid through the crack was observed under various conditions. Sand and fluid were injected into the crack at constant rates. The top and bottom of the crack were closed so that the fluid flowed horizontally. Because of gravity most of the sand settled to the bottom before moving very far through the crack. If the fluid velocity exceeded a certain critical value, then all the sand injected was washed on through the crack even though it had settled to the bottom. When the fluid velocity was less than this value when sand injection was started, most of the sand which settled in the crack remained in place until enough of the area open to fluid flow was blocked by the settled sand to increase the fluid velocity to the critical value.. At this point all injected sand moved on through the crack even though it settled to the lower portion of the moving fluid section. All sand previously settled remained in place. When fluid velocity was increased at this paint by increasing fluid injection rate (without also increasing sand injection rate), some of the previously settled sand was washed out until enough area was open to flow that the velocity dropped to the critical value. Conversely, when the fluid velocity was decreased by decreasing the fluid injection rate (without changing the rate of sand injection), additional sand would settle until the critical velocity was again attained. In short, the critical velocity is an equilibrium value which the system will automatically seek, if possible. The equilibrium (or critical) velocity was measured under several conditions. The results of these measurements are shown in Pig. 2 where the equilibrium velocity is shown as a function of the amount of sand injected per minute. The points falling in the shaded band shown in Fig. 2 were obtained with water. The higher viscosities were obtained by adding CMC (carboxymethylcellu-lose). Data indicate that the equilibrium velocity is not very sensitive to sand size or transport fluid viscosity, or to sand injection rate (except at very low rates). Points connected by the solid CUrve in Fig. 2 were obtained with water and 20- to 40-mesh steel shot. The equilibrium velocity is apparently fairly sensitive to difference in density between particle and fluid. Only one run was made with a gelled fluid and that was gelled water at zero sand injection rate as shown in Fig. 2. (Measurements of equilibrium velocity at zero sand injection rate were made by filling the crack

By J. W. Wilson, P. C. Graham

SUMMARY The Witwatersrand quartzites in which South African gold mining operations are moat exclusively conducted, are notoriously difficult and costly to drill. Despite this situation, however, with the high cost of developing new mines and extending existing mines, together with the rising cost of labour and mining problems resulting from the ever-increasing depths of workings, the demand for raise-boring in these formations is increasing rapidly. Not only is the demand for raises and shafts increasing, but also the length and size of these excavations. Raise-boring studies carried out in South African gold mines have indicated that increased penetration rates and possibly reduced costs could be obtained if higher thrusts were available at the reaming head. Until fairly recently there has been no raise-boring machine suitable for underground use that possessed the thrust and torque characteristics necessary to achieve high penetration rates in hard abrasive quartzite formations and the cutters available were not really developed for high loading. In response to these requirements a raise-borer, the Robbins 83R was designed and built in Seattle, U.S.A. for the Anglo American Corporation. This machine is operating in South African gold mines and is currently being used at a depth of 12 000 ft below surface in one of the. Group's mines. The initial raises bored have substantiated that increased penetration is attainable at high thrust and it is now apparent that the machine is sufficiently versatile to drill raises of up to 12 ft in diameter in quartzite formation over a length of 2 000 ft.

Jan 1, 1974

By V. C. Kelessidis

The interaction between rock and drill bit during drilling has been modeled for many years, but a complete understanding of the phenomena occurring has yet to materialize. Successful models will allow the prediction of rate of penetration in a given environment and optimal selection of drill bit and drilling parameters, thus minimizing exploration costs. In most rock-drilling models the value of the unconfined compressive strength of the rock (UCS) is used in the predictive equations, within the concept of specific energy, and the value of UCS is the percentage of the value of the stress applied on the drilling bit in order for the bit to advance. While the exact percentage depends on the model used and it is not known with certainty, good knowledge of UCS is nevertheless required before any decent prediction can be made on rate of penetration. Determination of UCS, normally done via destructive testing, requires not only the availability of sound rock core samples but also expensive testing and significant time for the test, which frequently are not available for routine drillability predictions. Hence, a multitude of methods and techniques has been proposed for estimating UCS from various indirect and/or non-destructive measurements, or combination of measurements with neural networks, such as point load index, block punch index, unit weight, and apparent porosity, water absorption by weight, sonic velocity, and Schmidt hardness. The many proposed approaches are critically reviewed and the results are compared, and what becomes apparent is that after many years, not only in mining but also in oil-well drilling, accurate indirect determination of UCS is still an elusive goal. An equation to predict UCS from sonic velocity data is suggested based on several data sets reported in the literature. Use of the specific energy equation with UCS or sonic data and utilization of drilling data allows an estimation of the efficiency of energy transfer from the bit to the rock and of the friction coefficient. Analysis of data reported in the literature, both from laboratory and field studies, has shown that this approach is sound and enables the determination of energy transfer efficiencies and friction coefficients, which for the cases studied range between 15 and 30% and 0.15 and 0.30 respectively. Thus, the suggested data analysis approach allows drillers to focus on inefficiencies and optimize drilling practices in future campaigns. Keywords Rock drillability, unconfined compressive strength, prediction.

Jan 1, 2011

The usual metallurgical, engineering and administrative activities associated with the handling and smelting of ores, and the subsequent handling and treatment of the products of smelting, present also problems of hygiene that engage the earnest attention of executives in all well-managed concerns.Again, associated with the employment of any considerable number of men, there is always present the problem of accident prevention.INDUSTRIAL HYGIENE.In the earliest records of lead min.ing and smelting there are references to the injurious effects of lead oh the health of the employees, and, with the advancement of medical science, lead poisoning has been the subject of many works by various authorities in many countries.Moreover, in practically every civilised country, there are laws governing the conduct of the lead industry, and in most cases these laws stipulate that employees shall receive compensation for disability caused by lead poisoning.This provision gives the problem an economic aspect. Apart from the legal and the economic aspects, however, there is the humanitarian aspect, which implies that the...

Jan 1, 1937

By Eldon L. Abbott, Rebecca K. Bolan

The Florida Department of Transportation, Florida’s Turnpike Enterprise is studying the feasibility of a 1128 meter (3,700 foot) vehicular tunnel to provide direct access for Port of Miami traffic to/from I-395, I-95, SR-836 (Dolphin Expressway) and Miami International Airport. Both Bored and Immersed Tube tunnels were evaluated and re-evaluated for constructing two, two-lane, 11.9 meter (39-foot) diameter tunnels beneath the Main Shipping Channel lying between Watson Island and the Port of Miami on Dodge Island in Biscayne Bay, Miami, Florida, USA. Bedrock Geology of South Florida is predominately very permeable, vuggy limestone with sand seams and occasional voids. Groundwater inflows in deep cut-and-cover excavations, tunnel buoyancy, grouting, maintenance of Port operations and potential/possible environmental impacts to Biscayne Bay were significant issues.

Jan 1, 2005

By Roger Scarr, Richard A. Walker

Interactive video is the combination of computer and laser disc -technologies that allows for the storing of 54,000 single images or 30 minutes of video with the ability to access any segment or single image within a half a second. This capability combined with the use of a graphics overlay on the video and accessed through a keyboard or touchscreen creates a very powerful and versatile marketing or training tool.

Jan 1, 1990

By W. P. Tassie

"The location of Quintette Coal Limited's pit and geologic nature of the dedicated reserves combine to introduce a number of factors which can adversely affect waste dump stability. These factors include steep terrain, variable material type and particle size, and precipitation. This paper describes the solutions to related waste dump problems. A brief geotechnical review of the waste dumps is given and Quintette's operational strategies during periods of dump stability and instability are discussed. Despite best efforts, failures occasionally occur and discussion is included on Quintette's success at bringing failed dumps safely back into use. IntroductionQuintette Coal Limited (QCL) property is situated on the east slope of the Rocky Mountains near Tumbler Ridge, approximately 120 km southwest of Dawson Creek, British Columbia. This surface mine is located on mountainous terrain and is subject to climatic extremes of wind, precipitation and temperature.QCL has a current annual production of 4.75 million tonnes of metallurgical coal with a stripping ratio of 7: 1. This correctly implies the extraction of over 33 million bank cubic metres (BCM) of waste which is placed on numerous waste dumps at various locations adjacent to the pit.There are three active pits - Mesa, Wolverine, and Shikano (Fig. 1). Shikano is a newly developed pit located near the plant site. It is not subject to the unique dump management problems prevalent at the Mesa and Wolverine pits, therefore the Shikano waste dumps will not be discussed . The dumps for the Mesa and Wolverine pits, however, have been technically and operationally challenging since shortly after mining began in 1983. Their characteristics, associated site specifics and management, therefore, are the subject of this paper.Waste dump locations for the Mesa and Wolverine pits are shown in Figures 2 and 3 as is the relative waste distribution . Each sub-pit is connected to a principal waste dump in reasonable proximity and to an alternate dump should disposal of waste be necessary at that location. The waste dumps are constructed from the top elevations initially to coincide with subpit development. In the initial years (1-7) waste dump heights will be up to 250 m, then, as the mine matures (8-20 years), waste dump maximum heights will continuously decrease to coincide with lower bench elevations"

Jan 1, 1988

By Y X. Xue, J Pan, D Q. Zhu

In order to reveal the correlation between the fundamental sintering characteristics of iron ores and their real sintering behaviours, a comprehensive evaluation index is proposed based on the measurement of four high temperature indexes, ie assimilation temperature, liquid phase bonding strength, liquid fluidity and calcium ferrite formation percentage, and the sintering pot tests of single ore fines and their blends. The results show that both the lowest assimilation temperature and liquid fluidity of ore blends appear to be the linear superposition of those of single iron ores except for the liquid phase bonding strength and calcium ferrite formation percentage. Furthermore, the tumble index of the sinter product obtained from blended iron ores also corresponds to a linear superposition of that of single ores, but not for the solid fuel rate and productivity. The comprehensive strength index YT exhibits a credible linear positive correlation with the four high temperature reactivity indexes, whereas the comprehensive productivity index YP possesses a lower correlation with the four high temperature reactivity indexes. The comprehensive strength index YT developed can predict the tumble index of the sinter product quite well, but the comprehensive productivity index YP cannot be used to evaluate the productivity effectively.CITATION:Zhu, D Q, Xue, Y X, Pan, J and Shi, B J, 2017. Correlation between high temperature sintering characteristics and sintering behaviours of iron ore fines, in Proceedings Iron Ore 2017, pp 123–132 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By J. S. Mason

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Detailed paragenetic studies of the post-tectonic fracture-hosted vein mineralisation have demonstrated a complex paragenesis, reflecting a multi-phase combination of regional metallogenesis and tectonics through time. Previously published work regarding paragenesis and zoning was oversimplified. Two major epochs of mineralisation resulted in the emplacement of the A1 group of assemblages, from which lead, copper and silver were the main metals mined, and the A2 group, whose galena is only moderately argentiferous but which were major sources of lead and zinc. Tectonic and tentative isotopic evidence points to post-orogenic relaxation as the mechanism for development of the A1 assemblages in the early Devonian, whereas the A2 assemblages are believed to reflect Variscan extensional regimes and regional metallogenesis in the early Carboniferous and Permian

Jun 19, 1905

In a previous paper the writer dealt -with the jasper bar formations and their relationship to the structural geology of older pre-Cambrian rocks in the goldfields districts of Western Australia (24). He has pointed out in this ahd other papers that jasper bars, or banded iron formations, banded hematite or ,magnetite quartzites, jaspilites and related banded ferruginous or non-ferruginous cherts, occur in abundan'ce in the Older Greenstone Series of Western Australia (22), (24), (26). They are considered to represent special forms of banded ferruginous sediments, and are usually fpund in the field interbedded with more or less metamorphosed pasaltic 01' andesitic lavas and tuffs, now amphibolites, together with occasional thin bands of normal pelitic sediments, which go to make up a large proportion of the Older Greenstones in thfs State (26).Great thicknesses of fiat-bedded ]:landed ferruginous cherts are also found associated with cherty' carbonate rocks; quartzites, shales and thin-bedded dolomite whicIi constit'ute the Nullagine (Pl'oterozoic) system in the northwest of Western Australia. In the Hamersley Range district these banded ferruginous chert beds are the hosts of important deposits of blue amphibole asbestos.In the paper mentioned above brief reference was> made to the importance, of geological structure in relation to economic geology, particularly in the goldfields regions of Western Australia, and it was shown that jasper bars may have an important role in the study of 'the structural geology of many of these regions. Of possibly more immediate economic importance is the part that these rocks play, both directly and indirectly, as host rocks for mineral deposits-the chief of Which are gold, iron ores, blue asbestos, and manganese ores. The blue asbestos bearing banded iron formations mentioned above are confined to the younger pre-Cambrian Nullagine formations. They have been described in detail elsewhere (23). In this paper it is proposed to discuss the economic geology of the jasper bars found in the older pre-Cambrian series.The jasper 'bars have in themselves little or no intrinsic value except perhaps some of the more highly coloured and banded varieties which may be utilised for ornamental and decorative purposes. Probably the best known of such varieties is the so-called "marble bar;" a belt of, strikingly coloured banded chert occurring just south and west of the famous town of that name (see Fig. 1t). This consists of a hard, very fine, even-grained rock with alternate individual stripes varying from the thickness of a sheet of paper up to an inch or more in width, and ranging in colour from clear white to yellow, from various shades of pink to brilliant...

Jan 1, 1943

By B. S. Terry, C. L. Harris

Reduction kinetics from slags containing CuO(0.5), ZnO, PbO, NiO and SnO into a Cu-based metal phase were subjected to computer simulation using a previously developed model for the kinetics of metal-slag-gas reactions that assumes mass-transfer control in all phases. The effects were examined of changing bulk Fe oxide activity, gas reducing potential, temperature, Fe content of the Cu phase and metal/slag ratio. The results permit practical conclusions to be drawn about industrial slag-cleaning practice, but the model is still limited in terms of thermodynamic inputs and the idealisation of reaction conditions

Aug 1, 1995

By G. G. Barbante

Anode slimes produced during copper electrorefining are a valuable source of silver, gold, selenium and tellurium. The conventional pyrometallurgical process for treating slimes involves preliminary leaching in sulphuric acid followed by smelting in a reverberatory furnace with fluxes, but it is slow and has many recycle streams. The chemistry of the phases and the reactions that occur in slimes smelting are poorly understood and and this prevents major improvements to the process. Laboratory-scale experiments were conducted using unleached slimes, with and without the addition of fluxes and under neutral, oxidising and reducing conditions. Results show that selenium is readily removed as gaseous selenium dioxide and that molten Cu-Ag-Se-O phases form when fluxes are added. Oxidation-refining of these phases by air injection and flux addition can result in the formation of silver suitable for further electrorefining

Aug 1, 1995