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By Isabel F. Barton, MarkD. Barton, Christian A. Rathkopf

Molybdenite is the world’s principal source of rhenium (Re), a critical element in multiple high-tech applications. However, the Re contents in molybdenite vary by orders of magnitude on scales ranging from single grains to whole deposits. In order to better understand the systematics of this variation and what geochemical factors control molybdenite Re concentration, and hence overall Re resources, we examine global patterns in molybdenite Re contents through a compilation of > 3000 measurements of Re in molybdenite from > 700 mainly ore-bearing moderate- to high-temperature hydrothermal systems of different types. Our results are similar to but expand on those of earlier studies. Rhenium concentration in molybdenite has a lognormal distribution and varies systematically with type of geologic system, intrusive lithology, and Mo grade. The lowest-Re molybdenite occurs in greisens (geometric mean 1 ppm ± a multiplicative standard deviation of 9), quartz vein-hosted W-Sn deposits (2 ± 5 ppm), unmineralized granites and granodiorites (12 ± 8 ppm), intrusion-related deposits (24 ± 8 ppm), and porphyry W-Sn deposits (16 ± 11 ppm). Rhenium is most enriched in molybdenites from volcanic sublimates (23,800 ± 5 ppm), with skarn Fe and Au (560 ± 5 ppm and 540 ± 3 ppm respectively) and porphyry Cu and Cu-Au deposits next (470 ± 4 and 430 ± 7 ppm respectively). Among porphyries, skarns, and quartz vein-hosted deposits, Re is most highly concentrated in molybdenites from Cu and Au systems and its concentration decreases systematically through Cu-Mo, Mo, Sn, and W deposits. In nearly all cases, molybdenites from systems associated with intermediate igneous rocks contain more Re than molybdenites from systems of the same type with more felsic rock associations. The disparity between Re contents of molybdenite in felsic and intermediate systems is largest for porphyries, quartz vein-hosted, and skarn deposits and is near zero for subeconomic or barren granite and granodiorite Mo systems; felsic intrusion-related deposits have slightly higher molybdenite Re than their equivalents associated with intermediate intrusions. In most systems, molybdenite Re content does not correlate with metal grade, but may have an inverse correlation with Au grade in intrusion-related deposits (based on a small number of data points) and does exhibit a strong inverse correlation with deposit Mo grade. Dilution of Re through larger amounts (higher deposit grades) of molybdenite explains about 40% of this correlation, but the relative enrichment of Re in molybdenite from low-Mo deposits must also reflect some selective enrichment of Re/Mo in porphyry Cu systems compared to porphyry Mo systems. We found no evidence for secular increase or other systematic temporal variation in molybdenite Re content. The data regarding the use of molybdenite Re content as a proxy for mantle influence are ambiguous. Nearly all observed empirical correlations can be traced back to differences in redox state and sulfide concentration, the two geochemical factors identified here and by previous experimental work as the controlling influences on Re mobility under hydrothermal conditions. Hydrothermal systems with reducing conditions (W- and Sn-rich) tend to have low molybdenite Re even though compiled whole-rock data indicate that their source rocks have as much or more Re as those of more oxidized systems (e.g., Cu-rich). Vapor-phase exsolution, crustal assimilation, and mixing with external fluids may all enrich molybdenite Re concentrations in individual deposits and deposit types, but their extent and importance in overall hydrothermal concentration of Re is uncertain. Thus, it appears that the available molybdenite Re resource in an ore deposit largely depends on how the deposit’s redox and sulfidation conditions have varied over time and space during the timespan of hydrothermal activity. Oxidized, high-sulfide conditions tend to concentrate Re in molybdenite, whereas reducing conditions tend to leave Re dispersed at low concentrations in the bulk rock.

By F. R. Hensel

P. R. Kalischer.*—I should like to amplify a little one of the points made by Dr. Hensel, and rather violently disagree with him at the same time. He brought out the point that when the higher forming pressures are used on the green compacts there is a marked decrease in the density as sintered. We found that to be true and, of course, many of you notice that that is true with copper compacts also. But, in my opinion at least, it is not true that the expansion is due to entrapped air. We have vacuum-pressed both silver and copper compacts and obtained almost exactly the same numerical expansion as we secured by pressing in air. The powder, however, that is vacuum-annealed does show a slight decrease in expansion on sintering, but almost the entire increase on expansion can be overcome by very slow rates of heating. And it is our opinion that a majority of the expansion is due to dissolved oxygen in the discrete metal particles themselves rather than to entrapped gases. Another interesting observation that we have made is that often with silver or copper compacts it is desirable to silver solder or braze the compact into some part of a piece of equipment after completing powder metallurgical operations on it. If such a compact is sintered and coined, say a silver compact, given an initial forming pressure of 10 to 15 tons per square inch, and sintered, there is an adequate amount of shrinkage and it can be coined at about 50 or 60 tons per square inch and bring up the density nearly to theoretical. If, then, that compact is silver-soldered into some part of a fixture or a machine, it will expand very beautifully, and the only way that this can be overcome. as far as we know, has been to reanneal after the coining operation at a temperature higher than is to be used in any subsequent operation. In that way, a density very nearly theoretical can be achieved, but the coining operation cannot be carried to the excessively high pressures or expansion and bubbling of the compact will occur again.

Jan 1, 1945

By WILLIAM F. McMURRAY, James O. Lewis

The Bureau of Mines is investigating the technology of petroleum and its products, the investigation including well-drilling methods and the transportation, treatment, and utilization of petroleum and of natural gas, with especial reference to the prevention of waste and to increased efficiencyin the development of oil and gas resources in land belonging to or controlled by the Government. During. the winter of 1912-13 the enormous waste of the gas encountered while drilling for oil in the Cushing field, Oklahoma, called forth protests from various sources, and appeal was made to the President of the United States and to the Secretary of the Interior in behalf of the landowner and of the public in general. The facts were wanted regarding the amount of waste and the technical conditions that were responsible for practices causing it. An investigation was ordered and conducted under the direct supervision of the late J. A. Holmes, the first Director of the Bureau of Mines. R. S.Blatchley was sent to investigate the amount of waste going on in the Mid-Continent flelds.s In the latter part of March, 1913, J. A. Pollard and A. G. Heggem were sent to Oklahoma to study well-drilling methods with reference to the waste of gas from wells on Indian lands and to suggest means of preventing the waste of natural gas on such lands. Pollard and Heggem decided that the mud-laden fluid process, which had been used successfully for some years in Texas, Louisiana, and California was the method that would meet the situation most efficiently and economically. The method was accordingly demonstrated in Oklahoma. In 1914 Congress provided for the employment of six oil and gas inspectors to supervise oil and gas mining operations on lands of the Five Civilized Tribes in Oklahoma and to conduct investigations with a view to the prevention of waste. Positions under this appropriation have been held by William F. McMurray, James O. Lewis, Harry D. Aggers, Ralph R. "Weed,George W. McPherson, James C. Fowler, Louis W. Courtney, and Carl H. Beal, the technical work of these men being directed "byW. A. Williams, chief of the petroleum division, Bureau of Mines. After careful and impartial investigation of conditions in Oklahoma, these men also decided that the mud-laden fluid process was the one best adapted to prevent further wastes. In 1915 laws were passed by the State of Oklahoma that provide for the conservation of natural gas and oil, authority being given to the corporation commission to make rules and regulations and to employ agents to enforce them. After hearings and investigations, the corporation commission reached substantially the same conclusions as the Federal agents regarding the importance of the wastes and the best methods of conserving the gas. Technical Papers 66a and 68b were published by the Bureau of Mines in December, 1913, and January, 1914, respectively. Technical Paper 66 deals with the mud-laden fluid process in general and No. 68 with its application in Oklahoma. The interest aroused by these publications has been so widespread that within two years the first editions have been practically exhausted. Rather than reprint these publications, it has been considered advisable to replace them with the present report, which includes the results of more recent investigations. The methods of using the mud-laden fluid are an outgrowth of the rotary drilling system, which was developed in Texas and later employed in Louisiana and California. Some of the principles of the use of mud fluid had been observed and used to a limited extent for a long time in cable-tool drilling. So far as known it was first used successfully with a circulator and cable tools in the Coalinga field, California, in 1906,Harry D. Aggers, one of the contributors to this paper, working on the well. The part of the Bureau of Mines has been to call attention to its merits and to demonstrate its practical use in fields like those of the Mid-Continent.

Jan 1, 1916

By W. E. Tournay

In accordance with a cooperative agreement between the Bureau of Mines, United States Department of the Interior, and the Linde Air Products Co., an investigation was made at the Bureau Explosives Testing Station, Bruceton, Pa., to develop suitable test methods for evaluating the performance and sensitivity characteristics of liquid-oxygen explosives. This report presents the results of the investigation. The unique nature of liquid-oxygen explosives necessitated both modification of standard techniques and development of entirely new test methods. The latter requirement was due to the fact that differences exist in the kind of information that must be developed for studying relative safety and performance properties of these explosives compared to that of fixed explosives.

Jan 1, 1949

By Paul Downing

Anyone in business today knows how difficult and time consuming it is to keep abreast of new and revised federal regulations. Those in the explosives industry know that such a task can be next to impossible as the regulatory environment faced by those in the hazardous materials community continues to undergo a major overhaul following the events of September 11th, 2001. This paper will attempt to clarify today’s regulatory picture by identifying some of the regulatory “hotspots” and “pitfalls” that affect individuals and companies involved in the sale, transportation, distribution and use of explosives.

Jan 1, 2003

By A. P. Bois, K. Saleh, A. Ghorbal, V. Hajiabdolmajid, G. Ballivy

"The knowledge of the initial stress field is not always sufficient to ensure the stability of mining stopes due to the high-stress variations generated by mining. Monitoring of these openings is then necessary and can provide quantitative information (deformations and stress variations) as well as qualitative information (state of stability).An applied technique for following the variations of stress and deformation in static and dynamic conditions, in relation to the evaluation of the stability of underground openings known as “Cylindre Instrumenté de l’Université de Sherbrooke” (CIUS) is discussed in this paper. In addition, a data acquisition system combined with a rock failure warning system has been developed to be connected to the CIUS for detecting the instabilities, which can endanger the stability of underground openings. Also, the installation of six CIUS and a data acquisition system as well as the selected procedure of programming in a warning system are briefly described."

Jan 1, 2003

By Donald Koch

The project investigated regional impacts of mining on the ground water system of the Powder River Basin by: 1) establishment of a regional ground water monitoring network. and 2)development at a set pit digital computer models to simulate ground water flow and quality, ground water contributions to surface water flow and quality (i.e., baseflow), and watershed run-off and recharge. Over 100 wells were monitored for physical and chemical parameters. Data were used as input to the models and for the development of a comprehensive data base. The basin was modeled on a regional and subregional scale using a finite -difference model employing an alternating difference technique. Two water-shed models were evaluated fur their ability to provide runoff and recharge inputs to the basic ground water model. Application of the regional and subregional models using conservative mining scenarios showed that drawdowns may extend west from the mines as far as ten miles but that impacts would be insignificant on a regional scale. The watershed model could be effectively applied to small watersheds only.

Jan 1, 1982

By Youjun Tao

Falcon centrifugal gravity separation tests were conducted to study desulfurization and de-ashing performance with different size fractions of a high-sulfur Chinese -0.5mm fine coal in a dense medium. Performance indicators such as combustible recovery, ash and sulfur rejection, and desulfurization efficiency were used to evaluate the separation efficiency. The results show that for -0.5 mm coal particles, all performance indicators except ash rejection are higher for the Falcon concentrator than for flotation. More specifically, for the +0.125 mm size fraction, Falcon centrifugal separation produced better ash and sulfur rejection performance than froth flotation. However, the Falcon concentrator also showed higher combustible recovery but lower ash and sulfur rejection than froth flotation for the -0.125 mm size fraction.

Aug 1, 2013

By Syd S. Peng

Is the laboratory sized coal specimen much stronger than underground coal pillars? The answer to this question has a profound implication to many coal operators. It will decide how much of the coal reserve can be recovered. Or, in many cases, it will determine whether it can be mined economically. Recent trends in several eastern states to establish regulations regarding coal pillar design to prevent surface subsidence long after mining heighten the debates. And, in some cases, these trends highlight the existing practices that seriously question the conventional wisdom. Currently, nearly all researchers and practitioners agree that as the size of rock specimens increases, its strength decreases. This concept has been universally adopted as the basic principle for coal pillar design in the United States. Several formulas have been derived to account for this effect. The reduction factor for underground coal pillars ranges from one-half to one-sixth of the strength obtained in the laboratory, depending on the formula selected. Recent case studies indicate that the reduction factor is not justifiable, at east in some cases. The use of a reduction factor is based on the assumption hat smaller rock specimens as tested in he laboratory contain none or fewer fractures or planes of weakness than larger specimens or underground coal pillars. In other words, the larger the rock materials, the more fractures it contains and subsequently weaker in strength. Do all underground coal pillars have more fractures than laboratory sized coal specimens? Not necessarily. All coal contains cleats. Some are con¬spicuous but others are not. In terms of cleat density (number of cleats per unit area), there is no difference between an underground coal pillar and a laboratory sized specimen, provided the specimen size is larger than the cleat spacing, which is mostly 25 to 75 mm (1 to 3 in.).

Jan 1, 1993

By J. R. Kunkel, V. Lishnevsky

At mine sites, the operational and required storage volumes of solution and water storage ponds and reservoirs are usually calculated based upon a water-balance approach. Many climatological variables including precipitation, air temperature, solar radiation, pan evaporation and relative humidity along with operating parameters, are used in the water-balance model. The water-balance model often seeks to find a “critical period” of wet or dry climatological sequences which result in a “maximum” pond storage volume or water demand. The problem with this approach is that the designer usually does not know when the project will come on line in relation to the historical record. To avoid this pitfall, we use a more robust approach. In the more robust method, the water-balance calculations begin in each year of the historic climatological record. This method results in the same number of water-balance runs (or realizations) as the number of years of climatological record. Results of this type of analysis guarantee that the critical period or maximum required pond volume will be found if it is assumed that the historical climatological record repeats itself or if a synthetic time series is used. In addition, this method permits calculation of the likelihood (probability) that a given pond volume will be equaled or exceeded in any given month of the operational life of the facility. In this paper, the results of the sizing of a heap leach pad solution pond are presented along with the probabilities of a given solution pond size being equaled or exceeded based on the robust water-balance approach.

Jan 1, 2002

By S. Dixon

The Phelps Dodge - PD/PERI Heap2D Model is a phenomenological stockpile leaching model that has been used to investigate the best operating practices for leaching chalcocite. The model was used to investigate the interrelationships of raffinate application rate, aeration rate, raffinate iron grade, acid cures, lift height, crush size, bulk density, air injection spacing and raffinate drip emitter spacing.

Jan 1, 2006

By Donald W. Gentry

This paper presents some of the results of a rock mechanics in¬strumentation program designed for, and implemented at, longwall panel 4N at the York Canyon Mine near Raton, New Mexico. The objective of this particular instrumentation program was to determine the response of the rock mass to longwall mining of a thick coal seam utilizing shield-type supports. Measurements were made in the rock along the ground surface, above the coal seam, in the coal seam and immediately below the coal seam. Longwall test panel 411 had a total developed length of 762 m (2500 ft) and a face width of 168 m (550 ft). The seam mining height in the panel area was approximately 3 m (10 ft). The average depth of overburden above the panel is 107 m (350 ft) al¬though it ranges from 73-134 m (240 - 440 ft). Roof support at the face was provided by Hemscheidt shields. These shield-type supports weigh 11.4 metric tons each.

Jan 1, 1977

By M. E. Shank, J. Wulff

At the present time, the designer of dies for metal powder pressing is handicapped by relative ignorance of stress distribution and frictional effects at the interior surface of the die. Unckell was the first to develop a method for the study of wall friction. He used three Brinell balls on which the die rested during pressing. The total frictional wall force was determined by the size of impression these balls left on a soft metal plate. Since the method does not give radial pressures, or distribution of such pressures, coefficients of friction could not be determined. Although Unckel measured density distribution, he was not able to determine radial or shear stresses. Shaler2 has proposed theoretical expressions for the stress and density distribution within cylindrical compacts during pressing, in accordance with the experimental results of Kamm, Steinberg, and Wulff.3 By application of Siebel's method,4 Kamm et a13 plotted stress trajectories for two compacts. From the stress trajectories they calculated coefficients of friction from point to point along the die wall. As pointed out by Shaler in the discussion of Ref. 3, these values are based on progressive point-to-point calculations on finite size grid squares across the compact. In the region of the die wall such calculated values may therefore have considerable cumulative error. The purpose of the present paper is to develop an experimental method by which the nonhydrostatic pressures and shears acting on the interior wall of a cylindrical die can be measured. Such measurements can then he correlated with existing data to aid in the explanation of the pressing process. The method used is based on the elastic: properties of the thick-walled tube used as the die. The principle of super-position of force systems on an elastic body is assumed to hold. Electric strain gauges were mounted in adjacent positions on the exterior die wall in order to get an exact measurement of the variation of tangential strain over the length of the die during pressing. While in this paper, measurements in terms of only tangential strains are considered, it is well to note that similar calculations may be set up for axial strains. The latter are not preferred, since they tend to be smaller than the tangential strains and therefore permit less sensitive measurements. Discussion in this work is restricted to compacts pressed from both ends, since the elastic deformation of the die is then more amenable to analysis. Before choosing the electric strain gauge method, a more direct line of attack was considered and discarded. The discarded idea was the insertion of a pressure gauge through a hole in the die wall.* The gauge would have been in the form of a small piston. If pressure were exerted against such a gauge, it would move outward along a radius of the die. One disadvantage of the scheme is its inability to measure shears along the die wall. Another more serious disadvantage is the disturbance caused by the device itself. It would serve to change the forces it was designed to measure. No matter how small the movement of the gauge, when pressure is applied a discontinuity would exist in the wall surface at that point. Due to the stress concentration caused by the hole, abnormal deflections of the die wall would occur around the gauge. During pressing, powder would be forced into the resulting depression. The depression would then become larger with increasing compacting pressure. Powder, not being a fluid, is capable of supporting shear. The ease with which it would flow into the die wall depression to further move the piston is an indication, not of the radial pressure at that point, but of the state of shear retarding the movement. Thus the "pressure" gauge is really a criterion of flowability, and of the capability of the powder to support shear. For these reasons, it was decided that the electric strain method, herein employed, was more reliable, if more indirect. The gauges and lead wires, mounted on the external die wall do not in any way affect the behavior of the metal powder or the die during pressing. Theory of the Method THE EFFECT OF RADIAL PRESSURE ON THE DIE WALL Effect of a Single Small Band of Hydrostatic Pressure Consider a die which is a thick-walled cylinder of outer radius R. and inner radius Ri. If over a small finite length L there is a normal pressure P, a tangential strain distribution at the outer wall results. This is shown schematically in Fig 1. The exact shape of the curve may he predicted by an extension of the theory of a semi-infinite beam on an elastic foundation.6 This

Jan 1, 1950

By Gennaro Marino

Documented case histories are studied where data were found on the initial collapse of the overburden above the longwall panels. Under this scenario, the most controlled conditions exist for assessing the span capacity of the overburden (i.e., before failure the roof spans to fin coal abutments on two to all four sides). In an attempt to correlate theory to field observations, data are used on the overburden lithology, and the depth, width, and face advance of the panel, as well as, the subsidence conditions noted on the surface. The subsidence measured on the surface is used to determine when complete failure in the over- burden rock has occurred.

Jan 1, 1987

By Robert F. Randolph

Real-world levels of attenuation from hearing protection devices are usually much lower than the rated values obtained under near-ideal circumstances. The shortfall is even more extreme for earplugs than it is for earmuffs, primarily because of the complicated process of fitting the plugs within the ear canal. This study examines the use of a commercially-available lubricant for hearing aids to determine whether it would facilitate improved fit and attenuation for earplugs. In this experiment, ten participants inserted earplugs with and without using the lubricant. Average attenuation was assessed with the Real-Ear-Attenuation-at-Threshold (REAT) technique, and showed over 5 dB improvement when the lubricant was used. Participants obtained an 85% mastery rate using the lubricant versus a 50% mastery rate without. These results indicate several possible applications for improved earplug performance in real-world settings where hazardous noise is unavoidable and effective hearing protection is necessary.

Jan 1, 2008

By Charles L. Kimbell

In overall aggregate, the world's mineral industry in 1987 experienced a more satisfactory year than in 1986, at least insofar as its performance could be assessed from traditional statistical indicators. Production, trade and consumption seemingly advanced in the case of the majority of commodities, and prices for a number of commodities advanced. It was by no means certain, however, whether 1987 investment in mineral industry ventures would top the levels of 1986, when, in the case of petroleum industry investment expenditures there had been a sharp decline, this in contrast to evidences of a slight upturn in steel industry investment. World crude mineral output value was estimated at more than $1,084 billion, and the value added by minerals industry processing of this material probably raised the total value of the industry's production from primary materials to more than $2,600 billion constant 1983 dollars. Less easy too assess was the value of mineral commodities moving in international trade, but with a resurgence in oil prices from the 1986 levels, an increase above the 1986 $500 billion mark seemed assured. There are no comprehensive aggregate statistics on mineral consumption comparable to those on production and trade, but quantitative growth recorded for most major commodities suggested a favorable trend, particularly when coupled with a general (though by no means universal) upturn in unit prices.

Jan 1, 1989

By Rodney D. Lamond

The need for blast vibration monitoring can be attributed to a combination of three factors: Structural damage, Blast design and Human annoyance. Traditionally, vibration damage criteria are prescribed in terms of peak particle velocity (PPV), as measured or predicted in the ground surrounding a blast. The PPV in the vicinity of a blasthole is strongly influenced by the quantity of the explosive per delay. In general, the existing prediction models give reliable results but fall short of addressing the change in PPV when the charge is decoupled and/or distributed.

Jan 1, 1995

By Anil Bhandari

Using subsurface data collected at each drilled shaft location is an ideal approach for conducting drilled shaft design. However, conducting subsurface tests at each drilled shaft location and subsequently performing the drilled shaft design can be a daunting task for a noise barrier wall that is divided into six (6) sections and stretches for approximately four (4) miles. In addition, having individual drilled shaft designs complicates the construction process. Grouping the subsurface conditions into broad categories and performing the design for each of those categories is an attractive alternative to the design per boring approach. Currently there are no existing guidelines to aid a designer on grouping the subsurface conditions for the drilled shaft design for the noise barrier walls. Therefore, a method was developed based on the Standard Penetration Test (SPT) N values of the near surface soils to categorize the soil profiles into distinct categories. Since the soil engineering properties of the near surface soils are known to be critical for drilled shaft lateral capacity, these soils were emphasized in the methodology. This method was successfully implemented for the design of drilled shafts supporting the noise barrier walls along the I-20 in Columbia, SC. For this project, two distinct soil profiles, labeled as ?strong? and ?weak?, were used. An overview of the soil profile grouping methodology is presented as well as the vertical and lateral drilled shaft capacity analyses for this project for the two general soil profiles. The analyses indicated that the axial capacity governed the design in the ?weak? soil profile and the lateral capacity controlled the design in the ?strong? soil profile. However, this is not a generalization and whether the axial or the lateral capacity governs the design of drilled shaft depends on the soil profile and design loads. Nonetheless, our findings emphasize that both lateral and axial capacity should be checked for drilled shaft design even when the vertical load are minor.

Jan 1, 2011

By Rachel Bernau

Water wells, aquifers, and pipelines rarely incur damage from nearby blast vibrations. Extensive ground vibrations may cause a drop in the water table thereby changing an aquifer’s structure or drying up a well. Studies on the reactions of aquifers and water wells have been performed in Montana, North Dakota, and the Appalachia Coal Region. All of these studies reported that vibrations did not change the properties of the monitored aquifers and water wells. Rather, evidence suggests that any incurred damage was caused by block motion and downsloping.

Jan 1, 2001

By J. A. Kost

The objectives of this contract were to determine the amount, size, and deposition of float coal dust (74 x 10 microns) generated during the mining and transporting of coal in underground U.S. mining operations. Rock dust distributed by trickle dusters was also sampled. In addition to four belt-transfer points, two continuous and two conventional mining sections were sampled at five mines located in Pennsylvania, West Virginia, Kentucky, and Illinois. Float-dust samples were collected on deposition pans; total airborne dust was collected with MSA Model C personal samplers equipped with Unico filter casettes; Andersen cascade impactors provided relative size distributions of the samples. Production, airflow, and water flow were monitored to examine their effect on dust levels.

Jan 1, 1981