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By Sadegh Firoozi

Experiments measuring the kinetics of oxidation and making visual observations of the oxidation of approximately 6 g static lead baths containing arsenic, antimony and tin were conducted in the temperature range from 500 to 600 oC. A range of repeatable behaviours were observed, notably: the formation of a coherent, solid oxide layers on pure lead and lead-tin alloys; the formation of liquid oxide droplets during the initial oxidation of lead-arsenic and lead-antimony alloys and the eventual formation of a complete oxide layer covering the entire free surface of these alloys. Thermogravimetric measurements revealed that the rate of oxygen uptake was strongly influenced by the form of oxides being generated at the melt/gas interface. Compared to the rates of oxidation of pure lead, arsenic increased the rate of oxygen uptake throughout the temperature range via the formation of liquid oxidation products. The presence of antimony resulted in a moderate increase in the rate of oxygen uptake as compared to arsenic. Tin was effective in lowering the rate of oxidation even in the presence of arsenic because the oxidation product was always a coherent layer that acted as a physical barrier to oxygen transport to the underlying alloy.

Jan 1, 2006

By B. R. Stewart, L. W. Zelazny

The exclusion of coal fly ash from regulation as a hazardous waste has led to increased interest in returning ash to the coalfields for co-disposal. A multi-year column study used coal refuse with high potential acidity (4% total-S), and two alkaline ashes in various bulk-blends. The unamended refuse acidified rapidly, producing acidic (pH 1.7) leachates, high in dissolved metals. Treatments blended with sufficiently high amounts (20 to 33%) of alkaline ash produced alkaline (pH >8.4) leachates with low metal levels, while lower ash blending rates acidified over time to produce metalliferous leachates. Examination of solid materials indicated that pyrite oxidation was occurring to some extent in all treatments. A regression equation (r2 = 0.95) was developed to estimate time to net acid release for mixtures of these materials. Ash alkalinity and refuse potential acidity must be balanced to insure water quality for co-disposal environments, or the ash materials should be isolated away from acidic drainage waters.

Feb 24, 1997

By J. A. Berger, R. J. Towner

The pjPocesses of polygonization and subgrain growth were followed in slightly stretched 99.99 pct A1 single crystals heated for cumulative times at 400°, 500°, and 600°C. Changes in sub-grain size and boundary angle were determined from measurements on X-ray micrographs. CAHN1, 2 studied polygonization in stretched and heated aluminum single crystals of 99.99 pct A1 using various techniques, including etch pits, Laue patterns, and a slight restretching of heated specimens to reveal small changes in lattice orientation by the direction of new slip lines. He found that kink bands, which had well-defined boundaries lying in a plane perpendicular to the slip direction (at least in the early stages of deformation), formed during stretching. Also, he noted that bending occurred about the <211> axis lying in the (111) slip plane perpendicular to the <110> slip direction. His studies of polygonization were largely confined to the kink bands rather than to the weakly bent matrix regions between bands. The minimum temperature required to bring about polygonization was established at about 450 "C. Guinier and Tenevin used a focusing Laue X-ray diffraction technique to study polygonization in aluminum single-crystal specimens of 99.99 pct purity. Stretching the crystals 5 pct in tension caused a widening of the focused Laue spots. After heating for 4 hr at 450°C, their method revealed no change in the specimen. Above 450°C polygonization was detected and further annealing near 600°C led to subgrain growth. They concluded that the orientation of the crystal relative to the axis of deformation had no marked effect on polygonization. Gay and Honey-combe4 using an X-ray microbeam technique found that polygonization did not occur in a stretched aluminum crystal heated at 250oC, although some decrease in the yield strength occurred. When the temperature was raised to 475oC, the asterism became broken up as a result of polygonization. Honeycombe5 noted that reflections on X-ray mi-

Jan 1, 1961

By Jennifer Riefenberg

Ground control hazards, coal quality, ore reserve estimation, and pollution modeling seem unrelated topics from most mining perspectives. However, geostatistical methods can be used to characterize each of these, and more topics. Exploratory drill core data, and continued drilling and field measurements, can provide a wealth of information related to each of the above areas and are often severely underutilized. Recent studies have led to the development of the Multiple Parameter Mapping (MPM) technology, which utilizes geostatistics and other numerical modeling methods, to generate a "hazard index" map, often from exploratory drill core data. This mapping has been presented for ground control hazards relating roof quality, floor quality, numerically modelled stresses due to mining geometry, and geologic features. A review of the MPM method, future directions with the MPM, and a discussion of using these and other geostatistical methods to quantify coal quality, ore reserve estimation, and pollutant modeling are presented in this paper.

Jan 1, 1996

Gas well tests were performed on 17 wells in the Roma area. The procedure used in the test programme incorporates an initial isochronal test followed by what is described as the &quot;two flow drawdown&quot; technique. The second flow of the two flow drawdown test was conducted for sufficient time to allow transient investigation of the surrounding reservoir. This combination of tests allows the evaluation of stabilized production capacity in addition to the determination ,of several important reservoir characteristics.It also provides a qualitative indication of reserves, by reflecting the presence or absence of reservoir boundaries within the drainage area affected during the test.

Jan 1, 1968

By L Barro

There is currently a worldwide interest in coal-oil technology as the search continues for alternative energy sources to reduce the consumption of petroleum crude. An important aspect of this coal-oil technology study is to obtain information on the flow properties of coal-oil slurries. While some work has been reported on the flow behaviour of black coal-oil suspensions, very little work on brown coal-oil suspensions has been reported. In this paper flow characteristics of brown coal-oil suspensions for various coal concentration and temperatures have been presented. A capillary rheometer, designed to handle settling suspension, has been used for determining rheological properties. Brown coal of 0.0725 mm average particle diameter has been used in this work. The oil was a coal derived product having a boiling point range of 234¦C - 319¦C. Apparent viscosity of all suspensions was found to increase on storage due to ageing. Ageing might have occurred due to physicochemical interactions between coal and oil. Flow behaviour of some suspensions changed from Newtonian to non-Newtonian on storage. Apparent viscosity increased sharply with increase in solids concentration and suspensions at higher concentration behaved as non Newtonian liquids. Viscosity decreased with increase in temperature; rate of decrease slowed down with increase in temperature.

Jan 1, 1980

By J. A. Caceres

Mining planning and mineral processing are almost two unconnected areas. The mining area builds its economical models considering the plant like a constant parameter: a constant throughput, an average recovery and a unitary cost. On the other hand, the mineral processing area assumes a mine plan with grades, ore type, work index, estimating the performances in an independent way. Previous researches have evaluated the advantage for increasing throughput by increasing the liberation size, thus sacrificing recovery. These valuables approaches have left behind the work index factor, critical variable for Recovery-Throughput capacity estimation. This study describes a method combining mineral processing and mining planning. This method incorporates the grinding and flotation performances into the mining economic models optimizing simultaneously the Throughput- Wi(Work index)- Recovery relations with mining sequence, cut-off strategies, and reserve schedules. This method has been used at Andina Mine Chile, showing 18% net present value increasing with minimum investment associated.

May 1, 2003

By A. Bouvard, N. Hoteit, E. Boidy, F. Pellet

In the context of the construction of an Underground Research Laboratory devoted to the feasibility studies of radioactive waste deposits, it appears of the utmost importance to study the long-term behaviour of rock, over a long time period. In this paper, some results of tests performed on the argillite from the Meuse-Haute-Marne site test in Eastern France are presented. Then a numerical simulation of one of this test using the viscoplastic damaging constitutive law proposed by Lemaitre is presented. Finally, this law is used to simulate numerically the behaviour of the rock at the wall of a circular tunnel in order to determine the extension and the change along the time of the Excavated Damaged Zone (EDZ). Advantages and limitations of the model are discussed. Dans le cadre de la réalisation d’un laboratoire de recherche souterrain conçu pour étudier la faisabilité d’installations de stockage de déchets radioactifs, il apparaît fondamental de caractériser non seulement le comportement viscoplastique à très long terme des matériaux mais aussi les phénomènes d’endommagement consécutif à la redistribution de contraintes provoquées par l’excavation des cavités. On présente ici les résultats d’essais réalisés sur les argilites du site de Meuse/Haute-Marne et destinés à caractériser leur comportement visco-endommageable. Il est ensuite procédé à une application de la loi viscoplastique endommageable de Lemaitre pour simuler l&apos;un de ces tests. Les apports et les limites d&apos;un tel modèle sont mis en évidence par des simulations numériques du comportement de la roche au pourtour d&apos;une galerie circulaire permettant de suivre l’évolution au cours du temps de la zone endommagée (EDZ) à la paroi . Im Rahmen des Baus eines unterirdischen Forschungslabors für die Untersuchung der Machbarkeit von Deponien für radioaktive Abfälle erweist es sich als äußerst wichtig, das langfristige Verhalten von Gestein über einen langen Zeitraum zu untersuchen. Im vorliegenden Artikel werden einige Ergebnisse von Untersuchungen vorgestellt, die mit Tonschiefer aus der Meuse-Haute-Marne in Frankreich durchgeführt wurden. Anschließend wird eine numerische Simulation der Untersuchungen unter Verwendung des von Lemaitre vorgeschlagenen viskoplastischen Verformungsgesetzes vorgestellt. Schließlich wird dieses Gesetz auf die numerische Simulation eines Kreistunnels angewandt, um die Ausdehnung und die zeitliche Entwicklung der Auflockerungszone (EDZ) zu bestimmen. Es werden die Vorteile und Grenzen des Modells diskutiert.

Jan 1, 2003

Apparently there is little inclination on the part of mining engineers to supplant the transmission of power by compressed air with it&apos;s formidable rival, electrical transmission. No doubt there are many advantages to be claimed for compressed air that render it parculiary well suited for the conditions which characterise underground work.

Jan 1, 1902

By William D. Spielvogel

The Massachusetts Highway Department awarded the Porter Street Outfall Project to the J.M. Cashman Company in November 1991. Timely completion of the Project in one and one half years is critical to the start of the subsequent Third Harbor Tunnel North Approach project. Existing subsurface conditions and the Project&apos;s location at Boston&apos;s Logan International Airport significantly increases the difficulty of construction. The major contractual work involves relocating a reinforced concrete double box culvert supported on a continuous wood pile foundation. This existing culvert crosses and interferes with the future Third Harbor Tunnel North Approach alignment. Two parallel culverts constructed approximately 20 feet from either side of the future Third Harbor Tunnel alignment replace the existing double box culvert structure. Under the original contract design, approximately 3,100 feet of 14 ft. by 15 ft. reinforced concrete culvert is cast in place adjacent to the west side of the Third Harbor Tunnel and is located in the center of the Airport&apos;s main service roadway, Harborside Drive. This culvert is the Porter Street Combined Sewer, PSCS, which handles a combined flow of sewerage from the East Boston community and storm water runoff from Logan Airport. In addition, approximately 2,230 feet of 17 ft. by 15 ft. reinforced concrete culvert is cast in place adjacent to the east side of the Third Harbor Tunnel and is within 20 feet of an active aircraft taxiway and heliport. This culvert is the Bird Island Flats Storm Drain, BIFSD, which handles storm water runoff from the Logan Airport airfield. The existing outfall, on the west side of the Third Harbor Tunnel alignment is to remain in service and is to be connected to the new PSCS and BIFSD culverts. Therefore, a portion of the BIFSD culvert is designed as a bridge to span 128 ft. across the Third Harbor Tunnel excavation during construction.

Jan 1, 1994

By Floyd D. Varley

Outbursts, the sudden and violent out- pouring of material into mine openings, is a ground control problem increasingly encountered in the United States as deeper seams are developed. Outbursts, caused by several mechanisms, are the result of the loading of ground support systems be- yond their designed capacity to failure, manifested in a violent release of stored energy. There are several types of outbursts typical to deep underground coal mines. - Outbursts of the coal face due to the presence of pressure abutments in close proximity to the face. These outbursts are usually accompanied by liberation of large amounts of methane. - Instantaneous convergence of the ribs and floor due to overloading and failure of ribs which lengthens the beam of floor strata sometimes resulting in a chain reaction failure of the mine floor. - violent failure of the confined core of a pillar due to rapid loading beyond the yield point of the pillar.

Jan 1, 1986

By Dimitri Frantzos, Stewart Thompson, Ed Skiba, Hans Tammemagi

On behalf of Acres International we would like to thank Frank Chiappetta of Blasting Analysis International for inviting our organization to participate in this state-of-the-art course on blasting analysis techniques.

Jan 1, 1989

During the last 125 years, the steel industry has witnessed revolutionary changes in the process of steelmaking. The Bessemer process was the predominant steel production technology during the last two decades of the 19th century. The open hearth process accounted for the lion&apos;s share of world steel production for six decades from 1910 to 1970. With the appearance of the LD process on the industrial stage in 1952, the importance of open hearth process declined and currently the basic oxygen processes are contributing more than 60 per cent of the world steel production. The LD process also led to the development of several other oxygen blown processes such as LDAC, OLP, OBM, QBOP, EOF, Clc.

Jan 1, 1999

By William Reininger

Microtunneling provides a necessary solution for multiple utility crossings associated with the New York Metropolitan Transportation Authority Capital Construction Company?s (MTACC) Eastside Access Project for the Long Island Rail Road. Construction of four TBM tunnels and their approach structures at the eastern end of the project in Sunnyside, Queens required significant modification and expansion of the railroad infrastructure at this location. Maintenance of railroad traffic during project construction is a principal requirement. As a consequence fourteen (14) utility crossing segments are being installed under active traffic by microtunneling methods. Microtunnels were installed in a variety of conditions including depths, types of soils and construction restraints.

THE furnace described in this paper was installed and has been used by the writer for the melting of rich gold-bearing material, and has given complete satisfaction. It may, therefore, prove of interest to other metallurgists who are faced with a similarproblem. A furnace of this type should be most suitable for the reduction of &quot;cyanide preeipitate,&quot; &quot;charcoal ash,&quot; &quot;anode sludge,&quot; &amp;c. formerly the melting was done in fire-clay crucibles, using coke or crude oil as fuel, but this method is costly, slow, and unsatisfactory. A small water-jacketed blastfurnace was also tried on this material after briquetting it, but was discarded in favour of the electric furnace. The furnace may be described as a simple form of the Heroult resistance furnace, with an adjustable upper electrode and a fixed bottom electrode. This is in accordanee with Stansfield&apos;s classification of electric furnaces. The heating is mostly due to the resistance offered the current by the molten slag. The melting chamber consists of a steel drum 14 in. in diameter and 21 in. high, and is lined with silica bricks specially made to fit the shell. The internal diameter is G in. The bricks contain 92 % silica, are made from calcined quartzite bonded with fireclay, and are similar in composition to those used for lining steel converters. They are set in a mixture of finely-ground quartzite and clay, and well dried out. The shell is bolted to a steel plate, which forms the decking of a truck running on rails, so that the furnace can be moved under ahood for carrying off the fumes. A cast-iron slag spout is bolted to the shell below the tapping hole, which is 4 in. from the bottom of the shell. Opposite this another hole 1 in. in diameter is drilled through the shell and lining for the passage of the lower...

Jan 1, 1918

By Muir DM, Ritchie IM, Gibbons SL

Fundamental studies on the transformations of iron oxides have been carried out and related to the solution conditions in the Becher Process. The results show that a number of iron oxide interconversion reactions occur in the aeration reactor with the products depending on the pH, temperature and oxidation potential of the aeration liquor. It is concluded that the lack of process control in the aeration reactor of the Becher Process significantly hinders the ability to predict and produce high quality single phase iron oxides of a consistent colour.

Jan 1, 1989

By M. Shahabi, M. Kashfi

This paper briefly describes the excavation procedure of a powerhouse, comprising of its incremental excavation, reinforcement measures, and the installed monitoring system. During the first phase of excavation, the data obtained from monitoring of the behavior of Mudstone layers were used to recommend extra support measures. These data are also used to design the support of the powerhouse during its extension phase. In diesen bericht wird die bohrmcthode von kraftwerk ecavation in stupenweise dargestelt, und in die richtung d.sicherung, Mit hilfe von monitoring systeme. Die monitoring in (mudstone) schichten ist an schutz in bohrung entworfen und montiert in diese methode in K.W. fase 1 schutzung das K.W. in erweiterung der K.W. das berte auserwelt worden ist Cet article décrit brièvement le procédé d&apos;excavation d&apos;une centrale électrique, comportant de son excavation incrémental, de mesures de renfort, et du système de surveillance installé. Pendant la première phase de l&apos;excavation, les données obtenues à partir de la surveillance du comportement des couches de schiste ont été utilisées pour recommander des mesures supplémentaires de soutien. Ces données sont également utilisées pour la conception de la soutènement de la centrale électrique pendant sa phase d’extension.

Jan 1, 2003

Up to 19 chemical parameters were studied in flotation pulps in six Australian lead-zinc concentrators with the aim of obtaining a better understanding of the nature of, and changes in, the chemical environment. This paperdiscusses pH, redox potential, and oxygen concentrations, which were all measured continuously.Two plants operated at natural pH in slightly acid circuit and one at natural pH in alkaline circuit, and pH was stable at all these plants. In two plants varying amounts of cement fill were present in mill feed and pHwas variable. At the other plant pH was controlled with soda ash and lime.Redox potentials became more positive as the pulp passed through the plant. The minimum change was 20 mV and the maximum about 250 mV. Potentials tended to be variable at any point early in the circuit, but were more stable later on. In some plants reagent additions had no noticeable effect on redox potentials. However in the two plants operating in acid circuit the redox potential of .zinc rougher feed was markedly affected by changes in copper sulphate addition rate. Sodium sulphite additions had an effect at other plants.Oxygen concentrations in grinding circuits tended to be low (30 per cent of saturation) and very variable. Flotation was usually conducted in pulps at least 90 per cent saturated with oxygen. Addition of sodium sulphite had a marked effect on oxygen content in one plant, but less effect in two others.Statistically significant relationships were found in some plants between pH and redox potential, redox potential and oxygen saturation, and oxygen saturation and pH.Improved control of copper sulphate and sodium sulphite additions could result from applications of this work.

Jan 1, 1970

By T. Gammatikopoulos, C. Gibson, M. Aghamirian

Lithium is an alkali metal found in brine deposits in the United States, Chile and Argentina, as well as in hard rock deposits in Australia and North America. In hard rock deposits, spodumene (LiAl(Si2O6)) is the major economic lithium bearing mineral. Spodumene is typically upgraded through a combination of dense media separation, flotation and magnetic separation. One of the major spodumene concentrate quality specifications is the iron oxide content because it will help determine if the concentrate is considered ceramic grade for use in ceramics and glass or chemical grade for use in lithium ion batteries. The rejection of iron bearing silicate minerals from artificial ore composites (high amphibole and low amphibole, high quartz/feldspar) from a hard-rock spodumene deposit was investigated using magnetic separation and flotation. The efficacy of Wet High Intensity Magnetic Separation (WHIMS) in iron rejection was found to be dependent on the mineralogy of the iron-bearing silicate minerals including modal distribution, liberation and association. When magnetic separation was conducted prior to flotation, the Fe2O3 grade in the final flotation spodumene concentrate was reduced from ~3% to ~1% Fe2O3 , and improved lithium recovery in flotation was observed. It was determined that it was most effective to conduct WHIMS on the flotation feed after scrubbing and de-sliming because this reduced the required magnetic field to recover iron-bearing minerals, likely because slime coating was greatly reduced. Flotation collector screening of four different collectors with varying rosin acid content demonstrated a potential increase in selective flotation of spodumene over some iron silicate minerals with decreasing rosin acid content in the fatty acid collector. However, due to marginal difference in flotation results with the various collectors tested, further testing is required to confirm the observations made and establish a hypothesis regarding the effect of rosin acid content.

Jan 1, 2017

By J. A. Delgadillo

Computer simulation and mineral modeling was applied to the optimization of a grinding circuit in a plant processing 256 t/h magnetite. These tools were used to develop a grinding and classification configuration to decrease the grade of silica in the magnetite concentrate, which is produced by the plant. Empirical grinding and classification models were finely tuned using plant experimental data. The JKSimMetTM 5.0 software was used to simulate the grinding and classification units. By applying changes in the original circuit, a throughput increment of 100% was achieved with an important reduction in the energy consumption. The silica content in the magnetite concentrate can be decreased by regrinding the coarse fraction of fine screens into a separate ultrafine grinding unit instead of returning this flow to the ball grinding mills.

Jan 1, 2008